KR101599794B1 - Eco-friendly Inorganic Penetrative waterproof agent - Google Patents
Eco-friendly Inorganic Penetrative waterproof agent Download PDFInfo
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- KR101599794B1 KR101599794B1 KR1020150065696A KR20150065696A KR101599794B1 KR 101599794 B1 KR101599794 B1 KR 101599794B1 KR 1020150065696 A KR1020150065696 A KR 1020150065696A KR 20150065696 A KR20150065696 A KR 20150065696A KR 101599794 B1 KR101599794 B1 KR 101599794B1
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- 230000000149 penetrating effect Effects 0.000 title description 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 28
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000077 silane Inorganic materials 0.000 claims abstract description 15
- 239000004111 Potassium silicate Substances 0.000 claims abstract description 13
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052913 potassium silicate Inorganic materials 0.000 claims abstract description 13
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 13
- 239000004568 cement Substances 0.000 claims abstract description 11
- 239000012153 distilled water Substances 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- 238000004078 waterproofing Methods 0.000 claims description 44
- 239000000463 material Substances 0.000 claims description 27
- 230000035515 penetration Effects 0.000 claims description 4
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical group CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000012466 permeate Substances 0.000 claims description 2
- 239000005871 repellent Substances 0.000 abstract description 9
- 229910052700 potassium Inorganic materials 0.000 abstract description 3
- 239000011591 potassium Substances 0.000 abstract description 3
- 239000012528 membrane Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 230000002940 repellent Effects 0.000 description 5
- 230000001681 protective effect Effects 0.000 description 4
- 239000010426 asphalt Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 230000035699 permeability Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 230000009965 odorless effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- -1 etc. Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
- C04B41/4905—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
- C04B41/4922—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
- C04B41/4933—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane containing halogens, i.e. organohalogen silanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
- Paints Or Removers (AREA)
Abstract
Description
본 발명은 친환경 무기계 침투형 방수제에 관한 것으로, 보다 상세하게는 콘크리트 또는 시멘트 건축물의 내외벽용 방수제로 사용되며, 친환경적이면서 우수한 방수성 및 발수성을 제공할 수 있도록 한 친환경 무기계 침투형 방수제에 관한 것이다.The present invention relates to an environmentally friendly inorganic penetration type waterproofing agent, and more particularly, to an environmentally friendly inorganic waterproofing agent which is used as a waterproofing agent for inner and outer walls of concrete or cement buildings and is capable of providing an environmentally friendly and excellent waterproofing and water repellency.
대부분의 현대식 건축물은 콘크리트 또는 시멘트를 재료로 지어지며, 상기 콘크리트 또는 시멘트 건축물은 건축 후 내외벽에 페인트로 칠을 하여 마감을 하게 되는데, 이때 비 또는 건축물 자체의 결로 등에 의한 누수를 방지할 수 있도록 방수제를 사용하여 방수 및 발수 처리가 이루어진다.Most of the modern buildings are made of concrete or cement. The concrete or cement building is painted with paint on the inner and outer walls after construction. In order to prevent leakage due to the rain or the condensation of the building itself Waterproofing and water repellent treatment are performed by using a waterproofing agent.
일반적으로 방수제는 방수성을 갖게 하기 위하여 사용되는 재료를 말하며, 방수포와 같이 무명, 삼베의 발에 아스팔트 등을 함침 시킨 것 또는 콘크리트 블록 등의 아스팔트루핑이나 모르타르, 콘크리트 제품 등의 표면 또는 천, 종이, 섬유 제품의 표면에 발라서 발수성을 갖게 하는 것, 또한 모르타르, 콘크리트의 혼합, 용해제로서 방수성과 수밀성을 증대시킨 것 등 다양하다.Generally, a waterproofing agent is a material used to impart waterproofing. It is a material such as tarpaulins, cotton asphalt impregnated with asphalt, etc., asphalt roofing such as concrete block, mortar, concrete products, Water repellency by spraying on the surface of textile products, mixing of mortar, concrete, and dissolving agents, which are improved in water resistance and watertightness.
