SU353531A1 - The method of wastewater treatment from fine suspended particles with a high content of silicon dioxide - Google Patents

The method of wastewater treatment from fine suspended particles with a high content of silicon dioxide

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Publication number
SU353531A1
SU353531A1 SU1373540A SU1373540A SU353531A1 SU 353531 A1 SU353531 A1 SU 353531A1 SU 1373540 A SU1373540 A SU 1373540A SU 1373540 A SU1373540 A SU 1373540A SU 353531 A1 SU353531 A1 SU 353531A1
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SU
USSR - Soviet Union
Prior art keywords
solution containing
suspension
wastewater
silicon dioxide
content
Prior art date
Application number
SU1373540A
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Russian (ru)
Inventor
Б.М. Щепачев
М.Б. Зеликин
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Priority to SU1373540A priority Critical patent/SU353531A1/en
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Publication of SU353531A1 publication Critical patent/SU353531A1/en

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  • Removal Of Specific Substances (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Description

(54) СПОСОБ ОЧИСТКИ СТОЧНЫХ ВОД ОТ ТОНКОДИСПЕРСНЫХ ВЗБЕШЕННЫХ ВЕЩЕСТВ. С ВЫСОКИМ СОДЕРЖАНИЕМ ДВУОКИСИ(54) METHOD FOR CLEANING WASTE WATER FROM THIN-DISPERSED FOLDED SUBSTANCES. WITH HIGH CONTENT OF DIOXIDE

Изобретение относитс  к области очистки сточных вод предпри тий химической промышленности.The invention relates to the field of wastewater treatment of chemical industry enterprises.

Известен способ очистки сточных вод от тонкодисперсных взвешенных веществA known method of purification of waste water from fine suspended solids

путем их обработки железосодержащим дсоагул  том и соединени ми кальци  или магни  при значении рН 7,1-8,8 и соотноше2+SL4НИИ ИОНОВ Саили Mg к взвесиby treating them with iron-containing docoagulum and calcium or magnesium compounds at a pH of 7.1-8.8 and a ratio of 2 + SL4 of the ION Sails Mg to suspension

1:1.1: 1.

Недостатками известного способа  вл ютс  низка  степень очистки и значительный расход реагентов.The disadvantages of this method are the low degree of purification and the significant consumption of reagents.

Предложенный способ отличаетс  от известного тем, что процесс очистки осущест вл ют при весовом соотношении ионов кальци  или магни  к тонкодисперсной взвеси двуокиси кремни , равном 1:( 10-60). Это позвол ет повысить степень очистки на 1520% и снизить расход железосодержащего коагул нта в 3 раза.The proposed method differs from the known one in that the purification process is carried out with a weight ratio of calcium or magnesium ions to a fine silica slurry equal to 1: (10-60). This makes it possible to increase the degree of purification by 1520% and reduce the consumption of iron-containing coagulum by 3 times.

КРЕМНИЯSilicon

средним размером частиц менее 1 мк), кар-бонизуют до превращени  sMciHCOj. Затем в суспензию вЬод т при перемешивании 10 мл раствора, содержащего 28 г/л Со се2 и 20,5 г/л Fe (весовое отношение Са : взвесь 1:ЗО); рН среды 7,8. Образовавшиес  хлопь  вместе со взвешенными веществами быстро отстаиваютс . Через 2 час кажущийс  объем осадка 9,3%, а через сутки 6,5%. Содержание взвешенных веществ в жидкой фазе не превыщает ЗО мг/л.average particle size less than 1 micron), is carbonized to make sMciHCOj. Then, with suspension, 10 ml of a solution containing 28 g / l of Co ce2 and 20.5 g / l of Fe (weight ratio Ca: suspension 1: 30) are mixed into the suspension; pH of 7.8. The formed flakes together with suspended solids are quickly settled. After 2 hours, the apparent volume of sediment was 9.3%, and in a day, 6.5%. The content of suspended solids in the liquid phase does not exceed 300 mg / l.

