SU504781A1 - Method for preparing cyclohexylaminophosphonates - Google Patents

Method for preparing cyclohexylaminophosphonates

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Publication number
SU504781A1
SU504781A1 SU1446651A SU1446651A SU504781A1 SU 504781 A1 SU504781 A1 SU 504781A1 SU 1446651 A SU1446651 A SU 1446651A SU 1446651 A SU1446651 A SU 1446651A SU 504781 A1 SU504781 A1 SU 504781A1
Authority
SU
USSR - Soviet Union
Prior art keywords
cyclohexyl
amine
iso
chz
dimethylphosphonyl
Prior art date
Application number
SU1446651A
Other languages
Russian (ru)
Inventor
Гюнтер Эберхард
Летге Вильхельм
Original Assignee
Феб Хемикомбинат Биттерфельд (Инопредприятие)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Феб Хемикомбинат Биттерфельд (Инопредприятие) filed Critical Феб Хемикомбинат Биттерфельд (Инопредприятие)
Application granted granted Critical
Publication of SU504781A1 publication Critical patent/SU504781A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4018—Esters of cycloaliphatic acids

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Molecular Biology (AREA)
  • Agronomy & Crop Science (AREA)
  • Biochemistry (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Fertilizers (AREA)
  • Cultivation Of Plants (AREA)

Description

(54) СПОСОБ ПОЛУЧЕНИЯ ЦИКЛОГЕКСИЛАМИНОФОСФОНАТОВ(54) METHOD FOR PRODUCING CYCLOHEXYLAMINOPHOSPHONATES

N-n-xflop4 eHKn-N- (1- (0,0-диметилфосфонил ) - вдклогексил )-аминN-n-xflop4 eHKn-N- (1- (0,0-dimethylphosphonyl) -doclohexyl) -amine

N-n- метнлфенил- N- (1- (О.О-диметилФОСФОНИЛ ) -1ЩКЛОгвксил )-а1УШнNn-methylphenyl-N- (1- (O.O-dimethylPHOSPHONYL) -1CHClOX)

Ы-л -метилфенил-Ы (1- (0,0-диметилфосфони л) - циклогексил )-аминN-l-methylphenyl-Y (1- (0,0-dimethylphosphonyl l) - cyclohexyl) -amin

N-o-метилфенил- (0,0-диметилфосфонил ) -цнклогексил )-аминN-o-methylphenyl- (0,0-dimethylphosphonyl) -cyclohexyl) -amine

N-фeнил-N-((0,0 диметилфосфонил ) N-phenyl-N - ((0.0 dimethylphosphonyl)

циклогексил)-аминcyclohexyl) -amin

N-n-нитрофенил-N- (1- (0,0 димегилфосфонил ) -циклогексил-аминNn-nitrophenyl-N- (1- (0.0 dimethylphosphonyl) -cyclohexyl-amine

N- циклогексил- N- (1- (0,0-диметилфосфонил ) - циклогексил .аминN-cyclohexyl-N- (1- (0,0-dimethylphosphonyl) -cyclohexyl. Amine

N-6eH3M-N-(l-(0,0-диметилфосфонил ) нциклогексил )-аминN-6eH3M-N- (l- (0,0-dimethylphosphonyl) ncyclohexyl) -amin

N-rt- меток сифенил- N- (I- (0,0-диметилфос фонил )-циклогексил-аминN-rt-labels of siphenyl-N- (I- (0,0-dimethylphos fonyl) -cyclohexyl-amine

N-2,4- дихлорфенил-N- (1 - (0,0-диметилфосфогпш )-циклогексил)-амин Н СНзN-2,4-dichlorophenyl-N- (1 - (0,0-dimethylphosphogpsh) -cyclohexyl) -amine H CH3

