SU1052164A3 - Method for continuous gasification of coal - Google Patents
Method for continuous gasification of coal Download PDFInfo
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- SU1052164A3 SU1052164A3 SU762355407A SU2355407A SU1052164A3 SU 1052164 A3 SU1052164 A3 SU 1052164A3 SU 762355407 A SU762355407 A SU 762355407A SU 2355407 A SU2355407 A SU 2355407A SU 1052164 A3 SU1052164 A3 SU 1052164A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- oxygen
- coal
- pipe
- containing gas
- contg
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/42—Constructional features of converters
- C21C5/46—Details or accessories
- C21C5/48—Bottoms or tuyéres of converters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/57—Gasification using molten salts or metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/74—Construction of shells or jackets
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/74—Construction of shells or jackets
- C10J3/76—Water jackets; Steam boiler-jackets
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/30—Regulating or controlling the blowing
- C21C5/34—Blowing through the bath
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/152—Nozzles or lances for introducing gas, liquids or suspensions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0969—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C10J2300/0976—Water as steam
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Industrial Gases (AREA)
- Manufacture Of Iron (AREA)
Abstract
Description
Изобретение относитс к способам переработки углеродсодер ащего оырь в частйости к способу непрерывной газификации угл . Известен способ непрерывйой газификации угл в футерованном peakторе с расплавленным металле, BKJTO чающий подачу угл и кисло|зоДсо ержаадего газа в реактор ниже уровн расплавленного металла по трубам введенным в расплавленный металл и последук цую газиФлкацию угл f 1 J НедЬстатком известного способа вл етс частое прерывание процесса дл замены труб и неудовлетврритедь ное качество получаемого газаг чтЬ отрицательно сказываетс на: производительности процесса, : Цель изобретени - повышейие про изводительностй процесса. Поставленна цель достигаетс тем что соглас.но способу непрерывной га зификации угл в футерованном реакторе с расплавленным металлом, вклю чающему подачу угл и кислородсодер жащего газа в реактор ниже уровн расплавленного Металла и последующую газификацию, уголь и .кислородсодер жащий газ подгиот в расплавленйый ме талл посредством конЦентрично уста нов ленных труб, выходные сопла ко торых расположены на уровне Футеровк С уменьшени износа трубы дл . подачи кислородсодержшцего taa-a подают .|7азо6браэйые или жидкие углеводороды посредством трубы, расположенной конЦейтрично по отношению к трубе дл подачи кйслородсоДер жащего газа, или в трубу дл подачи угл ввод т газообразные или жидкие углеводороды. Перед подачей в расплавленный металл уголь смешивают. ,с кислородсодержащим газов в трубе дл йодачи кислородсодержащего газа, потоку . угл сообщают вращательйое движение П р и м ер 1 Процесс непрерывной газификации провод т в футеррвайном реакторе емкостью 20 м, снаб женном четырьм соплами в днище, ка сдое из которых выполнено из трех концентрично установленных труб выходные отверсти которых располо жены на уровне футеровки . Центральна труба каждого сопла диаметром в свету 10 мм служит дл подачи угольной пыли. Кольцевой зазор между внутренней и второй трубами шириной 3 мм служит дл подачи кислорода, а по наружному кольцевому зазору между второй и третьей трубами шириной 1 мм подают пропан Реактор содержит 30 т расплавленного железа, в состав которого входит 1,5-2,5% углерОда. Температура расплава 137 0-1450 С. В расплавленный 4eтгuпл ввод т 12000 кг/ч угл , 10800 ймуч О и , 216 нмЗ/Ч пропана., При этом получают 25000 . газа содержащего, %: СО 65,5Г Йу 34,2 и СО 0,3. В течение одного МесЯцё (720 ч) сопла равномерно обогревают йа 200 мм без нарушений процесса газификации . По истечении указаннрго периода процесс прекращают Дл замены сопел. П р .и М е Р 2. Повтор ют пример 1 с той разницей. Что реагенты подают по соплам, расположенным в боКОвой стенке реактора ниже уровн металла.При этом получают 25000 газа, содержащего, %: СО 65,51 Т |Н 34,3 и СО, 0,2.Процесс провод т без ; каких-либо нарушений в течение 740 Ч . П Риме р 3. Повтор ют пример 1 с той разницей, реагенты подают йо с.оплам,, каждое :из которых вып,6л-1 йено Из двух концейтрично располоЯсенньос труб. При этом по внутренней трубе подают уголь вместе : прОпаноМ , а ЙО кольцевому зазору между внутрейней и наружной трубами подает кислород. Получают 25000 нмЗ/ч газа следующего состава %5 СО 65,5/ Bg 34,2 и СО 0,3. Процесс провод т без Каких-л Во йарущёний в течение :ббо.