SU567179A1 - Impregnant for capacitors - Google Patents

Impregnant for capacitors

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Publication number
SU567179A1
SU567179A1 SU7301897019A SU1897019A SU567179A1 SU 567179 A1 SU567179 A1 SU 567179A1 SU 7301897019 A SU7301897019 A SU 7301897019A SU 1897019 A SU1897019 A SU 1897019A SU 567179 A1 SU567179 A1 SU 567179A1
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SU
USSR - Soviet Union
Prior art keywords
alkyl
halogen
free
biphenyl
diarylsulfone
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Application number
SU7301897019A
Other languages
Russian (ru)
Inventor
Хоуард Манч Ралф
Original Assignee
Монсанто Компани (Фирма)
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Publication of SU567179A1 publication Critical patent/SU567179A1/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
    • H01G4/00—Fixed capacitors; Processes of their manufacture
    • H01G4/002—Details
    • H01G4/018—Dielectrics
    • H01G4/20—Dielectrics using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06
    • H01G4/22—Dielectrics using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06 impregnated
    • H01G4/221—Dielectrics using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06 impregnated characterised by the composition of the impregnant
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02—Well-defined aliphatic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02—Well-defined aliphatic compounds
    • C10M2203/022—Well-defined aliphatic compounds saturated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02—Well-defined aliphatic compounds
    • C10M2203/024—Well-defined aliphatic compounds unsaturated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/04—Well-defined cycloaliphatic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/06—Well-defined aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/042—Epoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/16—Dielectric; Insulating oil or insulators
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/14—Electric or magnetic purposes
    • C10N2040/17—Electric or magnetic purposes for electric contacts

Landscapes

  • Engineering & Computer Science (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
  • Organic Insulating Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Description

(54) МАТЕРИАЛ ДЛЯ ПЮПИТКИ КОНДЕНСАТОРОВ(54) MATERIAL FOR CALCULATING CAPACITORS

1one

Изобретение относитс  к технологии изготовлени  радиоаппаратуры, а именно к материалам дл  пропитки конденсаторов.The invention relates to the technology of radio equipment, in particular to materials for the impregnation of capacitors.

Известен материал дл  пропитки конденсаторов на основе зпоксидных и ароматических органических соединений.A known material for impregnation of capacitors based on zpoxy and aromatic organic compounds.

Однако известный материал  вл етс  недостаточно устойчивым к атмосферному воздействию.However, the known material is not weather resistant enough.

Цель изобрете1ш  - повышение устойчивости материала к атмосферноглу воздействию.The purpose of the invention is to increase the resistance of the material to weathering.

Дл  достижени  цели он в качестве ароматического органического соединени  содержит свободное от галогена ароматическое соединение и дополнительно.содержит диарилсульфон при следующем соотношении исходных компонентов, вес. %: Диарилсульфон10,0 - 80,0To achieve the goal, it contains an aromatic compound free of halogen as an aromatic organic compound and additionally contains diarylsulfone in the following ratio of initial components, wt. %: Diarylsulfon10.0 - 80.0

Эпоксидное соединение0,1 - 3,0Epoxy compound 0.1 - 3.0

Свободное от галогена органическое соединениеОстальное.Halogen-free organic compound Else.

Свободное от галогена ароматическое органическое соединение выбрано из группы, состо щей из алкилбензола, алкилнафталина, а килбифешша, алкариловььх сложных зфиров и их алкилзамещенНых производных, диарилалканов и их алкилзамещенных производных, и диариловых слошп-гкThe halogen-free aromatic organic compound is selected from the group consisting of alkyl benzene, alkyl naphthalene, and kilbifesch, alkaryl esters and their alkyl substituted derivatives, diaryl alkanes and their alkyl substituted derivatives, and diaryl sloshp

эфиров и их алкилзамещешгых производ П)1Х, в которой указаггные алкиловые н алкатах имеют от 1 до 20 атомов углерода, причем упом нутые ариловые радикаль есть бензол, нафталин, бифенил, потшфешш, а упом нутые поллфеншты включают от 3 до 5 фе1шловььх групп.ethers and their alkyl-substituted products P) 1X, in which the indices of alkyls on alkatas have from 1 to 20 carbon atoms, and the aryl radicals mentioned are benzene, naphthalene, biphenyl, potflesh, and the mentioned pollengshty include from 3 to 5 minerals.

В качестве алкилбифенила он содержит изопропилбифенил .As alkylbiphenyl, it contains isopropylbiphenyl.

Диарилсульфон представлен структурной формулойDiarylsulfon represented by the structural formula

(R)f -Ar-S-Ar(R) f -Ar-S-Ar

пP

где Af- фениловый, нафтиловьш, индановый радикал, R - алкиловый радикал с количеством атомов углерода от 1 до 8, п 1-3.where Af is phenyl, naphthyl, indane radical, R is alkyl radical with 1 to 8 carbon atoms, n 1-3.

