SG182166A1 - Improvement of power output in hydraulic systems - Google Patents

Abstract

-41 - IMPROVEMENT OF POWER OUTPUT IN HYDRAULIC SYSTEMS AbstractThe present invention describes use of a fluid having a VI of at least 130 to improve the power output of a hydraulic system. Preferentially, engine speed can be maintained at the same rate selected while using the standard HM oil, and deliver >3% higher hydraulic power output.Figure: 1

Description

Improvement of Power Output in Hydraulic Systems

Description

The present invention relates to the increase of power output in hydraulic pumps and mo- tors, achieved by the use of hydraulic fluids with high viscosity index. Use of such fluids can increase the power output of the system without any modification of the hardware.

Hydraulic systems are designed to transmit energy and apply large forces with a high degree of flexibility and control. It is desirable to build systems that efficiently convert input energy from an engine, electric motor, or other source into usable work. Hydraulic power can be used to create rotary or linear motion, or to store energy for future use in an accumulator.

Hydraulic systems provide a significantly more accurate and adjustable means to transmit energy than electrical or mechanical systems. In general, hydraulic systems are reliable, effi- cient, and cost effective, leading to their wide use in the industrial world. The fluid power industry is constantly improving the cost effectiveness of hydraulic systems by employing new mechanical components and materials of construction.

Water and many other liquids can be utilized to make practical use of Pascal's Law, which states that a fluid compressed in a closed container will transmit the resulting pressure throughout the system undiminished and equal in all directions.

Standard "HM" monograde oil is typically selected as it is the lowest cost option and has a long history of dependable performance with no maintenance issues. Outdoor applications of fluid power that experience wide variations in temperature will make use of lower viscos- ity grade fluids in the winter and higher viscosity grade fluids in the summer. Some hydrau-

lic fluids are formulated with PAMA additives as viscosity index improvers, in order to achieve good low temperature fluidity properties under cold start-up conditions ("HV" grade oils). PAMA additives are not known to offer any other performance benefits.

E.g., the document WO 2005108531 describes the use of hydraulic fluids comprising

PAMA additives in order to reduce the temperature increase of a hydraulic fluid under work load. However, an improvement with regard to power output is not indicated or suggested by that document.

Additionally, the document WO 2005014762 discloses a functional fluid having an im- proved fire resistance. The fluid can be used in hydraulic systems. However, the document "is silent with regard to the power output of the system using such a fluid.

Achieving higher power output in a hydraulic system is typically achieved by selecting a lar- ger pump, or by other hardware construction improvements of the unit providing mechani- : cal energy to the hydraulic system. However, such an approach is usually connected with higher energy consumption and increased cost.

A further common object is the improvement of the volume output. According to prior art, these objects are achieved by a combustion engine or an electric motor having more power.

However, such approach is usually connected with higher energy consumption and in- creased cost, and is often constrained by space or weight limitations. :

Taking into consideration the prior art, it is an object of this invention to provide hydraulic systems having increased power output in order to facilitate increased work loads and im- : proved productivity. Increased power output can be used to generate increased digging force, lifting capacity, or machine speed. Furthermore, an improvement of the lifetime and the service interval of the hydraulic system is a common object.

- 3 =

These as well as other not explicitly mentioned objects, which, however, can easily be de- rived or developed from the introductory part, are achieved by the use of a fluid according to present claim 1.

Especially, the improvement in hydraulic power output is achieved by the use of a fluid ac- cording to present claim 1. Expedient modifications of the use in accordance with the inven- tion are described in the dependent claims.

The use of a fluid having a VI of at least 130 provides an unexpected increase in the hydrau- lic power output of a pump. The increased power output from the pump results in increased power output from the hydraulic motor (cylinder or rotary motor).

The hydraulic fluid of the present invention shows an improved low temperature perform- ance and broader temperature operating window. Furthermore, the hydraulic fluid provides an improvement in volume output. Additionally, a hydraulic system using a hydraulic fluid having a VI of at least 130 shows an improvement of the power drop, especially at a high load of the unit providing mechanical work. Therefore, the constancy of the power output is improved by the use of the present invention.

The hydraulic fluid of the present invention can be sold on a cost favorable basis with fast investment pay-back time.

It is also possible to design a hydraulic system utilizing a high viscosity index hydraulic fluid that operates at a lower pressure level, and generates an equivalent amount of hydraulic power output with lower pump input energy. A system that operates at lower pressure will have longer component life (seals, hoses, wear surfaces, fluid), and will result in lower fluid operating temperature.

The hydraulic fluid of the present invention exhibits good resistance to oxidation and is chemically very stable, compared to a standard HM fluid.

The viscosity of the hydraulic fluid of the present invention can be adjusted over a broad range.

Furthermore, the hydraulic fluids of the present invention are appropriate for high pressure applications, in the range of 100 to 700 bars. The hydraulic fluids of the present invention show a minimal change in viscosity in-service due to good shear stability.

Additionally, the improvement of power output and system productivity can be achieved without constructional changes of the hydraulic system. Consequently, the power output of both new and old hydraulic systems can be improved at very low cost. The composition of such hydraulic fluids are fully compatible with existing elastomeric materials used in seals, bladders, and hoses making them immediately acceptable for use in existing industrial hy- draulic systems.

The hydraulic fluid used according to the present invention has a viscosity index of at least 130, preferably at least 150, more preferably at least 180 and most preferably at least 200.

According to a preferred embodiment of the present invention, the viscosity index is in the . range of 150 to 400, more preferably 200 to 300. The viscosity index can be determined ac- cording to ASTM D 2270.

The use according to the present invention provides an improvement of the power output of a hydraulic system. The expression “power output” means energy usable as work, typically measured and quantified as output torque from a rotary hydraulic motor in horsepower or kilowatts.

Preferably, the fluid of the present invention is effective in increasing the power output of the hydraulic system by at least 3%, more preferably at least 5 % and more preferably at least 10%, compared to the power output of a system using a monograde hydraulic fluid having a VI of about 100 operating at the same pressure and temperature with identical me-

= 5 - chanical power input from the engine or electric motor. Therefore, equal amounts of en- ergy are consumed (fuel or electricity), however, the system using the high VI fluid will produce more usable output power in an equal period of time.

According to a preferred embodiment of the present invention, the volume output is in- creased. Preferably, the fluid of the present invention is effective in increasing the volume output of the hydraulic system by at least 3%, more preferably at least 5 % and more pref- erably at least 10%, compared to the volume output of a system using a monograde hydrau- lic fluid having a VI of about 100 operating at the same pressure and temperature with iden- tical mechanical power input from the engine or electric motor. The expression “volume output” means volume provided to a hydraulic motor usable as work at a specific pressure difference, typically measured and quantified in m’ or liter.

The present invention could additionally provide a method for improving the constancy of oo the power output. Surprisingly, the constancy of the power output can also be increased at the maximum load. For example, the drop of the power output after at least 10 minutes of operating time is preferably at most 3%, measured at a load of 90% of the maximum load or more of a unit providing mechanical energy.

The improvements mentioned above can be used to increase the performance of a hydraulic system in an astonishing manner. By providing a system having a low and postponed drop of the power output, the system can be used at the power limits of the unit creating me- chanical energy. Therefore, a defined work can be done within a shorter time without the need of constructional changes of the system. Preferably, the engine speed of a unit provid- ing mechanical energy is maintained at a constant rate and the system delivers an increased level of hydraulic power.

According to a preferred embodiment of the present invention, the hydraulic system can be designed to operate at a lower pressure, such that the output power is equivalent to that de- livered by a reference system using a hydraulic fluid with a VI of 100. The person skilled in

. the art can easily perform such design changes. E.g., in an excavator the shovel can be changed. By using a lower pressure, the lifetime and the service intervals of the hydraulic system can be improved in an astonishing manner. . According to a preferred embodiment of the present invention, the hydraulic system can demonstrate an improvement in the ratio of hydraulic power output to power input, such that the ratio of power output/power input is preferably improved by at least 3%, more preferably at least 5 % compared to that delivered by a reference system using a hydraulic fluid with a VI of 100.