상기 방수제 중에서 콘크리트 제품이나 구조물에 사용하는 기존의 방수제는 다양한 유기질 및 화학적 성분을 포함하며, 도포한 모재 표면에 방수층을 형성하여 방수 효과를 제공한다.Among the above waterproofing agents, conventional waterproofing agents used for concrete products and structures include various organic and chemical components and provide a waterproof effect by forming a waterproof layer on the surface of the coated base material.
그러나, 기존의 방수제는 콘크리트 또는 시멘트 건축물의 내외벽에 도포된 것 중에서 일부만 콘크리트 또는 시멘트 모재와 반응하여 모재 표면에 방수막을 형성하고 나머지 부분은 용출되는바 사용량 대비 방수 및 발수 효율이 그다지 높지 않다. 또한, 기존의 유기성 방수막은 단순히 모재 표면에 형성된 것으로서 모재에 대한 부착력 및 자체강도가 약해 시간이 경과 하면 비나 바람에 의해 방수막 중 일부가 쉽게 벗겨지거나 제거되어 페인트칠이 벗겨지거나 심한 경우 건물에 누수가 발생되는 원인이 되는 것이다.However, the conventional waterproofing agent is only partially applied to the inner and outer walls of concrete or cement building and reacts with concrete or cement base material to form a waterproof film on the surface of the base material. In addition, the existing organic waterproofing membrane is formed on the surface of the base material. When the adhesive force or self-strength of the organic waterproofing membrane is weak, the waterproof membrane is easily peeled or removed by the rain or wind and the paint is peeled off. Is generated.
또한, 기존의 방수제는 냄새가 강하고 인체에 해로운 화학물질들을 포함하고 있어서 작업시 보호도구가 반드시 필요하고, 특히 폐쇄공간에서 방수작업을 하는 경우 보호복이 필수이며 그 외에도 주의사항이 많아 작업성이 현저히 저하되는 문제가 있다.In addition, existing waterproofing agents contain chemicals that are strong in odor and harmful to the human body, so it is necessary to use protective equipment in the work. In case of waterproofing work in closed space, protective clothing is essential. There is a problem of remarkably deteriorating.
본 발명은 위와 같은 종래의 문제점을 고려하여 안출된 것으로서, 친환경적이면서 콘크리트 또는 시멘트 모재 내부에 완전히 침투되도록 하여 사용량 대비 방수 및 발수 효율을 높이고 방수막과 모재의 내구성을 향상시킬 수 있는 친환경 무기계 침투형 방수제를 제공하는데 그 목적이 있다.SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned conventional problems, and it is an object of the present invention to provide an eco-friendly inorganic penetration type which is environmentally friendly and fully penetrates into a concrete or cement base material to improve the waterproofing and water- The purpose of the present invention is to provide a waterproofing agent.
본 발명의 일 측면에 의하면, 증류수 25 내지 35중량%; 포타슘실리케이트 35 내지 45중량%; 포타슘실리코네이트 15 내지 25중량%; 실란 5 내지 15중량%; 및 계면활성제 0.5 내지 1.5중량%; 를 포함하는 친환경 무기계 침투형 방수제를 제공한다.According to an aspect of the present invention, there is provided a method for producing a water-soluble polymer comprising 25 to 35% by weight of distilled water; 35 to 45% by weight of potassium silicate; 15-25% by weight of potassium silicate; 5 to 15% by weight silane; And 0.5 to 1.5% by weight of a surfactant; Resistant inorganic water-repellent agent.
본 발명의 바람직한 특징에 의하면, 상기 실란은 알콕시실란일 수 있다.According to a preferred feature of the present invention, the silane may be alkoxysilane.
본 발명의 더 바람직한 특징에 의하면, 상기 실란은 메틸 트리 메톡시 실란일 수 있다.According to a more preferred aspect of the present invention, the silane may be methyltrimethoxysilane.
