SU1191486A1 - Solution for chemical passivation of copper and its alloys - Google Patents

Solution for chemical passivation of copper and its alloys Download PDF

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Publication number
SU1191486A1
SU1191486A1 SU843735302A SU3735302A SU1191486A1 SU 1191486 A1 SU1191486 A1 SU 1191486A1 SU 843735302 A SU843735302 A SU 843735302A SU 3735302 A SU3735302 A SU 3735302A SU 1191486 A1 SU1191486 A1 SU 1191486A1
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SU
USSR - Soviet Union
Prior art keywords
solution
copper
alloys
chemical passivation
benzotriazole
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Application number
SU843735302A
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Russian (ru)
Inventor
Виктория Васильевна Орехова
Алина Григорьевна Мозговая
Владимир Иванович Пискарев
Зоя Николаевна Андреева
Original Assignee
Харьковский Ордена Ленина Политехнический Институт Им.В.И.Ленина
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Priority to SU843735302A priority Critical patent/SU1191486A1/en
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Abstract

РАСТВОР ДЛЯ ХИМИЧЕСКОГО ПАССИВИРОВАНИЯ МЕДИ И ЕЕ СПЛАВОВ, содержащий бензотриазол, о т л .и ч а ю щ и и с   тем, что, с целью уме11ьше ни  дефектности и улучшени  защитных свойств пассивной пленки, он дополнительно содержит метаналь и клей животный при следующем соотношении . компонентов, мас.%: Бензотриазол 0,2 - 0,6 Метаналь0,05-0,08 Клей животный 0,01-0,03 ВодаОстальное.SOLUTION FOR CHEMICAL PASSIVATION OF COPPER AND ITS ALLOYS, containing benzotriazole, is so that, in order to reduce the defects and improve the protective properties of the passive film, it additionally contains methanol and animal glue in the following ratio . components, wt.%: Benzotriazole 0,2 - 0,6 Metanal 0.05-0.08 Animal glue 0.01-0.03 Water Remaining.

Description

СWITH

Изобретение относитс  к защите от коррозии, в частности к раствору дл  химического-пассивировани  меди.и ее crolaBOB. The invention relates to protection against corrosion, in particular to a solution for the chemical passivation of copper and its crolaBOB.

Цель изобретени  - уменьшение де- 5 фектности и улучшение защитных свойств пассивной пленки, ,, Сущность изобретени  заключаетс  в том, что дл  пассивации меди и ее 1Й1Лавов используют раствор, содержа О щий, мас..%:The purpose of the invention is to reduce the defects and improve the protective properties of the passive film, ,, The essence of the invention is that for the passivation of copper and its 1X1Lavs, a solution containing O ..% is used:

Бензотриазол . 0,2-0,6 Метаналь . 0,05-0,08 Клей животный 0,01-0,03 Вода . Остальное 15 Процесс нанесени  пассивной пленки ведут при 40-80°С в течение 0,331ч ..Benzotriazole. 0.2-0.6 Metanal. 0.05-0.08 Animal glue 0.01-0.03 Water. The rest 15 The process of applying a passive film is carried out at 40-80 ° C for 0.331 hours.

Присутствие в растворе кле  живот-20 ного и метанал  способствует заполHeHiiio пор, имеющих в пленке, и ее уплотнению. гThe presence in the glue solution of the stomach and methane contributes to the filling of the pores in the film and its compaction. g

Раствор сохран етс  в течение дли-25 тельного време.ни.The solution is maintained for a long time.

Изобретение иллюстрируетс  следующими примерами.The invention is illustrated by the following examples.

Раствор пассивировани  готовитс  следующим образом. Все компоненты раствор ютс  в о.тдельных порци х во .ды и сливаютс  в последовательности: бензотриазол, метаналь, клей животный . Объем раствора довод т водой до нужного значени . The passivation solution is prepared as follows. All components are dissolved in approximately portions of water and merged in the sequence: benzotriazole, methane, animal glue. The volume of the solution is adjusted with water to the desired value.

Примеры раствора дл  химического пассивировани  меди и ее сплавов представлены в табл. 1.Examples of the solution for the chemical passivation of copper and its alloys are presented in Table. one.

Вли ние концентрации компонентов пассивирующего раствора и режима обработки на снижение дефектности пленок представлено в табл. 2.The effect of the concentration of the components of the passivating solution and the mode of treatment on the reduction of the defects of the films is presented in Table 2

Ускоренные коррозионные испытани  осуществл лись в двух.коррозионных средах: 3%-ный раствор натри  хлористого и влажна  ткань. Результаты испытаний представлены в табл.. 3.Accelerated corrosion tests were carried out in two corrosive environments: 3% sodium chloride solution and a damp cloth. The test results are presented in table. 3.

Длительна  зксплуатаци  раствора показала, что он сохран ет устойчивость по составу и качеству плен2Prolonged operation of the solution showed that it retains stability in composition and quality of the film2.

ки при обработке до 100 дм поверх-; ности в 1 л раствора. . . .ki when processing up to 100 dm surface; 1 liter of solution. . . .

Т а б л и ц а J T a b l and c a J

Пол ризационное сопротивление, определ лось измерений. из трех параллельных  The polarization resistance was determined by measurements. of three parallel

40 60 80 60 6040 60 80 60 60

60 60 60 6060 60 60 60

2 3 4 5 62 3 4 5 6

60 6060 60

ТаблицаЗTable3

2323

-24-24

24,524.5

25,525.5

22,522.5

23,823.8

23,323.3

14,314.3

7,57.5

9,5 9.5

. 14,0. 14.0

Claims (1)

РАСТВОР ДЛЯ ХИМИЧЕСКОГО ПАССИВИРОВАНИЯ МЕДИ И ЕЕ СПЛАВОВ, содержащий бензотриазол, отличающ и й с я тем, что, с целью уменьшения дефектности и улучшения защитных свойств пассивной пленки, он дополнительно содержит метаналь и клей животный при следующем соотношении компонентов, мас.%:A SOLUTION FOR CHEMICAL PASSIVATION OF COPPER AND ITS ALLOYS, containing benzotriazole, characterized in that, in order to reduce the defectiveness and improve the protective properties of the passive film, it additionally contains methanal and animal glue in the following ratio, wt.%: Бензотриазол Benzotriazole 0,2 - 0,6 0.2 - 0.6 Метаналь Methanal 0,05-0,08 0.05-0.08 Клей животный Animal glue 0,01-0,03 0.01-0.03 Вода Water Остальное. Rest.
соwith I 191486I 191486
SU843735302A 1984-04-29 1984-04-29 Solution for chemical passivation of copper and its alloys SU1191486A1 (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
SU843735302A SU1191486A1 (en) 1984-04-29 1984-04-29 Solution for chemical passivation of copper and its alloys

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Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Патент GB № 907793, кл. 94.1 .С, I960. Патент GB № 933979, кл. I23.I.D, 1962. *

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