SG11201907913RA - Alkylation process with improved octane number - Google Patents

Alkylation process with improved octane number

Info

Publication number
SG11201907913RA
SG11201907913RA SG11201907913RA SG11201907913RA SG11201907913RA SG 11201907913R A SG11201907913R A SG 11201907913RA SG 11201907913R A SG11201907913R A SG 11201907913RA SG 11201907913R A SG11201907913R A SG 11201907913RA SG 11201907913R A SG11201907913R A SG 11201907913RA
Authority
SG
Singapore
Prior art keywords
international
alkylation process
applicant
pct
rule
Prior art date
Application number
SG11201907913RA
Inventor
Broekhoven Emanuel Hermanus Van
Ruben Theodoor Pronk
Jackeline Medina
Original Assignee
Albemarle Europe Srl
Lummus Technology Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albemarle Europe Srl, Lummus Technology Inc filed Critical Albemarle Europe Srl
Publication of SG11201907913RA publication Critical patent/SG11201907913RA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G35/00—Reforming naphtha
    • C10G35/04—Catalytic reforming
    • C10G35/06—Catalytic reforming characterised by the catalyst used
    • C10G35/095—Catalytic reforming characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G7/00—Distillation of hydrocarbon oils
    • C10G7/02—Stabilising gasoline by removing gases by fractioning
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1081—Alkanes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1081—Alkanes
    • C10G2300/1085—Solid paraffins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1088—Olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/04—Diesel oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/08—Jet fuel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 07 September 2018 (07.09.2018) WIP0 I PCT omit °nolo onm mil Imola° oimIE (10) International Publication Number WO 2018/158377 Al (51) International Patent Classification: ClOG 29/20 (2006.01) (21) International Application Number: (22) International Filing Date: PCT/EP2018/055063 Declarations under Rule 4.17: as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(ii)) as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.17(iii)) 01 March 2018 (01.03.2018) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/465,535 01 March 2017 (01.03.2017) US (71) Applicant: ALBEMARLE EUROPE SPRL [BE/BE]; Parc Scientifique de LLN, Rue du Bosquet 9, 1348 Lou- vain-la-Neuve (BE). (72) Inventors: VAN BROEKHOVEN, Emanuel Hermanus; Trintel 131, 1141, DN Monnickendam (NL). PRONK, Ruben Theodoor; Weiver 16, 1546, LB Jisp (NL). (74) Agent: SCHWABE SANDMAIR MARX PATENTAN- WALTE RECHTSANWALT PARTNERSCHAFT MBB; Joseph-Wild-Str. 20, 81829 Munich (DE). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: with international search report (Art. 21(3)) 1-1 N N GC kr) 00 O 1-1 1-1 N C (54) Title: ALKYLATION PROCESS WITH IMPROVED OCTANE NUMBER (57) : An improved alkylation process with improved octane number and lower fmal boiling point. Further, the present dis- closure comprises an alkylation system that allows flexibility in the operating parameters without loss of productivity. This enhances the advantage of the solid acid alkylation process of the invention over the liquid acid processes, as the C9+ alkylate will mainly contain the desired highly branched paraffin's in the case of solid acid alkylation. By fractionation of C9+, the RON number of the gasoline alkylate after fractionation remains very high, while the fmal boiling point of the gasoline fraction will decrease, improving value and blending flexibility.
SG11201907913RA 2017-03-01 2018-03-01 Alkylation process with improved octane number SG11201907913RA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201762465535P 2017-03-01 2017-03-01
PCT/EP2018/055063 WO2018158377A1 (en) 2017-03-01 2018-03-01 Alkylation process with improved octane number

Publications (1)

Publication Number Publication Date
SG11201907913RA true SG11201907913RA (en) 2019-09-27

Family

ID=61526820

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201907913RA SG11201907913RA (en) 2017-03-01 2018-03-01 Alkylation process with improved octane number

Country Status (12)

Country Link
US (1) US11225614B2 (en)
EP (1) EP3589721A1 (en)
JP (1) JP2020510742A (en)
KR (1) KR102529299B1 (en)
CN (1) CN110573594B (en)
AU (1) AU2018226543B2 (en)
BR (1) BR112019018112B1 (en)
CA (1) CA3054985C (en)
RU (1) RU2762589C2 (en)
SA (1) SA519402536B1 (en)
SG (1) SG11201907913RA (en)
WO (1) WO2018158377A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG11202112991XA (en) * 2019-05-24 2021-12-30 Lummus Technology Inc Flexible production of gasoline and jet fuel in alkylation reactor
CN115591577B (en) * 2022-09-28 2024-02-06 中国石油大学(北京) Composite ionic liquid and preparation method and application thereof