본 발명의 일 실시예에 따른 친환경 무기계 침투형 방수제에 따르면, 무해, 비휘발성 및 무취한 무기계 성분들로 구성되어 친환경적이므로 작업자가 폐쇄공간에서도 보호복 없이 방수작업을 할 수 있는 등 작업성을 개선할 수 있고, 콘크리트 또는 시멘트 모재 내부에 완전히 침투하여 방수막을 형성함으로써 사용량 대비 방수 및 발수 효율이 우수하며, 콘크리트와 화학적으로 반응하여 형성된 방수막을 통해 상기 방수력 및 발수력을 장시간 유지할 수 있고, 모재의 내구성도 향상시킬 수 있는 효과가 있다.According to the environmentally friendly inorganic penetrant type water repellent agent according to the embodiment of the present invention, since it is environment-friendly composed of harmless, nonvolatile and odorless inorganic components, the worker can perform the waterproof work without the protective clothing even in the closed space The waterproofing and water repellent force can be maintained for a long time through the waterproof membrane formed by chemically reacting with the concrete, and the waterproofing and water repellent force can be maintained for a long time, Durability can be improved.
도 1은 본 발명의 일 실시예에 따른 친환경 무기계 침투형 방수제의 특성을 시험한 결과를 나타낸 표이다.1 is a table showing the results of testing the characteristics of the environmentally friendly inorganic penetrating type waterproofing agent according to an embodiment of the present invention.
이하, 첨부된 도면을 참조하여 본 발명의 바람직한 실시예를 설명한다. 그러나, 본 발명의 실시예는 여러 가지 다른 형태로 변형될 수 있으며, 본 발명의 범위가 이하 설명하는 실시예로 한정되는 것은 아니다.Hereinafter, preferred embodiments of the present invention will be described with reference to the accompanying drawings. However, the embodiments of the present invention can be modified into various other forms, and the scope of the present invention is not limited to the following embodiments.
덧붙여, 명세서 전체에서 어떤 구성요소를 '포함'한다는 것은 특별히 반대되는 기재가 없는 한 다른 구성요소를 제외하는 것이 아니라 다른 구성요소를 더 포함할 수 있다는 것을 의미한다.In addition, to include an element throughout the specification does not exclude other elements unless specifically stated otherwise, but may include other elements.
본 실시예의 무기계 방수제는, 콘크리트 또는 시멘트 모재의 표면에 붓이나 스프레이 장비 등을 이용하여 발라 사용하는 것으로서, 25 내지 35중량%의 증류수; 35 내지 45중량%의 포타슘실리케이트; 15 내지 25중량%의 포타슘실리코네이트; 5 내지 15중량%의 실란; 및 0.5 내지 1.5중량%의 계면활성제; 를 포함한다.The inorganic waterproofing agent of the present invention is applied to the surface of a concrete or cement base material by using a brush or a spraying equipment, and comprises 25 to 35% by weight of distilled water; 35 to 45% by weight of potassium silicate; 15 to 25% by weight of potassium siliconate; 5 to 15% by weight of silane; And 0.5 to 1.5% by weight of a surfactant; .
상기 증류수는 일반적인 증류수이며 각각의 물질을 혼합 및 용해시키는 역할을 한다. 이때, 상기 증류수의 함량이 25중량% 미만이면 각 성분들을 혼합할 때 용해되지 않고 남는 물질이 일부 발생될 수 있고, 상기 증류수의 함량이 35중량%를 초과하면 점도가 지나치게 묽어져 도장시 모재 표면을 타고 흘러내려 방수막의 두께가 균일하지 않게 되는 문제가 발생할 수 있다.The distilled water is generally distilled water and serves to mix and dissolve the respective materials. If the content of the distilled water is less than 25% by weight, some of the remaining materials may not be dissolved when mixing the components, and when the content of the distilled water exceeds 35% by weight, the viscosity may become too thin, The thickness of the waterproof membrane may become uneven.