The viscosity of the hydraulic fluid of the present invention can be adapted with in wide range, according to the requirements of the hydraulic pump/motor manufacturer. ISO VG 15,22, 32, 46, 68, 100, 150 fluid grades can be achieved, e.g.

ISO 3448 Viscosity | Typical Viscosity, | Minimum Viscosity, | Maximum Vis- °C move | wv | wo | mor

Preferably the kinematic viscosity 40°C according to ASTM D 445 of is the range of 15 mm?/s to 150 mm/s, preferably 28 mm/s to 110 mm®/s.

For the use according to the present invention, preferred hydraulic fluids are NFPA (Na- tional Fluid Power Association) multigrade fluids, e.g. double, triple, quadra and/or penta grade fluids as defined by NFPA T2.13.13-2002.

Preferred fluids comprise at least a mineral oil and/or a synthetic oil. : Mineral oils are substantially known and commercially available. They are in general ob- tained from petroleum or crude oil by distillation and/or refining and optionally additional purification and processing methods, especially the higher-boiling fractions of crude oil or petroleum fall under the concept of mineral oil. In general, the boiling point of the mineral oil is higher than 200°C, preferably higher than 300°C, at 5000 Pa. Preparation by low tem- perature distillation of shale oil, coking of hard coal, distillation of lignite under exclusion of air as well as hydrogenation of hard coal or lignite is likewise possible. To a small extent mineral oils are also produced from raw materials of plant origin (for example jojoba, rape- seed (canola), sunflower, and soybean oil) or animal origin (for example tallow or neat foot - oil). Accordingly, mineral oils exhibit different amounts of aromatic, cyclic, branched and linear hydrocarbons, in each case according to origin.

In general, one distinguishes paraffin-base, naphthenic and aromatic fractions in crude oil or mineral oil, where the term paraffin-base fraction stands for longer-chain or highly branched isoalkanes and naphthenic fraction stands for cycloalkanes. Moreover, mineral oils, in each case according to origin and processing, exhibit different fractions of n-alkanes, isoalkanes with a low degree of branching, so called monomethyl-branched paraffins, and compounds with heteroatoms, especially O, N and/or S, to which polar properties are attributed. How- ever, attribution is difficult, since individual alkane molecules can have both long-chain branched and cycloalkane residues and aromatic components. For purposes of this inven- tion, classification can be done in accordance with DIN 51 378. Polar components can also be determined in accordance with ASTM D 2007.

The fraction of n-alkanes in the preferred mineral oils is less than 3 wt%, and the fraction of

O, N and/or S-containing compounds is less than 6 wt%. The fraction of aromatic com- pounds and monomethyl-branched paraffins is in general in each case in the range of 0-40 wt%. In accordance with one interesting aspect, mineral oil comprises mainly naphthenic

; and paraffin-base alkanes, which in general have more than 13, preferably more than 18 and especially preferably more than 20 carbon atoms. The fraction of these compounds is in general at least 60 wt%, preferably at least 80 wt%, without any limitation intended by this.

A preferred mineral oil contains 0.5-30 wt% aromatic components, 15-40 wt% naphthenic components, 35-80 wt% paraffin-base components, up to 3 wt% n-alkanes and 0.05-5 wt% polar components, in each case with respect to the total weight of the mineral oil.

An analysis of especially preferred mineral oils, which was done with traditional methods such as urea dewaxing and liquid chromatography on silica gel, shows, for example, the fol- lowing components, where the percentages refer to the total weight of the relevant mineral oil: n-alkanes with about 18-31 C atoms: 0.7-1.0%, low-branched alkanes with 18-31 C atoms: 1.0-8.0%, aromatic compounds with 14-32 C atoms: 0.4-10.7%, iso- and cycloalkanes with 20-32 C atoms: 60.7-82.4%, polar compounds: 0.1-0.8%, loss: 6.9-19.4%.

Valuable advice regarding the analysis of mineral oil as well as a list of mineral oils that have other compositions can be found, for example, in Ullmann's Encyclopedia of Industrial

Chemistry, 5th Edition on CD-ROM, 1997, under the entry "lubricants and related prod- ucts."

Preferably, the hydraulic fluid is based on mineral oil from API Group I, II, or III. Accord- ing to a preferred embodiment of the present invention, a mineral oil containing at least 90 % by weight saturates and at most about 0.03 % sulfur measured by elemental analysis is used. Especially, API Group II oils are preferred.

API Group IV and V synthetic oils are, among other substances, organic esters like carbox- ylic esters and phosphate esters; organic ethers like silicone oils and polyalkylene glycol; and

Cy synthetic hydrocarbons, especially polyolefins and Fischer-Tropsch (GTL) derived base oils.

They are for the most part somewhat more expensive than the mineral oils, but they have advantages with regard to performance. For an explanation reference is made to the 5 API classes of base oil types (API: American Petroleum Institute).

American Petroleum Institute (APT) Base Oil Classifications

Base stock Group Viscosity Index [Sulfur (weight %) |Saturates

Group IV all synthetic > 120 <0.03 >99

Group V all not in- >120 <0.03 cluded in Groups I-1V, e.g. esters, polyalkylene glycols

Synthetic hydrocarbons, especially polyolefins are well known in the art. Especially polyal- phaolefins (PAO) are preferred. These compounds are obtainable by polymerization of al- kenes, especially alkenes having 3 to 12 carbon atoms, like propene, hexene-1, octene-1, and dodecene-1. Preferred PAOs have a number average molecular weight in the range of 200 to 10000 g/mol, more preferably 500 to 5000 g/mol.

According to a preferred aspect of the present invention, the hydraulic fluid may comprise an oxygen containing compound selected from the group of carboxylic acid esters, poly- ether polyols and/or organophosphorus compounds. Preferably, the oxygen containing compound is a carboxylic ester containing at least two ester groups, a diester of carboxylic acids containing 4 to 12 carbon atoms and/or a ester of a polyol. By using an oxygen con- taining compound as a basestock, the fire resistance of the hydraulic fluid can be improved.

Phosphorus ester fluids can be used as a component of the hydraulic fluid such as alkyl aryl phosphate ester; trialkyl phosphates such as tributyl phosphate or tri-2-ethylhexyl phos- phate; triaryl phosphates such as mixed isopropylphenyl phosphates, mixed t-butylphenyl phosphates, trixylenyl phosphate, or tricresylphosphate. Additional classes of organophos- phorus compounds are phosphonates and phosphinates, which may contain alkyl and/or aryl substituents. Dialkyl phosphonates such as di-2-ethylhexylphosphonate; alkyl phosphinates such as di-2-ethylhexylphosphinate are useful. As the alkyl group herein, linear or branched chain alkyls comprising 1 to 10 carbon atoms are preferred. As the aryl group herein, aryls comprising 6 to 10 carbon atoms that maybe substituted by alkyls are preferred. Especially, the hydraulic fluids may contain 0 to 60 % by weight, preferably 5 to 50% by weight or- ganophosphorus compounds.

As the carboxylic acid esters reaction products of alcohols such as polyhydric alcohol, monohydric alcohol and the like, and fatty acids such as mono carboxylic acid, polycarbox- ylic acid and the like can be used. Such carboxylic acid esters can of course be a partial es- ter.

Carboxylic acid esters may have one carboxylic ester group having the formula R-COO-R, wherein R is independently a group comprising 1 to 40 carbon atoms. Preferred ester com- pounds comprise at least two ester groups. These compounds may be based on polycarbox- ylic acids having at least two acidic groups and/or polyols having at least two hydroxyl groups.

