SU1645277A1 - Method for applying antistatic coating to polymeric materials - Google Patents

Method for applying antistatic coating to polymeric materials Download PDF

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Publication number
SU1645277A1
SU1645277A1 SU874342317A SU4342317A SU1645277A1 SU 1645277 A1 SU1645277 A1 SU 1645277A1 SU 874342317 A SU874342317 A SU 874342317A SU 4342317 A SU4342317 A SU 4342317A SU 1645277 A1 SU1645277 A1 SU 1645277A1
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USSR - Soviet Union
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eleven
stains
thirteen
fifteen
weight
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SU874342317A
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Russian (ru)
Inventor
Светлана Алексеевна Верухина
Лариса Андреевна Бударина
Евгений Васильевич Кузнецов
Татьяна Степановна Лучихина
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Казанский Химико-Технологический Институт Им.С.М.Кирова
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Priority to SU874342317A priority Critical patent/SU1645277A1/en
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Publication of SU1645277A1 publication Critical patent/SU1645277A1/en

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Abstract

Изобретение относитс  к области получени  полимерных антистатических покрытий. Изобретение позвол ет по- вчснть влагостойкость покрытий за счет получеш   покрытий путем нанесени  на полимерную подложку композшцш состапа, лас.ч.: сополимер метакрило- вон кислотн с N-валероилметакрилами- дом при содержании кислоты 65-85 мас.% от 1,0 до 3,0; полиэтштенполиамин от 0,02 до 0,06; вода ел 96,94 до 93,98, и последующей сутой при 75-85°С в течет: с 4-6 ч. 2 табл. 3 (ЛThis invention relates to the field of polymer antistatic coatings. The invention allows the water resistance of coatings to be obtained by making half-coatings by applying a composite coating on a polymer substrate, as follows: methacrylonone acid copolymer with N-valeromethacrylamide with an acid content of 65-85% by weight from 1.0 to 3.0; polyetherpolyamine from 0.02 to 0.06; water ate 96.94 to 93.98, and the following day at 75-85 ° C flows: from 4-6 hours. 2 tabl. 3 (L

Description

(СН2): СН7(CH2): CH7

Продолжение табл. 2Continued table. 2

римечание.note

Во всех примерах по изобретению адгези  покрыти  к полимерным подложкам равна 1 баллу.In all examples according to the invention, the adhesion of the coating to the polymer substrates is 1 point.

т щие однородные , без матовых п тен, отслаиваний , раэmelting uniform, without matte spots, flaking, rae

Подложка 7,82.10Substrate 7,82.10

1,035-10 5,41-Ю9 1,55-10 2,79-101,035-10 5,41-Ю9 1,55-10 2,79-10

0,505-Ю9 0,70-10 4,65-Ю90,505-Ю9 0,70-10 4,65-Ю9

6,975-Ю9 2,17-Н) 8,0340 6,05-10 4,18- 10 0,80-10 6,4010 0,70406.975-U9 2.17-H) 8.0340 6.05-10 4.18- 10 0.80-10 6.4010 0.7040

2 И2 and

1,60 Ю 3,76-10 4,36-10 8,83-10 7,28-10 3,96-10 4,84- 10 6,71-10 Подложка 4,26 -10 1.60 Yu 3.76-10 4.36-10 8.83-10 7.28-10 3.96-10 4.84- 10 6.71-10 Substrate 4.26 -10

|Ј 1 12 | Ј 1 12

4242

12 41 12 12 12 11 12.12 41 12 12 12 11 12.

22

33

5five

77

1one

22

33

5five

77

6,46.4

8,6 3,768.6 3.76

7,8 5,34 4,867.8 5.34 4.86

3,2 1,55 0,34 6,65 8,48 0,18 1,703.2 1.55 0.34 6.65 8.48 0.18 1.70

6,3 2,74 5,18 3,616.3 2.74 5.18 3.61

10 10 10 10 -10 10Ч 10 10 10 10 10 -10 10Ч 10

ОABOUT

10ten

10 10 1010 10 10

ю1y1

.10.ten

-10-ten

10ten

10ten

10ten

«"

1212

(2 «(2 "

Таблица2Table 2

винипласт 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 2 2 2 2Viniplast 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 7 2 2 2 2

2 , слоисто-декоративный пластик2, laminated decorative plastic

Ровные, однородные , без отслаивани  и матовых п тен То жеSmooth, uniform, without peeling and dull spots. Same

м || || ||m || || ||

|| 11 |||| 11 ||

Покрыти  ровные , однородные , без отслаивани  и матовых п тенCover smooth, uniform, without peeling and matt stains.