그리고, 상기 포타슘실리케이트는 침투성을 가지는 것으로서, 방수제가 모재 내부로 스며들어 모재 표면과 내부에 걸쳐 방수막이 형성되도록 하는 역할을 한다. 이때, 방수제는 콘크리트의 공극을 통해 콘크리트 내부로 침투된 부분에서 상기 포타슘실리케이트가 콘크리트의 수산화칼슘과 화학적 반응을 하여 방수막이 콘크리트 성분과 일체화되도록 하는 작용을 한다. 상기 포타슘실리케이트의 함량이 35중량% 미만이면 상기 작용이 제대로 구현되지 못할 수 있고, 상기 포타슘실리케이트의 함량이 45중량%를 초과하면 사용량 대비 효율성이 낮은 문제가 있다.The above-mentioned potassium silicate has permeability, and the waterproofing agent permeates into the base material, thereby forming a waterproof film on the surface and inside of the base material. At this time, the waterproofing agent chemically reacts with the calcium hydroxide of the concrete in the portion penetrated into the concrete through the pores of the concrete, so that the waterproofing membrane integrates with the concrete component. If the content of the potassium silicate is less than 35% by weight, the above-mentioned action may not be realized properly. If the content of the potassium silicate is more than 45% by weight, the efficiency is low.
그리고, 상기 포타슘실리코네이트는 발수 기능을 더 부여한다. 이때, 상기 포타슘실리코네이트의 함량이 15중량% 미만이면 발수력이 저하될 수 있으며, 상기 포타슘실리코네이트의 함량이 25중량%를 초과하면 사용량 대비 효율성이 낮은 문제가 있다.And, the above-mentioned potassium silicoate further imparts a water-repellent function. If the content of the potassium silicate is less than 15% by weight, the water repellency may be lowered. If the content of the potassium silicate is more than 25% by weight, the efficiency is low.
그리고, 상기 실란은 n개의 규소 원자에 2n+2개의 수소 원자가 결합한 화합물로서, 탄화수소의 탄소 대신 규소가 결합한 모양이며, 방수제 시공시 모재와의 점착성을 높이고, 방수제 도포 및 양생 후에는 모재 내부에 침투 및 방수막을 형성하면서 시공된 방수막의 방수성을 향상시키는 역할을 한다. 이때, 상기 실란의 함량이 5중량% 미만이면 상기 점착성 및 방수성 향상효과가 제대로 구현되지 않을 수 있으며, 상기 실란의 함량이 15중량%를 초과하면 사용량 대비 효율성이 낮은 문제가 있다. 이때, 상기 실란은 방수제의 분산성 및 시공된 방수막의 발수성 및 내마모성 등을 더 향상시킬 수 있도록 예컨대 메틸 트리 메톡시 실란과 같은 알콕시실란을 사용하는 것이 바람직하나, 본 발명이 반드시 이에 한정되는 것은 아니다.The silane is a compound in which 2n + 2 hydrogen atoms are bonded to n silicon atoms, and silicon is bonded instead of hydrocarbon. The adhesion of the silane to the base material is improved when the waterproofing agent is applied and the penetration into the base material And to improve the waterproof property of the waterproof film formed while forming the waterproof film. If the content of the silane is less than 5% by weight, the adhesiveness and waterproofing effect may not be achieved. If the content of the silane exceeds 15% by weight, the efficiency of the silane is lowered. At this time, the silane is preferably used, for example, alkoxysilane such as methyltrimethoxysilane to further improve the dispersibility of the waterproofing agent and the water repellency and abrasion resistance of the applied waterproof film, but the present invention is not limited thereto .
그리고, 상기 계면활성제는 묽은 용액 속에서 계면에 흡착하여 그 표면장력을 감소시키는 물질로서, 본 실시예에서는 액상인 방수제의 표면장력을 낮추어 방수시공시 방수재가 모재에 침투되기 더 용이하도록 하고, 모재의 공극에 방수제가 용이하게 채워지도록 하며, 방수막 형성 후 모재의 표면강도를 더 향상시키는 역할을 수행한다. 이때, 상기 계면활성제의 함량이 0.5중량% 미만이면 상기한 침투성 및 방수막 형성 후 모재의 표면강도를 향상시키는 효과가 제대로 구현되지 않을 수 있으며, 상기 계면활성제의 함량이 1.5중량%를 초과하면 사용량 대비 효율성이 낮은 문제가 있다.In the present embodiment, the surface tension of the liquid water-repellent agent is lowered to make it easier for the water-proof material to penetrate into the base material during waterproofing, And further enhances the surface strength of the base material after the formation of the waterproof film. If the content of the surfactant is less than 0.5% by weight, the effect of improving the surface strength of the base material after the formation of the water permeable and waterproof film may not be realized properly. If the content of the surfactant exceeds 1.5% by weight, There is a problem of low contrast efficiency.
