SU556730A3 - The method of obtaining supplementary auxiliary substances and tools for dressing - Google Patents

The method of obtaining supplementary auxiliary substances and tools for dressing

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Publication number
SU556730A3
SU556730A3 SU1962800A SU1962800A SU556730A3 SU 556730 A3 SU556730 A3 SU 556730A3 SU 1962800 A SU1962800 A SU 1962800A SU 1962800 A SU1962800 A SU 1962800A SU 556730 A3 SU556730 A3 SU 556730A3
Authority
SU
USSR - Soviet Union
Prior art keywords
dressing
tools
auxiliary substances
obtaining supplementary
supplementary auxiliary
Prior art date
Application number
SU1962800A
Other languages
Russian (ru)
Inventor
Энгельгардт Фриц
Гунцерт Вилли
Георг Ялке Гельмут
Рибка Йоахим
Векклер Гергард
Original Assignee
Касселла Фарбверке Майнкур Аг (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Касселла Фарбверке Майнкур Аг (Фирма) filed Critical Касселла Фарбверке Майнкур Аг (Фирма)
Application granted granted Critical
Publication of SU556730A3 publication Critical patent/SU556730A3/en

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8238—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye
    • D06P3/8252—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye using dispersed and reactive dyes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/31—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated nitriles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3566—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing sulfur
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/5214—Polymers of unsaturated compounds containing no COOH groups or functional derivatives thereof
    • D06P1/5228—Polyalkenyl alcohols, e.g. PVA
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D06P1/5257—(Meth)acrylic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58—Material containing hydroxyl groups
    • D06P3/60—Natural or regenerated cellulose
    • D06P3/66—Natural or regenerated cellulose using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8238—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye
    • D06P3/8247—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using different kinds of dye using dispersed and vat, sulfur or indigo dyes

Description

и реакционна  смесь нринимает прозрачный стекл нный вид, включают мешалку и при добавлении 1 200 мл воды продолжают нагревание аппарата, пока не будет образовыватьс  прозрачный однородный раствор. При продолжении нагревани  аппарата провод т пар через реакционную смесь, пока выход щий вод ной пар не будет свободным от аммиака. Затем добавл ют еще 700 мл воды, так что получаетс  раствор, который удобно можно перемешивать и выливать. После охлаждени  раствора до комнатной температуры довод т его значение рН до 6,6 путем добавлени  по капл м концентрированной серной кислоты. Получают 2 170 г в зкого раствора, который в пересчете на использованный сополимер  вл етс  8,05%-ным. Аналогичным образом можно провести омыление сополимеров акрилонитрила н аллилсульфокислоты, виннлсульфокислоты в винилбензольфокислоты.and the reaction mixture takes on a clear glass appearance, turns on the stirrer and, with addition of 1,200 ml of water, continues heating the apparatus until a clear homogeneous solution is formed. With continued heating of the apparatus, steam is passed through the reaction mixture until the outgoing water vapor is free from ammonia. Then another 700 ml of water is added, so that a solution is obtained which can be conveniently stirred and poured. After cooling the solution to room temperature, its pH is adjusted to 6.6 by the addition of concentrated sulfuric acid dropwise. 2 170 g of a viscous solution are obtained, which, based on the copolymer used, is 8.05%. Similarly, it is possible to carry out saponification of acrylonitrile n allyl sulfonic acid and vinyl sulfonic acid copolymers into vinyl benzene acid.