Причем в качестве диарнлсульфона он содержит толилк аишлсульфон.Moreover, as a diarnsulfon it contains tolyl aishlsulfone.

Представител тии Д11ариловых сульфонов, охватьюаемьк приведенной структурной формулой,  вл ютс  Д1{фенилсульфон, дитолилсульфон, фенилкси илсульфон , толилкснлилсульфон, фенилтолилсульфон , индантолилсульфон, индан-динафтилсульфон , нафтклфенилсульфон, нафтилк ж илсульфон и нафтилтолилсульфон.Representation of D11 aryl sulfones

К представител м свободных от галогена ароматических соеданеюш относ тс  алкилбензол, алкитаафталин, алкилбифенил, алкилполифенил, алкариловые сложные и их алкилзамещенные производные и диарнловые сложные эфиры и их алкилзамещенные прсмзводные, в которых упом нутьв алкиловые группы н алканы имеют от 1 до 20 атомов углерода, причем упом нутые аршювые радикалы есть бензол, нафталин, бифенил или полифенил, а упом нутые полифеншш включают от трех до п ти фениловых Групп.Representative of the halogen-free aromatic compounds are alkyl benzene, alkyl naphthalene, alkyl biphenyl, alkyl polyphenyl, complex alkaryl and their alkyl substituted derivatives and diarnoyl esters and their alkyl substituted ppalic, in which the alkyl groups take place, and their alkyl substitutes, in which the alkyl groups take place, and the alkyl groups under the code, they have the same name, they are the same, they have the same name, they have the same names, they are used by the same The aforementioned arysh radicals are benzene, naphthalene, biphenyl, or polyphenyl, and the aforementioned polyfensha include from three to five phenyl groups.

Специфическими примерами таких ароматических органических соединений, свободных от галогенов ,  вл ютс  Сз.4 алкилбензоциклогексилатилбензол ,) €3.4 алкилнафталин, €3-4 алкйлтетраалинизопрс шлбифенил , /циклогекшлбифенил, С4-4 алкилфенклэфиры, дифенилметилпентан, бе, зилзтилбензол, дифешшзфири феноксибифенил.|Specific examples of such aromatic organic compounds that are free from halogen, cp4, cpl4, cpc, cpc, cpc, ccp, ccp, ccp, ccp, ccpc

В качестве представителей зпоксидйых соедИ нений в материале дл  пропитки конденсаторов могут быть использованы 1 - зпокетэтил - 1,3,4 -эпоксициклогексан , 3,4 - эпоко - 6 - метилциклогексан карбоксил т. Эти эпоксиды содержатс  в материале в количестве от 0,1 до 3 вес.%.1 - zpoketethyl - 1,3,4-epoxycyclohexane, 3,4 - epoko - 6 - methylcyclohexane carboxyl t can be used as representatives of the zpoxidium compounds in the material for impregnation of capacitors. 3,4 - epoko - 6 - methylcyclohexane carboxyl t. These epoxides are contained in the amount from 0.1 to 3 wt.%.

Оптимальное содержание исходных компонентов материала дл  про1штки конденсаторов, вес. %. Толилкошилсульфон10 - ЗОThe optimal content of the initial components of the material for pro-jshtkami capacitors, weight % Tolylkosylsulfon10 - ZO

3,4 - зпокснциклогекшлметил-1 ,3,4- зпоксиплклогексанкарбокотлат0 ,1 - 3,03,4 - zpoksntsiklogekshlmetil-1, 3,4-zpoksiplkoheksanarbokotlat0, 1 - 3.0

ИзопропилбифенилОстальноеIsopropylbiphenylOther

Claims (5)

