SG11202013118VA - Modified y-type molecular sieve, catalytic cracking catalyst comprising the same, its preparation and application thereof - Google Patents

Modified y-type molecular sieve, catalytic cracking catalyst comprising the same, its preparation and application thereof

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Publication number
SG11202013118VA
SG11202013118VA SG11202013118VA SG11202013118VA SG11202013118VA SG 11202013118V A SG11202013118V A SG 11202013118VA SG 11202013118V A SG11202013118V A SG 11202013118VA SG 11202013118V A SG11202013118V A SG 11202013118VA SG 11202013118V A SG11202013118V A SG 11202013118VA
Authority
SG
Singapore
Prior art keywords
modified
preparation
application
same
molecular sieve
Prior art date
Application number
SG11202013118VA
Inventor
Shuai Yuan
Lingping Zhou
Huiping Tian
Zhenyu Chen
Weilin Zhang
Hao Sha
Original Assignee
China Petroleum & Chem Corp
Research Institute Of Petroleum Processing Sinopec
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN201810713533.2A external-priority patent/CN110652997B/en
Priority claimed from CN201810715455.XA external-priority patent/CN110653002B/en
Priority claimed from CN201810714440.1A external-priority patent/CN110653000B/en
Priority claimed from CN201810713603.4A external-priority patent/CN110652998B/en
Application filed by China Petroleum & Chem Corp, Research Institute Of Petroleum Processing Sinopec filed Critical China Petroleum & Chem Corp
Publication of SG11202013118VA publication Critical patent/SG11202013118VA/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084Y-type faujasite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/33Electric or magnetic properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06Washing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/10Heat treatment in the presence of water, e.g. steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/30Ion-exchange
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04Oxides
    • C10G11/05Crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/16After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/32Reaction with silicon compounds, e.g. TEOS, siliconfluoride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/36Steaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/301Boiling range
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/302Viscosity
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/30Physical properties of feedstocks or products
    • C10G2300/308Gravity, density, e.g. API
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70Catalyst aspects

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
SG11202013118VA 2018-06-29 2019-06-27 Modified y-type molecular sieve, catalytic cracking catalyst comprising the same, its preparation and application thereof SG11202013118VA (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN201810713533.2A CN110652997B (en) 2018-06-29 2018-06-29 High-stability modified Y-type molecular sieve for producing more dimethyl isomeric hydrocarbon and preparation method thereof
CN201810715455.XA CN110653002B (en) 2018-06-29 2018-06-29 Catalytic cracking catalyst
CN201810714440.1A CN110653000B (en) 2018-06-29 2018-06-29 Catalytic cracking catalyst, preparation and application thereof
CN201810713603.4A CN110652998B (en) 2018-06-29 2018-06-29 High-stability modified Y-type molecular sieve for producing more isomeric hydrocarbon and preparation method thereof
PCT/CN2019/093250 WO2020001531A1 (en) 2018-06-29 2019-06-27 Modified y-type molecular sieve, catalytic cracking catalyst including same, and preparation and use thereof

Publications (1)

Publication Number Publication Date
SG11202013118VA true SG11202013118VA (en) 2021-02-25

Family

ID=68985963

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202013118VA SG11202013118VA (en) 2018-06-29 2019-06-27 Modified y-type molecular sieve, catalytic cracking catalyst comprising the same, its preparation and application thereof

Country Status (8)

Country Link
US (1) US11517886B2 (en)
EP (1) EP3815785A4 (en)
JP (1) JP7371033B2 (en)
AU (1) AU2019296817B2 (en)
SA (1) SA520420894B1 (en)
SG (1) SG11202013118VA (en)
TW (1) TWI802718B (en)
WO (1) WO2020001531A1 (en)

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CA891483A (en) * 1972-01-25 E. Pickert Paul Hydrocarbon reforming process and catalyst composition therefor
US4198319A (en) 1977-02-16 1980-04-15 Filtrol Corporation Method of producing zeolitic catalysts with silica alumina matrix
US4273753A (en) 1979-09-10 1981-06-16 Mobil Oil Corporation De-aluminization of aluminosilicates
US4429053A (en) 1981-12-04 1984-01-31 Union Oil Company Of California Rare earth-containing Y zeolite compositions
US4584287A (en) 1981-12-04 1986-04-22 Union Oil Company Of California Rare earth-containing Y zeolite compositions
US4438178A (en) 1982-10-27 1984-03-20 Fiber Industries, Inc. Adhesive activated polyester fibrous material
US4750988A (en) * 1983-09-28 1988-06-14 Chevron Research Company Vanadium passivation in a hydrocarbon catalytic cracking process
US5206194A (en) 1991-06-20 1993-04-27 Union Oil Company Of America Process for reactivating a deactivated crystalline molecular sieve group VIII metal catalyst
CN1057977C (en) 1997-03-31 2000-11-01 中国石油化工总公司 Process for preparation of catylist composition containing silicon-rich ultrastable Y zeolite
US5925235A (en) * 1997-12-22 1999-07-20 Chevron U.S.A. Inc. Middle distillate selective hydrocracking process
CN1162327C (en) 2001-04-28 2004-08-18 中国石油化工股份有限公司 Rare-earth Y-type zeolite
CN1121903C (en) 2001-04-28 2003-09-24 中国石油化工股份有限公司 Process for preparing rare-earth type high-silicon gamma-zeolite
CN1170634C (en) 2001-05-30 2004-10-13 中国石油化工股份有限公司 Prepn of high-silicon Y-Zeolite
CN1286565C (en) 2003-06-30 2006-11-29 中国石油化工股份有限公司 Cracking catalyst for hydrocarbon containing molecular sieve and preparation process thereof
CN100357398C (en) * 2003-06-30 2007-12-26 中国石油化工股份有限公司 Cracking catalyst for hydrocarbon containing molecular sieve and preparation process thereof
CN1286721C (en) * 2004-04-14 2006-11-29 中国石油化工股份有限公司 Gas phase aluminium extracting and silicon supplementing method of molecular sieve
CN102020289B (en) * 2009-09-10 2012-07-25 中国石油化工股份有限公司 Super-stable Y zeolite, preparation method and application thereof
CN102029177B (en) * 2009-09-28 2012-07-18 中国石油化工股份有限公司 Cracking catalyst and preparation method thereof
CN102291770B (en) * 2010-06-21 2014-07-30 上海贝尔股份有限公司 Method and device for optimizing user plane operation in communication system based on carrier aggregation
CN103157506B (en) * 2011-12-15 2015-09-23 中国石油天然气股份有限公司 High-light-yield heavy oil catalytic cracking catalyst and preparation method thereof
US9943836B2 (en) * 2013-10-22 2018-04-17 China Petroleum & Chemical Corporation Metal modified Y zeolite, its preparation and use
RU2621345C1 (en) 2016-08-03 2017-06-02 Акционерное общество "Газпромнефть-Омский НПЗ" Method of preparation of craking catalyst with alkaline earth elements

Also Published As

Publication number Publication date
JP2021529723A (en) 2021-11-04
SA520420894B1 (en) 2023-11-07
EP3815785A1 (en) 2021-05-05
US20210252490A1 (en) 2021-08-19
AU2019296817B2 (en) 2024-04-11
JP7371033B2 (en) 2023-10-30
TW202000595A (en) 2020-01-01
US11517886B2 (en) 2022-12-06
EP3815785A4 (en) 2021-10-06
TWI802718B (en) 2023-05-21
AU2019296817A1 (en) 2021-01-28
WO2020001531A1 (en) 2020-01-02

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