SU625621A3 - Lubricant for hot working of metals - Google Patents

Lubricant for hot working of metals

Info

Publication number
SU625621A3
SU625621A3 SU742074765A SU2074765A SU625621A3 SU 625621 A3 SU625621 A3 SU 625621A3 SU 742074765 A SU742074765 A SU 742074765A SU 2074765 A SU2074765 A SU 2074765A SU 625621 A3 SU625621 A3 SU 625621A3
Authority
SU
USSR - Soviet Union
Prior art keywords
lubricant
mandrel
germany
copolymer
metals
Prior art date
Application number
SU742074765A
Other languages
Russian (ru)
Inventor
Фенебергер Курт (Австрия)
Гели Рольф (Швейцария)
Original Assignee
Лонца Аг, (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Лонца Аг, (Фирма) filed Critical Лонца Аг, (Фирма)
Application granted granted Critical
Publication of SU625621A3 publication Critical patent/SU625621A3/en

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M7/00Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/0413Carbon; Graphite; Carbon black used as base material
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/04Elements
    • C10M2201/041Carbon; Graphite; Carbon black
    • C10M2201/042Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
    • C10M2201/0423Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride used as base material
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/085Phosphorus oxides, acids or salts
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087Boron oxides, acids or salts
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    • C10M2201/10Compounds containing silicon
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    • C10M2201/102Silicates
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    • C10M2201/105Silica
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/022Ethene
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    • C10M2205/026Butene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/06Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14Synthetic waxes, e.g. polythene waxes
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    • C10M2209/00Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
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    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
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    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/06Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an acyloxy radical of saturated carboxylic or carbonic acid
    • C10M2209/062Vinyl esters of saturated carboxylic or carbonic acids, e.g. vinyl acetate
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    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084Acrylate; Methacrylate
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    • C10M2209/02Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
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    • C10M2209/0845Acrylate; Methacrylate used as base material
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    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/086Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
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    • C10M2209/08Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/086Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
    • C10M2209/0863Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid used as base material
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    • C10M2217/00Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/24Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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    • C10N2040/241Manufacturing joint-less pipes
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    • C10N2040/242Hot working
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  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

