SU199849A1 - METHOD OF OBTAINING A DICIAN - Google Patents
METHOD OF OBTAINING A DICIANInfo
- Publication number
- SU199849A1 SU199849A1 SU1106702A SU1106702A SU199849A1 SU 199849 A1 SU199849 A1 SU 199849A1 SU 1106702 A SU1106702 A SU 1106702A SU 1106702 A SU1106702 A SU 1106702A SU 199849 A1 SU199849 A1 SU 199849A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- dician
- polar solvent
- obtaining
- aqueous polar
- cyanide
- Prior art date
Links
- IAHFWCOBPZCAEA-UHFFFAOYSA-N Succinonitrile Chemical compound N#CCCC#N IAHFWCOBPZCAEA-UHFFFAOYSA-N 0.000 title 1
- WEVYAHXRMPXWCK-UHFFFAOYSA-N acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 4
- XFXPMWWXUTWYJX-UHFFFAOYSA-N cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 239000002798 polar solvent Substances 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- 239000005749 Copper compound Substances 0.000 claims 2
- 150000001880 copper compounds Chemical class 0.000 claims 2
- 238000000034 method Methods 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 230000001590 oxidative Effects 0.000 claims 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L Copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- JMANVNJQNLATNU-UHFFFAOYSA-N Cyanogen Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- JXWXJWOMXJKLOG-UHFFFAOYSA-N disodium;copper(1+);tricyanide Chemical compound [Na+].[Na+].[Cu+].N#[C-].N#[C-].N#[C-] JXWXJWOMXJKLOG-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Description
Известен способ получени дициана взаимодействием сульфата меди и цианистого натри . Степень чистоты получаемого при этом продукта недостаточна , выход небольшой.A known method for producing cyanogen is the interaction of copper sulfate and sodium cyanide. The degree of purity of the resulting product is insufficient, the output is small.
Предложен способ получени дициана, по которому цианиды металлов окисл ют безводным куприхлоридом в среде неводного пол рного растворител , например ацетонитрила . По этому способу получают продукт высокой степени чистоты (99,5п/о), выход его до 80% и выше.A method for producing cyanide is proposed, in which metal cyanides are oxidized with anhydrous cupric chloride in a non-aqueous polar solvent, for example acetonitrile. According to this method, a product of high purity (99.5 p / o) is obtained, its yield up to 80% and higher.
Пример. В колбу, снабженную мешалкой , капельной воронкой, обратным холодильником и термометром, загружают смесь 51,8 г (0,39 моль) мелкоизмельченной безводной хлорной меди и 35,0 г (0,39 моль) цианистой закисной меди. Из канельной воронки приливают 50 мл сухого апетонитрила. Дл более полного протекани реакции реакционную смесь подогревают при непрерывном перемешивании до температуры, близкой к температуре кипени растворител . Газы из реакционной колбы проход т через обратный холодильник и три последовательно соединенные с ннм змеевиковые ловушки, охлаждаемые перва до -10°С, втора и треть до -40°С. В первой ловушке конденсируетс растворитель , во второй и третьей - дициан.Example. A mixture equipped with a stirrer, an addition funnel, a reflux condenser and a thermometer is charged with a mixture of 51.8 g (0.39 mol) of finely ground anhydrous chloric copper and 35.0 g (0.39 mol) of cyanide ferrous copper. 50 ml of dry apetonitrile are poured from the funnel. For a more complete reaction, the reaction mixture is heated with continuous stirring to a temperature close to the boiling point of the solvent. The gases from the reaction flask pass through a reflux condenser and three coil traps connected in series with the nanometer, cooled first to -10 ° C, second and third to -40 ° C. In the first trap the solvent is condensed, in the second and third - dicyan.
Получают 8,26 г (81,5о/о) дициана, содержаш ,его 39,5о/о основного вещества.This gives 8.26 g (81.5 o / o) of cyanogen containing 39.5 o / o of the basic substance.
Предмет изобретени Subject invention
Claims (2)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU199849A1 true SU199849A1 (en) |
Family
ID=
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4003983A (en) * | 1970-03-17 | 1977-01-18 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process of preparing dicyan |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4003983A (en) * | 1970-03-17 | 1977-01-18 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler | Process of preparing dicyan |
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