SK80797A3 - Fungicidal impregnant agent against micro-organisms - Google Patents

Fungicidal impregnant agent against micro-organisms Download PDF

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Publication number
SK80797A3
SK80797A3 SK807-97A SK80797A SK80797A3 SK 80797 A3 SK80797 A3 SK 80797A3 SK 80797 A SK80797 A SK 80797A SK 80797 A3 SK80797 A3 SK 80797A3
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SK
Slovakia
Prior art keywords
composition according
fungicidal
silicate
water
copper
Prior art date
Application number
SK807-97A
Other languages
Slovak (sk)
Inventor
Guido Schumy
Original Assignee
Riha Alfred
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Riha Alfred filed Critical Riha Alfred
Publication of SK80797A3 publication Critical patent/SK80797A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5089Silica sols, alkyl, ammonium or alkali metal silicate cements
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • A01N59/20Copper
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04GSCAFFOLDING; FORMS; SHUTTERING; BUILDING IMPLEMENTS OR AIDS, OR THEIR USE; HANDLING BUILDING MATERIALS ON THE SITE; REPAIRING, BREAKING-UP OR OTHER WORK ON EXISTING BUILDINGS
    • E04G23/00Working measures on existing buildings
    • E04G23/002Arrangements for cleaning building facades
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/2092Resistance against biological degradation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Architecture (AREA)
  • Wood Science & Technology (AREA)
  • Ceramic Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Structural Engineering (AREA)
  • Plant Pathology (AREA)
  • Materials Engineering (AREA)
  • Civil Engineering (AREA)
  • Dentistry (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)
  • Paints Or Removers (AREA)

Abstract

Fungicidal impregnating agent for treating concrete, bricks and plaster comprises (in wt.%): 0.1-80 inorganic silicates, 0.1-70 siliconates, 0.1-80 silicone- or acrylic- resin emulsion, 0.1-5 copper oxide, 0.1-10 copper sulphate (CuSO4.5H2O), optionally 0.1-5 cationic or anionic surfactant, and water. The silicate is preferably a sodium- or potassium- silicate. The siliconate is preferably methylsiliconate.

Description

Fungicídny impregnačný prostriedok proti mikroorganizmomFungicidal impregnating agent against microorganisms

Oblasť technikyTechnical field

Vynález sa týka fungicídneho impregnačného prostriedku proti mikroorganizmom na betóne, tehlách, malte a omietkach, ako aj v budovách a na budovách. Fungicídny impregnačný prostriedok podľa vynálezu je v dôsledku svojho chemického zloženia schopný účinne ničiť plesne, huby a riasy, ako aj zamedzovať napadnutie plesňami, hubami a riasami. Podstata chemického pôsobenia prostriedku podľa vynálezu spočíva v kombinácii chemicko-fyzikálnych vlastností, ktoré dokladajú novosť prostriedku podľa vynálezu.The invention relates to a fungicidal impregnating agent against microorganisms on concrete, bricks, mortar and plasters as well as in and on buildings. Due to its chemical composition, the fungicidal impregnating composition according to the invention is capable of effectively controlling molds, fungi and algae, as well as preventing mold, fungi and algae attack. The essence of the chemical action of the composition according to the invention lies in the combination of the chemical-physical properties which demonstrate the novelty of the composition according to the invention.

Doterajší stav technikyBACKGROUND OF THE INVENTION

Doterajšie ničenie plesní a hub je založené na používaní známych toxických chemických látok. Z týchto sa môžu menovať soli ťažkých kovov, ako soli ortuti, olova, cínu a zinku, ako aj krezoly, fenoly, kyanovodík, kvartérne amóniové zlúčeniny, sulfonylpyridíny, kaptány, triazíny, tiokarbamáty atď. Uvedené látky majú pomáhať odstraňovať mikroorganizmy o ktorých je známe, že spôsobujú ochorenie pľúc, krvi, pečene, kostí a kĺbov, z obytných domov. Zvlášť nebezpečné pre ľudský organizmus, prípadne pre jeho imunitný systém, sú plesne rodu Aspergillus, Penicillium a Rhizopus, ktoré môžu viesť k smrteľným mykózam.The current destruction of fungi and molds is based on the use of known toxic chemicals. Among these, heavy metal salts such as mercury, lead, tin and zinc salts as well as cresols, phenols, hydrogen cyanide, quaternary ammonium compounds, sulfonylpyridines, captants, triazines, thiocarbamates, etc. may be mentioned. Said substances are intended to help remove microorganisms known to cause lung, blood, liver, bone and joint disease from dwelling houses. Especially dangerous to the human body or its immune system are fungi of the genera Aspergillus, Penicillium and Rhizopus, which can lead to fatal mycoses.