Н СНэ СНз С1H CHE CH1 C1

С1 128C1 128

ОABOUT

Н СНз СНз 3H CHZ CHZ 3

9595

СН,CH,

116116

Н СНз СНзH CHZ CHZ

СНзSNS

riri

Н СНз СНзH CHZ CHZ

106106

Н СНз СНзH CHZ CHZ

.-О.-ABOUT

Н СНз СНз НОН СНз СНз НО

191191

Н СН, СНзH CH, CHZ

1,49151.4915

Н СНз СНз (( 1.5260H CHZ CHZ ((1.5260

Н СНз СНз }0 -H CHZ CHZ} 0 -

106106

0101

1,55111.5511

СНзSNS

СWITH

Kl-o- метоксифенил N (1- (0,0-диметилфосфонил ) циклогексил )-а1ишнKl-o-methoxyphenyl N (1- (0,0-dimethylphosphonyl) cyclohexyl) -a1

N-4-пиперидил- N (1- (0,0-диметилфосфонил ) - ЦИК логекси л) ЗМИИN-4-piperidyl-N (1- (0,0-dimethylphosphonyl) - CEC Logix L)

Ы-фенил-Ы(1-(0,0даэтилфосфонил ) -циклогекош ) -аминN-phenyl-N (1- (0,0 daethylphosphonyl) -cyclohexos) -amine

N- о- метилфенил- N (I- (0,0-диэтилфосфонил ) -циклогексил) аминN-o-methylphenyl-N (I- (0,0-diethylphosphonyl) -cyclohexyl) amine

М-л -метилфенил-Ы-(1 (0,0-диэтилфосфонил)циклогексил ) -аминM-l-methylphenyl-L- (1 (0,0-diethylphosphonyl) cyclohexyl) -amine

М-п-метилфенил-N-(I (0,0- да эти лфосфонил ) - циклогексил)аминMn-methylphenyl-N- (I (0,0-yes these lphosphonyl) - cyclohexyl) amine

N- о- хл орфенил- N (1- (0,0-диэтилфосфонил) циклогекснл) -аминN-o-chl orphenyl-N (1- (0,0-diethylphosphonyl) cyclohexnl) -amine

М-л-хлорфенил-Ы- (1 (О.О- диэтилфосфонил) циклогексил ) -аминM-l-chlorophenyl-L- (1 (O.O-diethylphosphonyl) cyclohexyl) -amine

онил) -onil) -

H CICjiUCICiH 3 VОСИ ,H CICjiUCICiH 3 VOSI,

Н СНэ СНэH Sne Sne

1,53781.5378

Н СНз СН, NHH CHZ CH, NH

1,49121.4912

Н CjHj CjHsH CjHj CjHs

9898

CHjCHj

d- d-

Н C,HS CjHsH C, HS CjHs

СН,CH,

103103

Н CjHs СаН,H CjHs SaN,

Н С,Н, CjH,H C, H, CjH,

9292

ClCl

H c,H, c,n, 1,H c, H, c, n, 1,

53005300

, rr

H CjHs QjH|H CjHs QjH |

122122

-У-Y

6868

1,50721.5072

Н ci02H4CiejH4H ci02H4CiejH4

Ы-циклогексил-М- (l- (0,0-диизoпpoпилфocфoшш) циклoгeкcил )-aминН ;Изо- ИзоN-cyclohexyl-M- (l- (0,0-diisopropylphosphol)) cyclohexyl) -aminH; Iso-Iso

1,76901.7690

-СэН, ч:зН, KН Изо- ИзоклоН CjHs CjHs-SeH, h: sN, KN Iso-isocloH CjHs CjHs

N-циклогекси л-N-(1- (0,0-диизобутилфосфонил) чщклогексил ) -аминN-cyclohexy-L-N- (1- (0,0-diisobutylphosphonyl) -cyclohexyl) -amin

N- циклогекси л- N - (1 - (0,0-дипропилфосфонил ) - илклогексил) -аминN-cyclohexyl l-N - (1 - (0,0-dipropylphosphonyl) - ilclohexyl) -amin

N-2-хлорфенилW- (1- (0,0-диизопрогтилфосфошл ) - циклогексил) аминN-2-chlorophenyl W- (1- (0,0-diisoprogtilphostoshl) - cyclohexyl) amine

N-циклогекснл- N- (1- (0,0-ддамилфосфонил)-циклогексил ) -аминN-cyclohexnl-N- (1- (0,0-ddamylphosphonyl) -cyclohexyl) -amine

