SK51393A3 - Oxidation of organic substances in water or in waste water - Google Patents
Oxidation of organic substances in water or in waste water Download PDFInfo
- Publication number
- SK51393A3 SK51393A3 SK513-93A SK51393A SK51393A3 SK 51393 A3 SK51393 A3 SK 51393A3 SK 51393 A SK51393 A SK 51393A SK 51393 A3 SK51393 A3 SK 51393A3
- Authority
- SK
- Slovakia
- Prior art keywords
- ozone
- waste water
- containing gas
- reaction
- water
- Prior art date
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 20
- 239000000126 substance Substances 0.000 title claims abstract description 6
- 230000003647 oxidation Effects 0.000 title description 3
- 238000007254 oxidation reaction Methods 0.000 title description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title description 3
- 238000006243 chemical reaction Methods 0.000 claims abstract description 28
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims description 9
- 230000005855 radiation Effects 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000010865 sewage Substances 0.000 claims 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 10
- 238000007872 degassing Methods 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Physical Water Treatments (AREA)
- Compounds Of Unknown Constitution (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Description
Vynález sa týka spôsobu oxidácie organických substancií vo vode alebo odpadovej vode. ktoré sú vopred alebo následne biologicky spracované, spracovaním plynom obsahujúcim ozón alebo tekutinou obsahujúcou ozón aspoň vo dvoch za sebou zaradených r..akčných nádržiach a UV žiarením v UV reaktore.The invention relates to a process for the oxidation of organic substances in water or waste water. which are pretreated or subsequently biologically treated, by treating with an ozone-containing gas or an ozone-containing fluid in at least two successive reaction tanks and UV radiation in a UV reactor.
botera jší s bav technikybotera with fun techniques
Kombináciou ozónu a IJV žiarenia sa môžu oxidovať také substancie. ktoré samotné s ozónom alebo UV žiarením nebudú reagovať. alebo len nepatrne. Reakčné produkty vzniknuté kombinovaným spracovaním ozónom a UV žiarením sú ľahko biologicky odbúrateľné.By combining ozone and IJV radiation, such substances can be oxidized. which do not react with ozone or UV alone. or only slightly. The reaction products resulting from the combined treatment with ozone and UV radiation are readily biodegradable.
U známych postupov tohto typu (Dr. 0. Leitzke. The combined applicatlon of ozone an UV irradiation for the treatment of vater. ISBN 92 - 9095 - 000 - 5. strana 357 až 370). sa spracovávaná odpadová voda zavedie v spoločnom prúde s plynom obsahujúcim ozón do viacerých, spravidla do dvoch, reakčných nádob a po oddelení zvyškových plynov sa vystaví UV žiareniu. Tento postup má pomerne vysokú spotrebu ozónu.For known procedures of this type (Dr. O. Leitzke. The combined applicatlon of ozone and UV irradiation for the treatment of the water. ISBN 92-9095-000-5 pages 357- 370). the treated waste water is fed together with the ozone-containing gas into a plurality, typically two, of the reaction vessels and subjected to UV radiation after separation of the residual gases. This process has a relatively high ozone consumption.
Podstata vynálezuSUMMARY OF THE INVENTION
Vynález spočíva v úlohe vytvoriť spôsob oxidácie organických substancií υ odpadovej vode kombinovaným spracovaním ozónom a UV žiarením, ktorý má nepatrnú špecifickú potrebu ozónu a nepatrnú spotrebu energie.The object of the present invention is to provide a process for the oxidation of organic substances to waste water by combined treatment with ozone and UV radiation, which has a low specific ozone requirement and a low energy consumption.
Vychádzajúc zo stavu techniky, ktorý zohľadňuje * predvýznaková časť nároku 1., je táto úloha podľa vynálezu vyriešená znakmi uvedenými vo význakovej časti nároku 1.Starting from the state of the art, which takes into account the preamble of claim 1, this object of the invention is solved by the features set forth in the characterizing portion of claim 1.
Ďalšie výhodné uskutočnenia vynálezu sú uvedené vo vedľajších nárokoch.Further advantageous embodiments of the invention are set forth in the subclaims.
(ipatreniami podľa vynálezu, ktorými sa odpadová voda a ozón ui.tlú v protiprúde a vstup plynu obsahujúceho ozón do reakčnej nádrže sa uskutočňuje ich rôznou tlakovou úrovňou, sa dosiahne vysoký stupeň využitia ozónu, spojený s priaznivou spotrebou energie. Na tomto základe sa tiež môžu dosiahnuť malé reakčné nádrže, čím sa znížia investičné náklady.(With the measures according to the invention, by which the wastewater and ozone flow in countercurrent and the entry of the ozone-containing gas into the reaction tank is carried out at different pressure levels, a high degree of ozone utilization associated with favorable energy consumption is achieved. to achieve small reaction tanks, thus reducing investment costs.