ч.- ;:- .: .- ,: : .. . .при Me р 4, Иовтор ют пример 3 с той разницей, что потоку угл сорбщают вращательйое движение. При этом в течейие ч получают г -s 25000 ймЗ/ч раза состава, % СО 65,5j Н2 и COg , При Me р 5 Повтор ют Пример 1 . с ТОЙ pasHHitei - - что процесс провид т в футерованйом реакторе емкостью 20 м сйаб: ениом четырьм соплами в дншсе, каждое йд которык выполнено Из койцентрично установленных труб. RO Вйутренней трубе подают угОйь, а по кольцевому зазору Между внутренйей и йаружйой трубами 1 |сйслород, ; ;,;-;, : , ,- /. Яри этоМ.й 400 ч получают 25000 газа соотава, %$ СО 65,ЗГ Н. 34,Э и СО 0,4. По истечении указаййОго периода.процесс j прекращают дл замены сопел. Приме р 6. Повтор ют пример 1 о той разййцей чТО вМесто йропайа йо йару ейому кольцевому зазору подают йрйродйый газ. При этом s . ТечейИе 720 j получают 25000 газа,содержащего. It со 65,5 Н,, 34,2 и СРг 0,2. , Ир и м е р ;7 сравйительйый, согласно прототипу) Повтор ют пример 1 с той разницей что процесс газификации провод т в футерованном реакторе емкостью 20 м, снабженном раздельными трубами дл подачи угл и кислорода, установленными в боковой стенке в противоположных местах. Выходные отверсти трубы диаметром 100 мм дл подачи угл и трубы ди/ - . Э : 10521644The invention relates to methods for processing carbon-containing gas, in particular, to a method for continuous gasification of coal. The known method of continuous gasification of coal in a lined peakor with a molten metal, BKJTO, which feeds coal and acidic gas of a second gas into the reactor below the level of the molten metal through pipes introduced into the molten metal and the subsequent gasification f 1 J A known method is partly broken. for the replacement of pipes and the poor quality of the gas produced, which adversely affects: the productivity of the process: The purpose of the invention is to increase the productivity of the process. This goal is achieved by the fact that according to the method of continuous gasification of coal in a lined reactor with molten metal, including the supply of coal and oxygen-containing gas to the reactor, is lower than the level of the molten Metal and subsequent gasification, coal and oxygen-containing gas will be poured into molten metal. centrally installed pipes, the output nozzles of which are located at the level of Lining C to reduce wear of the pipe for. oxygen-containing taa-a is supplied. 7-7 straight or liquid hydrocarbons through a pipe located close to the pipe to supply oxygen to the carrier gas, or gaseous or liquid hydrocarbons are introduced into the pipe to feed carbon. Before serving in the molten metal, the coal is mixed. , with oxygen-containing gases in the pipe for iodine oxygen-containing gas flow. coal is reported to rotate. PRIMER 1 The process of continuous gasification is carried out in a 20-meter futher-reactor with four nozzles in the bottom, each of which is made up of three concentrically installed pipes whose outlets are located at the lining level. The central tube of each nozzle with a diameter of 10 mm in light is used to supply coal dust. An annular gap between the inner and second pipes 3 mm wide serves to supply oxygen, and propane is fed through the outer annular gap between the second and third pipes 1 mm wide. The reactor contains 30 tons of molten iron, which contains 1.5-2.5% carbon. . The temperature of the melt is 137 ° C-1450 ° C. 12,000 kg / h of coal, 10,800 tons of ice, 216 nm3 / H of propane are introduced into the molten 4-melts. At the same time, 25,000 are obtained. gas containing,%: CO 65.5 G Yy 34.2 and CO 0.3. For one month (720 h), the nozzles evenly heat 200 mm in diameter without disrupting the gasification process. When the specified period expires, the process is stopped. To replace the nozzles. A and M 2. Example 1 is repeated with the difference. That the reagents are fed to the nozzles located in the side wall of the reactor below the metal level. At the same time, 25,000 gases are obtained containing,%: CO 65.51 T | H 34.3 and CO, 0.2. The process is carried out without; any violations within 740 hours. Rome, p. 3. Example 1 is repeated, with the difference that the reagents are supplied by yo soplam, each: of which the issue is 6-1-1 yen. From two district-located pipes. At the same time, coal is supplied along the inner pipe: PROPANO, and YO gives oxygen to the annular gap between the inner and outer pipes. 25000 nm3 / h of gas of the following composition are obtained:% 5 CO 65.5 / Bg 34.2 and CO 0.3. The process is carried out without any kind. For: bobo.ch.-;: -.: .