N-6eH3HH-N-(l (0,0-дихлорэтилфосфонил) -циклогексил )-аминN-6eH3HH-N- (l (0,0-dichloroethylphosphonyl) -cyclohexyl) -amine

N-бензил-N-(1- (0,0-диизобутилфосфонил ) -циклогексил) -аминN-benzyl-N- (1- (0,0-diisobutylphosphonyl) -cyclohexyl) -amine

N-бензил-N-(l- (0,0-диaмилфocфoиил ) -циклогексил) -аминN-benzyl-N- (l- (0,0-diamylphosphoyl) -cyclohexyl) -amine

8 Продолжение таблшоы8 Continuation of the table

С|C |

Н СНэ СНзH SNE SNZ

VV

eHj- 1,5070eHj- 1.5070

И Cj HS Cj Н jAnd Cj HS Cj H j

СН,- 1,4966CH, 1.4966

-03117 СзН7-03117 SzN7

1,48201.4820

1,47681.4768

Н Изо- ИзоС4Нс ) 04119H Izo-IsoS4Ns) 04119

1,47911.4791

СзН7 CjHSzN7 CjH

.Cl.Cl

Изо- Изо-СзН , -СзНтIzo-Iso-SzN, -SzNt

1,44101.4410

1,47751.4775

Н CjHji CsHiiH CjHji CsHii

Н CIC2H4CICiH4 ff V-еНо- 1.5330H CIC2H4CICiH4 ff V-eH-1.5330

Н Изо- Изо- 1,4995N Iso- Iso- 1.4995

С4 Нд С4 Н9 mfC4 Nd C4 H9 mf

Н CsH,, CsH,, Л-CHj- 1,4977H CsH ,, CsH ,, L-CHj- 1.4977

10 Продолжение таблицы 10 Continuation of the table

N-6yTHfl-N-(b (0,0-диметалфосфйнил ) -циклогексил) - мкиN-6yTHfl-N- (b (0,0-dimethylphosphynyl) -cyclohexyl) - mk

М-бутил-Ы- (1- I -(0,0-диэтилфосфонил ) - циклогексил)M-butyl-Y- (1- I - (0,0-diethylphosphonyl) - cyclohexyl)

N-бутил-N-(1 (0,0диизoпpoIшлфoc фонил) -циклогексил) N-butyl-N- (1 (0,0-diisopro-Ishloc fonyl) -cyclohexyl)

4tlVffiH4tlVffiH

N-6ymn-N-(l -(0,0-дкизобутнлфосфонил ) -циклогексил )-амииN-6ymn-N- (l - (0,0-dkisobutnlphosphonyl) -cyclohexyl) -amia

N-6ynui-N-(l (0,0-диамш1фосфонил ) -циклогексил)аминN-6ynui-N- (l (0,0-diamsh1phosphonyl) -cyclohexyl) amine

N- метоксиэтил- N ( 1-0,0-диметилфосфонил ) - циклогекса1л )-аминN-methoxyethyl-N (1-0,0-dimethylphosphonyl) - cyclohexa1l) -amine

N- MeTOkCH3nuj- N- (1- (0,0-диизопропилфосфотш ) -циклогексил )-аминN-MeTOkCH3nuj- N- (1- (0,0-diisopropylphosphoric) -cyclohexyl) -amine

N- метоксипропил- N- (1- (0,0-диизопропилфосфонил ) - циклогекот л)-аминN-methoxypropyl-N- (1- (0,0-diisopropylphosphonyl) -cyclohecot l) -amin

N- метоксипропил- N- (1 - 0,0-диизобутилфосфонил ) - цнклогексн л) амииN-methoxypropyl-N- (1 - 0,0-diisobutylphosphonyl) - cyclohexn l) ammonia

