EP3157671A4 - Molecular sieve catalyst compositions, catalytic composites, systems, and methods - Google Patents
Molecular sieve catalyst compositions, catalytic composites, systems, and methods Download PDFInfo
- Publication number
- EP3157671A4 EP3157671A4 EP15808974.8A EP15808974A EP3157671A4 EP 3157671 A4 EP3157671 A4 EP 3157671A4 EP 15808974 A EP15808974 A EP 15808974A EP 3157671 A4 EP3157671 A4 EP 3157671A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- systems
- methods
- molecular sieve
- catalyst compositions
- sieve catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003054 catalyst Substances 0.000 title 1
- 230000003197 catalytic effect Effects 0.000 title 1
- 239000002131 composite material Substances 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- 239000002808 molecular sieve Substances 0.000 title 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0215—Coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9436—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/763—CHA-type, e.g. Chabazite, LZ-218
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
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- B01J35/30—
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- B01J35/40—
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- B01J35/56—
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2067—Urea
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/104—Silver
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2063—Lanthanum
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/206—Rare earth metals
- B01D2255/2065—Cerium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20715—Zirconium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20723—Vanadium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/2073—Manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20738—Iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20746—Cobalt
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20753—Nickel
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/90—Physical characteristics of catalysts
- B01D2255/911—NH3-storage component incorporated in the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/10—After treatment, characterised by the effect to be obtained
- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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- B01J35/19—
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201462013847P | 2014-06-18 | 2014-06-18 | |
US201462081243P | 2014-11-18 | 2014-11-18 | |
US14/687,097 US9889437B2 (en) | 2015-04-15 | 2015-04-15 | Isomorphously substituted catalyst |
PCT/US2015/036255 WO2015195819A1 (en) | 2014-06-18 | 2015-06-17 | Molecular sieve catalyst compositions, catalytic composites, systems, and methods |
Publications (2)
Publication Number | Publication Date |
---|---|
EP3157671A1 EP3157671A1 (en) | 2017-04-26 |
EP3157671A4 true EP3157671A4 (en) | 2018-02-14 |
Family
ID=54936079
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15808974.8A Pending EP3157671A4 (en) | 2014-06-18 | 2015-06-17 | Molecular sieve catalyst compositions, catalytic composites, systems, and methods |
EP15809019.1A Pending EP3157672A4 (en) | 2014-06-18 | 2015-06-17 | Molecular sieve catalyst compositions, catalyst composites, systems, and methods |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP15809019.1A Pending EP3157672A4 (en) | 2014-06-18 | 2015-06-17 | Molecular sieve catalyst compositions, catalyst composites, systems, and methods |
Country Status (9)
Country | Link |
---|---|
EP (2) | EP3157671A4 (en) |
JP (2) | JP6615794B2 (en) |
KR (1) | KR102436905B1 (en) |
CN (2) | CN106660022B (en) |
BR (1) | BR112016029733B8 (en) |
CA (1) | CA2952437C (en) |
MX (2) | MX2016016920A (en) |
RU (1) | RU2727801C2 (en) |