The polycarboxylic acid residue usually has 2 to 40, preferably 4 to 24, especially 4 to 12 carbon atoms. Useful polycarboxylic acids esters are, e.g., esters of adipic, azelaic, sebacic, phthalate and/or dodecanoic acids. The alcohol component of the polycarboxylic acid com- pound preferably comprises 1 to 20, especially 2 to 10 carbon atoms.

Examples of useful alcohols are methanol, ethanol, propanol, butanol, pentanol, hexanol, heptanol and octanol. Furthermore, oxoalcohols can be used such as diethylene glycol, triethylene glycol, tetraethylene glycol up to decamethylene glycol.

Especially preferred compounds are esters of polycarboxylic acids with alcohols comprising one hydroxyl group. Examples of these compounds are described in Ullmanns Encyclopédie der Technischen Chemie, third edition, vol. 15, page 287 -292, Urban & Schwarzenber (1964).

Useful polyols to obtain ester compounds comprising at least two ester groups contain usu- ally 2 to 40, preferably 4 to 22 carbon atoms. Examples are neopentyl glycol, diethylene glycol, dipropylene glycol, 2,2-dimethyl-3-hydroxypropyl-2',2'-dimethyl-3'-hydroxy propi- onate, glycerol, trimethylolethane, trimethanol propane, trimethylolnonane, ditrimethylol- propane, pentaerythritol, sorbitol, mannitol and dipentaerythritol. The carboxylic acid com- ponent of the polyester may contain 1 to 40, preferably 2 to 24 carbon atoms. Examples are linear or branched saturated fatty acids such as formic acid, acetic acid, propionic acid, oc- tanoic acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, capric acid, unde- canoic acid, lauric acid, tridecanoic acid, myrisric acid, pentadecanoic acid, palmitic acid, heptadecanoic acid, stearic acid, nonadecanoic acid, arachic acid, behenic acid, isomyiristic acid, isopalmitic acid, isostearic acid, 2,2-dimethylbutanoic acid, 2,2-dimethylpentanoic acid, 2,2-dimethyloctanoic acid, 2-ethy1-2.3,3-trimethylbutanoic acid, 2,2,3,4- tetramethylpentanoic acid, 2,5,5-trimethyl-2-t-butylhexanoic acid, 2,3,3-trimethyl-2- ethylbutanoic acid, 2,3-dimethyl-2-isopropylbutanoic acid, 2-ethylhexanoic acid, 3,5,5- trimethylhexanoic, acid; linear or branched unsaturated fatty such as linoleic acid, linolenic acid, 9 octadecenoic acid, undecenoic acid, elaidic acid, cetoleic acid, erucic acid, brassidic acid, and commercial grades of oleic acid from a variety of animal fat or vegetable oil sources. Mixtures of fatty acids such as tall oil fatty acids can be used.

Especially useful compounds comprising at least two ester groups are, €.g., neopentyl glycol tallate, neopentyl glycol dioleate, propylene glycol tallate, propylene glycol dioleate, di- ethylene glycol tallate, and diethylene glycol dioleate.

Many of these compounds are commercially available from Inolex Chemical Co. under the trademark Lexolube 2G-214, from Cognis Corp. under the trademark ProEco 2965, from

Uniqema Corp. under the trademarks Priotube 1430 and Priolube 1446 and from Georgia

Pacific under the trademarks Xtolube 1301 and Xtolube 1320.

Furthermore, ethers are useful as a component of the hydraulic fluid. Preferably, polyether polyols are used as a component of the hydraulic fluid of the present invention. These com- pounds are well known. Examples are polyalkylene glycols like, e.g., polyethylene glycols, polypropylene glycols and polybutylene glycols. The polyalkylene glycols can be based on mixtures of alkylene oxides. These compounds preferably comprise 1 to 40 alkylene oxide units, more preferably 5 to 30 alkylene oxide units. Polybutylene glycols are preferred com- pounds for anhydrous fluids. The polyether polyols may comprise further groups, like e.g., alkylene or arylene groups comprising 1 to 40, especially 2 to 22 carbon atoms.

According to another aspect of the present invention, the hydraulic fluid is based on a syn- thetic basestock comprising polyalphaolefin (PAO), carboxylic esters (diester, or polyol es- ter), a vegetable ester, phosphate ester (trialkyl, triaryl, or alkyl aryl phosphates), and/or polyalkylene glycol (PAG). Preferred synthetic basestocks are API Group IV and/or Group

V oils.

Preferably, the hydraulic fluid is obtainable by mixing at least two components. At least one of the components shall be a base oil. The expression base oil includes mineral oil and/or synthetic oil on which the hydraulic fluid could be based as mentioned above. Preferably, the hydraulic fluid comprises at least 60 % by weight of base oil. Preferably, at least one of the components may have a viscosity index of 120 or less. According to a preferred embodi-

ment, the hydraulic fluid may comprise at least 60 % by weight of at least one component having a viscosity index of 120 or less.

Particularly, a polymeric viscosity index improver can be used as a component of the hy- draulic fluid. Viscosity index improvers are well known and, e.g. disclosed in Ullmann's En- cyclopedia of Industrial Chemistry, 5th Edition on CD-ROM, 1997.

Preferred polymers useful as VI improvers comprise units derived from alkyl esters having at least one ethylenically unsaturated group. These polymers are well known in the art. Pre- ferred polymers are obtainable by polymerizing, in particular, (meth)acrylates, maleates and fumarates. The term (meth)acrylates includes methacrylates and acrylates as well as mix- “tures of the two. These monomers are well known in the art. The alkyl residue can be linear, cyclic or branched.

Mixtures to obtain preferred polymers comprising units derived from alkyl esters contain 0 to 100 wt%, preferably 0,5 to 90 wt%, especially 1 to 80 wt%, more preferably 1 to 30 wt%, more preferably 2 to 20 wt% based on the total weight of the monomer mixture of one or more ethylenically unsaturated ester compounds of formula (I)

R

A .

RZ O where R is hydrogen or methyl, R' means a linear or branched alkyl residue with 1-6, espe- cially 1 to 5 and preferably 1 to 3 carbon atoms, R? and R? are independently hydrogen or a group of the formula ~-COOR', where R' means hydrogen or an alkyl group with 1-6 carbon atoms.

Examples of component (a) are, among others, (meth)acrylates, fumarates and maleates, which derived from saturated alcohols such as methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, isopropyl (meth)acrylate, n-butyl (meth)acrylate, tert-butyl

] us (meth)acrylate, pentyl (meth)acrylate and hexyl (meth)acrylate; cycloalkyl (meth)acrylates, like cyclopentyl (meth)acrylate.

Furthermore, the monomer compositions to obtain the polymers comprising units derived from alkyl esters contain 0 — 100 wt%, preferably 10-99 wt%, especially 20-95 wt% and more preferably 30 to 85 wt% based on the total weight of the monomer mixture of one or more ethylenically unsaturated ester compounds of formula (II)

R

A an,

RS 0 where R is hydrogen or methyl, R* means a linear or branched alkyl residue with 7-40, es- pecially 10 to 30 and preferably 12 to 24 carbon atoms, R® and R® are independently hydro- gen or a group of the formula ~COOR", where R" means hydrogen or an alkyl group with 7 to 40, especially 10 to 30 and preferably 12 to 24 carbon atoms.