1,47101.4710

Н СНэ СНз С4Н91 .4620H CHE CH3 C4H91 .4620

Н CjHs CjHs 04119H CjHs CjHs 04119

Н Изо- Изо- С4Нв1 ,4565 -СзН7. -CaHiH Iso-Iso-C4Hb1, 4565-SzN7. -CaHi

1,45971,4597

Н Изо- Изо-С4Н94 4 HS С4 9N Izo-Iso-C4H94 4 HS C4 9

Н CsHnCjH,, е4Н9 1,4630H CsHnCjH ,, e4H9 1.4630

Н СНз СН -CjHi-OCHjH CHS CH-CjHi-OCHj

Н Изо- Изо- СрэО-СаН4-1,4545N Iso-Iso-SreO-CaH4-1,44545

-СзН, зН,-SzN, SN,

1,45981,4598

Н Изо- Изо- СНз ОСзН7 СзН7СзН7H Izo-Iso-SNz OSzN7 SzN7SzN7

1,46281.4628

Н Изо- Изо- СНзО-СзН С Hj V4H9N Iso-Iso-СНзО-СзН С Hj V4H9

11eleven

(I- (0,0-диизобутилфосфонил ) -цнклогексил) -амин лоСНз Изо- ИзоСНз Изо- Изо- С4Н9Формула изобретени  i. Способ получени  пиклогексиламинофосфонатов , отличающийс  тем, что диалкилфосфиты подвергают взаимодействию с N-циклогексилиденаминами .(I- (0,0-diisobutylphosphonyl) -cyclohexyl) -amine loCN3 Iso-IsoCH3 Iso-Iso-C4H9 Formula of the invention i. A process for preparing piclohexylaminophosphonates, characterized in that the dialkyl phosphites are reacted with N-cyclohexylidene amines.

12 Продолжение таблицы12 Continuation of the table

Н Изо- Изо- CH30-CjH41 ,4595H Iso-Iso-CH30-CjH41, 4595

4 Н9 G4 Н94 H9 G4 H9

Н СуНц CjHji CHjO-CjH41 ,4625N SUNC CjHji CHjO-CjH41, 4625

1,4650 -CjH7 -СаН1.4650 -CjH7 -SaH

Claims (1)

1,45811.4558 С4 Hj 9 C4 Hj 9 30 2, Способ поп. 1,отличающийс  тем,«по процесс ведут при температуре 50-60° С.30 2, The way pop. 1, characterized in that "the process is carried out at a temperature of 50-60 ° C. 3. Способ по п. 1, о т л и ч а ю щ и и с   тем, что процесс ведут в среде органического растворител .3. The method according to claim 1, about tl and h and y and the fact that the process is carried out in an environment of an organic solvent.
SU1446651A 1969-08-04 1970-06-23 Method for preparing cyclohexylaminophosphonates SU504781A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DD14156069 1969-08-04

Publications (1)

Publication Number Publication Date
SU504781A1 true SU504781A1 (en) 1976-02-28

Family

ID=5481515

Family Applications (2)

Application Number Title Priority Date Filing Date
SU1446651A SU504781A1 (en) 1969-08-04 1970-06-23 Method for preparing cyclohexylaminophosphonates
SU721446651D SU574195A1 (en) 1969-08-04 1972-06-26 Plant growth control agent

Family Applications After (1)

Application Number Title Priority Date Filing Date
SU721446651D SU574195A1 (en) 1969-08-04 1972-06-26 Plant growth control agent

Country Status (8)

Country Link
AT (1) AT300454B (en)
CH (1) CH541278A (en)
DE (1) DE2022228C2 (en)
FR (1) FR2056340A5 (en)
HU (1) HU162750B (en)
NL (1) NL164863C (en)
RO (1) RO62001A (en)
SU (2) SU504781A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3855363A (en) * 1973-08-08 1974-12-17 Upjohn Co Cycloalkane, cycloalkene, and cycloalkanone phosphonates
DE2459491A1 (en) * 1974-12-17 1976-06-24 Bayer Ag AGAINST ISOCYANATE-REACTIVE PHOSPHORUS FLAME RETARDANTS

Also Published As

Publication number Publication date
NL164863B (en) 1980-09-15
AT300454B (en) 1972-06-15
SU574195A1 (en) 1977-09-30
NL7004960A (en) 1971-10-11
DE2022228A1 (en) 1971-02-18
HU162750B (en) 1973-04-28
RO62001A (en) 1977-11-15
FR2056340A5 (en) 1971-05-14
NL164863C (en) 1981-02-16
CH541278A (en) 1973-09-15
DE2022228C2 (en) 1982-11-04

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