SU199313A1 - METHOD OF OBTAINING MOTOR OIL - Google Patents
METHOD OF OBTAINING MOTOR OILInfo
- Publication number
- SU199313A1 SU199313A1 SU1068982A SU1068982A SU199313A1 SU 199313 A1 SU199313 A1 SU 199313A1 SU 1068982 A SU1068982 A SU 1068982A SU 1068982 A SU1068982 A SU 1068982A SU 199313 A1 SU199313 A1 SU 199313A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- motor oil
- barium
- obtaining motor
- pms
- oil
- Prior art date
Links
- 239000010705 motor oil Substances 0.000 title description 2
- 239000000654 additive Substances 0.000 description 11
- 230000000996 additive Effects 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 229910052788 barium Inorganic materials 0.000 description 6
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium(0) Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- CXQXSVUQTKDNFP-UHFFFAOYSA-N Simethicone Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- WMYJOZQKDZZHAC-UHFFFAOYSA-H trizinc;dioxido-sulfanylidene-sulfido-$l^{5}-phosphane Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([S-])=S.[O-]P([O-])([S-])=S WMYJOZQKDZZHAC-UHFFFAOYSA-H 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-M salicylate Chemical compound OC1=CC=CC=C1C([O-])=O YGSDEFSMJLZEOE-UHFFFAOYSA-M 0.000 description 2
- 229960001860 salicylate Drugs 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-L dithiophosphate(2-) Chemical compound OP([O-])([S-])=S NAGJZTKCGNOGPW-UHFFFAOYSA-L 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Description
Высокофорсировапные двигатели требуют масел с хорошими моющими, диспергирующими и противоизиосными свойствами. Дл обеспечени этих свойств к минеральным маслам добавл ют различные металлосодержащие присадки (алкилфенольные, алкилсалицилатные , сульфонатные, дитиофосфатные и др.), в состав которых вход т кальций, барий, магний, цинк и другие металлы.High-performance engines require oils with good detergent, dispersing and antiisosomal properties. To provide these properties, various metal-containing additives (alkylphenolic, alkylsalicylate, sulfonate, dithiophosphate, etc.) are added to mineral oils, which include calcium, barium, magnesium, zinc, and other metals.
Дл получени масел с высокими моющими и диспергирующими свойствами к ним приходитс добавл ть значительные количества присадок (10-15%). Однако при этом получаютс масла с высокой зольностью, что в р де случаев ведет к образованию в камере сгорани высокофорсированиых дизелей твердых зольных отложений. Зольные отложеии образуютс на детал х, имеющих высокие температуры (днище поршн , выхлопные клапаны, перва поршнева канавка), и нарушают нормальную работу двигател , вызыва прогар выхлопных клапанов, изиос и надиры цилиндровых втулок , поршневых колец и поршней.To obtain oils with high detergent and dispersant properties, significant amounts of additives must be added to them (10-15%). However, oils with high ash content are obtained, which in a number of cases leads to the formation in the combustion chamber of highly forced diesel engines of solid ash deposits. Ash deposits are formed on parts having high temperatures (piston bottom, exhaust valves, first piston groove), and disrupt the normal operation of the engine, causing burnout of exhaust valves, Izios and nadir cylinder sleeves, piston rings and pistons.
С целью улучшени эксплуатационных свойств, предлагаетс добавл ть к масл ной основе композицию присадок, состо щую из алкилсалицилата бари (АСБ), высокозольного сульфоната бари (ПМС-Ва), дитиофосфата цинка (ДФ-11) и кремнеорганической присадки (ПМС-200А). Зольные отложени этой композиции присадок имеют высокую температуру плавлени и м гкую структуру.In order to improve the performance properties, it is proposed to add to the oil-based additive composition consisting of barium alkyl salicylate (ASB), high-ash barium sulfonate (PMS-Ba), zinc dithiophosphate (DF-11) and silicon additive (PMS-200A). The ash deposits of this additive composition have a high melting point and a soft structure.
В таблице приведены температуры начала плавлепи зольных отлон ;еннй различных композиций присадок и характер структуры этих отложений.The table shows the onset temperatures of melting ash solids; enny of various additive compositions and the nature of the structure of these deposits.
Композици присадок, добавл ема к маслу в соотношении 8% АСК (алкилсалицилат кальци ) ПМС-Са (сульфонат кальци ) + 1,2% ДФ-11 +0,001% ПМС-200А, образующа зольные отложени с температурой начала плавлени 737° С и жесткой структурой, вызывает массовый прогар выхлопных клапапов судового двигател Д-42 за 500 час работы.The additive composition added to the oil in a ratio of 8% ASA (calcium alkyl salicylate) PMS-Ca (calcium sulfonate) + 1.2% DF-11 + 0.001% PMS-200A, forming ash deposits with a melting point of 737 ° C and hard structure, causes a massive burnout of the exhaust valves of the ship's engine D-42 for 500 hours of work.
Композици присадок 8% АСБ (алкилсалицинат бари ) +3% ПМС-Ва (сульфонат бари ) + 1,2% ДФ-11 -f 0,001%, ПМС-200А, образующа зольные отложени с температурой начала плавлени выше 1100° С и м гкой структурой, обеснечивает за 500 час работы того же двигател хорошее состо ние выхлопных клапанов и отсутствие плеики на их фаске . Предмет изобретени Способ получени моторного масла дл форсированных дизелей добавлением к масл ной основе композиции присадок, отличающийс 5 тем, что, с целью улучшени эксплуатационных свойств масла, добавл ют композицию присадок , состо щую из алкилсалицилата бари , высокопделочного сульфоиата бари , дитиофосфата цинка и кремнеорганической присадки.The composition of additives is 8% ASB (barium alkylsalinate) + 3% PMS-Ba (barium sulfonate) + 1.2% DF-11 -f 0.001%, PMS-200A, forming ash deposits with a melting start temperature above 1100 ° C and soft by the structure, for 500 hours of operation of the same engine, the good condition of the exhaust valves and the lack of flex on their chamfer. The subject of the invention is a method for producing engine oil for forced diesel engines by adding additives to an oil-based composition, characterized in 5 in that, in order to improve the performance properties of the oil, an additive composition consisting of barium alkylsalicylate, high-grade barium sulfoate, zinc dithiophosphate and an organosilicon additive is added .
Publications (1)
Publication Number | Publication Date |
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SU199313A1 true SU199313A1 (en) |
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