Among these are (meth)acrylates, fumarates and maleates that derive from saturated alco- hols, such as 2-ethylhexyl (meth)acrylate, heptyl (meth)acrylate, 2-tert-butylheptyl (meth)acrylate, octyl (meth)acrylate, 3-isopropylheptyl (meth)acrylate, nonyl (meth)acrylate, decyl (meth)acrylate, undecyl (meth)acrylate, 5-methylundecyl (meth)acrylate, dodecyl (meth)acrylate, 2-methyldodecyl (meth)acrylate, tridecyl (meth)acrylate, S-methyltridecyl (meth)acrylate, tetradecyl (meth)acrylate, pentadecyl © (meth)acrylate, 2-methylhexadecyl (meth)acrylate, heptadecyl (meth)acrylate, 5- isopropylheptadecyl (meth)acrylate, 4-tert-butyloctadecyl (meth)acrylate, 5-ethyloctadecyl (meth)acrylate, 3-isopropyloctadecyl (methacrylate, octadecyl (meth)acrylate, nonadecyl (meth)acrylate, eicosyl (meth)acrylate, cetyleicosyl (methacrylate, stearyleicosyl (meth)acrylate, docosyl (meth)acrylate, and/or eicosyltetratriacontyl (meth)acrylate; cycloalkyl (meth)acrylates such as 3-vinylcyclohexyl (meth)acrylate, cyclohexyl (meth)acrylate, bornyl (meth)acrylate, 2,4,5-tri-t-butyl-3-vinylcyclohexyl (meth)acrylate,

is - 2,3,4,5-tetra-t-butylcyclohexyl (meth)acrylate; and the corresponding fumarates and maleates.

The ester compounds with a long-chain alcohol residue, especially component (b), can be obtained, for example, by reacting (meth)acrylates, fumarates, maleates and/or the corre- sponding acids with long chain fatty alcohols, where in general a mixture of esters such as (meth)acrylates with different long chain alcohol residues results. These fatty alcohols in- clude, among others, Oxo Alcohol® 7911 and Oxo Alcohol ® 7900, Oxo Alcohol® 1100 (Monsanto); Alphanol® 79 (ICI); Nafol® 1620, Alfol® 610 and Alfol® 810 (Sasol); Epal® 610 and Epal® 810 (Ethyl Corporation); Linevol® 79, Linevol® 911 and Dobanol® 25L (Shell AG); Lial 125 (Sasol); Dehydad® and Dehydad® and Lorol® (Cognis).

Of the ethylenically unsaturated ester compounds, the (meth)acrylates are particularly pre- ferred over the maleates and furmarates, i.e., R%, R?, R®, R® of formulas (I) and (II) repre- + sent hydrogen in particularly preferred embodiments.

In a particular aspect of the present invention, preference is given to using mixtures of ethylenically unsaturated ester compounds of formula (IT), and the mixtures have at least one (meth)acrylate having from 7 to 15 carbon atoms in the alcohol radical and at least one (meth) acrylate having from 16 to 30 carbon atoms in the alcohol radical. The fraction of the (meth)acrylates having from 7 to 15 carbon atoms in the alcohol radical is preferably in the range from 20 to 95% by weight, based on the weight of the monomer composition for the preparation of polymers. The fraction of the (meth)acrylates having from 16 to 30 car- bon atoms in the alcohol radical is preferably in the range from 0.5 to 60% by weight based on the weight of the monomer composition for the preparation of the polymers comprising units derived from alkyl esters. The weight ratio of the (meth)acrylate having from 7 to 15 carbon atoms in the alcohol radical and the (meth) acrylate having from 16 to 30 carbon at- oms in the alcohol radical is preferably in the range of 10:1 to 1:10, more preferably in the range of 5:1 to 1.5:1.

Component (c) comprises in particular ethylenically unsaturated monomers that can co- polymerize with the ethylenically unsaturated ester compounds of formula (I) and/or (II).

Comonomers that correspond to the following formula are especially suitable for polymeri- zation in accordance with the invention:

RIY R2*

R3 I~. where R1* and R2* independently are selected from the group consisting of hydrogen, halogens, CN, linear or branched alkyl groups with 1-20, preferably 1-6 and especially pref- erably 1-4 carbon atoms, which can be substituted with 1 to (2n+1) halogen atoms, where n is the number of carbon atoms of the alkyl group (for example CF3), a, f-unsaturated linear or branched alkenyl or alkynyl groups with 2-10, preferably 2-6 and especially preferably 2- 4 carbon atoms, which can be substituted with 1 to (2n-1) halogen atoms, preferably chlo- rine, where 1 is the number of carbon atoms of the alkyl group, for example CH,=CCl-, cycloalkyl groups with 3-8 carbon atoms, which can be substituted with 1 to (2n-1) halogen atoms, preferably chlorine, where n is the number of carbon atoms of the cycloalkyl group;

C(=Y*)R5*, C(=Y*)NRTR”, Y*C(=Y*)R”", SOR*", SO,R™, OSO,R”, NR*'SO.R”,

PR), PEY*)R®",, Y#PR™,, Y*P(=Y*)R",, NR*",, which can be quaternized with an addi- tional RY, aryl, or heterocyclyl group, where Y* can be NR*", S or O, preferably O; R™" is an alkyl group with 1-20 carbon atoms, an alkylthio group with 1-20 carbon atoms, OR" (RY is hydrogen or an alkali metal), alkoxy with 1-20 carbon atoms, aryloxy or heterocycly- loxy; R* and R” independently are hydrogen or an alkyl group with one to 20 carbon at- oms, or R® and R”" together can form an alkylene group with 2-7, preferably 2-5 carbon at- oms, where they form a 3-8 member, preferably 3-6 member ring, and R¥ is linear or branched alkyl or aryl groups with 1-20 carbon atoms;

R3* and R4* independently are chosen from the group consisting of hydrogen, halogen (preferably fluorine or chlorine), alkyl groups with 1-6 carbon atoms and COOR’", where

: ! - 17 -

R®" is hydrogen, an alkali metal or an alkyl group with 1-40 carbon atoms, or R'" and R* can together form a group of the formula (CH,),, which can be substituted with 1-2n' halo- gen atoms or C,-C, alkyl groups, or can form a group of the formula C(=0)-Y*-C(=0), where 1' is from 2-6, preferably 3 or 4, and Y* is defined as before; and where at least 2 of the residues RY", R*, R*" and R*" are hydrogen or halogen.

The comonomers include, among others, hydroxyalkyl (meth)acrylates like 3-hydroxypropyl (meth)acrylate, 3,4-dihydroxybutyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2- hydroxypropyl (meth)acrylate, 2,5-dimethyl-1,6-hexanediol (meth)acrylate, 1,10-decanediol (meth)acrylate; aminoalkyl (meth)acrylates and aminoalkyl (meth)acrylamides like N-(3- dimethylaminopropyl)methacrylamide, 3-diethylaminopentyl (meth)acrylate, 3- dibutylaminohexadecyl (meth)acrylate; nitriles of (meth)acrylic acid and other nitrogen-containing (meth)acrylates like N- (methacryloyloxyethyl)diisobutylketimine, N-(methacryloyloxyethyl)dihexadecylketimine, (meth)acryloylamidoacetonitrile, 2-methacryloyloxyethylmethylcyanamide, cyanomethyl (meth)acrylate; aryl (meth)acrylates like benzyl (meth)acrylate or phenyl (meth)acrylate, where the acryl residue in each case can be unsubstituted or substituted up to four times; carbonyl-containing (meth)acrylates like 2-carboxyethyl (meth)acrylate, carboxymethyl (meth)acrylate, oxazolidinylethyl (meth)acrylate,

N-methyacryloyloxy)formamide, acetonyl (meth)acrylate, N-methacryloylmorpholine, N- methacryloyl-2-pyrrolidinone, N-(2-methyacryloxyoxyethyl)-2-pyrrolidinone, N-(3- methacryloyloxypropyl)-2-pyrrolidinone, N-(2-methyacryloyloxypentadecyl(-2- pyrrolidinone, N-(3-methacryloyloxyheptadecyl-2-pyrrolidinone;

