SG11202003478SA - Toluene free silica supported single-site metallocene catalysts from in-situ supported mao formation in aliphatic solvents - Google Patents

Toluene free silica supported single-site metallocene catalysts from in-situ supported mao formation in aliphatic solvents

Info

Publication number
SG11202003478SA
SG11202003478SA SG11202003478SA SG11202003478SA SG11202003478SA SG 11202003478S A SG11202003478S A SG 11202003478SA SG 11202003478S A SG11202003478S A SG 11202003478SA SG 11202003478S A SG11202003478S A SG 11202003478SA SG 11202003478S A SG11202003478S A SG 11202003478SA
Authority
SG
Singapore
Prior art keywords
formation
supported
metallocene catalysts
aliphatic solvents
free silica
Prior art date
Application number
SG11202003478SA
Other languages
English (en)
Inventor
Lubin Luo
Anupriya Jain
Charles Harlan
Original Assignee
Exxonmobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chemical Patents Inc filed Critical Exxonmobil Chemical Patents Inc
Publication of SG11202003478SA publication Critical patent/SG11202003478SA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
SG11202003478SA 2017-10-31 2018-09-17 Toluene free silica supported single-site metallocene catalysts from in-situ supported mao formation in aliphatic solvents SG11202003478SA (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762579587P 2017-10-31 2017-10-31
EP18152100 2018-01-17
PCT/US2018/051345 WO2019089144A1 (fr) 2017-10-31 2018-09-17 Catalyseurs métallocènes monosites supportés sur silice exempts de toluène contenus dans une formation de mao supportée in-situ dans des solvants aliphatiques

Publications (1)

Publication Number Publication Date
SG11202003478SA true SG11202003478SA (en) 2020-05-28

Family

ID=66332237

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11202003478SA SG11202003478SA (en) 2017-10-31 2018-09-17 Toluene free silica supported single-site metallocene catalysts from in-situ supported mao formation in aliphatic solvents

Country Status (4)

Country Link
EP (1) EP3704164A4 (fr)
CN (1) CN111356704B (fr)
SG (1) SG11202003478SA (fr)
WO (1) WO2019089144A1 (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4247822A1 (fr) * 2020-11-23 2023-09-27 ExxonMobil Chemical Patents Inc. Préparation exempte de toluène de la smao : chauffage avec du tma pour améliorer l'activité
CN116529253A (zh) * 2020-11-23 2023-08-01 埃克森美孚化学专利公司 改进的原位mao衍生的二氧化硅负载的单中心茂金属催化剂

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5015749A (en) * 1987-08-31 1991-05-14 The Dow Chemical Company Preparation of polyhydrocarbyl-aluminoxanes
US5006500A (en) * 1988-10-27 1991-04-09 Exxon Chemical Patents Inc. Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene
EP0877051B1 (fr) * 1993-05-13 2004-12-22 ExxonMobil Chemical Patents Inc. Copolymères d'éthylène ayant une distribution étroite de composition, leur production et utilisation
US5422325A (en) * 1993-09-17 1995-06-06 Exxon Chemical Patents Inc. Supported polymerization catalysts, their production and use
US5629253A (en) * 1994-04-26 1997-05-13 Exxon Chemical Patents, Inc. Polymerization catalyst systems, their production and use
US5468702A (en) * 1994-07-07 1995-11-21 Exxon Chemical Patents Inc. Method for making a catalyst system
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use

Also Published As

Publication number Publication date
EP3704164A4 (fr) 2020-12-23
WO2019089144A1 (fr) 2019-05-09
CN111356704B (zh) 2023-05-05
EP3704164A1 (fr) 2020-09-09
CN111356704A (zh) 2020-06-30

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