1. Материал дл  пропитки конденсаторов на основе эпоксидных и ароматических органических соединений, отличающийс  тем, что, с велью1. Material for impregnation of capacitors based on epoxy and aromatic organic compounds, characterized in that, with value повь 1ие1ш  устойчивости .его к атмосферному воздействию , он в качестве ароматического органического соединени  содержит свободное от галогена ароматическое соединение и дополнительно содержит диарилсульфон при следующем соотношении исходных компонентов, вес.%:It is weather resistant; it contains an aromatic compound free of halogen as a aromatic organic compound and additionally contains diarylsulfone in the following ratio of initial components, wt%: Диарилсульфон10,0 - 80,0Diarylsulfon10.0 - 80.0 Эпоксидное соединение0,1 - 3,0Epoxy compound 0.1 - 3.0 Свободное от галогенаHalogen free органическое соединениеОстальное.organic compound Else. 2. Материал по п. 1, отличающийс  тем, что свободное от галогена ароматическое органическое соединение выбрано из группы, состо щей из алкилбензола, алкилн фталина, алкилбифенила,2. The material according to claim 1, characterized in that the halogen-free aromatic organic compound is selected from the group consisting of alkyl benzene, alkyl n phthaline, alkyl biphenyl, алкариловых сложных зфиров и их алкш замещенных производных, диарилалканов и их алкилзамещенных производных, диариловых сложных эфиров и их алкилзамещенных производных, в которой указанные алкиловые грзшпы н алканыalkaryl esters and their alkyls substituted derivatives, diaryl alkanes and their alkyl substituted derivatives, diaryl esters and their alkyl substituted derivatives in which said alkyl groups n alkanes имеют от 1 до 20 атоМов углерода, причем упом нутые арнловые радикалы представл ют собой бензол, нафталин, бифенил, полифенил, а упом нутые полифенилы включают от трех до п та фениловых групп.have from 1 to 20 atoms of carbon, and the said Arnl radicals are benzene, naphthalene, biphenyl, polyphenyl, and the said polyphenyls include from three to five phenyl groups. 3. Материал по пп. 1 и 2, отличающийс  ГСМ, что в качестве алкилбифеннла он содержит Изопропилбифенил.3. Material on PP. 1 and 2, characterized by a fuel and lubricant that contains alkyl biphenl as isopropyl biphenyl. 4.Материал по п. 1, о т л и ч а ю щ и и с   тем, что диарилсульфон имеет структу 5ную формулу:4. The material according to claim 1, that is, with the fact that the diarylsulfone has the structure of the formula: ОABOUT .-S-AP-(R.V, О.-S-AP- (R.V, O гg где АГ - фениловый,нафтиловый, индановый радикал ,. where AG is a phenyl, naphthyl, indane radical,. R - алкиловый радикал с количеством атомов углерода от 1 до 8, п 1-3.R is an alkyl radical with the number of carbon atoms from 1 to 8, n 1-3. 5.Материал по п. 1 и 4, отличающийс  тем, что в качестве диарилсульфона он содержит то лил ксилил сульфон.5. Material according to Claims 1 and 4, characterized in that it contains taryl xylyl sulfone as diarylsulfone.
SU7301897019A 1972-03-06 1973-03-05 Impregnant for capacitors SU567179A1 (en)

Applications Claiming Priority (1)

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US23215272A 1972-03-06 1972-03-06

Publications (1)

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SU567179A1 true SU567179A1 (en) 1977-07-30

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AR (1) AR198405A1 (en)
BE (1) BE796293A (en)
BR (1) BR7301613D0 (en)
CA (1) CA1001838A (en)
CH (1) CH598688A5 (en)
DE (1) DE2310807C2 (en)
ES (1) ES412256A1 (en)
FR (1) FR2188259B1 (en)
GB (1) GB1383133A (en)
IT (1) IT981133B (en)
NL (1) NL7303042A (en)
SE (1) SE381360B (en)
SU (1) SU567179A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4054937A (en) * 1976-04-28 1977-10-18 Westinghouse Electric Corporation Capacitor
US4266264A (en) * 1977-06-24 1981-05-05 Westinghouse Electric Corp. Meta isopropyl biphenyl insulated electrical apparatus
DE2926609A1 (en) * 1979-07-02 1981-01-08 Bayer Ag IMPREGNANT AND ITS USE
US4348713A (en) * 1980-05-07 1982-09-07 General Electric Company Impregnants for metallized paper electrode capacitors
DE3809934A1 (en) * 1988-03-24 1989-10-05 Bayer Ag DIELECTRIC LIQUIDS

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH268032A (en) * 1941-12-04 1950-04-30 Westinghouse Electric Corp Dielectric material.
DE1589549C3 (en) * 1967-10-18 1978-04-27 Robert Bosch Gmbh, 7000 Stuttgart Electric alternating voltage capacitor with a dielectric containing plastic tapes
US3424957A (en) * 1967-10-31 1969-01-28 Gen Electric Electrical capacitor and dielectric material therefor

Also Published As

Publication number Publication date
BE796293A (en) 1973-09-05
GB1383133A (en) 1975-02-05
IT981133B (en) 1974-10-10
DE2310807C2 (en) 1982-04-08
CH598688A5 (en) 1978-05-12
SE381360B (en) 1975-12-01
FR2188259B1 (en) 1977-08-12
CA1001838A (en) 1976-12-21
BR7301613D0 (en) 1974-05-16
DE2310807A1 (en) 1973-09-13
FR2188259A1 (en) 1974-01-18
NL7303042A (en) 1973-09-10
ES412256A1 (en) 1976-01-01
AR198405A1 (en) 1974-06-21

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