! -18 - (meth)acrylates of ether alcohols like tetrahydrofurfuryl (meth)acrylate, vinyloxyethoxyethyl (meth)acrylate, methoxyethoxyethyl (meth)acrylate, 1-butoxypropyl (meth)acrylate, 1-

methyl-(2-vinyloxy)ethyl (meth)acrylate, cyclohexyloxymethyl (meth)acrylate, methoxy- methoxyethyl (meth)acrylate, benzyloxymethyl (methacrylate, furfuryl (meth)acrylate, 2-

butoxyethyl (meth)acrylate, 2-ethoxyethoxymethyl (meth)acrylate, 2-ethoxyethyl ~ (meth)acrylate, ethoxylated (meth)actylates, allyloxymethyl (meth)acrylate, 1-ethoxybutyl

(meth)acrylate, methoxymethyl (meth)acrylate, 1-ethoxyethyl (meth)acrylate, ethoxymethyl

(meth)acrylate; (meth)acrylates of halogenated alcohols like 2,3-dibromopropyl (meth)acrylate, 4-

bromophenyl (meth)acrylate, 1,3-dichloro-2-propyl (meth)acrylate, 2-bromoethyl

(meth)acrylate, 2-iodoethyl (meth)acrylate, chloromethyl (meth)acrylate;

oxiranyl (meth)acrylate like 2, 3-epoxybutyl (meth)acrylate, 3,4-epoxybutyl (meth)acrylate,

10,11 epoxyundecyl (meth)acrylate, 2,3-epoxycyclohexyl (methacrylate, oxiranyl

(meth)acrylates such as 10,11-epoxyhexadecyl (meth)acrylate, glycidyl (meth)acrylate;

phosphorus-, boron- and/or silicon-containing (meth)acrylates like 2-

(dimethylphosphato)propyl (meth)acrylate, 2-(ethylphosphito)propyl (meth)acrylate, 2-

dimethylphosphinomethyl (meth)acrylate, dimethylphosphonoethyl (meth)acrylate, diethyl-

methacryloyl phosphonate, dipropylmethacryloyl phosphate, 2-(dibutylphosphono)ethyl

(meth)acrylate, 2,3-butylenemethacryloylethyl borate, methyldiethoxymethacryloylethoxysil-

iane, diethylphosphatoethyl (meth)acrylate;

sulfur-containing (meth)acrylates like ethylsulfinylethyl (meth)acrylate, 4-thiocyanatobutyl

(meth)acrylate, cthylsulfonylethyl (meth)acrylate, thiocyanatomethyl (meth)acrylate, methyl-

sulfinylmethyl (meth)acrylate, bis(methacryloyloxyethyl) sulfide;

heterocyclic (meth)acrylates like 2-(1-imidazolyl)ethyl (meth)acrylate, 2-(4-

morpholinyl)ethyl (methacrylate and 1-(2-methacryloyloxyethyl)-2-pyrrolidone;

vinyl halides such as, for example, vinyl chloride, vinyl fluoride, vinylidene chloride and vi- nylidene fluoride; vinyl esters like vinyl acetate; vinyl monomers containing aromatic groups like styrene, substituted styrenes with an alkyl substituent in the side chain, such as a-methylstyrene and a-ethylstyrene, substituted styre- nes with an alkyl substituent on the ring such as vinyltoluene and p-methylstyrene, halo- genated styrenes such as monochlorostyrenes, dichlorostyrenes, tribromostyrenes and tetrabromostyrenes; heterocyclic vinyl compounds like 2-vinylpyridine, 3-vinylpyridine, 2-methyl-5- vinylpyridine, 3-ethyl-4-vinylpyridine, 2,3-dimethyl-5-vinylpyridine, vinylpyrimidine, vi- nylpiperidine, 9-vinylcarbazole, 3-vinylcarbazole, 4-vinylcarbazole, 1-vinylimidazole, 2- methyl-1-vinylimidazole, N-vinylpyrrolidone, 2-vinylpyrrolidone, N-vinylpyrrolidine, 3- vinylpyrrolidine, N-vinylcaprolactam, N-vinylbutyrolactam, vinyloxolane, vinylfuran, vinyl- thiophene, vinylthiolane, vinylthiazoles and hydrogenated vinylthiazoles, vinyloxazoles and hydrogenated vinyloxazoles; vinyl and isoprenyl ethers; maleic acid derivatives such as maleic anhydride, methylmaleic anhydride, maleinimide, me- thylmaleinimide; fumaric acid and fumaric acid derivatives such as, for example, mono- and diesters of fu- maric acid.

Monomers that have dispersing functionality can also be used as comonomers. These monomers are well known in the art and contain usually hetero atoms such as oxygen and/or nitrogen. For example the previously mentioned hydroxyalkyl (meth)acrylates, ami- noalkyl (meth)acrylates and aminoalky! (meth)acrylamides, (meth)acrylates of ether alco- hols, heterocyclic (meth)acrylates and heterocyclic vinyl compounds are considered as dis- persing comononers.

Especially preferred mixtures contain methyl methacrylate, lauryl methacrylate and/or stearyl methacrylate.

The components can be used individually or as mixtures.

The hydraulic fluid of the present invention preferably comprises polyalkylmethacrylate polymers. These polymers obtainable by polymerizing compositions comprising alkyl- methacrylate monomers are well known in the art. Preferably, these polyalkylmethacrylate polymers comprise at least 40 % by weight, especially at least 50 % by weight, more pref- erably at least 60 % by weight and most preferably at least 80 % by weight methacrylate re- peating units. Preferably, these polyalkylmethacrylate polymers comprise Co-Cp4 methacry- late repeating units and C;-Cg methacrylate repeating units.

The molecular weight of the polymers derived from alkyl esters is not critical. Usually the polymers derived from alkyl esters have a molecular weight in the range of 300 to 1,000,000 g/mol, preferably in the range of range of 10000 to 200,000 g/mol and more preferably in the range of 25000 to 100,000 g/mol, without any limitation intended by this.

These values refer to the weight average molecular weight of the polymers.

Without intending any limitation by this, the alkyl(meth)acrylate polymers exhibit a polydis- persity, given by the ratio of the weight average molecular weight to the number average molecular weight Mw/Mn, in the range of 1 to 15, preferably 1.1 to 10, especially prefera- bly 1.2 to 5. The polydispersity may be determined by gel permeation chromatography (GPC).

! - 21 -

The monomer mixtures described above can be polymerized by any known method. Con- ventional radical initiators can be used to perform a classic radical polymerization. These initiators are well known in the art. Examples for these radical initiators are azo initiators like 2,2’-azodiisobutyronitrile (AIBN), 2,2’-azobis(2-methylbutyronitrile) and 1,1 azo- biscyclohexane carbonitrile; peroxide compounds, e.g. methyl ethyl ketone peroxide, acetyl acetone peroxide, dilauryl peroxide, tert.-butyl per-2-ethyl hexanoate, ketone peroxide, methyl isobutyl ketone peroxide, cyclohexanone peroxide, dibenzoyl peroxide, tert.-butyl perbenzoate, tert.-butyl peroxy isopropyl carbonate, 2,5-bis(2-ethylhexanoyl-peroxy)-2,5- dimethyl hexane, tert.-butyl peroxy 2-ethyl hexanoate, tert.-butyl peroxy- 3,5,5-trimethyl hexanoate, dicumene peroxide, 1,1 bis(tert. butyl peroxy) cyclohexane, 1,1 bis(tert. butyl peroxy) 3,3,5-trimethyl cyclohexane, cumene hydroperoxide and tert.-butyl hydroperoxide.

Low molecular weight poly(meth)acrylates can be obtained by using chain transfer agents.