алкиленовый полимер или сополимер и диспергатор. Состав смазки, вес.%: Алкиленовый полимер или сополимер2-45 Диспергатор0,5-8 Графитдо 100 Смазочный материал получают путем сухого смешени  графита, алкиленовог полимера или алкиленового сополимера и диспергатора. Непосредственно пере применением смесь суспендируют в воде до образовани  суспензии, содержа щей предпочтительно 5-80 вес.% твердых ваществ. Алкиленовые полимеры или алкилено вые сополимеры целесообразно получат полимеризацией в эмульсии. Примен ть например, можно полимеры или сополимеры винилацетата, винилпропионата, виниллаурата, аллиловых сложных эфиров , моно- или диолефинов (этилен, бутадиен), акриловой кислоты и ее сложных эфиров, акриловой кислоты и ее сложных эфиров с сополимерами стирола, стирола с сополимерами ненасыщенных сложных эфиров дикарбоновой кислоты, например со сложным эфи ром малеиновой кислоты. Дл  достижени  оптимального смазы вающего действи  смазь1вающа  пленка должна быть сухой. Водную суспензию, содержащую смазочный материал, целе сообразно наносить на гор чий инстру мент, например, напылением или намазыванием , при этом вода испар етс  а полимер или сополимер образует, плав сь, пленку толщиной 0,05-1,0 мм предпочтительно 0,1-0,2 . в этой пленке частицы графита распредел ютс  равномерно по всей поверхности в виде пластинок. Полимер или сополимер в процессе обработки сгорает без образовани  каких-либо остатков. Горение вызывает образование газовой подушки, поддерживающей разделение трущихс  Поверхностей. Одновременно графит обеспечивает прочный дели тельный и смазывающий слой в услови х высоких нагрузок и температур. Можно полагать, что при сгорании предлагаемых добавок между заготовК9Й и инструментом образуетс  своего рода защитна  атмосфера, задерживающа  сгорание графита при повышенных температурах. Величина частиц графита, примен е мого в данном смазочном материале, предпочтительно составл ет не более 300 ммк при степени чистоты не менее 96%, более предпочтительно до 100 мм при степени чистоты 99,5%. В качестве диспергатора может быт использован полисахарид, алкилцеллюл за, например метилцеллюлоза/ или аль гинат. в суспензию может быть добавлено небольшое количество смачивател , ан имикробных добавок, ингибитора корроии . Предлагаемый смазочный материал примен етс  дл  деформации металла без стружки , например, в штамповочных цехах, в основном дл  ймазывани  оправки при производстве бесшовных труб, например, на так называвых пилигримовых, непрерывных или РМ-станах. Пример 1. Готов т смазку следующего состава, вес.%: Сополимер винилацетата и этилена4 Полисахарид1 Графит- 95 Полученный состав перемешивают с водой получа  5Q%-ную суспензию, и нанос т опрыскиванием на теплый инструмент дл  ковки бесшовных труб. Этот состав пригоден дл  процессов, при которых смазочна  пленка в течен ние длительного времени подвергаетс  высоким температурным превращени м. Состав смазочного материала позвол ет осуществл ть напыление смазывающей пленки на поверхность оправки во врем  ее обратного движени . На гор чей поверхности оправки сразу же образуетс  суха  водоотталкивающа  пленка. Сразу после нанесени  пленки оправку можно охладить в вод ной бане или путем разбрызгивани  воды под давлением, не смыва  смазывающей пленки. Эта пленка не разрушаетс  и при интенсивном охлаждении валков водой, которому оправка подвергаетс  в начале процесса прокатки. П р и м е р 2. Готов т смазку следующего состава, вес.%: Полиизобутилен45 Метилцеллюлоза2 Графит53 Полученный состав пepe.v;eшивaют с водой до получени  25%-ной суспензии. Этот состав также пригоден дл  непрерывного производства труб, в частности , с маленькими промежутками между прохождением отдельных полос. Высокое содержание полимера обеспечивает высокие термопластичные свойства. Примерз. Готов т смазку следующего состава, вес.%: Сополимер стирола и бутадиена 30 Метилцеллюлоза0,5 Графит69,5 Состав примен ют в виде 30%-нойсуспензии . Пример 4. Готов т смазку следующего состава, вес.%: Сополимер винилацетата и этилена 2 Полисахарид8 Графит90 Состав примен ют в виде 20%-ной суспензии 562 Провод т испытани  указанных составов 2 ,- 3 и. 4, сравнива  их с изBecTHfcOM составом, прин тым за прототип и представл ющим собой смесь 10 вес.% фторида натри  и 90 вес.% грйфита. Дл  придани  известному составу в зкотекучего состо ни  его перемешивают в растворе метафосфита натри . В таблице представлены результаты этих испытаний при непрерывном производстве труб на непрерывном стане.alkylene polymer or copolymer and dispersant. Composition of lubricant, wt.%: Alkylene polymer or copolymer 2-45 Disperser 0.5-8-8 Graphitdo 100 A lubricant is obtained by dry mixing graphite, alkylene-new polymer or alkylene copolymer and dispersant. Directly over use, the mixture is suspended in water until a suspension is formed, containing preferably 5-80% by weight of solid substances. Alkylene polymers or alkylen copolymers are expediently prepared by emulsion polymerization. For example, polymers or copolymers of vinyl acetate, vinyl propionate, vinyl laurate, allyl esters, mono- or di-olefins (ethylene, butadiene), acrylic acid and its esters, acrylic acid and its esters with copolymers of nonsaturated compounds can be used. dicarboxylic acid esters, for example, with maleic acid ester. In order to achieve an optimal lubricating effect, the lubricating film must be dry. An aqueous suspension containing a lubricant is purposefully applied to a hot tool, for example, by spraying or spreading, the water evaporating and the polymer or copolymer forms, melting, a film 0.05-1.0 mm thick, preferably 0.1 -0.2. In this film, graphite particles are distributed evenly over the entire surface in the form of plates. The polymer or copolymer burns in the process without any residues. Combustion causes the formation of a gas cushion supporting the separation of the rubbing surfaces. At the same time, graphite provides a durable separating and lubricating layer under conditions of high loads and temperatures. It can be assumed that during the combustion of the proposed additives, a kind of protective atmosphere is formed between the blank and the tool, which delays the combustion of graphite at elevated temperatures. The size of the graphite particles used in this lubricant is preferably not more than 300 mmk with a purity of at least 96%, more preferably up to 100 mm with a purity of 99.5%. A polysaccharide, alkyl cellulose, for example methylcellulose / or alginate, can be used as a dispersant. a small amount of wetting agent, antimicrobial additives, corrosion inhibitor can be added to the suspension. The proposed lubricant is used to deform metal without chips, for example, in stamping workshops, mainly for mandrel mandating in the production of seamless pipes, for example, in so-called piligrim, continuous or PM-mills. Example 1. A lubricant of the following composition is prepared, wt.%: A copolymer of vinyl acetate and ethylene4 Polysaccharide1 Graphite- 95 The resulting composition is mixed with water to obtain a 5Q% suspension, and sprayed onto a warm tool for forging seamless pipes. This composition is suitable for processes in which the lubricating film is subjected to high temperature transformations for a long time. The lubricant composition allows the lubricating film to be sprayed onto the surface of the mandrel during its reverse movement. A dry, water-repellent film is immediately formed on the hot surface of the mandrel. Once the film has been applied, the mandrel can be cooled in a water bath or by spraying water under pressure without flushing the lubricating film. This film is not destroyed even with intensive cooling of the rolls with water to which the mandrel is subjected at the beginning of the rolling process. Example 2: Preparing a lubricant of the following composition, wt.%: Polyisobutylene 45 Methylcellulose 2 Graphite53 The resulting composition is not.v; mixed with water to obtain a 25% suspension. This composition is also suitable for the continuous production of pipes, in particular, with small gaps between the passage of individual lanes. High polymer content provides high thermoplastic properties. Froze A lubricant of the following composition is prepared, wt.%: Styrene-butadiene copolymer 30 Methylcellulose 0.5 Graphite 69.5 The composition is used in the form of a 30% suspension. Example 4. A lubricant of the following composition is prepared, wt.%: A copolymer of vinyl acetate and ethylene 2 Polysaccharide 8 Graphite 90 Composition used in the form of a 20% suspension 562 Conducted tests of the compositions 2, -3 and. 4, comparing them with the BECTHfcOM composition adopted as a prototype and consisting of a mixture of 10% by weight sodium fluoride and 90% by weight of griffite. In order to impart a known composition in a flowing state, it is stirred in a solution of sodium metaphosphite. The table presents the results of these tests in the continuous production of pipes in a continuous mill.