Podstata vynálezuSUMMARY OF THE INVENTION

Podstata vynálezu spočíva okrem iného a na rozdiel od doterajšieho stavu techniky nie v toxickom chemickom účinku impregnácie betónu, tehál, malty a omietky, ale v použití ekologicky šetrnej a dokonca z veľkej časti biologicky odbúrateľnej chemickej zmesi, v ktorej sú prítomné tenzidy, ktoré však čo do účinku voči mikroorganizmom majú skôr podradnú úlohu. Okrem toho, na rozdiel od čisto chemického účinku, pôsobí ako prostriedok proti škodcom nie tenzidický, ale znižovaním povrchového napätia na fyzikálnom podklade v dôsledku použitia zlúčenín kremíka, ako sú silikóny, silikonáty, silikáty, ktoré citlivo narušujú vlhké životné prostredie mikroorganizmov. K tejto ekologickej skutočnosti, ktorá je podstatná aj pre ľudí, prípadne obyvateľov domov, prispieva ešte výber zlúčenín solí kovov šetrných voči potravinám, ako je napríklad síran meďnatý (CuS04.5 H2OJ a poskytuje tak chemicko-fyzikálny synergizmus.The essence of the invention lies, inter alia, and in contrast to the prior art, not in the toxic chemical effect of impregnating concrete, bricks, mortar and plaster, but in using an environmentally friendly and even largely biodegradable chemical composition in which surfactants are present. they have a rather minor role in the action against microorganisms. In addition, unlike a purely chemical effect, it acts as a pest control agent not tensile, but by reducing the surface tension on the physical substrate due to the use of silicon compounds such as silicones, siliconates, silicates that sensitively disturb the humid environment of microorganisms. The choice of compounds of food-friendly metal salts, such as copper sulphate (CuSO 4 .5 H 2 OJ), contributes to this ecological fact, which is also essential for people and / or home residents, providing chemical-physical synergism.

Predmetom vynálezu je fungicídny impregnačný prostriedok proti mikroorganizmom, ako sú napríklad plesne, huby, riasy, na betóne, tehlách, malte a omietkach v budovách a na budovách, pozostávajúci výhodne z organických a anorganických zlúčenín kremíka, prípadne tiež spolu s ďalšími organickými látkami, ako sú napríklad akryláty, tenzidy aniónového alebo katiónového pôvodu v kombinácii so soľami kovov, ako napríklad s modrou skalicou rozpustenou vo vode, ktorý spočíva v tom, že obsahuje 0,1 až 80 % hmotn. anorganických silikátov,The present invention relates to a fungicidal impregnating agent against microorganisms, such as fungi, fungi, algae, on concrete, bricks, mortar and plasters in and on buildings, preferably consisting of organic and inorganic silicon compounds, optionally also together with other organic substances, such as % are, for example, acrylates, surfactants of anionic or cationic origin in combination with metal salts, such as, for example, water dissolved in blue, comprising 0.1 to 80 wt. inorganic silicates,

0,1 až 70 % hmotn. silikonátov, 0,1 až 80% hmotn. silikónových emulzií alebo emulzií akrylátovej živice, 0,1 až 5 % hmotn.0.1 to 70 wt. % of siliconates, 0.1 to 80 wt. % silicone emulsions or acrylate resin emulsions, 0.1 to 5 wt.

tenzidov, 0,1 až 10 % hmotn. síranu meďnatého, 0,1 až 15 % hmotn. oxidov medi a vodu.% surfactants, 0.1 to 10 wt. % copper sulfate, 0.1 to 15 wt. copper oxide and water.

Ako silikáty sa pritom výhodne používajú nátrium- alebo káliumsilikáty a ako silikonáty sa výhodne používa metylsilikonát.Sodium or potassium silicates are preferably used as silicates, and methyl siliconate is preferably used as silicates.