This technology is ubiquitously known and practiced in the polymer industry and is de- scribed in Odian, Principles of Polymerization, 1991. Examples of chain transfer agents are sulfur containing compounds such as thiols, e.g. n- and t — dodecanethiol, 2- mercaptoethanol, and mercapto carboxylic acid esters, e.g. methyl-3-mercaptopropionate.

Preferred chain transfer agents contain up to 20, especially up to 15 and more preferably up to 12 carbon atoms. Furthermore, chain transfer agents may contain at least 1, especially at least 2 oxygen atoms.

Furthermore, the low molecular weight poly(meth)acrylates can be obtained by using transi- tion metal complexes, such as low spin cobalt complexes. These technologies are well known and for example described in USSR patent 940,487-A and by Heuts, et al., Macro- molecules 1999, pp 2511-2519 and 3907-3912.

Furthermore, novel polymerization techniques such as ATRP (Atom Transfer Radical Po- lymerization) and or RAFT (Reversible Addition Fragmentation Chain Transfer) can be ap- plied to obtain useful polymers derived from alkyl esters. These methods are well known.

The ATRP reaction method is described, for example, by J-S. Wang, et al., J. Am. Chem.

Soc., Vol. 117, pp. 5614-5615 (1995), and by Matyjaszewski, Macromolecules, Vol. 28, pp. 7901-7910 (1995). Moreover, the patent applications WO 96/30421, WO 97/47661,

WO 97/18247, WO 98/40415 and WO 99/10387 disclose variations of the ATRP explained above to which reference is expressly made for purposes of the disclosure. The RAFT method is extensively presented in WO 98/01478, for example, to which reference is ex- pressly made for purposes of the disclosure.

The polymerization can be carried out at normal pressure; reduced pressure or elevated pressure. The polymerization temperature is also not critical. However, in general it lies in the range of -20-200°C, preferably 0-130°C and especially preferably 60-120°C, without any limitation intended by this.

The polymerization can be carried out with or without solvents. The term solvent is to be broadly understood here.

According to a preferred embodiment, the polymer is obtainable by a polymerization in API

Group II or Group III mineral oil. These solvents are disclosed above.

Furthermore, polymers obtainable by polymerization in a polyalphaolefin (PAO) are pre- ferred. More preferably, the PAO has a number average molecular weight in the range of 200 to 10000, more preferably 500 to 5000. This solvent is disclosed above.

The hydraulic fluid may comprise 0.5 to 50 % by weight, especially 1 to 30 % by weight, and preferably 3 to 20% by weight, based on the total weight of the fluid, of one or more polymers derived from alkyl esters. According to a preferred embodiment of the present in- vention, the hydraulic fluid comprises at least 5 % by weight of one or more polymers de- rived from alkyl esters.

PH

According to a preferred aspect of the present invention, the fluid may comprise at least two polymers having a different monomer composition. Preferably, at least one of the polymers is a polyolefin. Preferably, the polyolefin is useful as a viscosity index improver.

These polyolefins include in particular polyolefin copolymers (OCP) and hydrogenated sty- rene/diene copolymers (HSD). The polyolefin copolymers (OCP) to be used according to the invention are known per se. They are primarily polymers synthesized from ethylene, propylene, isoprene, butylene and/or further olefins having 5 to 20 carbon atoms. Systems which have been grafted with small amounts of oxygen- or nitrogen-containing monomers (e.g. from 0.05 to 5% by weight of maleic anhydride) may also be used. The copolymers which contain diene components are generally hydrogenated in order to reduce the oxida- tion sensitivity and the crosslinking tendency of the viscosity index improvers.

The molecular weight Mw is in general from 10 000 to 300 000, preferably between 50 000 and 150 000. Such olefin copolymers are described, for example, in the German Laid-Open

Applications DE-A 16 44 941, DE-A 17 69 834, DE-A 19 39 037, DE-A 19 63 039, and

DE-A 20 59 981.

Ethylene/propylene copolymers are particularly useful and terpolymers having the known ternary components, such as ethylidene-norbornene (cf. Macromolecular Reviews, Vol. 10 (1975)) are also possible, but their tendency to crosslink must also be taken into account in the aging process. The distribution may be substantially random, but sequential poly- mers comprising ethylene blocks can also advantageously be used. The ratio of the mono- mers ethylene/propylene is variable within certain limits, which can be set to about 75% for ethylene and about 80% for propylene as an upper limit. Owing to its reduced tendency to dissolve in oil, polypropylene is less suitable than ethylene/propylene copolymers. In addi- tion to polymers having a predominantly atactic propylene incorporation, those having a more pronounced isotactic or syndiotactic propylene incorporation may also be used.

Such products are commercially available, for example under the trade names Dutral® CO 034, Dutral® CO 038, Dutral® CO 043, Dutral® CO 058, Buna® EPG 2050 or

Buna® EPG 5050.

The hydrogenated styrene/diene copolymers (HSD) are likewise known, these polymers be- ing described, for example, in DE 21 56 122. They are in general hydrogenated iso- prene/styrene or butadiene/styrene copolymers. The ratio of diene to styrene is preferably in the range from 2:1 to 1:2, particularly preferably about 55:45. The molecular weight Mw is in general from 10000 to 300 000, preferably between 50000 and 150000. According to a particular aspect of the present invention, the proportion of double bonds after the hydro- genation is not more than 15%, particularly preferably not more than 5%, based on the number of double bonds before the hydrogenation.

Hydrogenated styrene/diene copolymers can be commercially obtained under the trade name

SHELLVIS® 50, 150, 200, 250 or 260.

Preferably, at least one of the polymers of the mixture comprises units derived from mono- mers selected from acrylate monomers, methacrylate monomers, fumarate monomers and/or maleate monomers. These polymers are described above.

The weight ratio of the polyolefin and the polymer comprises units derived from monomers selected from acrylate monomers, methacrylate monomers, fumarate monomers and/or maleate monomers may be in the range of 1:10 to 10:1, especially 1:5 to 5:1.

The hydraulic fluid may comprise usual additives. These additive include e.g. antioxidants, antiwear agents, corrosion inhibitors and/or defoamers, often purchased as a commercial additive package.

Preferably, the hydraulic fluid has a viscosity according to ASTM D 445 at 40°C in the range of 10 to 150 mm®/s, more preferably 22 to 100 mm?/s.

Preferably, the hydraulic system includes the following components: 1. A unit creating mechanical energy, e.g. a combustion engine or an electrical motor. 2. A fluid flow or force-generating unit that converts mechanical energy into hydraulic power, such as a pump. 3. Piping for transmitting fluid under pressure. 4. A unit that converts the hydraulic power of the fluid into mechanical work or motion, such as an actuator or fluid motor. There are two types of motors, cylindrical and ro- tary. 5. A control circuit with valves that regulate flow, pressure, direction of movement, and applied forces. 6. A fluid reservoir that allows for separation of water, foam, entrained air, or debris be- fore the clean fluid is returned to the system through a filter. : 7. A liquid with low compressibility capable of operating without degradation under the conditions of the application (temperature, pressure, radiation).

Most complex systems will make use of multiple pumps, rotary motors, cylinders, electroni- cally controlled with valves and regulators.

According to a preferred embodiment of the present invention, a vane pump or a piston pump can be used in order to create hydraulic power.

The system may be operated at high pressures. The improvement of the present invention can be achieved at pressures in the range of 50 to 700 bars, preferably 100 to 400 bars and more preferably 150 to 350 bars.

The unit creating mechanical energy, e.g. a motor can be operated at a speed of 500 to 5000 rpm, preferably 1000 to 3000 rpm and more preferably 1400 to 2000 rpm.

The hydraulic fluid can be used at a wide temperature window. Preferably, the fluid can be used at a temperature in the range of -30°C to 200°C, more preferably 10°C to 150°C. Usu- ally, the operating temperature depends on the base fluid used to manufacture the hydraulic fluid.

