SU253345A1 - ANTI ADHESIVE COMPOSITION - Google Patents
ANTI ADHESIVE COMPOSITIONInfo
- Publication number
- SU253345A1 SU253345A1 SU1189819A SU1189819A SU253345A1 SU 253345 A1 SU253345 A1 SU 253345A1 SU 1189819 A SU1189819 A SU 1189819A SU 1189819 A SU1189819 A SU 1189819A SU 253345 A1 SU253345 A1 SU 253345A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- diluents
- adhesive composition
- polyvinyl alcohol
- ethylene glycol
- amount
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 13
- 230000000181 anti-adherence Effects 0.000 title claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- -1 alginate Chemical class 0.000 claims description 5
- 239000003085 diluting agent Substances 0.000 claims description 5
- 235000019441 ethanol Nutrition 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 3
- 230000003014 reinforcing Effects 0.000 claims description 3
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 229940072056 alginate Drugs 0.000 claims 1
- 235000010443 alginic acid Nutrition 0.000 claims 1
- 229920000615 alginic acid Polymers 0.000 claims 1
- 239000000945 filler Substances 0.000 claims 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 239000004698 Polyethylene (PE) Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N Caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000001681 protective Effects 0.000 description 2
- 229920001817 Agar Polymers 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N Hexamethylenediamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N Polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229940005550 Sodium alginate Drugs 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive Effects 0.000 description 1
- 239000008272 agar Substances 0.000 description 1
- 235000010419 agar Nutrition 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000002209 hydrophobic Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- MSXHSNHNTORCAW-UHFFFAOYSA-M sodium 3,4,5,6-tetrahydroxyoxane-2-carboxylate Chemical compound [Na+].OC1OC(C([O-])=O)C(O)C(O)C1O MSXHSNHNTORCAW-UHFFFAOYSA-M 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Description
При получении в пр01мышлен.ных услови х полиэтилена низкого давлени в растворе бензина в присутствии катализатора Циглера - Напа на внутренних стенках аппаратов и трубопроводов происходит интенсивное .нарастание налипающего полимера с примесью катализатора.In the production of low pressure polyethylene in gasoline solution in the presence of a Ziegler-Napa catalyst, on the inner walls of the apparatuses and pipelines, an intensive growth of the adhering polymer with admixture of the catalyst occurs.
Это преп тствует непрерывному протека.ниЕО процесса вследствие быстрого зарастани сечени аппарата (полимеризатора и трубопровода ).This impedes the continuous flow of the process due to the rapid growth of the cross section of the apparatus (polymerizer and pipeline).
Операпи очистки аппарата трудоемка, при этом антикоррозионное ла:ковое покрытие поверхности металла разрушаетс наиболее интенсивно и загр зн ет полиэтилен.Operator cleaning apparatus is laborious, while the anticorrosive la: the forging coating of the metal surface is destroyed most intensively and contaminates polyethylene.
Из;вестны антиадгезионные составы, содержащие поливиниловый спирт, воду, алшны, мочевино-формальдегидную смолу, анионоактнвные соединени , гликоли и спиртыOf; anti-adhesive formulations containing polyvinyl alcohol, water, alsna, urea formaldehyde resin, anionic compounds, glycols and alcohols are known
Сб-Сю и Сд.Sat-Xu and Sd.
Дл повышени продолжительности действи антиадгезнонного состава в него ввод т выс0комолекул р.ное студнеобразное соединение , нанример альги ат, натрийкарбоксиметилцеллюлозу , агар, желатину в количестве 5-10%, тлиперин 58-35%, сульфированное масло 10-20% н наполнители 7-5%, а поливиниловый спирт, этиленгликоль и разбавители- в количестве 10-15, 5-8 и 5-7% соответственно.To increase the duration of the anti-adhesive composition, high molecular weight R. gelatinous compound is added to it, nanografed algiatum, sodium carboxymethylcellulose, agar, gelatin in the amount of 5-10%, tliperin 58-35%, sulphonated oil 10-20% n excipients 7-5 %, and polyvinyl alcohol, ethylene glycol and diluents, in the amount of 10-15, 5-8 and 5-7%, respectively.
Кроме того, в состав ввод т армирующие материалы, а в качестве разбавителей - метиловый или этиловый спирт.In addition, reinforcing materials are introduced into the composition, and methyl alcohol or ethyl alcohol are used as diluents.
Пример 1. Рецептура состава (дл прессовани ), %:Example 1. Formulation formulation (for compression),%:
поливиниловый спирт10polyvinyl alcohol 10
альгинат натри 5sodium alginate 5
глицерин58glycerin58
этиленгликоль5 спирг этиловый или метиловый 5Ethylene glycol 5 alcohol ethyl or methyl 5
сульфированное масло10sulfonated oil10
бела сажа7white soot7
Пример 2. Рецептура состава (дл Example 2. Formulation formulation (for
лить ), %:pour),%:
поливиниловый с.ии.рт15polyvinyl s.irt15
натрийкарбоксиметилцеллюлоза10sodium carboxymethylcellulose10
глицерин35glycerin35
этнлеигликоль8ethnyleglycol8
спирт этиловый или метиловый7ethyl alcohol or methyl 7
сульфированное масло20sulfonated oil20
бела сажа5white soot5
Такое антиадгезионное покрытие в виде слоев достаточно прочного однородного студн в результате весьма медленного синерезиса всегда образует .на своей .поверхности тонкий скользкий слой нластнфикатора, предотвращающий образование новой гидрофобной фазы в виде налипщего полиэтилена.As a result of very slow syneresis, such an anti-adhesive coating in the form of layers of a sufficiently durable uniform gelding always forms on its surface a thin slippery layer of elasticizer that prevents the formation of a new hydrophobic phase in the form of adhered polyethylene.
