SU330688A1 - Method of coal and ore flotation - Google Patents

Method of coal and ore flotation Download PDF

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Publication number
SU330688A1
SU330688A1 SU671142454A SU1142454A SU330688A1 SU 330688 A1 SU330688 A1 SU 330688A1 SU 671142454 A SU671142454 A SU 671142454A SU 1142454 A SU1142454 A SU 1142454A SU 330688 A1 SU330688 A1 SU 330688A1
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SU
USSR - Soviet Union
Prior art keywords
coal
phenols
reagent
flotation
toxicity
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Application number
SU671142454A
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Russian (ru)
Inventor
Б.М. Пац
И.И. Еру
Г.И. Папков
Г.И. Пивень
Н.М. Базанова
Р.М. Безродная
Original Assignee
Украинский Научно-Исследовательский Углехимический Институт "Ухин"
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Priority to SU671142454A priority Critical patent/SU330688A1/en
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Publication of SU330688A1 publication Critical patent/SU330688A1/en

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Abstract

Способ флотации углей с применением эффективных и малотоксичных реагентов на основе технических смесей фенолов, отличающий- с   тем, что, с целью уменьшени  токсичности реагента и повышени  его эффективности, гидрируют технические смеси фенолов с получением реагента гидроксила, представл ющего собой смесь алкилциклогексанолов.The method of coal flotation with the use of effective and low-toxic reagents based on technical mixtures of phenols, is characterized in that in order to reduce the toxicity of the reagent and increase its effectiveness, technical mixtures of phenols are hydrogenated to obtain a hydroxyl reagent, which is a mixture of alkyl cyclohexanols.

Description

СО соCO with

Од Od

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Дгм флотации углей и руд цветных металлов примен ютс  различные реагентЫу в числе органические соединени , в структуре которых содержитс  гидроксипьна  грзтта, (спирты, фенолы и др.). Однако к некоторьйи из-этих реагентов, несмотр  на их эффективность, интерес утер н, так как часть их неизбежно попадала в вода обогатительных фабрик, вызыва  в последукщем затруднени  с обезвреживанием стоков. К числу таких эффективных , но вместе с тем токсичиык реагентов относ тс  соединени  р да фенолов (ксиленолы и другие высококип щие фенолы). Широко примен вшиес  ранее в качестве вспенивателей фенолы вытесн ютс  менее токсичньми реагентами, среди которых основное место принадлежит спиртам.Dgm of flotation of coal and ores of non-ferrous metals, various reagents are used, including organic compounds in the structure of which hydroxypnas are contained, (alcohols, phenols, etc.). However, to some of these reagents, despite their effectiveness, interest has been lost, since some of them inevitably fell into the water of the beneficiation plants, causing subsequent difficulties in disposing of the effluent. Among such effective, yet toxic, reagents are compounds of a number of phenols (xylenols and other high-boiling phenols). Previously widely used as blowing agents, phenols are replaced by less toxic reagents, among which the main place belongs to alcohols.

Цель изобретени  - уменьшение токсичности реагента и повышение его эффективности.The purpose of the invention is to reduce the toxicity of the reagent and increase its effectiveness.

Дл  этого по предлагаемому способу дл  флотации углей и руд примен ют различные изомеры алкипциклогексанолов , полученные гидрированием технических смесей, фенолов, в частности высококип щих, самих по себе не представл ющих ценности, например фeнoJШ поглотительных масел, содержащие в основном ксиленога 1 и другие алкилфенолы. Токсичность смеси алкилциклогексанолор в сотни раз ниже токсичности фенолов.To do this, the proposed method for flotation of coal and ores uses various isomers of alkympicyclohexanols obtained by hydrogenation of technical mixtures, phenols, in particular high boilers, which are not valuable in themselves, such as pheno-absorbant oils, containing mainly xylene-1 and other alkylphenols. The toxicity of the mixture of alkylcyclohexanolor is hundreds of times lower than the toxicity of phenols.

Claims (1)

СПОСОБ ФЛОТАЦИИ УГЛЕЙ И РУД. Способ флотации углей с применением эффективных и малотоксичных реагентов на основе технических смесей фенолов, о тлич ающийс я тем, что, с целью уменьшения токсичности реагента и повышения его эффективности, гидрируют технические смеси фенолов с получением реагента гидроксила, представляющего собой смесь алкилциклогексанолов.METHOD OF FLOTATION OF COAL AND ORES. A method of coal flotation using effective and low-toxic reagents based on technical mixtures of phenols, characterized in that, in order to reduce the toxicity of the reagent and increase its efficiency, technical phenol mixtures are hydrogenated to obtain a hydroxyl reagent, which is a mixture of alkylcyclohexanols.
SU671142454A 1967-03-24 1967-03-24 Method of coal and ore flotation SU330688A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU671142454A SU330688A1 (en) 1967-03-24 1967-03-24 Method of coal and ore flotation

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Application Number Priority Date Filing Date Title
SU671142454A SU330688A1 (en) 1967-03-24 1967-03-24 Method of coal and ore flotation

Publications (1)

Publication Number Publication Date
SU330688A1 true SU330688A1 (en) 1985-03-30

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SU671142454A SU330688A1 (en) 1967-03-24 1967-03-24 Method of coal and ore flotation

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4770767A (en) * 1987-05-06 1988-09-13 The Dow Chemical Company Method for the froth flotation of coal
US4820406A (en) * 1987-05-06 1989-04-11 The Dow Chemical Company Method for the froth flotation of coal
US4915825A (en) * 1989-05-19 1990-04-10 Nalco Chemical Company Process for coal flotation using 4-methyl cyclohexane methanol frothers

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4770767A (en) * 1987-05-06 1988-09-13 The Dow Chemical Company Method for the froth flotation of coal
US4820406A (en) * 1987-05-06 1989-04-11 The Dow Chemical Company Method for the froth flotation of coal
US4915825A (en) * 1989-05-19 1990-04-10 Nalco Chemical Company Process for coal flotation using 4-methyl cyclohexane methanol frothers

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