Preferably, the fluid is used in military hydraulic systems, in hydraulic launch assist systems for hybrid propulsion vehicles, in industrial, marine, mining and/or mobile equipment hy- draulic systems.

Furthermore, the present invention provides a hydraulic system comprising a hydraulic fluid having a VI of at least 130, a unit for creating mechanical power, a unit that converts me- chanical power into hydraulic power, and a unit that converts hydraulic power into me- chanical work or motion. * Preferentially, engine speed can be maintained at a constant level to deliver higher amounts of hydraulic power. Preferably, the mechanical power output of the engine or electrical mo- tor can be operated at its full power capacity to deliver higher amounts of hydraulic power compared to the hydraulic system utilizing a standard HM grade fluid with a viscosity index less than 120.

The invention is illustrated in more detail below by examples and comparison examples, without intending to limit the invention to these examples.

Examples 1 and 2 and Comparative Example 1

A Denison T6C mobile vane pump is operated under the following controlled conditions:

Speed = 1500 rpm, Pressure = 200 bars, Fluid Temperature = 80° C

An ISO VG 46 HM oil is run as a reference fluid, generates 6.97 kW of hydraulic power.

By comparison, several ISO VG 46 HV oils are run under the same conditions, and gener- ate 6 to 11% higher levels of hydraulic power output, as shown in Table 1.

- 27 ~

Table 1- Denison T6C Mobile Vane Pump Power Output

Comparative Example 1 Example 2 fee

Hydraulic 6.97 7.42 7.74

Power Output, ee

Power Output 6.6% 11.1% ee | [7

Operating Conditions: 1500 rpm, 200 bars, 80°C

Examples 3 to 5 and Comparative Example 2

An Eaton-Vickers V20 vane pump is operated under the following controlled conditions:

Speed = 1200 rpm, Pressure = 138 bars, Fluid Temperature = 80° C.

An ISO VG 46 HM oil is run as a reference fluid, generates 8.69 kW of hydraulic power.

By comparison, several ISO VG 46 HV oils are run under the same conditions, and gener- ate 3 to 6% higher levels of hydraulic power output, as shown in Table 2.

Table 2: Eaton-Vickers V20 Vane Pump Power Output

Comparative Example 3 Example 4 Example 5

I = i a

Hydraulic 8.69 9.01 9.09 9.16

Power Output, kW pow | [we Ja [sw ww]

Operating Conditions: 1200 rpm, 138 bars, 80°C

Examples 6 to 8 and Comparative Example 3

An Eaton-Vickers V104C vane pump is operated under the following controlled conditions:

Speed = 1200 rpm, Pressure = 138 bars, Fluid Temperature = 80° C

An ISO VG 46 HM oil is run as a reference fluid, generates 8.35 kW of hydraulic power.

By comparison, several ISO VG 46 HV oils are run under the same conditions, and gener- ate 5 to 7% higher levels of hydraulic power output, as shown in Table 3.

Table 3: Eaton-Vickers V104C Vane Pump Power Output :

Comparative Example 6 Example 7 Example 8 fem

Hydraulic 8.35 8.76 8.86 8.95

Power Output, ee

Power Output 4.9% 6.0% 7.2% ""

Operating Conditions: 1200 rpm, 138 bars, 80°C

Examples 9 to 11 and Comparative Example 4

A Komatsu 35+35 dual piston pump is operated under the following controlled conditions:

Speed = 2100 rpm, Pressure = 350 bars, Fluid Temperature = 100° C

An ISO VG 46 HM oil is run as a reference fluid, generates 5.83 kW of hydraulic power.

By comparison, several ISO VG 46 HV oils are run under the same conditions, and gener- ate 4 to 6% higher levels of hydraulic power output, as shown in Table 4.

] - 29 -

Table 4: Komatsu 35+35 Dual Piston Pump Power Output

Comparative Example 9 Example 10 Example 11

Hydraulic 583 6.07 6.13 6.18

Power Output,

Power Output 4.0% 5.0% 6.0% pel I RN

Operating Conditions: 2100 rpm, 350 bars, 100°C

Examples 12 to 14 and Comparative Example 5

An Eaton L2 gear pump is operated under the following controlled conditions:

Speed = 2750 rpm, Pressure = 207 bars, Fluid Temperature = 80° C

An ISO VG 46 HM oil is run as a reference fluid, generates 21.5 kW of hydraulic power.

By comparison, several ISO VG 46 HV oils are run under the same conditions, and gener- ate 6 to 8.8% higher levels of hydraulic power output, as shown in Table 5.

Table 5- Eaton L2 Gear Pump Power Output

Comparative Example 12 Example 13 Example 14

CL fee

! -30-

Comparative Example 12 Example 13 Example 14

Hydraulic 21.5 22.8 23.2 23.4

Power Output, aw

Increase, %

Operating Conditions: 2750 rpm, 207 bars, 80°C

The data gathered in the examples demonstrate that the "HV" multigrade oil formulated with Group II PAMA was responsible for increased hydraulic power output from the hy- draulic pumps. The increased work output enables the excavator to complete the work cy- cle in a shorter period of time, and thus complete higher levels of work output in equivalent periods of time.

Examples 15 to 18 and Comparative Example 6

A further advantage of the present invention is the potential to design a hydraulic system that operates at a lower pressure level and delivers an equivalent amount of hydraulic power output. Table 6 contains data comparing the relative power input and hydraulic power out- put in a Denison P09 piston pump at about 5000 psi (345 bar).

Table 6: Comparison of Piston Pump Power Output at Lower Pressure % % Change

Flow Change | Overall

Rate, | Power Overall Power Effi-

Pressure, psi gpm | In, kW | Efficiency In ciency

Comparative | 5000, Mono- rere | un [sa| we |]

Example 15 5000 psi,

MEHF 48.87 | 149.9 82.9 -4.1 4.3

Example 16 4950 psi,

Example 17 4750 psi,

Example 18 4500 psi,

Table 6 continuation % Change

Hydraulic power

Power % Change in power out/power (kW) power out out/power in in

Comparative re Jon | |e

Fas | wey | as [ow

The data is also expressed graphically in Figure 1, and demonstrates that a system can be designed to operate at a 5% lower pressure level which delivers an equivalent level of hy- draulic power output.

Examples 19 to 22 and Comparative Example 7

A further experiment shows the improvement of the relative power input and hydraulic power output in a Denison T6C vane pump at about 3000 psi. (207 bar) being achieved by the present invention. The results achieved are shown in Table 7. Additionally, the data is also expressed graphically in Figure 2, and demonstrates that a system can be designed to operate at a 6% lower pressure level which delivers an equivalent level of hydraulic power output.

Table 7: Comparison of Vane Pump Power Output at Lower Pressure % % Change

Flow Change | Overall

Rate, | Power Overall Power Effi-

Pressure, psi lpm | In, kW | Efficiency In ciency | .

Comparative | 3000, Mono- fl fg PY FE

Example 19 3000 psi,

Ja on | me | a

Example 20 2970 psi,

Jann | on | 0

Example 21 2850 psi, = Jon mn] na alo

Example 22 2700 psi,

NE EE

Table 7 continuation % Change power

Hydraulic Power % Change in power out/power (kW) power out out/power in in

Comparative omer | we | a

% Change power

Hydraulic Power % Change in power out/power (kW) power out out/power in in

Claims (1)

1. i -34- Claims : Co

   1. A use of a fluid having a VI of at least 130 to improve the power output of a hy- . . draulic system.

   2. The use according to claim 1, wherein the power output is increased at least 3%.

   3. The use according to claim 2, wherein the power output is increased at least 5%.

   4. The use according at least one of the preceding claims, wherein the volume output is increased.

   5. The use according to claim 4, wherein the volume output is increased at least 3%.

   6. The use according to claim 5, wherein the volume output is increased at least 5%.

   7. The use according to at least one of the preceding claims, wherein the constancy of the power output is increased.

   8. The use according to claim 7, wherein the constancy of the power output is in- creased at the maximum load.

   9. The use according to claim 7 or 8, wherein the drop of the power output after at least 10 minutes of operating time is at most 3%, measured at a load of 90% of the maximum load or more of a unit providing mechanical energy.