Покрытие обладает химической стойко-стью в эксплуатации (долговечностью). Проведенные промышленные испытани подтверждают его высокую эффективность и продолжительность действи .The coating has chemical resistance in operation (durability). Conducted industrial tests confirm its high efficiency and duration of action.
Предлагаемое покрытие мож1но непрерывно использовать в .промышленных услови х в течение более 2500 час.The proposed coating can be continuously used in industrial conditions for more than 2500 hours.
Его нанос т а рабочую поверхность аппаратов и трубопроводов в виде сло толщиной 2-3 мм.It is applied to the working surface of apparatuses and pipelines in the form of a layer with a thickness of 2-3 mm.
Изготавливать айтиадгезионное покрытие можно г.ор чим прессованием, экструзией или литьем в -виде вкладышей, эластичных труб или колец, примен емых без наклейки.An IT adhesive coating can be made by pressing, extruding or casting in the form of inserts, elastic pipes or rings, used without a sticker.
При двухслойном варианте покрытие указанного выше состава наклеивают с образованием переходного сло на грунтов ку, наносимую непосредственно на поверхность металла или защитного а тикоррозионного лака (если он .предварительно .нанесен на металл).In the two-layer variant, the coating of the composition indicated above is glued to form a transition layer on the primers applied directly to the surface of the metal or protective ticking lacquer (if it is previously applied to the metal).
Слой грунтовки состоит из сополимера капролактама с гексаметилендиамином и диаминОВОЙ кислотой, совмещенной с поливиниловым спиртом, эпоксидной смолой или поливинилацетатной эмульсией. Така грунтовка обеспечивает прочиое сцепление с поверхностью металла или защитного лака, а а своей внешней поверхности-с антиадгезионным покрытием на основе поливинилового спирта.The primer layer consists of a copolymer of caprolactam with hexamethylenediamine and diamine acid, combined with polyvinyl alcohol, epoxy resin or polyvinyl acetate emulsion. This primer provides a firm adhesion to the surface of the metal or protective lacquer, and its outer surface with an anti-adhesive coating based on polyvinyl alcohol.
Антиадгезионный состав может быть также нанесен на армирующий материал, например стеклоткань, металлическую сетку и т. п.Anti-adhesive composition can also be applied to the reinforcing material, such as fiberglass, metal mesh, etc.
Предмет изобретени Subject invention
Claims (3)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU253345A1 true SU253345A1 (en) |
Family
ID=
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7265098B2 (en) * | 1999-12-27 | 2007-09-04 | Fziomed, Inc. | Polyacid/polyalkylene oxide gels and methods for their delivery |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7265098B2 (en) * | 1999-12-27 | 2007-09-04 | Fziomed, Inc. | Polyacid/polyalkylene oxide gels and methods for their delivery |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2420398C (en) | Polyamide-based compound for flexible pipes containing petroleum or gas | |
| EP2132030B1 (en) | Flexible pipes for conveying crude oil or gas and flexible pipe using a polyamide composition | |
| US5939492A (en) | Adhesion binder with glutarimide units moieties | |
| JPH0623928A (en) | Multilayer plastic tube and transport tube made of said tube for chemicals, etc. | |
| FR2896571A1 (en) | Multi-layer flexible hose, useful for the compressed air for brake systems of the high power vehicles, comprises a polyamide outer layer, optionally an intermediate layer and an inner layer of polymers with specific flexural moduli | |
| EP1378696B1 (en) | Hoses made of polyamide for compressed air | |
| CN1062285C (en) | Water resistant composition | |
| SU253345A1 (en) | ANTI ADHESIVE COMPOSITION | |
| RU2319887C2 (en) | Flexible pipe made of material including thermoplastic polymer and polyolefin and used in oil or gas field development (variants) | |
| JP4996471B2 (en) | Marine cable containing hydrolysis-resistant polyamide | |
| JP2009511676A (en) | Submarine umbilical containing hydrolysis-resistant polyamide | |
| JPH10246202A (en) | Gas impermeable elastic membrane and hydro-pneumatic accumulator provided with the membrane | |
| FR2759755A1 (en) | GAS WATERPROOF ELASTIC MEMBRANE AND HYDROPNEUMATIC ACCUMULATOR EQUIPPED WITH THIS MEMBRANE | |
| FR2727879A1 (en) | AQUEOUS COMPOSITION AND METHOD FOR TREATING HYDROPHILIZATION FOR A METAL MATERIAL CONTAINING ALUMINUM | |
| CN1840735A (en) | Steel sheet coated with chemical conversion film and process for producing the same | |
| JPS60255833A (en) | Elastomer tackiness enhancement | |
| CA2622819A1 (en) | Method for producing a plaster composition | |
| CA1270410A (en) | Polymeric antifouling compositions | |
| CN1087369A (en) | Multifunctional protective agent for tyre | |
| JPH0717880B2 (en) | NBR-based vulcanizing adhesive | |
| CN101046233A (en) | Brake member and bonding method | |
| JPH03265764A (en) | Laminate plate for gasket | |
| CN108676289A (en) | A kind of antifouling anti-corrosion sewage disposal special PVC pipeline and preparation method thereof | |
| CN112707932B (en) | Benzoxazine, preparation method thereof, coating and method for forming coating on surface of substrate | |
| CN217977809U (en) | Flexible composite pipe for gas transmission |