SU1051230A1 - Polymeric composition for isolating formations traversed by wells - Google Patents

Polymeric composition for isolating formations traversed by wells Download PDF

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Publication number
SU1051230A1
SU1051230A1 SU823439207A SU3439207A SU1051230A1 SU 1051230 A1 SU1051230 A1 SU 1051230A1 SU 823439207 A SU823439207 A SU 823439207A SU 3439207 A SU3439207 A SU 3439207A SU 1051230 A1 SU1051230 A1 SU 1051230A1
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SU
USSR - Soviet Union
Prior art keywords
composition
synthetic
tartaric acid
hardener
dibutyl phthalate
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Application number
SU823439207A
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Russian (ru)
Inventor
Владимир Леонидович Назаренко
Александр Иванович Бережной
Лариса Александровна Езлова
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Украинский научно-исследовательский институт природных газов
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Priority to SU823439207A priority Critical patent/SU1051230A1/en
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Publication of SU1051230A1 publication Critical patent/SU1051230A1/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/50Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls

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  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

ПОЛИМЕРНЫЙ СОСТАВ ДЛЯ ИЗОЛЯЦИИ ПЛАСТСВ В СКВАЖИНЕ, соаержащий мочев1шсх|йормальаегиднофур фуро ьную смолу, полнвиншювый сперт и отверднтель, отличающийс  тем, что. с цепью повышени  прочности на сжатие и снижени  усадки состава, оа содержит дополнительно дибутилфтапат , а а отвердител  содержит синтетическую -вшшокаменную кислоту при следующем соотношении компонентов, вес,%:. Мочевиноформальдегиднофурфурольна  смола91,0-97,9 Поливиниловый стфт1,43-5,О Дибутилфталат0,57-2,0 Синтетическа  р S виннокаменна  кислота0, (ЛPOLYMER COMPOSITION FOR INSULATION OF PLASTICS IN THE WELL, containing urea-normal and hydrophilic resin, full swollen filler and hardener, characterized in that. With a chain of increased compressive strength and reduced shrinkage of the composition, oa additionally contains dibutylphaptane, and the hardener contains synthetic -scopic acid in the following ratio of components, weight,% :. Urea formaldehyde fururural resin91.0-97.9 Polyvinyl stft1,43-5, O Dibutyl phthalate 0.57-2.0 Synthetic p S tartaric acid 0, (L

Description

Изобретение относитс  к нефтегазодобывающей промышленности, в частности к полимерным тампонажным составам и может быть использовано дл  изол ции зон поглощений и водопритоков в скваж не, & также дл  восстановпени  герметич ности обсадных колонн. Известен состав, содержащий мочеви нофс рмальдегидную смолу, полиакриламид воду и хлорное железо i.Недостатками указанного состава.  Ёл ютс  низкце адгезионные свойства и усадка отвержденного материала. Наиболее близким к предлагаемому  вл етс  состав, содержащий, мочевиноффмаладегиднофурфурольную смолу, поливиниловый спирт и отвердитель 2Q. Недостатками известного сосггава - вл ютс  невысока  прочность на сжатие и усадка состава. Цень изобретени  - повышение прочности на сжатие и снижение .усадки состава . Поставленна  цельдостигаетс  гем,чго подимерньш состав дл2й изол ции пластов в скважине, содержащий мочевиноформаль дегиднофурфурольную смолу, поливиниловы спирт и отвердитель, дополнительно содер жит дибутилфталат, а в качестве отвердител  содержит синтетическую виннокаменную кислоту, при следующем соотношении компонентов , вес.%: Моч евиноформ альдегид нофурфуроль- , на  смола81, 97, 9 Поливиниловый СЯП1ФТ.1,43-5,0 ДибутилфталатQ,57-2,0 Синтетическа  виннокаменна  кислота0,1-2,0 Ссютав готов т следующим образом. Цредва рйтельно псфошок поливинилового спирта раствор ют в воде и получают 4%-нь.1Й водный раствор, к этому раствору добавл ют дибутилфталат в соотноше- . гши 1:2,5. Полученную смесь ввод т i в мочевинофррмальдегиднофурфуродьную j смолу, а затем добавл ют синтетическую виннокаменную кислотуСостав испытывают б лабфаторных услови х : . , .. В Таблице приведены результаты испытани  предлагаемого состава в сравнени  с составом по Прототипу.The invention relates to the oil and gas industry, in particular to polymer cement compositions and can be used to isolate zones of absorption and water inflow into the well, & also to restore casing tightness. Known composition containing urea nofs rmaldehyde resin, water polyacrylamide and ferric chloride i. The disadvantages of this composition. Low adhesion properties and shrinkage of the cured material. The closest to the present invention is a composition containing, urea-amino acid-furfurol resin, polyvinyl alcohol and hardener 2Q. The disadvantages of the well-known coaxinge are the low compressive strength and shrinkage of the composition. The value of the invention is an increase in compressive strength and a reduction in the reduction of the composition. This goal is achieved by haem, which is a substitute composition for insulating formations in a well, containing urea-formaldehyde-furfurol resin, polyvinyl alcohol and a hardener, additionally contains dibutyl phthalate, and as a hardener it contains a synthetic tartaric acid, a body dimension, which is a simple tweeter, also contains a synthetic tartaric acid, a dibutyl phthalate, and has a synthetic tartaric acid, and a metric will include a synthetic tartaric acid, a dibutyl phthalate, and a body hint containing a synthetic tartaric acid, and a metric will include a synthetic tartaric acid, a dibutyl phthalate, and a metric will contain a synthetic tartaric acid, a body dimension, and a metric will include a synthetic tartaric acid, a dibutyl phthalate, and a metric that contains a synthetic tartaric acid, a body dimension, a tweeter, and a synthetic hint of tartaric acid that contains synthetic tartaric acid, and contains a synthetic tartaric acid and a hardening agent that contains synthetic tartaric acid and a hint of synthetic tartaric acid; nofurfural-, for resin81, 97, 9 Polyvinyl СЯП1ФТ.1,43-5,0 Dibutyl phthalate Q, 57-2.0 Synthetic tartaric acid 0.1-2.0 Prepared as follows. Credible polyvinyl alcohol solvents are dissolved in water and a 4% aqueous solution is obtained; to this solution dibutyl phthalate is added. Gshi 1: 2,5. The resulting mixture is injected into urea urea resin and resin, and then synthetic tartaric acid is added. Composition is tested using laboratory conditions:. , .. The table shows the results of testing the proposed composition in comparison with the composition according to the Prototype.