   10. The use according to at least one of the preceding claims, wherein the engine speed of a unit providing mechanical energy is maintained at a constant rate and the system delivers an increased level of hydraulic power.

   : ] - 35 -

   11. The use according to at least one of the preceding claims, wherein the engine speed of a unit providing mechanical energy is in the range of 1000 to 3000 rpm.

   12. The use according to claim 11, wherein the engine speed of a unit providing me- chanical energy is in the range of 1400 to 2000 rpm.

   13. The use according to at least one of the preceding claims, wherein the pressure pro- vided by a unit providing hydraulic power is in the range of 50 to 700 bars.

   14. The use according to claim 13, wherein the pressure provided by a unit providing : hydraulic power is in the range of 150 to 350 bars.

   15. The use according to at least one of the preceding claims, wherein the hydraulic sys- tem is designed to operate at a lower pressure, such that the output power is equiva- lent to that delivered by a reference system using a hydraulic fluid with a VI of 100.

   16. The use according to at least one of the preceding claims, wherein the hydraulic sys- tem demonstrates an improvement in the ratio of hydraulic power output to power input, such that the ratio of power output/power input is improved by at least 3%, compared to that delivered by a reference system using a hydraulic fluid with a VI of

   100.

   +17. The use according to at least one of the preceding claims, wherein the fluid has a VI of at least 150.

   18. The use according to claim 17, wherein the fluid has a VI of at least 180.

   19. The use according to at least one of the preceding claims, wherein the fluid is a NFPA double viscosity grade, triple viscosity grade, quadra viscosity grade, or penta viscosity grade hydraulic fluid.

   20. The use according to at least one of the preceding claims, wherein the fluid is ob- tainable by mixing a base fluid and a polymeric viscosity index improver.

   21. The use according to claim 20, wherein the fluid comprises at least 60 % by weight of at least one base fluid.

   22. The use according to claim 21, wherein the fluid comprises at least 60 % by weight of at least one base fluid having a viscosity index of 120 or less.

   23. The use according to at least one of the preceding claims, wherein the fluid com- prises a mineral oil and/or a synthetic oil. 24, The use according to claim 23, wherein the fluid comprises a API group I, API group II, API group III oil, a API group IV or API group V oil, or a Fischer- Tropsch (GTL) derived oil.

   25. The use according to at least one of the preceding claims, wherein the fluid com- prises a polyalphaolefin (PAO), a carboxylic ester, a vegetable ester, a phosphate es- ter and/or a polyalkylene glycol (PAG).

   26. The use according to at least one of the preceding claims, wherein the fluid com- prises at least one polymer.

   27. Theuse according to claim 26, wherein the polymer comprises units derived from monomers selected from acrylate monomers, methacrylate monomers, fumarate monomers and/or maleate monomers.

   28. The use according to claim 27, wherein the fluid comprises a polyalkylmethacrylate polymer.

   29. The use according to at least one of the claims 26 to 28, wherein the fluid comprises a polymer obtainable by polymerizing a mixture of olefinically unsaturated mono- mers, which consists of a) 0-100 wt% based on the total weight of the ethylenically unsaturated monomers of one or more ethylenically unsaturated ester compounds of formula (I) R

   A o. RZ O where R is hydrogen or methyl, R' means a linear or branched alkyl residue with 1-6 carbon atoms, R” and R® independently represent hydrogen or a group of the for- mula —COOR', where R' means hydrogen or a alkyl group with 1-6 carbon atoms, b) 0-100 wt% based on the total weight of the ethylenically unsaturated monomers of one or more ethylenically unsaturated ester compounds of formula (IT) R AN a, RS O where R is hydrogen or methyl, R* means a linear or branched alkyl residue with 7- 40 carbon atoms, R® and R® independently are hydrogen or a group of the formula — COOR", where R" means hydrogen or an alkyl group with 7-40 carbon atoms, ¢) 0-50 wt% based on the total weight of the ethylenically unsaturated monomers COMONOMeErs.

   30. The use according to at least one of the claims 26 to 29, wherein the polymer is ob- tainable by a polymerisation in a API group II or group III mineral oil.

   31. The use according to at least one of the claims 26 to 29, wherein the polymer is ob- tainable by a polymerisation in a polyalphaolefin (PAO).

   32. The use according to one of the claims 26 to 31, wherein the polymers are obtain- able by polymerizing a mixture comprising dispersant monomers.

   33. The use according to one of the claims 26 to 32, wherein the polymers are obtain- able by polymerizing a mixture comprising vinyl monomers containing aromatic groups.

   34. The use according to at least one of the claims 26 to 33, wherein the polymer has a molecular weight in the range of 10000 to 200000 g/mol, specifically 25000 g/mol to 100000 g/mol. :

   35. The use according to at least one of the claims 26 to 34, wherein the fluid comprises

   0.5 to 40% by weight polymer.

   36. The use according to claim 35, wherein the fluid comprises 3 to 20% by weight polymer.

   37. The use according to at least one of the claims 26 to 36, wherein the fluid comprises at least two polymers having a different monomer composition.

   38. The use according to claim 37, wherein at least one of the polymers is a polyolefin.

   39. The use according to claim 38, wherein at least one of the polymers comprises units derived from alkyl ester monomers.

   40. The use according to claim 39, wherein the weight ratio of the polyolefin and the polymer comprises units derived from alkyl ester monomers is in the range of 1:10 to 10:1.

   41. The use according to at least one of the preceding claims, wherein the fluid com- prises an oxygen containing compound selected from the group of carboxylic acid esters, polyether polyols and/or organophosphorus compounds.

   42. The use according to claim 41, wherein the oxygen containing compound is a car- boxylic ester containing at least two ester groups.

   43. The use according to claim 41 or 42, wherein the oxygen containing compound is a diester of carboxylic acids containing 4 to 12 carbon atoms.

   44. The use according to claim 41, wherein the oxygen containing compound is a ester of a polyol.

   45. The use according to at least one of the preceding claims, wherein the fluid has an ISO viscosity grade in the range of 15 to 150.

   46. The use according to at least one of the preceding claims, wherein the fluid is used at a temperature in the range of -40°C to 120°C.

   47. The use according to at least one of the preceding claims, wherein the fluid com- prises antioxidants, antiwear agents, corrosion inhibitors and/or defoamers.

   48. The use according to at least one of the preceding claims, wherein the fluid is used in military hydraulic systems, in hydraulic launch assist systems (for hydraulic hybrid vehicle propulsion), in industrial, marine, mining and/or mobile equipment hydraulic Systems.

   :

   49. The use according to at least one of the preceding claims, wherein the fluid is used in a hydraulic system comprising at least one unit providing mechanical energy, at least one unit that converts mechanical energy into hydraulic power, at least one pipe for transmitting fluid under pressure and at least a unit that converts the hy- draulic power of the fluid into mechanical work.

   50. The use according to claim 48, wherein the unit providing mechanical energy com- prises a combustion engine.

   51. The use according to claim 49 or 50, wherein the unit converting mechanical energy into hydraulic power is a vane pump.

   52. The use according to claim 49 or 50, wherein the unit converting mechanical energy : into hydraulic power is a piston pump.

   53. The use according to claim 49 or 50, wherein the unit converting mechanical energy into hydraulic power is a gear pump.