То же иSame thing

6 6

6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6 66 6 6 6 6 6 6 6 6 6 6 6 6 6 6 6

Ровные, блест 0 tine однородные, Smooth, glossy 0 tine homogeneous,

без отслаиванийwithout flaking

и матовых п тенand matte pen

То жеAlso

Claims (5)

Формула изобретенияClaim Способ получения антистатического покрытия на полимерных материалах пу тем нанесения на их поверхность композиции на основе водного раствора карбоксилсодержащего акрилового сополимера с последую1цей сушкой, о т л и ч а ю ч и й с я тем, что, с целью повышения влагостойкости, наносят композицию состава, мас.ч.:A method of obtaining an antistatic coating on polymeric materials by applying to their surface a composition based on an aqueous solution of a carboxyl-containing acrylic copolymer, followed by drying, coating with the aim of increasing the moisture resistance by applying a composition composition parts by weight: Сополимер метакриловой кислоты с N-валероилметакриламидом с содержанием кислоты 6585 мас.% 1-3A copolymer of methacrylic acid with N-valeroyl methacrylamide with an acid content of 6585 wt.% 1-3 Полиэтиленполиамин 0,02-0,06Polyethylene Polyamine 0.02-0.06 Вода 96,94-98,98, а последующую сушку осуществляют путем термообработки при 75-85°С в течение 4-6 ч.Water 96.94-98.98, and subsequent drying is carried out by heat treatment at 75-85 ° C for 4-6 hours Таблица 1Table 1 При- At- Солер- Soler Количе- Quantity [Количе- [Quantity Количе— Quantity— мер measures жание burning ство state 'ство 's ство state кисло- sour с о пол и- with about gender and (ПОЛИ- (POLY- воды, water, ТЫ в YOU in мера measure этилен- ethylene- мас.ч. на parts by weight on the сопо- co- МАК с IAC with поли- poly- 100 мас.ч 100 parts by weight лиме- limo N-BMA, N-BMA амина, amine компо- compo ре, re мае.ч. m.ch. мас.ч. parts by weight зиции position i i мас.% wt.% на on the на 100 at 100 100 мае ч 100 may h мае.ч. m.ch. компо- compo компо- compo зиции position зиции position 2 2 75 75 1 1 0,02 0.02 98,98 98.98 3 3 85 85 1 1 0,02 0.02 98,98 98.98 4 4 65 65 2 2 0,04 0.04 97,96 97.96 5 5 75 75 2 2 0,04 0.04 97,96 97.96 6 6 85 85 2 2 0,04 0.04 97,96 97.96 7 7 65 65 3 3 0,06 0.06 96,94 96.94 8 8 75 75 3 3 0,06 0.06 96,94 96.94 9 9 85 85 3 3 0,06 0.06 96,94 96.94 10 10 65 65 0.5 0.5 0,01 0.01 99,49 99.49 11 eleven 75 75 0,5 0.5 0,01 0.01 99,49 99.49 12 12 85 85 0,5 0.5 0,1 0.1 99,49 99.49 13 thirteen 65 65 4 4 0,08 0.08 95,92 95.92 14 14 75 75 4 4 0,08 0.08 95,92 95.92 15 fifteen 85 85 4 4 0,08 0.08 95,92 95.92