Поглощение энергии по одной станине (валу)Energy absorption on one bed (shaft)

Как видно, применение предлагаемой смазки требует меньшего количества затрат электроэнергии в процессе прокатки , обеспечива  при этом более низкую шероховатость. Прокатные кисти работали намного спокойнее, срок службы оправок, примен емых при изготовлении бесшовных труб, повысилс  на 30%. Поверхность обрабатываемых изделий чиста , без видимых следов смазки после прокатки на предлагаемых составах.As you can see, the application of the proposed lubricant requires less energy in the rolling process, while providing a lower roughness. Roller brushes worked much calmer, the service life of the mandrels used in the manufacture of seamless pipes increased by 30%. The surface of the processed products is clean, without visible traces of lubricant after rolling on the proposed formulations.

При процессе ковки специальных сталей на пилигримовых станах до необходимости замены оправки было изготовлено 150 труб на предлагаемом составе из примера 3 и 80 труб на известном составе. При прокатке сортовой стали было переработано в шпунтовые балки до необходимости замены профильных валков на предлагаег ом составе из примера 4 1800 т, на известном 567 т.During the process of forging special steels on pilger mills, before the need to replace the mandrel, 150 pipes were made on the proposed composition of Example 3 and 80 pipes on a known composition. During the rolling of high-grade steel, it was processed into sheet piles before the need to replace the profile rolls on the proposed composition of Example 4 1800 tons, on the well-known 567 tons.