Пример 2. Па плюсовке с расходованием красильной ванны в 60% подвергают хлопчатобумажную ткань пропитыванию красильной ванной следующего состава, г:Example 2. Pa plusovke with the expenditure of dye bath in 60% is subjected to cotton fabric soaking dye bath of the following composition, g:

Пндантреновый коричневый30Brown antrum30

Омыленный по примеру 1 акрилонитрильный сополимер10Acrylonitrile copolymer 10 as washed as in Example 1

Вода при 20°С960Water at 20 ° С960

10001000

Красильную ванну дл  плюсовки изготовл ют разбавлением полученного согласно примеру 1 продукта 10-20-кратным весом воды ири комнатной температуре и добавлением диспергированного в воде индантренового красител . Объем красильной ванны увеличивают до 1000 г. После обработки материала на плюсовке высушивают его на шпан-раме.The dye plus bath is made by diluting the product obtained according to Example 1 by 10 to 20 times the weight of water and room temperature and adding indanthrene dye dispersed in water. The volume of the dyebath is increased to 1000 g. After the material is processed on the pad, it is dried on the frame.

При шлихтовании сырых хлопчатобумажных нитей метрического номера 34/1 в положении нитей 35/20-34/20When dressing raw cotton yarns of metric number 34/1 in the position of yarns 35 / 20-34 / 20

Достигают пропитки ткани, отличающийс  наивысшей однородностью глубины цвета на верхней и нижней сторонах ткани. Аналогичный опыт с омыленным акрилонитрильным гомополимером показал очень заметные различи  в глубине цвета между верхней и нижней сторонами ткани.Impregnation of the fabric is achieved, characterized by the highest uniformity of color depth on the upper and lower sides of the fabric. A similar experiment with saponified acrylonitrile homopolymer showed very noticeable differences in color depth between the upper and lower sides of the fabric.

Пример 3. Акрилонитрильный сополимер, содержащий 0,2 вес. % аллилсульфокислоты,Example 3. Acrylonitrile copolymer containing 0.2 weight. % allylsulfonate,

подвергают гидролизу согласно описанному в примере 1 методу. При помощи серной кислоты довод т значение рП до 7, разбавлением водой получают раствор, содержащий 25 вес. % твердых веществ. Полученный продукт используют в качестве шлихты согласно следующим данным.subjected to hydrolysis as described in example 1 method. With the help of sulfuric acid, the RP was adjusted to 7, and a solution containing 25 wt. % solids. The resulting product is used as a dressing according to the following data.

Па 9-барабанной шлихтовальной машине фирмы «Суккер (Fa. Sucker, Monchengladbach ), обрабатывают сырые хлопчатобумажные нити шлихтовальной ванной. Нити погружают один раз в шлихтовальную ванну 85- 95°С и два раза пропускают их через пары плющильных валиков с покрыти ми из DEICO.Pa 9-drum sizing machine company "Sukker (Fa. Sucker, Monchengladbach), process raw cotton yarn sizing bath. The threads are immersed once in a sizing bath of 85-95 ° C and twice passed through pairs of flatting rollers with DEICO coatings.

Температура нагреваемых барабанов 130- 135°С. Остальные услови  обработки, как нат жение основы, остаточна  влажность обработанных основных нитей и т. д. соответствуют обычным услови м при шлихтовании хлопчатобумажной пр жи. Дл  различных рецептур шлихтовальной ванны определ ют расходование ванны и полезную мощность ткачества за счет установлени  числа обрывов основных нитей в пересчете на 1000 основных и 100000 уточных нитей.The temperature of the heated drums is 130-135 ° C. The rest of the processing conditions, such as base tension, residual moisture of the treated warp threads, etc., correspond to the usual conditions when sizing cotton yarn. For different formulations of a sizing bath, the consumption of the bath and the useful weaving power are determined by determining the number of breaks in the main threads in terms of 1000 basic and 100000 weft threads.

Получают результаты, приведенные в таблице .Get the results shown in the table.