; Продолжение табл.; Continuation of the table. 2 < 22 <2 33 44 19 ' 19 ' 7,83*10° 7.83 * 10 ° 6 6 _11_ _eleven_ 20 20 7,38.10” 7.38.10 ” 2 2 21 21 1,84.1015 1.84.10 15 2 2 22 22 0,36 · 10*f 4,21 ·10*3 5,43 · 10 Подложка -0.36 · 10 * f 4.21 · 10 * 3 5.43 · 10 Substrate - 2 2 23 23 2 2 — П —- P - 24 24 2 плитка ПВХ 2 PVC tile — П —- P - 1 1 2,79-10’ 2.79-10 ’ 7 7 Ровные, блестящие однородные, без матовых пятен, отслаиваний, разводов Smooth, shiny uniform, without dull spots, exfoliation, stains 2 2 6,2-10’ 6.2-10 ’ 7 7 То же Also 3 3 4,7-10’ 4.7-10 ’ 7 7 —” — - ”- 4 4 0,41·1θ’ 0.41 · 1θ ’ 7 7 5 5 1,395-Ю4 1,395-U 4 7 7 —” — - ”- 6 6 1,2.4-10’ 1,2.4-10 ’ 7 7 — ” — - ”- 7 7 2,48-10’ 2,48-10 ’ 7 7 8 8 6,25*10’ 6.25 * 10 ’ 7 7 9 9 0,16-104 3^8- 10’2 0.16-10 4 3 ^ 8-10 ' 2 7 7 10 10 7 7 __ 11_ __ eleven_ 1 1 eleven 6,34· 10*' 6.3410 * ' 7 7 _<|_ _ <| _ 12 12 . 9,3-10° . 9.3-10 ° 7 7 13 thirteen 4,7 ЧО’2 4.7 HO ' 2 7 7 14 14 2,38-10 12 2.38-10 12 7 7 15 fifteen 6,21 · 1011 6.2110 11 7 7 — П —- P - 16 16 7>4-1О° 7 > 4-1 ° C 7 7 — П —- P - 17 17 3,79 40* 3.79 40 * 7 7 — Н-.- N -. 18 18 2,13-10* 4,71 ,10L2.13-10 * 4.71 , 10 L 7 7 — п —- n - 19 19 7 7 — п —- n - 20 20 3,55 4 0* 3.55 4 0 * 2 2 —п —- n - 21 21 5,24-10* 5.24-10 * 2 2 22 22 7,23-10й 7,23-10 th 2 2 —И — —And - 23 23 2,73· 10* 2.7310 * 2 2 —’i — —’I - 24 24 8,76-10* 8.76-10 * 2 2 —’ί — —’Ί -
По прототипуAccording to the prototype на вини- 12 пласте 1,6-10 on vinyl 12 layer 1.6-10 1 1 Отслаивания, разводы Peeling, stains на слоде- on the коре 4,3’10° bark 4.3’10 ° 1 1 То же Also на плит- on the plates ке ПВХ 1,7-10.’ ke PVC 1.7-10. ’ О ABOUT Вез отслаиваний, однородные No flaking, uniform Примечание. Note. Во всех примерах по In all examples of изобретению invention адгезия adhesion покрытия к cover to полимерным polymer
подложкам равнаsubstrates equal 1 баллу.1 point. 5 1645277 6 5 1645277 6 Таблица2Table 2 Покрытие по примеру Example coating р5, Онp 5 He — Количество влажных обработок - Number of wet treatments Качество покрытий Coating quality 4 4 2 2 3 3 4 4
Подложка - Substrate - винипласт vinyl plastic 1 1 7,82 7.82 . 10’ . 10' 7 7 Ровные, одно- Smooth, single 2 2 1,085 1,085 . 10’ . 10' 7 7 родные, без relatives, without 3 3 5,41 5.41 • 10’ • 10' 7 7 отслаивания peeling 4 4 1,55 1.55 • 10’ • 10' 7 7 и матовых and matte 5 5 2,79 2.79 • 10’ • 10' 7 7 пятен spots 6 6 0,505 0.505 • ю’ • Yu' 7 7 То же Also 7 7 0,70 0.70 • 10’ • 10' 7 7 8 8 4,65 4.65 • 10’ • 10' 7 7 _П — _P - 9 9 6,975 6,975 • 10’ • 10' 7 7 —п—- n - 10 10 2,17 2.17 ·1θ’Ζ 1θ ' Ζ 7 7 — п—- n - 11 eleven 8,03 8.03 ’ ю” ' Yu" 7 7 —п—- n - 12 12 6,05 6.05 • ю’‘ • Yu'' 7 7 . !1 — . ! 