Claims (4)

Таким образом, предлагаемый состав облада  высокими суспендирующими свойствами в воде, обеспечивает чистое сгорание смазки без образовани  загр зн ющих окружающую среду газообразных масл ных отходов, поверхность оправки при этом чиста ,без 7 ...62 каких-либо остатков. Усилие,необходимое дл  прот гивани  труб через прокатный стан, значительно уменьшаетс , прокатные клети работают более равномерно , износ оправки сильно снижаетс . Труба равномерно обхватывает оправку , что обуславливает повышение качества поверхности. Кроме того, по вл етс  возможность получени  труб с более тонкими стенками с помощью имеющейс  установки. Формула изобретени  Смазка дл  гор чей обработки металлов на основе графита, о т л и чающа с  тем, что, с целью повышени  смазывающих свойств и качаетва обрабатываемой поверхности, смазка 18 дополнительно содержит алкиленовый полимер или сополимер и диспергатор при следующем содержании компонентов, вес.%: Алкиленовый полимер или сополимер2-45 Диспергатор . 0,5-8 Графитдо 100 Источники информации, прин тые во внимание при экспертизе: 1. Вейлер С.Я.,Действие смазок при обработке металлов давлением. М., АН СССР, 1960, с. 190-198. Thus, the proposed composition has high suspending properties in water, ensures clean combustion of lubricant without the formation of gaseous oil waste contaminating the environment, while the surface of the mandrel is clean without any residues. The force required to pull the pipes through the rolling mill is significantly reduced, the rolling stands work more evenly, and the wear of the mandrel is greatly reduced. The pipe evenly embraces the mandrel, which causes an increase in surface quality. In addition, it is possible to produce pipes with thinner walls using an existing installation. The invention is a lubricant for the hot treatment of metals based on graphite, which is so that, in order to increase the lubricating properties and pumping the surface to be treated, the lubricant 18 additionally contains an alkylene polymer or copolymer and a dispersant at the following content of components, wt.% Alkylene polymer or copolymer 2-45 Dispersant. 0.5-8 Grafitdo 100 Sources of information taken into account during the examination: 1. Weiler S.Ya., Effect of lubricants in the processing of metals by pressure. M., USSR Academy of Sciences, 1960, p. 190-198. 2. Патент ФРГ № 2046727, кл. 23 с 1/04, 1973. 2. Patent of Germany No. 2046727, cl. 23 of 1/04, 1973. 3. Патент ФРГ № 2154232, кл. 23 с 1/04, 1973. 3. Patent of Germany No. 2154232, cl. 23 of 1/04, 1973. 4. Патент ФРГ № 2028804, кл. 23 с 1/01, 1973.4. Patent of Germany No. 2028804, cl. 23 from 1/01, 1973.
SU742074765A 1974-05-08 1974-11-13 Lubricant for hot working of metals SU625621A3 (en)

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CH669856A5 (en) * 1984-01-04 1989-04-14 Lonza Ag
CH665847A5 (en) * 1985-10-02 1988-06-15 Lonza Ag METHOD FOR SUSPENDING SOLID LUBRICANTS.
US5271854A (en) * 1986-09-23 1993-12-21 Lonza Ltd. High temperature lubricant containing carboxylated styrene-butadiene latex
CH674096A5 (en) * 1988-01-19 1990-04-30 Lonza Ag
CH674477A5 (en) * 1988-03-30 1990-06-15 Lonza Ag
US5099667A (en) * 1989-06-16 1992-03-31 Lonza Ltd. System for suspending and applying solid lubricants to tools or work pieces
DE59102889D1 (en) * 1990-03-26 1994-10-20 Lonza Ag Method and device for spraying a lubricant suspension at intervals.
DE102005043542A1 (en) * 2005-09-13 2007-03-15 Graphit Kropfmühl AG Stable aqueous graphite dispersion with high solids content
WO2007138914A1 (en) 2006-05-26 2007-12-06 Sumitomo Metal Industries, Ltd. Process for producing seamless stainless-steel pipe

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