SU316662A1 - GLASS CRYSTALLINE ENAMEL - Google Patents

GLASS CRYSTALLINE ENAMEL

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Publication number
SU316662A1
SU316662A1 SU1326638A SU1326638A SU316662A1 SU 316662 A1 SU316662 A1 SU 316662A1 SU 1326638 A SU1326638 A SU 1326638A SU 1326638 A SU1326638 A SU 1326638A SU 316662 A1 SU316662 A1 SU 316662A1
Authority
SU
USSR - Soviet Union
Prior art keywords
enamel
glass crystalline
coating
crystalline enamel
mgo
Prior art date
Application number
SU1326638A
Other languages
Russian (ru)
Original Assignee
В. Е. Горбатенко , В. П. Ратькова
Новочеркасский ордена Трудового Красного Знамени политехнический институт С. Орджоникидзе
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by В. Е. Горбатенко , В. П. Ратькова, Новочеркасский ордена Трудового Красного Знамени политехнический институт С. Орджоникидзе filed Critical В. Е. Горбатенко , В. П. Ратькова
Priority to SU1326638A priority Critical patent/SU316662A1/en
Application granted granted Critical
Publication of SU316662A1 publication Critical patent/SU316662A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C03C10/0036Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
    • C03C10/0045Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents containing SiO2, Al2O3 and MgO as main constituents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Description

Изобретение относит1с  к составу эмали, используемой дл  образовани  стекло.кристаллического покрыти  на легированных стал х и сплавах.The invention relates to the composition of the enamel used to form a glass crystal coating on alloyed steels and alloys.

Известна эмаль, включающа  SiO2, АЬОз, MgO, TiOz, Li2O, NaaO.Enamel is known, including SiO2, ABO3, MgO, TiOz, Li2O, NaaO.

Предлагаема  эыалъ обладает повышенным коэффициентом термического раснлирени , мало измен ющимс  .при ситаллизации, улучшенными защитными свойствами.The proposed formulation has a high thermal dilution coefficient, which does not change much during sitalization, and has improved protective properties.

Это достигаетс  тем, что она содержит указанные компоненты в следующих количествах , шее. %: Si02 48,4-54,4; АЬОз 16,1 - 19,4;This is achieved in that it contains these components in the following amounts, the neck. %: Si02 48.4-54.4; ABOZ 16.1 - 19.4;

Толщина двухслойного .покрыти  После обжига не должна превышать 60 ./икл. Температура обжига грунтового покрыти , в зависимости от содержани  Сг2Оз колеблетс  от 1050 до 1150°С, нокроеного сло  -1050°С.The thickness of the double-layer. After firing should not exceed 60. / Cycle. The firing temperature of the primer coating, depending on the Cr2Oz content, ranges from 1050 to 1150 ° C, but the thickness of the layer is –1050 ° C.

MgO 11,8-14,6; TiOa 9-12; LizO 3-5; ЫагО 5-7; и кроме того сверх 100% К2О до 30, Сг2Оз до 30.MgO 11.8-14.6; TiOa 9-12; LizO 3-5; Yo 5-7; and besides, in excess of 100% K2O up to 30, Cr2Oz up to 30.

Коэффициент термического расщирени  давней эмали 117-10 гра&- ; :после ситаллизации- 122-10 град, начала разм гчени  до 580°С; температура обжига 1покрыти  до 1050°С. Микротвердость ситаллизированного покрыти  1892 кг/мл1-.The coefficient of thermal expansion of the old enamel 117-10 gra &-; : after sitalization, 122–10 degrees, the onset of softening to 580 ° C; firing temperature 1cover to 1050 ° C. The microhardness of the crystallized coating is 1892 kg / ml1-.

Эмаль нанос т на обезжиренную поверхность .хромоникелевого сплава ЭИ-435 в виде шликера состава (в вес. ч.)The enamel is applied to the degreased surface of the EI-435 nickel alloy in the form of a slip composition (in weight parts)

ни  не более 3°С в минуту в интервале тем15 ператур нуклеации (590-640°С) ,и выдержкой в течение двух часов при оптимальной температуре кристаллизации (730°С).Not more than 3 ° C per minute in the range of nucleation temperatures (590–640 ° C), and exposure for two hours at the optimum crystallization temperature (730 ° C).

эмали повышаетс  с 580 до 900°С, а покров .ной -до 860°С.enamel rises from 580 to 900 ° C, and the cover of the enamel rises to 860 ° C.

Эмали при введении в шликер от 5 до 30% СгаОз могут служить грунтовым слоем или самосто тельным покрытием на сплаве ЭИ-435 |при температуре эксплуатации 900- 1000°С, а эмали б&з доба,вки СгаОз могут быть использованы а качестве покровиой эмали при температуре 900°С в газовой среде.Enamels, when introduced into the slip from 5 to 30% of CO2, can serve as a base coat or an independent coating on the alloy EI-435 | at a operating temperature of 900-1000 ° C, and enamels can be used as a coating of enamel at a temperature of 900 ° C in a gaseous environment.

Предмет изобретени Subject invention

Стеклокристаллическа  эмаль, включающа  SiOa, АЬОз, MgO, TiOa, LizO, NasO, отличающа с  тем, что, с целью улучшени  защитных свойств -покрыти , она содержит указанные компоненты в следующих .количествах , вес. %: SiOs 48,4-54,4; АЬОз 16,1 - 19,4; MgO 11,8-14,6; TiO2 9-12; LiaO 3-5; Na2O 5-7 и, кроме того, сверх 100% КдО до 30, Сг2Оз до 30.Glass enamel, including SiOa, HbOz, MgO, TiOa, LizO, NasO, characterized in that, in order to improve the protective properties of the coating, it contains these components in the following amounts, weight %: SiOs 48.4-54.4; ABOZ 16.1 - 19.4; MgO 11.8-14.6; TiO2 9-12; LiaO 3-5; Na2O 5-7 and, in addition, in excess of 100% CdO up to 30, Cr2Oz up to 30.

SU1326638A 1969-04-18 1969-04-18 GLASS CRYSTALLINE ENAMEL SU316662A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU1326638A SU316662A1 (en) 1969-04-18 1969-04-18 GLASS CRYSTALLINE ENAMEL

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU1326638A SU316662A1 (en) 1969-04-18 1969-04-18 GLASS CRYSTALLINE ENAMEL

Publications (1)

Publication Number Publication Date
SU316662A1 true SU316662A1 (en) 1971-12-17

Family

ID=39884235

Family Applications (1)

Application Number Title Priority Date Filing Date
SU1326638A SU316662A1 (en) 1969-04-18 1969-04-18 GLASS CRYSTALLINE ENAMEL

Country Status (1)

Country Link
SU (1) SU316662A1 (en)

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