WO (1) | WO2015195819A1 (en) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6615794B2 (en) * | 2014-06-18 | 2019-12-04 | ビーエーエスエフ コーポレーション | Molecular sieve catalyst composition, catalyst composite, system, and method |
JP6702759B2 (en) * | 2015-03-05 | 2020-06-03 | 国立大学法人広島大学 | AEI-type zeolite containing titanium and method for producing the same |
WO2017210812A1 (en) * | 2016-06-06 | 2017-12-14 | Rhodia Operations | Rare earth zeolite and the method of preparation thereof |
CN109311006B (en) | 2016-06-08 | 2022-09-27 | 巴斯夫公司 | Copper-promoted gmelinite and its use in selective catalytic reduction of NOx |
KR102643225B1 (en) * | 2017-09-07 | 2024-03-12 | 바스프 코포레이션 | Zeolites with reduced extra-skeletal aluminum |
JP7138697B2 (en) * | 2017-10-27 | 2022-09-16 | シェブロン ユー.エス.エー. インコーポレイテッド | Molecular sieve SSZ-112, its synthesis and use |
FR3081340B1 (en) * | 2018-05-24 | 2020-06-26 | IFP Energies Nouvelles | CATALYST COMPRISING A MIXTURE OF AN AFX STRUCTURAL TYPE ZEOLITE AND A BEA STRUCTURAL TYPE ZEOLITE AND AT LEAST ONE TRANSITIONAL METAL FOR THE SELECTIVE NOX REDUCTION |
JP7412354B2 (en) * | 2018-05-25 | 2024-01-12 | ビーエーエスエフ ソシエタス・ヨーロピア | Aluminum-rich rare earth element-containing zeolite material |
CN108722477B (en) * | 2018-06-06 | 2021-01-15 | 中国科学院过程工程研究所 | Anti-alkalosis efficient denitration catalyst and preparation method and application thereof |
WO2020092111A1 (en) * | 2018-10-31 | 2020-05-07 | Basf Corporation | Catalytic washcoat with added alumina for no x abatement |
WO2020115318A1 (en) * | 2018-12-06 | 2020-06-11 | Basf Se | Aqueous suspension comprising a zeolitic material and a zirconium chelate complex |
CN114025877A (en) * | 2019-04-27 | 2022-02-08 | 萨德化学制品印度私人有限公司 | Process for preparing metal-exchanged zeolites |
JP2022550274A (en) * | 2019-09-25 | 2022-12-01 | ビーエーエスエフ コーポレーション | Cu-CHA SCR catalysts with specific lattice strain and domain size properties |
CN110947415A (en) * | 2019-12-10 | 2020-04-03 | 惠州市瑞合环保科技有限公司 | Selective reduction catalyst and preparation method thereof |
CN110961144A (en) * | 2019-12-14 | 2020-04-07 | 中触媒新材料股份有限公司 | Symbiotic composite molecular sieve with CHA/LEV topological structure, preparation method thereof and SCR application thereof |
CN115304077A (en) * | 2022-08-10 | 2022-11-08 | 浙江浙能技术研究院有限公司 | Molecular sieve for selective catalytic reduction of nitrogen oxides and preparation method and application thereof |
CN115301281B (en) * | 2022-08-17 | 2023-05-26 | 四川大学 | Sulfur-resistant water-resistant catalyst, and preparation method and application thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996029140A1 (en) * | 1995-03-17 | 1996-09-26 | Osaka Gas Company Limited | Nitrogen oxide-reducing catalyst and process for reducing nitrogen oxides in exhaust gas |
DE102010055680A1 (en) * | 2010-12-22 | 2012-06-28 | Süd-Chemie AG | Composition, useful in e.g. extrudate, comprises an aluminosilicate zeolite and a titano-(silico)-alumino-phosphate, where both aluminosilicate zeolite and titano-(silico)-alumino-phosphate comprise a transition metal e.g. iron or copper |
US20130323164A1 (en) * | 2012-06-04 | 2013-12-05 | Basf Se | CHA-type Zeolite Materials and Methods for Their Preparation Using Cycloalkyammonium Compounds |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7998423B2 (en) * | 2007-02-27 | 2011-08-16 | Basf Corporation | SCR on low thermal mass filter substrates |
US10384162B2 (en) * | 2007-03-26 | 2019-08-20 | Pq Corporation | High silica chabazite for selective catalytic reduction, methods of making and using same |
CN103771440B (en) * | 2008-05-21 | 2015-12-30 | 巴斯夫欧洲公司 | Direct synthesis has the method containing Cu zeolite of CHA structure |
EP2161070B1 (en) * | 2008-09-04 | 2013-11-27 | Haldor Topsoe A/S | Process and catalyst system for NOx reduction |