-,::: .... In Me p 4, Example 3 is developed with the difference that rotational motion is absorbed by the flow of coal. In this case, g -s 25,000 dm3 / h times the composition,% CO 65.5j H2 and COg are obtained during the course of h. With Me p 5 Example 1 is repeated. with TOH pasHHitei - - that the process was carried out in a 20-meter lined reactor with a syringe: by using four nozzles in the reactor, each of which was made of co-centrically installed pipes. RO The inner tube is fed, and through the annular gap between the inner and outer pipes 1 | ;,; - ;,:,, - /. Yari etom.y 400 h receive 25,000 gas respectively,% $ CO 65, SG N. 34, E and CO 0.4. When the specified period expires. Process j is stopped to replace the nozzles. Example 6. Example 1 is repeated. On that occasion, in order to place a yropaya yo yar, a yellow gas is fed to its annular gap. With this s. Leaks 720 j receive 25,000 gas containing. It with 65.5 N, 34.2 and CPg 0.2. , Ir and 7; comparative, according to the prototype) Repeat example 1 with the difference that the gasification process is carried out in a 20-meter-lined reactor equipped with separate pipes for supplying coal and oxygen installed in the side wall in opposite places. Outlets of a pipe with a diameter of 100 mm for supplying coal and pipe di / -. E: 10521644
аметроМ 3 мм дл подачи кисЛоролаСО 60,5;Н2 32 и COj . По истече расположены в расп авленном Металле.;нии укаэайногр периода процесс пре- i3 mm meter for the supply of acid LOROLCO 60.5; H2 32 and COj. After they are located in the expanded Metal.;
; При этом в течение 12 ч полуда-Кращавдт дл зеадены трубы дл подачи ; At the same time, within 12 hours half a year, the Crustavdt for the zeadena of the pipe for feeding
;ют 2500Р нм газа состава %:кислорода.; 2500 Pm nm gas of composition%: oxygen.
Claims (5)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19752520883 DE2520883B2 (en) | 1975-05-10 | 1975-05-10 | Process and device for the continuous gasification of coal or carbonaceous fuels in an iron bath reactor |
Publications (1)
Publication Number | Publication Date |
---|---|
SU1052164A3 true SU1052164A3 (en) | 1983-10-30 |
Family
ID=5946244
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU762355407A SU1052164A3 (en) | 1975-05-10 | 1976-05-07 | Method for continuous gasification of coal |
Country Status (3)
Country | Link |
---|---|
JP (1) | JPS528004A (en) |
DE (1) | DE2520883B2 (en) |
SU (1) | SU1052164A3 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2540614C2 (en) * | 2009-05-14 | 2015-02-10 | ШЛЮТЕР Хартвиг | Method and device for carrying out chemical processes |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2838983C3 (en) * | 1978-09-07 | 1986-03-27 | Klöckner CRA Technologie GmbH, 4100 Duisburg | Process for producing steel in the converter |
DE2813208A1 (en) * | 1978-03-25 | 1979-10-04 | Kloeckner Humboldt Deutz Ag | Gasification of solid fuels in molten slag bath - giving synthesis or reducing gas mixts. of improved compsn. |
NL183096C (en) * | 1979-06-13 | 1988-07-18 | Shell Int Research | BURNER FOR THE PARTIAL BURNING OF A FINE DISTRIBUTED OXYGEN FUEL AND MODERATOR GAS. |
US4330326A (en) * | 1979-08-24 | 1982-05-18 | Eisenwerk-Gesellschaft Maximilianshutte Mbh. | Method and a means for introducing close-grained carbonaceous fuels into a molten iron bath |
DE3024977A1 (en) * | 1980-07-02 | 1982-01-28 | Klöckner-Humboldt-Deutz AG, 5000 Köln | METHOD FOR PRODUCING REACTION GAS |
DE3031680A1 (en) * | 1980-08-22 | 1982-03-11 | Klöckner-Werke AG, 4100 Duisburg | METHOD FOR GAS GENERATION |
US4391611A (en) * | 1981-03-05 | 1983-07-05 | The United States Of America As Represented By The United States Department Of Energy | Gasification system |
DE4238020C2 (en) * | 1992-11-11 | 1994-08-11 | Kct Tech Gmbh | Procedure for the operation of a multimedia nozzle and the nozzle system |
JP5622747B2 (en) * | 2008-12-29 | 2014-11-12 | テート アンド ライル テクノロジー リミテッド | Molten salt treatment system and method |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5156806A (en) * | 1974-11-13 | 1976-05-18 | Mitsui Shipbuilding Eng | Yojutetsuyokunyoru kotainenryogasukaro |
-
1975
- 1975-05-10 DE DE19752520883 patent/DE2520883B2/en not_active Ceased
-
1976
- 1976-05-07 SU SU762355407A patent/SU1052164A3/en active
- 1976-05-10 JP JP5229276A patent/JPS528004A/en active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2540614C2 (en) * | 2009-05-14 | 2015-02-10 | ШЛЮТЕР Хартвиг | Method and device for carrying out chemical processes |
Also Published As
Publication number | Publication date |
---|---|
JPS5724397B2 (en) | 1982-05-24 |
DE2520883B2 (en) | 1979-07-05 |
JPS528004A (en) | 1977-01-21 |
DE2520883A1 (en) | 1976-11-18 |
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