위와 같이 구성된 본 실시예의 무기계 침투형 방수제는, 접착력이 뛰어나며 우수한 탄성을 가지고 있어 붓이나 롤러 또는 스프레이 등을 이용하여 콘크리트나 시멘트 모재 표면에 간단하게 도포할 수 있어서 시공이 간편한 이점이 있다. 또한, 이러한 시공상의 간편함을 통해 건물을 신축할 때는 물론 기존 건물의 하자를 보수하는 용도로도 효과적으로 활용할 수 있다.The inorganic penetrant type waterproofing agent of the present embodiment having the above-described structure is excellent in adhesion strength and has excellent elasticity, and can be easily applied to the surface of concrete or cement base material by using a brush, roller, spray or the like. In addition, through the simplicity of the construction, it is possible to effectively utilize the structure for repairing defects of an existing building as well as a new building.
또한, 본 실시예의 방수제는 접착제를 사용하지 않으며, 물리적 결합이 아닌 화학결합으로 모재 표면에 형성되어 있는 틈새나 균열에 완전히 침투되어 콘크리트 또는 시멘트 모재와 반응하면서 방수막을 형성하는 것으로서, 용출되는 부분이 없어 사용량 대비 내투수성과 내흡수성 개선효과 및 이에 따른 발수 및 방수 효율을 향상시킬 수 있다. 또한, 이와 같이 방수막이 콘크리트 내부에서 콘크리트의 성분과 화학적으로 결합된 상태를 유지하므로 방수막의 모재에 대한 부착력이 우수하여 방수막이 형성된 이후 장시간 경과해도 외부의 비나 바람 등의 요인에 의해 방수막이 쉽게 벗겨지거나 제거되는 것을 최소화할 수 있다.The waterproofing agent of the present embodiment does not use an adhesive but forms a waterproof film by completely penetrating into cracks or cracks formed on the surface of the base material by chemical bonding rather than physical bonding and reacting with the concrete or cement base material, It is possible to improve the water permeability and the water absorptivity and the water repellency and the waterproof efficiency as compared with the used amount. In addition, since the waterproofing film is chemically bonded with the concrete components in the concrete, the adhesion of the waterproofing film to the base material is excellent, so that even if the waterproofing film is formed for a long time, the waterproofing film easily peels off It is possible to minimize or prevent the occurrence of a defect.
또한, 상기 방수막은 모재의 강도를 보강하며, 방수제가 모재 내부에 침투시 이미 콘크리트의 수산화칼슘과 반응된 상태가 되므로 방수막 형성 후에 모재 표면의 산화를 방지하고 콘크리트의 내구성을 높여 페인팅 된 상태를 장시간 유지하며 건축물의 내외벽의 수명을 연장시키는 효과를 기대할 수 있다.In addition, since the waterproofing membrane reinforces the strength of the base material and the waterproofing agent is already reacted with the calcium hydroxide of the concrete when the waterproofing agent penetrates into the base material, the surface of the base material is prevented from being oxidized and the durability of the concrete is improved. And the life of the inner and outer walls of the building can be prolonged.
또한, 방수제의 성분이 모두 무취, 비휘발성 및 무기계 재질로만 구성되므로 친환경적이어서 작업자가 폐쇄공간에서도 보호복 없이 작업을 할 수 있으며, 용해된 상태를 지속적으로 균일하게 유지하므로 작업시 별도의 교반 및 희석 작업이 필요 없어 작업성을 획기적으로 개선할 수 있다. 또한, 유성 재료를 포함하지 않아서 필요시 수성 페인트와 같은 수용성 제품에 다양하게 활용이 가능하다.
In addition, since all of the components of the waterproofing agent are made of odorless, nonvolatile and inorganic materials, it is eco-friendly so that the worker can work without the protective clothing even in the closed space and maintains the dissolved state continuously and uniformly. The work is unnecessary, and the workability can be remarkably improved. In addition, it does not contain oily materials and can be used in water-soluble products such as water-based paints, if necessary.