Из данных таблицы следует, что прочность предлагаемого осютаьа на сжатие в 1,5--2,0 раза выше по сравнению с 5 составом по прототипу, а усадка в 2 раза ниже по сравнению с этим же соста- j BOM. Испытани  также показали, что соче-iFrom the data of the table it follows that the strength of the proposed compression test is 1.5–2.0 times higher than that of the prototype composition, and the shrinkage is 2 times lower compared to the same composition j BOM. Tests also showed that comp-i

танне дйбутипфтааата в поливинилового спирта, Б оредпагаемом составе нар ду с повышением гфочностных свойств придает ему упругоэластнчные свойства. При сжатии отвердевших , последние сжимаютс  до 1/3 высоты, не разруша сь,;The tanne dibutiptaata in polyvinyl alcohol, the bridging composition, along with the enhancement of the plastic properties, gives it elastic elastic properties. When compressed solidified, the latter are compressed to 1/3 of the height, without breaking ,;

3 1О5123О. 43 1О5123О. four

хфй разгрузке восстанавливают свою вы-не ра1 уша сь, а уплотн  сь, надежно,Hfy unloading restore their you-not rasch us, but compacted, reliably,

соту а обраахы из состава по прототипузакупоривать 1Езол1фуемый пласт. Приарк этих испытани х растрескиваютс .менение полимерного , в силуA cell of the specimens from the composition according to the prototypical packing of the Ezol1fuy layer. Priark these tests crack. Change polymer, due to

Примерный состав в услови х скважиныгфисущих ему свойств,;обеспечит повыпод действием гидростатического или5 шение эффективности йарвции зон попзтастового давлений будет сэкима-рл ,глощений и водопритокрв э скважине.The approximate composition in the conditions of the well, of the properties that it confers, will provide the effect of hydrostatic or 5 the effectiveness of the development of the zones of the peak pressure will be sekim-rl, absorptions and water flow in the well.

Claims (1)

ПОЛИМЕРНЫЙ СОСТАВ ДЛЯ ИЗОЛЯЦИИ ПЛАСТОВ В СКВАЖИНЕ, содержащий мочевиноформальдегиднофурфурсльную смолу, поливиниловый спирт и отвердитель, отличающийся тем, что, с целью повышения прочности на сжатие и снижения усадки состава, он содержит дополнительно дибутилфталат, а в качестве отвердителя содержит синтетическую виннокаменную кислоту при следующем соотношении компонентов, вес,%: .POLYMERIC COMPOSITION FOR INSULATING LAYERS IN A WELL containing urea-formaldehyde-furfur resin, polyvinyl alcohol and a hardener, characterized in that, in order to increase the compressive strength and reduce shrinkage of the composition, it additionally contains dibutyl phthalate, and as the hardener contains synthetic tartrate , weight,%: . • Мочевиноформальдегйднофурфурольная смола Поливиниловый спирт Дибутилфталат Синтетическая виннокаменная кислота• Urea-formaldehyde-furfural resin Polyvinyl alcohol Dibutyl phthalate Synthetic tartaric acid 91,0-97,991.0-97.9 1,43-5,01.43-5.0 0,57-2,00.57-2.0 0,1-2,00.1-2.0
SU823439207A 1982-03-23 1982-03-23 Polymeric composition for isolating formations traversed by wells SU1051230A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0881353A1 (en) * 1997-05-28 1998-12-02 Institut Francais Du Petrole Process and material for well cementing

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
t. Авторское свидетельство СССР 1 675168, iw. -Е 21 Б 33/138, 1979. 2. Автфское свидетельство СССР J 355337, кл. Ё 21 В 33/138, 1970 (прОТрТШ). *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0881353A1 (en) * 1997-05-28 1998-12-02 Institut Francais Du Petrole Process and material for well cementing
FR2763991A1 (en) * 1997-05-28 1998-12-04 Inst Francais Du Petrole METHOD AND MATERIAL FOR CEMENTING WELLS

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