При шлихтовании сырых хлопчатобумажных нитей метрического номера 60/1 в положении нитей 42/28-50/50When dressing raw cotton yarns of metric number 60/1 in the position of yarns 42 / 28-50 / 50

Claims (1)

1. Способ получени  плюсовочно-вспомогательных веществ и средств дл  шлихтовани  путем гидролиза в щелочной среде акрилонитрильного полимера, отличающийс  тем, что, с целью уменьшени  миграции красител  и повышени  стабильности основных нитей в1. A method for producing additionally excipients and sizing agents by hydrolysis of an acrylonitrile polymer in an alkaline medium, characterized in that, in order to reduce dye migration and increase the stability of the main yarns процессе ткачества, в качестве акрилонитрильного полимера используют сополимер акрилонитрила , содержаший от 0,1 до 70 вес. % сульфогрупп.during the weaving process, an acrylonitrile copolymer containing from 0.1 to 70 weight by weight is used as an acrylonitrile polymer. % sulfo. Источники информации, прин тые во внимание при экспертизе:Sources of information taken into account in the examination: 1. Патент Германии 623404, кл. 12S, 1935 (прототип).1. German patent 623404, cl. 12S, 1935 (prototype).
SU1962800A 1972-10-09 1973-10-08 The method of obtaining supplementary auxiliary substances and tools for dressing SU556730A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2249443A DE2249443C2 (en) 1972-10-09 1972-10-09 Water-soluble copolymers containing sulfonic acid groups and their use as textile auxiliaries

Publications (1)

Publication Number Publication Date
SU556730A3 true SU556730A3 (en) 1977-04-30

Family

ID=5858559

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1962800A SU556730A3 (en) 1972-10-09 1973-10-08 The method of obtaining supplementary auxiliary substances and tools for dressing

Country Status (15)

Country Link
JP (1) JPS5639649B2 (en)
AT (1) ATA854473A (en)
BE (1) BE805846A (en)
BR (1) BR7307719D0 (en)
CA (1) CA1006298A (en)
CH (1) CH600029A5 (en)
DD (1) DD107060A5 (en)
DE (1) DE2249443C2 (en)
ES (1) ES419429A1 (en)
FR (1) FR2202187B1 (en)
GB (1) GB1415557A (en)
IT (1) IT995683B (en)
NL (1) NL7313128A (en)
SU (1) SU556730A3 (en)
ZA (1) ZA737819B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2444823C3 (en) * 1974-09-19 1982-05-19 Basf Ag, 6700 Ludwigshafen Process for dyeing cellulose fibers
CH627490A5 (en) * 1977-04-19 1982-01-15 Ciba Geigy Ag AQUEOUS DYE PREPARATIONS.
JPS6280348A (en) * 1985-10-03 1987-04-13 Meiwa Denki Kk Tension roller mechanism

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL175295B (en) * 1952-01-14 Lonza Ag PROCESS FOR PREPARING CYANACETYLCARBAMATES.
US2812317A (en) * 1953-08-19 1957-11-05 Monsanto Chemicals Hydrolyzed polyacrylonitrile polymers and process of preparing same
US3021301A (en) * 1958-05-19 1962-02-13 American Cyanamid Co Process for producing a novel hydrolyzed polyacrylonitrile reaction product containing polyvinyl alcohol and the product produced thereby
BE579309A (en) * 1958-10-03 1959-10-01 Nopco Chem Co Ion exchange materials.
FR1566803A (en) * 1967-04-01 1969-05-09
CS159358B1 (en) * 1970-03-26 1975-01-31

Also Published As

Publication number Publication date
FR2202187A1 (en) 1974-05-03
CA1006298A (en) 1977-03-01
DE2249443A1 (en) 1974-04-25
BR7307719D0 (en) 1974-09-05
GB1415557A (en) 1975-11-26
AU6109973A (en) 1975-04-10
ZA737819B (en) 1974-08-28
FR2202187B1 (en) 1977-05-27
JPS5639649B2 (en) 1981-09-14
DE2249443C2 (en) 1984-11-15
IT995683B (en) 1975-11-20
JPS4971294A (en) 1974-07-10
DD107060A5 (en) 1974-07-12
ES419429A1 (en) 1976-04-16
BE805846A (en) 1974-04-09
CH600029A5 (en) 1978-06-15
ATA854473A (en) 1978-05-15
NL7313128A (en) 1974-04-11

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