DE112011103996T8 (en) * | 2010-12-02 | 2013-12-19 | Johnson Matthey Public Limited Company | Metal-containing zeolite catalyst |
DE102010055679A1 (en) * | 2010-12-22 | 2012-06-28 | Süd-Chemie AG | Titano-silico-alumino-phosphate |
US9174849B2 (en) * | 2011-08-25 | 2015-11-03 | Basf Corporation | Molecular sieve precursors and synthesis of molecular sieves |
US20120258032A1 (en) * | 2011-11-02 | 2012-10-11 | Johnson Matthey Public Limited Company | Catalyzed filter for treating exhaust gas |
BR112014018506A8 (en) * | 2012-01-31 | 2017-07-11 | Johnson Matthey Plc | CATALYST COMPOSITION, METHOD TO TREAT NOX, AND CATALYTIC ARTICLE |
RU2767067C1 (en) * | 2012-10-19 | 2022-03-16 | Басф Корпорейшн | 8-ring molecular sieve with small pores as high-temperature scr catalyst |
JP6615794B2 (en) * | 2014-06-18 | 2019-12-04 | ビーエーエスエフ コーポレーション | Molecular sieve catalyst composition, catalyst composite, system, and method |
-
2015
- 2015-06-17 JP JP2016573737A patent/JP6615794B2/en active Active
- 2015-06-17 KR KR1020177001106A patent/KR102436905B1/en active IP Right Grant
- 2015-06-17 CN CN201580044158.1A patent/CN106660022B/en active Active
- 2015-06-17 EP EP15808974.8A patent/EP3157671A4/en active Pending
- 2015-06-17 EP EP15809019.1A patent/EP3157672A4/en active Pending
- 2015-06-17 CA CA2952437A patent/CA2952437C/en active Active
- 2015-06-17 RU RU2017101429A patent/RU2727801C2/en active
- 2015-06-17 WO PCT/US2015/036255 patent/WO2015195819A1/en active Application Filing
- 2015-06-17 CN CN201580043934.6A patent/CN106660021B/en active Active
- 2015-06-17 MX MX2016016920A patent/MX2016016920A/en unknown
- 2015-06-17 BR BR112016029733A patent/BR112016029733B8/en active IP Right Grant
-
2016
- 2016-12-16 MX MX2023001935A patent/MX2023001935A/en unknown
-
2019
- 2019-11-06 JP JP2019201425A patent/JP6882427B2/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996029140A1 (en) * | 1995-03-17 | 1996-09-26 | Osaka Gas Company Limited | Nitrogen oxide-reducing catalyst and process for reducing nitrogen oxides in exhaust gas |
DE102010055680A1 (en) * | 2010-12-22 | 2012-06-28 | Süd-Chemie AG | Composition, useful in e.g. extrudate, comprises an aluminosilicate zeolite and a titano-(silico)-alumino-phosphate, where both aluminosilicate zeolite and titano-(silico)-alumino-phosphate comprise a transition metal e.g. iron or copper |
US20130323164A1 (en) * | 2012-06-04 | 2013-12-05 | Basf Se | CHA-type Zeolite Materials and Methods for Their Preparation Using Cycloalkyammonium Compounds |
Non-Patent Citations (1)
Title |
---|
EINAR ANDRÉ EILERTSEN ET AL: "Synthesis of Titanium Chabazite: A New Shape Selective Oxidation Catalyst with Small Pore Openings and Application in the Production of Methyl Formate from Methanol", CHEMCATCHEM, vol. 3, no. 12, 28 September 2011 (2011-09-28), pages 1869 - 1871, XP055028197, ISSN: 1867-3880, DOI: 10.1002/cctc.201100281 * |
Also Published As
Publication number | Publication date |
---|---|
CA2952437A1 (en) | 2015-12-23 |
MX2016016920A (en) | 2017-10-31 |
BR112016029733B8 (en) | 2022-09-27 |
EP3157671A1 (en) | 2017-04-26 |
BR112016029733A8 (en) | 2020-10-20 |
JP2020037108A (en) | 2020-03-12 |
BR112016029733A2 (en) | 2017-08-22 |
CN106660022A (en) | 2017-05-10 |
JP6615794B2 (en) | 2019-12-04 |
RU2017101429A (en) | 2018-07-18 |
WO2015195819A1 (en) | 2015-12-23 |
RU2017101429A3 (en) | 2018-11-09 |
MX2023001935A (en) | 2023-03-16 |
EP3157672A1 (en) | 2017-04-26 |
CN106660021A (en) | 2017-05-10 |
KR102436905B1 (en) | 2022-08-29 |
CN106660021B (en) | 2020-09-11 |
BR112016029733B1 (en) | 2022-09-06 |
KR20170021835A (en) | 2017-02-28 |
CN106660022B (en) | 2020-09-22 |
CA2952437C (en) | 2023-08-29 |
JP2017521241A (en) | 2017-08-03 |
JP6882427B2 (en) | 2021-06-02 |
EP3157672A4 (en) | 2018-04-04 |
RU2727801C2 (en) | 2020-07-24 |
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