Claims (2)

Пример 2.К1л сточных вод, со держащих 2,2 г/л взвещенных веществ (бела  сажа), 2 г/л NdigCO-j и 0,43 г/л Na2SOrдобавл ют 15 мл стачных вод химически осажденного мела (Са : взвесь 1:5О). Смесь карбонизуют до превращени  в NaHCO 3 и ввод т при перемешивании 5 мл раствора, содержащего 15,6 г/л 6(504)3 . Температура 35°С: рН 8,3. Через 2 час отстаивани  кажущийс  объем осадка 5%, а через сутки 1,5%. 1 идка  фаза прозрачна (содержание взвешенных веществ менее 30 мг/л). Пример 3.1л сточных вод, содержащих 2,5 г/л взвешенных вешеств (бела  сажа), 2,3 г/л NOjCOg и О,3 г/л N0(2.50 нейтрализуют 5%-ной НдбО по фенолфталеину, ввод т при перемешивании 10 мл раствора, содержащего 55 г/  MgCP (Mg .взвесь 1:15), а затем Ю мл раствора, содержащего 15,6 г/л Ге(,,. Температура 26°С; рН 7,Example 2. Sewage containing 2.2 g / l of particulate matter (white soot), 2 g / l of NdigCO-j and 0.43 g / l of Na2SO-15 ml of wastewater of chemically precipitated chalk (Ca: suspension 1 : 5O). The mixture is carbonized to become NaHCO 3 and 5 ml of a solution containing 15.6 g / l 6 (504) 3 is added with stirring. Temperature 35 ° С: pH 8.3. After 2 hours of settling, the apparent sediment volume is 5%, and in a day, 1.5%. 1 phase is transparent (suspended matter content less than 30 mg / l). Example 3.1l of wastewater containing 2.5 g / l of suspended solids (white soot), 2.3 g / l of NOjCOg and O, 3 g / l of N0 (2.50 is neutralized with 5% NdBO for phenolphthalein, is introduced with stirring 10 ml of a solution containing 55 g / MgCP (Mg. Suspension 1:15) and then Yu ml of a solution containing 15.6 g / l of Ge (,,. Temperature 26 ° C; pH 7, 2. Через 2 час отстаивани  кажущийс  объем осадка 8%, а через сутки 3,5%. Жидка  фаза прозрачна (содержание взвещенных ве ществ менее 30 мг/л). Пример 4. К1л сточных вод, со держащих 2,4 г/л взвещенных веществ (бе ла  сажа), 3,15 г/л NaHCO O,22 г/л NdjCO-i, и 0,4 г/л добавл ют 10 мл раствора, содержащего 28 г/лСаСР (весовое отношение Са:взвесь 1:23), и при перемешивании - 8 мл раствора, содержащего 18,2 г/л ГеЗОд. Температура 19°С; рН 8,5. Через 2 час отстаивани  кажущийс  объем осадка 10%, а через сутки 7,5%. Жидка  фаза прозрачна (содержание взвещенных веществ менее 30 мг/л). Таким образом, технико-экономические преимущества предлагаемого способа заключаютс  в достижении достаточно высокой степени очистки сточных вод, содержащих тонкодисперсную двуокись кре1ини , при малых расходах реагентов. Формула изобретени  Способ очистки сточных вод от тонкодисперсных взвешенных. веществ с высоким содержанием двуокиси кремни  путем их обработки железосодержащим коагул нтом и водорастворимыми соединени ми калыш  или магни  при значении рН 7,1-8,8, о тличающийс  тем, что, с целью повышени  степени очистки и снижени  расхода реагентов, процесс осуществл ют при весовом соотнощении ионов кальци  или магни  к тонкодисперсной взвеси двуокиси , равном 1:(10-60).2. After 2 hours of settling, the apparent volume of sediment is 8%, and in a day 3.5%. The liquid phase is transparent (the content of the material is less than 30 mg / l). Example 4. K1l of wastewater containing 2.4 g / l of particulate matter (white carbon), 3.15 g / l of NaHCO O, 22 g / l of NdjCO-i, and 0.4 g / l of 10 ml of a solution containing 28 g / lCaCP (weight ratio Ca: suspension 1:23), and with stirring, 8 ml of a solution containing 18.2 g / l geozd. Temperature 19 ° С; pH 8.5. After 2 hours of settling, the apparent sediment volume is 10%, and in a day, 7.5%. The liquid phase is transparent (the content of substances is less than 30 mg / l). Thus, the technical and economic advantages of the proposed method consist in achieving a sufficiently high degree of purification of wastewater containing finely dispersed silicon dioxide, with low reagent consumption. The invention of the method of wastewater treatment from fine suspended suspended. substances with a high content of silicon dioxide by treating them with iron-containing coagulant and water-soluble compounds of kalysh or magnesium at a pH of 7.1-8.8, which is characterized by the fact that, in order to increase the degree of purification and reduce the consumption of reagents, the weight ratio of calcium or magnesium ions to a finely dispersed suspension of dioxide, equal to 1: (10-60).
SU1373540A 1969-11-03 1969-11-03 The method of wastewater treatment from fine suspended particles with a high content of silicon dioxide SU353531A1 (en)

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