실험예Experimental Example
위와 같이 구성된 본 발명의 일 실시예에 의한 방수제는 아래 표 1과 같은 성분함량으로 제작되었다.
The waterproofing agent according to one embodiment of the present invention constituted as described above was prepared with the ingredients as shown in Table 1 below.
(다우코닝)OFS-0777
(Dow Corning)
도 1은 본 발명의 일 실시예에 따른 친환경 무기계 침투형 방수제의 KS 규격에 따른 시험결과를 나타낸 표이다. 여기서, 사용된 친환경 무기계 침투형 방수제의 도포량은 1㎠당 0.3g이다.1 is a table showing test results according to the KS standard of an environmentally friendly inorganic penetrant type waterproofing agent according to an embodiment of the present invention. Here, the application amount of the environmentally friendly inorganic penetrant type water repellent agent used is 0.3 g per 1 cm 2.
도 1에 나타난 바와 같이, 상기의 친환경 무기계 침투형 방수제는 내흡수성능이 0.32이고, 내투수성능이 0.09로 나타나 우수한 방수성 및 발수성을 가짐을 확인할 수 있다. 그리고, 냄새와 맛 테스트 결과, 색도 테스트 결과, 중금속 테스트 결과 및 pH 테스트 결과를 볼 때 친환경적 성분임을 확인할 수 있다.As shown in FIG. 1, the above-mentioned environmentally friendly inorganic penetrant type waterproofing agent has an excellent water absorption property and water repellency because the water absorption performance is 0.32 and the water permeability is 0.09. As a result of odor and taste test, color test result, heavy metal test result and pH test result, it can be confirmed that it is an environmentally friendly ingredient.
본 발명은 상술한 실시예 및 첨부된 도면에 의해 한정되는 것이 아니며 첨부된 청구범위에 의해 한정하고자 한다. 따라서, 청구범위에 기재된 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 당 기술분야의 통상의 지식을 가진 자에 의해 다양한 형태의 치환, 변형 및 변경이 가능할 것이며, 이 또한 본 발명의 범위에 속한다고 할 것이다.The present invention is not limited by the above-described embodiment and the accompanying drawings, but is intended to be limited by the appended claims. It will be apparent to those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. something to do.
Claims (3)
포타슘실리케이트 35 내지 45중량%;
포타슘실리코네이트 15 내지 25중량%;
실란 5 내지 15중량%; 및
계면활성제 0.5 내지 1.5중량%; 를 포함하며
콘크리트 또는 시멘트 모재 내부로 침투하여 방수막을 형성하는 친환경 무기계 침투형 방수제.25 to 35% by weight of distilled water;
35 to 45% by weight of potassium silicate;
15-25% by weight of potassium silicate;
5 to 15% by weight silane; And
0.5 to 1.5% by weight of a surfactant; And it includes a
It is an environmentally friendly inorganic penetration type waterproofing agent that permeates into concrete or cement base material to form a waterproof film.
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CN108821638A (en) * | 2018-06-20 | 2018-11-16 | 河南阳光防水科技有限公司 | Modified early strong waterproofing agent of organosilicon |
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US5356716A (en) * | 1992-09-04 | 1994-10-18 | Patel Pratim R | Waterproofing sealer/repellent compositions for concrete, masonry and porous surfaces |
JPH10139568A (en) * | 1996-11-11 | 1998-05-26 | Mitsubishi Chem Corp | Water absorption inhibitor composition |
KR100474166B1 (en) | 2001-10-15 | 2005-03-08 | 임기채 | Method for carrying out water-proof and using thereof water-proof material |
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US5356716A (en) * | 1992-09-04 | 1994-10-18 | Patel Pratim R | Waterproofing sealer/repellent compositions for concrete, masonry and porous surfaces |
JPH10139568A (en) * | 1996-11-11 | 1998-05-26 | Mitsubishi Chem Corp | Water absorption inhibitor composition |
KR100474166B1 (en) | 2001-10-15 | 2005-03-08 | 임기채 | Method for carrying out water-proof and using thereof water-proof material |
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