Príklady uskutočnenia vynálezuDETAILED DESCRIPTION OF THE INVENTION

Zloženie prostriedku podľa vynálezu bližšie ilustrujú nasledujúce príklady:The following examples illustrate the composition of the composition of the invention:

Príklad 1 % hmotn. emulzie silikónovej živice % hmotn. káliumsilikátu % hmotn. kálium-metylsilikonátu % hmotn. síranu meďnatéhoExample 1 wt. % silicone resin emulsion wt. % silicate silicate wt. % potassium methyl siliconate wt. copper sulphate

0,1 % hmotn. aniónaktívneho zmáčadla0.1 wt. of an anionic wetting agent

0,1 % hmotn. oxidu medi0.1 wt. copper oxide

58,8 % hmotn. vody.58.8 wt. water.

Príklad 2 % hmotn. nátriumsilikátu % hmotn. emulzie silikónovej živice % hmotn. káliumpropylsilikonátu % hmotn. katiónaktívneho zmáčadla % hmotn. oxidu medi % hmotn. vody.Example 2 wt. % sodium silicate wt. % silicone resin emulsion wt. % potassium propylsiliconate wt. % cationic wetting agent; % copper oxide wt. water.

Príklad 3 % hmotn. káliumsilikátu % hmotn. emulzie akrylovej živice % hmotn. káliummetylsilikonátuExample 3 wt. % silicate silicate wt. % acrylic resin emulsion wt. káliummetylsilikonátu

0,1 % hmotn. aniónaktívneho zmáčadla0.1 wt. of an anionic wetting agent

0,2 % hmotn. oxidu medi0.2 wt. copper oxide

0,25 % hmotn. síranu meďnatého0.25 wt. copper sulphate

39,45 % hmotn. vody.39.45 wt. water.

Príklad 4 % hmotn. emulzie akrylovej živice % hmotn. káliummetylsilikonátu % hmotn. káliumsilikátuExample 4 wt. % acrylic resin emulsion wt. wt% potassium methyl siliconate wt. potassium silicate

0,1 % hmotn. síranu meďnatého0.1 wt. copper sulphate

59,9 % hmotn. vody.59.9 wt. water.

Priemyselná využiteľnosťIndustrial usability

Využitie prostriedku podľa vynálezu prichádza do úvahy zvlášť pri ochrane budov voči napadnutiu mikroorganizmami.The use of the composition according to the invention is particularly suitable for the protection of buildings against attack by microorganisms.

Claims (5)

1. Fungicídny impregnačný prostriedok proti mikroorganiz- mom, ako sú napríklad plesne, huby, riasy, na betóne, tehlách, malte a omietkach, v budovách a na budovách, pozostávajúci výhodne z organických a anorganických zlúčenín kremíka, prípadne tiež spolu s ďalšími organickými látkami, ako sú napríklad akryláty, tenzidy aniónového alebo katiónového pôvodu v kombinácii so sol'ami kovov, ako napríklad so síranom meďnatým rozpusteným vo vode, vyznačujúci sa tým, že obsahuje 0,1 až 80 % hmotn. anorganických silikátov, 0,1 až 70 % hmotn. silikonátov, 0,1 až 80 % hmotn. emulzie silikónovej živice alebo emulzie akrylátovej živice, 0,1 až 5 % hmotn. tenzidov, 0,1 až 10 % hmotn. síranu meďnatého, 0,1 až 15 % hmotn. oxidu medi a vodu.A fungicidal impregnating agent against microorganisms, such as molds, fungi, algae, on concrete, bricks, mortar and plasters, in buildings and on buildings, consisting preferably of organic and inorganic silicon compounds, optionally together with other organic substances %, such as acrylates, surfactants of anionic or cationic origin in combination with metal salts, such as copper sulfate dissolved in water, characterized in that it contains 0.1 to 80 wt. % of inorganic silicates, 0.1 to 70 wt. % of siliconates, 0.1 to 80 wt. % silicone resin emulsion or acrylic resin emulsion, 0.1 to 5 wt. % surfactants, 0.1 to 10 wt. % copper sulfate, 0.1 to 15 wt. copper oxide and water. 2. Prostriedok podľa nároku 1, vyznačujúci sa tým, že ako silikát obsahuje nátrium- alebo/a káliumsilikát.Composition according to claim 1, characterized in that it contains sodium and / or potassium silicate as the silicate. 3. Prostriedok podľa nároku 1, vyznačujúci sa tým, že ako silikonát obsahuje metylsilikonát.Composition according to claim 1, characterized in that it contains methyl siliconate as siliconate. 4. Prostriedok podľa nároku 1, vyznačujúci sa tým, že sa používa tenzid aniónového alebo katiónového charakteru .Composition according to claim 1, characterized in that an anionic or cationic surfactant is used. 5. Prostriedok podľa nároku 1, vyznačujúci sa tým, že sa ako soľ kovu používa síran meďnatý.Composition according to claim 1, characterized in that copper metal is used as the metal salt.
SK807-97A 1996-06-24 1997-06-19 Fungicidal impregnant agent against micro-organisms SK80797A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
AT0111296A AT403235B (en) 1996-06-24 1996-06-24 IMPREGNANT AGAINST MOLD, MUSHROOM AND ALGAE