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3644565A (en) 1968-09-18 1972-02-22 Union Oil Co Alkylation process
US3851004A (en) 1973-09-27 1974-11-26 Union Carbide Corp Hydrocarbon alkylation process using catalyst regeneration
US4404418A (en) 1982-06-04 1983-09-13 Phillips Petroleum Company HF Alkylation process
US4456779A (en) * 1983-04-26 1984-06-26 Mobil Oil Corporation Catalytic conversion of olefins to higher hydrocarbons
BE1006675A3 (en) * 1993-02-02 1994-11-16 Fina Research Method for producing species high octane.
CN1088449C (en) 1996-11-27 2002-07-31 阿克佐诺贝尔公司 Process for alkylating hydrocarbons
DE10125230B4 (en) * 2001-05-22 2014-12-04 Air Liquide Global E&C Solutions Germany Gmbh Process for the catalytic conversion of isoparaffins with olefins to alkylates
EP1527035B1 (en) 2001-06-08 2015-03-04 Albemarle Netherlands B.V. Continuous process for the alkylation of hydrocarbons
JP4303583B2 (en) 2001-06-08 2009-07-29 アルベマーレ ネザーランズ ビー．ブイ． Process for catalytic alkylation of hydrocarbons
US7361797B2 (en) * 2002-02-05 2008-04-22 Abb Lummus Global Inc. Hydrocarbon conversion using nanocrystalline zeolite Y
CN1291954C (en) * 2004-01-19 2006-12-27 中国石油化工股份有限公司 Akylation reaction method for solid acid catalyzed isomeric paraffine and olefins
CN1997610B (en) * 2004-02-09 2010-09-15 阿尔伯麦尔荷兰公司 Alkylation process using a catalyst comprising a solid acid and a hydrogenation
EP1656993A1 (en) 2004-11-03 2006-05-17 Albemarle Netherlands B.V. Alkylation catalyst, its preparation and use
RU2313391C2 (en) * 2005-02-09 2007-12-27 Общество с ограниченной ответственностью "ВАМИК" Catalyst and gasoline-alkylate production process
US20060194998A1 (en) * 2005-02-28 2006-08-31 Umansky Benjamin S Process for making high octane gasoline with reduced benzene content
CN100410219C (en) * 2005-03-15 2008-08-13 中国石油化工股份有限公司 Solid acid alkylating process of isomerized alkane and olefin
JP4916742B2 (en) * 2006-03-24 2012-04-18 Ｊｘ日鉱日石エネルギー株式会社 High octane number environment-friendly gasoline composition and method for producing the same
TWI433829B (en) 2007-01-26 2014-04-11 Albemarle Netherlands Bv Alkylation process using a catalyst comprising rare earth containing zeolites and a hydrogenation metal
US7727486B2 (en) * 2007-08-01 2010-06-01 Uop Llc Apparatus for heating regeneration gas
US20100234661A1 (en) 2007-10-17 2010-09-16 Albemarle Netherlands, BV Alkylation process using a catalyst comprising rare earth containing zeolites and reduced amount of noble metal
FR2925065B1 (en) * 2007-12-17 2012-11-30 Inst Francais Du Petrole NEW DIAGRAM FOR OPTIMIZING HIGH OCTANE INDEX PRODUCTION AND COPRODUCTION OF AROMATIC BASES
FR2932495B1 (en) * 2008-06-17 2011-03-25 Inst Francais Du Petrole DEVICE FOR CONTROLLING OPERATIVE CONDITIONS IN A CATALYTIC CRACKING UNIT WITH TWO RISERS.
EP2396291A1 (en) 2009-02-11 2011-12-21 Albemarle Europe Sprl. Alkylation catalyst and related process
CN102439121B (en) * 2009-03-30 2015-05-13 印度石油股份有限公司 A fluidized catalytic cracking process
US8487154B2 (en) 2010-03-17 2013-07-16 Chevron U.S.A. Inc. Market driven alkylation or oligomerization process
EP2404980A1 (en) * 2010-07-08 2012-01-11 Total Raffinage Marketing Hydrocarbon feedstock average molecular weight increase
US8524630B2 (en) * 2010-10-08 2013-09-03 Exxonmobil Research And Engineering Company Mesoporous aluminas stabilized with rare earth and phosphorous
WO2014109766A1 (en) * 2013-01-14 2014-07-17 Badger Licensing Llc Process for balancing gasoline and distillate production in a refinery
AU2015286798B2 (en) * 2014-07-07 2020-03-12 Albemarle Europe Sprl Alkylation process using a catalyst comprising cerium rich rare earth containing zeolites and a hydrogenation metal
DK3310480T3 (en) 2015-06-22 2020-09-07 Exelus Inc IMPROVED CATALYZED ALKYLATION, ALKYLATION CATALYSTS AND METHODS OF PREPARING ALKYLATION CATALYSTS
US20170369395A1 (en) * 2016-06-23 2017-12-28 Exxonmobil Research And Engineering Company Isoparaffin-olefin alkylation

Also Published As

Publication number Publication date
CN110573594A (en) 2019-12-13
KR102529299B1 (en) 2023-05-08
BR112019018112B1 (en) 2022-10-11
AU2018226543A1 (en) 2019-10-10
US20200002624A1 (en) 2020-01-02
RU2762589C2 (en) 2021-12-21
US20210371758A9 (en) 2021-12-02
SA519402536B1 (en) 2023-02-07
BR112019018112A2 (en) 2020-04-07
WO2018158377A1 (en) 2018-09-07
AU2018226543B2 (en) 2023-03-30
CA3054985A1 (en) 2018-09-07
RU2019130714A3 (en) 2021-05-25
KR20190134629A (en) 2019-12-04
US11225614B2 (en) 2022-01-18
JP2020510742A (en) 2020-04-09
CA3054985C (en) 2022-03-01
CN110573594B (en) 2022-10-25
RU2019130714A (en) 2021-04-01
EP3589721A1 (en) 2020-01-08

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