Popis obrázku na výkreseDescription of the drawing in the drawing
Obrázok znázorňuje v schématickej podobe uskutočnenie vynálezu.The figure shows in schematic form an embodiment of the invention.
Príklad uskutočnenia vynálezuDETAILED DESCRIPTION OF THE INVENTION
Je znázornené zariadenie na spracovanie skôr biologicky spracovaných odpadových vôd, ktoré v podstate pozostáva z reakčných nádrží 1.2, výrobníka 8 ozónu, nádrže 4 odplynenia a IJV-reaktora 5. Podľa vynálezu budú nádrže i, 2 pracovať s pribúdajúcim tlakom v smere prúdenia odpadových vôd, a to prvá reakčná nádrž i s tlakom 5 barrov a druhá reakčná nádrž·2 s tlakom 7 barrov.An apparatus for treating previously biologically treated waste water is shown, which essentially consists of reaction tanks 1.2, ozone generator 8, degassing tank 4 and an IJ reactor 5. According to the invention, tanks 1, 2 will operate at increasing pressure in the direction of wastewater flow. the first reaction tank with a pressure of 5 bar and the second reaction tank · 2 with a pressure of 7 bar.
Vopred biologicky spracovaná odpadová voda sa privedie do zariadenia prívodným vedením 6 a uvedie ša čerpadlom 7 na tlak 5 barrov. Privedie sa do prvej reakčnej nádrže L, ktorej plniaci stav sa reguluje regulátorom 8 plniaceho stavu a regulačným ventilom 9. Podľa vynálezu sa do prvej reakčnej nádrže 1 privedie vedením 10 ozónu v protiprúde k odpadovej vode plyn obsahujúci ozón. Zvyškový plyn opúšťa priestor hlavy prvej reakčnej nádrže i vedením 11 zvyškového plynu.The pre-treated waste water is fed to the plant via a feed line 6 and brought through a pump 7 to a pressure of 5 bar. It is fed to a first reaction tank L, the filling state of which is controlled by the filling state regulator 8 and the control valve 9. According to the invention, a ozone-containing gas is supplied to the first reaction tank 1 in a countercurrent flow to the waste water. The residual gas leaves the head space of the first reaction tank through the residual gas line 11 as well.
Z prvej reakčnej nádrže 1_ prúdi odpadová voda regulačným ventilom 9 & odvodným vedením 12 do nádrže 4 odplynenia, kde sa oddifľuje zvyškový plyn obsahujúci ozón a privádza sa spojovacím vodením 13 do zariadenia 14 rozkladu ozónu. Odplynená odpadová voda sa z nádrže 4 odplynenia vedie druhým spojovacím vedením 15 do UV reaktora 5 a pomocou druhého čerpadla 16 sa stlačí na tlak 7 bánov. Odtiaľ prúdi tretím spojovacím vedením 17 do druhej reakčnej nádrže 2. Čast odplynenej odpadovej vody sa odvádza ako úplne spracovaná odpadová voda odvodným ventilom 18 a výstupným vedením 19. Plniaci stav v nádrži 4 sa nastaví regulátorom 20 plniaceho stavu.From the first reaction tank 7, the waste water flows through the control valve 9 through the discharge line 12 to the degassing tank 4, where the ozone-containing residual gas is separated and fed via the connecting line 13 to the ozone decomposition device 14. The degassed waste water from the degassing tank 4 is passed through a second connecting line 15 to the UV reactor 5 and is compressed to a pressure of 7 by means of a second pump 16. From there it flows through the third connection line 17 to the second reaction tank 2. Part of the degassed waste water is discharged as completely treated waste water via the outlet valve 18 and the outlet line 19. The filling state in the tank 4 is adjusted by the filling state controller 20.
Z druhej reakčnej nádrže 2 sa odpadová voda odoberá druhým odvodným vedením 21 a pomocou tretieho čerpadla 22 sa zvyšuje tlak. v injektore 23 sa upravuje zmesou ozón - kyslík a štvrtým spojovacím vedením 24 sa znova zavádza do druhej reakčnej nádrže 2. Cast odvodnej vody sa pred injektorom 23 odvádza piatym spojovacím vedením 25 a ventilom 26 do prvej i?eakčnej nádrže 1. Plyn z hlavy druhej reakčnej nádrže 2 sa podľa vynálezu vedením 10 ozónu na základe tlakového spádu zavádza cez filtračnú dosku do prvej reakčnej nádoby 1. Plniaci stav v druhej reakčnej nádrži 2 sa reguluje druhým regulátorom 29 plniaceho stavu.From the second reaction tank 2, the waste water is taken off by the second drain line 21 and the pressure is increased by the third pump 22. in injector 23 it is treated with an ozone-oxygen mixture and recirculated through the fourth connecting line 24 to the second reaction tank 2. Part of the effluent before the injector 23 is discharged through the fifth connecting line 25 and the valve 26 into the first reaction tank 1. According to the invention, the reaction tank 2 is fed through a filter plate to the first reaction vessel 1 via a pressure gradient 10 via a filter plate. The filling state in the second reaction tank 2 is controlled by the second filling state controller 29.