Publications (1)

Publication Number Publication Date
SK80797A3 true SK80797A3 (en) 1998-01-14

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SK807-97A SK80797A3 (en) 1996-06-24 1997-06-19 Fungicidal impregnant agent against micro-organisms

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AT (1) AT403235B (en)
CZ (1) CZ198397A3 (en)
DE (1) DE19703705A1 (en)
HU (1) HUP9701091A2 (en)
PL (1) PL320721A1 (en)
SK (1) SK80797A3 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6649569B2 (en) 2001-01-12 2003-11-18 Jacques Vionnet Composition intended for the protection of a solid substrate and its use
EP1223200A1 (en) * 2001-01-12 2002-07-17 Vionnet, Jacques Composition for protecting a solid substrate and its use
EP1253178A1 (en) * 2001-04-17 2002-10-30 Vionnet, Jacques Aqueous composition for the hydrophobisation of substrates
DE10219191A1 (en) * 2002-04-29 2003-12-11 Ransmann Ursula Objects with antifouling protection, e.g. house wrap, tents and building materials, coated with material which becomes alkaline, with fungicidal and-or antibacterial activity, when exposed to environmental moisture
WO2003104159A1 (en) * 2002-06-06 2003-12-18 Radi Al-Rashed An aqueous chemical mixture to mitigate water associated problems in concrete pavements
DE102004028941B4 (en) * 2004-06-15 2006-05-04 Reul, Horst, Dr. Use of lithium ion containing aqueous solution (e.g. lithium hydroxide solution) for treating and preventing the growth of algae (e.g. green and red algae) and fungi on building surfaces, sculptures, gravestone (e.g. on the frontages)
CZ23591U1 (en) * 2011-11-10 2012-03-26 Effmert@Vilém Concrete mixture, concrete and concrete product exhibiting increased resistance to formation of moss and/or lichen
FR3065861B1 (en) * 2017-05-04 2020-03-13 Hbco Herbals And Bio Chemicals Outsourcing USE OF MONOMETHYLSILANETRIOL AND / OR ITS SALTS TO PROTECT CROPS
US20210171780A1 (en) 2018-08-14 2021-06-10 Basf Se Process of making silicone-in-water emulsions
DE202021101670U1 (en) 2020-11-04 2021-11-11 Mslsolutions Gmbh Coating against algae and fungal attack

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2875888B2 (en) * 1991-10-17 1999-03-31 シーン バイオテクノロジー ピーティーワイ エルティーディー Insecticides and fungicides
US5421867A (en) * 1993-10-18 1995-06-06 Cucorp, Inc. Composition and process of combining a grout or mortar mix with copper-8-quinolinolate to form an antimicrobial composition

Also Published As

Publication number Publication date
DE19703705A1 (en) 1998-01-02
ATA111296A (en) 1997-05-15
PL320721A1 (en) 1998-01-05
HU9701091D0 (en) 1997-08-28
HUP9701091A2 (en) 1998-04-28
AT403235B (en) 1997-12-29
CZ198397A3 (en) 1998-01-14

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