1 - 13 thirteen 4,18 4.18 7 7 —,,—> - ,, - > 14 14 0,80 0.80 - ίο12 - ίο 12 7 7 — Н —- N - 15 fifteen 6,40 6.40 7 7 Покрытия ров- Ditch Coatings 16 16 0,70 0.70 7 7 ные, однород-. ny, homogeneous. 17 17 1 ,60 1, 60 7 7 ные, без от- ny, without 18 18 3,76 3.76 7 7 слаивания и layering and 19 19 4,36 4.36 • 10υ • 10 υ 7 7 матовых пятен matte stains 20 20 8,83 8.83 • 10U • 10 U 2 2 То же Also 21 21 7,28 7.28 • ю’2 • u ' 2 2 2 __ 1»_ __ 1"_ 22 22 . 3,96 . 3.96 •10 ί • ю’2 • 10 ί • yu ' 2 2 2 23 23 4,84 4.84 2 2 24 24 6,71 6.71 • ю12 • 12 2 , 2 — ” — - ”- Подложка - Substrate - слоисто-декоративный пластик laminated decorative plastic 1 1 4,26 · 4.26 10’ 10' 6 ~ 6 ~ Ровные, блестя- 0 щие однородные, без отслаиваний и матовых пятенSmooth, shiny - homogeneous, without peeling and matte stains 2 2 6,4 6.4 ю9 w 9 6 6 То же Also 3 3 8,6 8.6 ю9 w 9 6 6 —” — - ”- 4 4 3,76 3.76 10’ 10' 6 6 5 5 7,8 7.8 109 10 9 6 ’ 6 ’ 6 6 5,34 5.34 ю9 w 9 6 6 7 7 4,86 4.86 ю9 w 9 6 6 8 8 3,2 3.2 ю’ Yu' 6 6 _н_ _n_ 9 9 1,55 1.55 ч 1θ’ h 1θ ’ 6 6 —**— - ** - 10 10 0,34 0.34 6 6 11 eleven 6,65 6.65 ю12 10 о 10 12 o 6 6 —п —- n - 12 12 8,48 8.48 6 6 13 thirteen 0,18 0.18 6 6 —п —- n - 14 14 1,70 1.70 10 2 10 2 6 6 15 fifteen 6,3 6.3 10° 1012 10 ° 10 12 6 6 16 16 2,74 2.74 6 6 — ” — - ”- 17 17 5,18 5.18 10° 10 ° 6 6 — - 18 18 3,61 3.61 10<2 10 <2 6 6
SU874342317A 1987-12-14 1987-12-14 Method for applying antistatic coating to polymeric materials SU1645277A1 (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994029401A1 (en) * 1993-06-07 1994-12-22 Vitaly Iliich Kryshtob Process for obtaining antistatic polymer compounds
US5576383A (en) * 1993-06-07 1996-11-19 Kryshtob; Vitaly I. Method for production of antistatic polymer materials
CN1055718C (en) * 1993-06-07 2000-08-23 维塔利·伊里奇·克里施托波 Process for obtaining antistatic polymer compounds

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Авторское свидетельство СССР f 3310С 8, кл. С 08 Л 7/04, 1966. Авторское свидетельство СССР К 225443, кл. С 08 F 220/06, 196Г,. Авторское свидетельство СССР № 1141101, кл. С 08 F 220/34, 1983. *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1994029401A1 (en) * 1993-06-07 1994-12-22 Vitaly Iliich Kryshtob Process for obtaining antistatic polymer compounds
US5576383A (en) * 1993-06-07 1996-11-19 Kryshtob; Vitaly I. Method for production of antistatic polymer materials
CN1055718C (en) * 1993-06-07 2000-08-23 维塔利·伊里奇·克里施托波 Process for obtaining antistatic polymer compounds

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