Zvyškový plyn odobraný z prvej reakčnej nádrže 1 vedením li zvyškového plynu prúdi sušiakom 27, mieša sa s kyslíkom z vedenia 28 kyslíka a vo výrobníku 3 ozónu sa znova čiastočné premení na ozón.The residual gas removed from the first reaction tank 1 flows through the residual gas line 11 through a dryer 27, mixed with oxygen from the oxygen line 28 and is partially converted to ozone again in the ozone generator 3.
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE4216784A DE4216784A1 (en) | 1992-05-21 | 1992-05-21 | Process for the oxidation of organic substances in water or waste water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SK51393A3 true SK51393A3 (en) | 1993-12-08 |
Family
ID=6459394
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SK513-93A SK51393A3 (en) | 1992-05-21 | 1993-05-20 | Oxidation of organic substances in water or in waste water |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0570756B1 (en) |
| AT (1) | ATE148678T1 (en) |
| CZ (1) | CZ96193A3 (en) |
| DE (2) | DE4216784A1 (en) |
| HU (1) | HU210437B (en) |
| SI (1) | SI9300273A (en) |
| SK (1) | SK51393A3 (en) |
| ZA (1) | ZA933495B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997029997A1 (en) * | 1996-02-12 | 1997-08-21 | Aqua System A/S | Method and plant for purification of contaminated water |
| WO2002102723A1 (en) * | 2001-06-15 | 2002-12-27 | Vrm Enterprises Pty Ltd | Method and apparatus for the treatment of water |
| DE102008008031A1 (en) | 2008-02-06 | 2009-08-13 | Delta Umwelt-Technik Gmbh | Combined in-situ and on-site cleaning of water containing harmful substances e.g. phenol and alkylphenols, comprises in-situ cleaning of contaminated groundwater in subsurface oxidation and on-site removing substances in the groundwater |
| DE102008008029A1 (en) | 2008-02-06 | 2009-08-13 | Delta Umwelt-Technik Gmbh | Method for cleaning an aqueous medium with toxic and/or highly degradable organic-containing materials, comprises carrying out a complex cleaning operation in a process combination consisting of pre-treatment and conditioning |
| SG176623A1 (en) * | 2009-06-02 | 2012-01-30 | Ian Geoffrey Cummins | Fluid treatment apparatus |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1583394A (en) * | 1976-07-16 | 1981-01-28 | Boc Ltd | Method and apparatus for sterilizing liquids |
| US4792407A (en) * | 1986-11-25 | 1988-12-20 | Ultrox International | Oxidation of organic compounds in water |
| US5124051A (en) * | 1990-11-29 | 1992-06-23 | Solarchem Enterprises Inc. | Process for treatment of contaminated waste water or groundwater |
| JPH05104084A (en) * | 1991-10-18 | 1993-04-27 | Nec Corp | Method for decomposing organochlorine type solvent component in water and apparatus therefor |
| US5178755A (en) * | 1992-02-20 | 1993-01-12 | Estr Inc. | UV-enhanced ozone wastewater treatment system |
-
1992
- 1992-05-21 DE DE4216784A patent/DE4216784A1/en not_active Withdrawn
-
1993
- 1993-05-04 EP EP93107193A patent/EP0570756B1/en not_active Expired - Lifetime
- 1993-05-04 AT AT93107193T patent/ATE148678T1/en active
- 1993-05-04 DE DE59305368T patent/DE59305368D1/en not_active Expired - Fee Related
- 1993-05-10 HU HU9301349A patent/HU210437B/en not_active IP Right Cessation
- 1993-05-19 ZA ZA933495A patent/ZA933495B/en unknown
- 1993-05-20 SK SK513-93A patent/SK51393A3/en unknown
- 1993-05-20 CZ CZ93961A patent/CZ96193A3/en unknown
- 1993-05-21 SI SI9300273A patent/SI9300273A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP0570756A1 (en) | 1993-11-24 |
| HUT66419A (en) | 1994-11-28 |
| EP0570756B1 (en) | 1997-02-05 |
| ZA933495B (en) | 1994-07-18 |
| CZ96193A3 (en) | 1993-12-15 |
| SI9300273A (en) | 1993-12-31 |
| ATE148678T1 (en) | 1997-02-15 |
| DE59305368D1 (en) | 1997-03-20 |
| HU210437B (en) | 1995-04-28 |
| DE4216784A1 (en) | 1993-11-25 |
| HU9301349D0 (en) | 1993-09-28 |
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