SU512699A3 - Способ получени гептаметиленимина - Google Patents
Способ получени гептаметилениминаInfo
- Publication number
- SU512699A3 SU512699A3 SU1965042A SU1965042A SU512699A3 SU 512699 A3 SU512699 A3 SU 512699A3 SU 1965042 A SU1965042 A SU 1965042A SU 1965042 A SU1965042 A SU 1965042A SU 512699 A3 SU512699 A3 SU 512699A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- catalyst
- temperature
- lactam
- reaction
- hydrogen
- Prior art date
Links
- QXNDZONIWRINJR-UHFFFAOYSA-N azocane Chemical compound C1CCCNCCC1 QXNDZONIWRINJR-UHFFFAOYSA-N 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000003054 catalyst Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 10
- 239000007789 gas Substances 0.000 claims description 7
- JGDFBJMWFLXCLJ-UHFFFAOYSA-N copper chromite Chemical compound [Cu]=O.[Cu]=O.O=[Cr]O[Cr]=O JGDFBJMWFLXCLJ-UHFFFAOYSA-N 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- CJYXCQLOZNIMFP-UHFFFAOYSA-N azocan-2-one Chemical compound O=C1CCCCCCN1 CJYXCQLOZNIMFP-UHFFFAOYSA-N 0.000 claims description 4
- 239000012071 phase Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000007791 liquid phase Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 150000003951 lactams Chemical class 0.000 claims 11
- 238000006243 chemical reaction Methods 0.000 claims 9
- 239000001257 hydrogen Substances 0.000 claims 7
- 229910052739 hydrogen Inorganic materials 0.000 claims 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 4
- 238000005984 hydrogenation reaction Methods 0.000 claims 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims 3
- 238000004821 distillation Methods 0.000 claims 3
- 229910002804 graphite Inorganic materials 0.000 claims 3
- 239000010439 graphite Substances 0.000 claims 3
- 238000010438 heat treatment Methods 0.000 claims 3
- 239000011541 reaction mixture Substances 0.000 claims 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims 2
- 230000035484 reaction time Effects 0.000 claims 2
- GXDVEXJTVGRLNW-UHFFFAOYSA-N [Cr].[Cu] Chemical compound [Cr].[Cu] GXDVEXJTVGRLNW-UHFFFAOYSA-N 0.000 claims 1
- 230000004913 activation Effects 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 claims 1
- 238000006555 catalytic reaction Methods 0.000 claims 1
- 238000001816 cooling Methods 0.000 claims 1
- WLKVBNIHWHTLAI-XNJYKOPJSA-N gazer Chemical compound N=1C=NC=2N(C3C(C(O)C(CO)O3)O)C=NC=2C=1NC\C=C(/C)COC(C(C1OC2C(C(OC3C(C(O)C(O)C(CO)O3)OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)O)OC(CO)C1OC1OCC(O)C(O)C1O WLKVBNIHWHTLAI-XNJYKOPJSA-N 0.000 claims 1
- LHDGISWXLILHQA-UHFFFAOYSA-N gazer Natural products CC(=C/CNc1ncnc2c1ncn2C3OC(CO)C(O)C3O)COC4OC(CO)C(OC5OC(CO)C(O)C5O)C(OC6OC(CO)C(OC7OC(CO)C(O)C(O)C7OC8OC(CO)C(O)C(O)C8O)C6O)C4O LHDGISWXLILHQA-UHFFFAOYSA-N 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 150000002466 imines Chemical class 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- 229910052757 nitrogen Inorganic materials 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 238000011084 recovery Methods 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 239000000047 product Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 229910052573 porcelain Inorganic materials 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- ZFYIQPIHXRFFCZ-QMMMGPOBSA-N (2s)-2-(cyclohexylamino)butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NC1CCCCC1 ZFYIQPIHXRFFCZ-QMMMGPOBSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 201000005505 Measles Diseases 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 241000218657 Picea Species 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N acetic acid Substances CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 description 1
- CYKXSVXXQPXNCO-UHFFFAOYSA-N azete-2-carboxylic acid Chemical compound OC(=O)C1=NC=C1 CYKXSVXXQPXNCO-UHFFFAOYSA-N 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate trihydrate Substances [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 1
- 239000012280 lithium aluminium hydride Substances 0.000 description 1
- -1 lithium aluminum hydride Chemical compound 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D225/00—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom
- C07D225/02—Heterocyclic compounds containing rings of more than seven members having one nitrogen atom as the only ring hetero atom not condensed with other rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HUCI001280 HU170390B (enrdf_load_stackoverflow) | 1972-09-29 | 1972-09-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU512699A3 true SU512699A3 (ru) | 1976-04-30 |
Family
ID=10994459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1965042A SU512699A3 (ru) | 1972-09-29 | 1973-09-28 | Способ получени гептаметиленимина |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS4985079A (enrdf_load_stackoverflow) |
| CA (1) | CA1015359A (enrdf_load_stackoverflow) |
| DE (1) | DE2347905A1 (enrdf_load_stackoverflow) |
| FR (1) | FR2201291B1 (enrdf_load_stackoverflow) |
| GB (1) | GB1403143A (enrdf_load_stackoverflow) |
| HU (1) | HU170390B (enrdf_load_stackoverflow) |
| SU (1) | SU512699A3 (enrdf_load_stackoverflow) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2837290A1 (de) * | 1978-08-26 | 1980-03-13 | Basf Ag | Verfahren zur herstellung von hexamethylenimin |
-
1972
- 1972-09-29 HU HUCI001280 patent/HU170390B/hu unknown
-
1973
- 1973-09-24 DE DE19732347905 patent/DE2347905A1/de active Pending
- 1973-09-27 GB GB4538373A patent/GB1403143A/en not_active Expired
- 1973-09-28 FR FR7334806A patent/FR2201291B1/fr not_active Expired
- 1973-09-28 JP JP48110102A patent/JPS4985079A/ja active Pending
- 1973-09-28 SU SU1965042A patent/SU512699A3/ru active
- 1973-09-28 CA CA182,166A patent/CA1015359A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| HU170390B (enrdf_load_stackoverflow) | 1977-06-28 |
| DE2347905A1 (de) | 1974-04-04 |
| GB1403143A (en) | 1975-08-13 |
| JPS4985079A (enrdf_load_stackoverflow) | 1974-08-15 |
| FR2201291B1 (enrdf_load_stackoverflow) | 1977-08-19 |
| CA1015359A (en) | 1977-08-09 |
| FR2201291A1 (enrdf_load_stackoverflow) | 1974-04-26 |
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