SU259090A1 - METHOD FOR GETTING NITROGEN-MAGNETIC FERTILIZERS - Google Patents
METHOD FOR GETTING NITROGEN-MAGNETIC FERTILIZERSInfo
- Publication number
- SU259090A1 SU259090A1 SU1178368A SU1178368A SU259090A1 SU 259090 A1 SU259090 A1 SU 259090A1 SU 1178368 A SU1178368 A SU 1178368A SU 1178368 A SU1178368 A SU 1178368A SU 259090 A1 SU259090 A1 SU 259090A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- fertilizers
- magnetic
- salt
- ammonium
- nitrogen
- Prior art date
Links
- 239000003337 fertilizer Substances 0.000 title description 8
- 239000000203 mixture Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- PRKQVKDSMLBJBJ-UHFFFAOYSA-N Ammonium carbonate Chemical compound N.N.OC(O)=O PRKQVKDSMLBJBJ-UHFFFAOYSA-N 0.000 description 7
- 239000001099 ammonium carbonate Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 235000012501 ammonium carbonate Nutrition 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 3
- -1 nitrogen-magnesium Chemical compound 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 210000000988 Bone and Bones Anatomy 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 239000001166 ammonium sulphate Substances 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- XKUUMWKWUZRRPD-UHFFFAOYSA-N heptan-2-amine;sulfuric acid Chemical compound [O-]S([O-])(=O)=O.CCCCCC(C)[NH3+].CCCCCC(C)[NH3+] XKUUMWKWUZRRPD-UHFFFAOYSA-N 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
Description
Изобретение относитс к -способам получени азотномагниевых удобрений на основе карбоната аммони и соли магни .This invention relates to methods for producing nitrogen-magnesium fertilizers based on ammonium carbonate and a magnesium salt.
Известен способ получени азотномагниевых удобрений на основе бикарбоната аммони , заключающийс в том, что влажный кристаллический бикарбонат аммони смешивают с MgNHiPOi бНаО или MgHPO4MgHPO4-3H20 либо с их смесью. При этом образуетс оболочка из MgNH4PO4 6Н2О, охран юща от выветривани аммиака карбонат аммони . Получаетс .продукт, содержащий 12-16,8% азота.A known method for producing ammonium bicarbonate-based nitrogen-magnesium fertilizers, which consists in mixing the wet crystalline ammonium bicarbonate with MgNHiPOi bNaO or MgHPO4MgHPO4-3H20 or with their mixture. In this case, a shell of MgNH4PO4 6H2O is formed, protecting ammonium carbonate from ammonia weathering. A product containing 12-16.8% nitrogen is obtained.
Педостатком этого способа получени удобрени вл етс сравнительна сложность изготовлени фосфорных соединений магни , а также мала растворимость в виде получаемых продуктов.The disadvantage of this method of producing fertilizer is the comparative complexity of the manufacture of magnesium phosphorus compounds, as well as the low solubility in the form of the products obtained.
С целью устранени недостатков и повыщени качества продукта предложен способ, в котором исходным продуктом вл етс обезвоженна соль двойного сульфата магни и аммони MgSO4(NH4)2SO4 - соль Туттона. Порощок этой соли смещивают с измельченным порощком карбоната аммони , и смесь затвор ют небольщим количествол воды (10- 25% от веса смеси). При этом смесь схватываетс и твердеет аналогично в жущим материалам , например гипсу. Процесс схватывани длитс недолго - всего 5-10 мин.In order to eliminate the drawbacks and increase the quality of the product, a method has been proposed in which the initial product is the dehydrated salt of magnesium and ammonium double sulfate MgSO4 (NH4) 2SO4 - Tutton salt. The powder of this salt is shifted with a crushed powder of ammonium carbonate, and the mixture is closed with a small amount of water (10-25% by weight of the mixture). In this case, the mixture seizes and hardens in a similar manner to the holding materials, for example gypsum. The process of setting does not last long - only 5-10 minutes.
Дл осуществлени процесса может бытьTo carry out the process can be
использован и порошок карбонатаused and carbonate powder
аммони . В этом случае количество воды затворени уменьшаетс в соответствии с количеством влаги в карбонате.ammonium. In this case, the amount of mixing water is reduced in accordance with the amount of moisture in the carbonate.
Получаемые гранулы обладают высокой прочностью и воздухоустойчивостью. Удобрение хорощо растворимо в воде, негигроскопично и не слеживаетс при храненИИ, поэтому удобно дл применени .The resulting granules have high strength and air resistance. The fertilizer is well soluble in water, non-hygroscopic and does not clog when stored, therefore it is convenient for use.
Химический состав получаемых удобрений может быть выражен суммарной формулой MgS04(NH4)2S04 т(тН4)2СОз-«ПоО; значени т vi п завис т от весовых соотнощений обезвоженной соли Туттона, карбоната аммони и воды в смеси. Практически т может прин ть значени от 1 до 10, а - от 6 до 12.The chemical composition of the obtained fertilizers can be expressed by the total formula MgS04 (NH4) 2S04 t (tH4) 2CO3 - “Poo; the values of t vi p depend on the weight ratios of the dehydrated Tutton salt, ammonium carbonate and water in the mixture. Practically, t can take values from 1 to 10, and - from 6 to 12.
Пример. Смешивают карбонат аммони , содержащий аммиака 31%, и обезвоженную соль Туттона, содержащую, %: MgO 15-20; SOs 64,76; NHs 12,81 в следующих весовых соотношени х комГонентоБ на 1 вес. ч. обезвоженной соли Туттона:Example. Mix ammonium carbonate, containing ammonia 31%, and dehydrated Tutton salt, containing,%: MgO 15-20; SOs 64.76; NHs 12.81 in the following weight ratios of comGontoB per weight. h. Tutton's dehydrated salt:
2525
арбонат аммони , ammonium arbonate,
Вода, Чо от веса с.месн вес. ч.Water, Cho on the weight of c.mesnesn weight. h
1515
16 18 17 1416 18 17 14
1,5 1,8 2,0 4,0 Химический удобрений состав полученных %: приведен ниже, Содержание полезных компонентов в продуктах 4 и 5 равно 19,21 и 21,32%. Полученное удобрение не Слеживаетс , гигросконич5 10 кость слаба , растворимость в воде на 100 г раствора 14,04 г. i Предмет изобретени Способ получени азотномагниевых удобре;ний путем смешени ка-рбоната аммони с магнийсодержащим соединением, отличающийс тем, что, с целью повышени качества продукта, в качестве соединени магни нримен ют измельченную соль обезвоженного двойного сульфата магни и аммони - соль Туттона, и затвор ют водой.1.5 1.8 2.0 4.0 Chemical fertilizer composition of the obtained%: is shown below, The content of useful components in products 4 and 5 is 19.21 and 21.32%. The resulting fertilizer does not agglomerate, the hygroscopic5 10 bone is weak, the solubility in water per 100 g of the solution is 14.04 g. I The subject of the invention The product, as a compound of magnesium, uses crushed salt of anhydrous magnesium and ammonium sulphate double - Tutton's salt, and is sealed with water.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU259090A1 true SU259090A1 (en) |
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