SG11201901880SA - Volume change compensated silicon-silicon oxide-lithium composite material having nano silicon particles embedded in a silicon: silicon lithium silicate composite matrix, and cyclical ex-situ manufacturing processes - Google Patents

Volume change compensated silicon-silicon oxide-lithium composite material having nano silicon particles embedded in a silicon: silicon lithium silicate composite matrix, and cyclical ex-situ manufacturing processes

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Publication number
SG11201901880SA
SG11201901880SA SG11201901880SA SG11201901880SA SG11201901880SA SG 11201901880S A SG11201901880S A SG 11201901880SA SG 11201901880S A SG11201901880S A SG 11201901880SA SG 11201901880S A SG11201901880S A SG 11201901880SA SG 11201901880S A SG11201901880S A SG 11201901880SA
Authority
SG
Singapore
Prior art keywords
silicon
sslc material
volume change
prelithiated
sslc
Prior art date
Application number
SG11201901880SA
Inventor
Yuriy Matus
Yongbong Han
Michael Pak
Original Assignee
Eocell Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eocell Ltd filed Critical Eocell Ltd
Publication of SG11201901880SA publication Critical patent/SG11201901880SA/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/364Composites as mixtures
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0438Processes of manufacture in general by electrochemical processing
    • H01M4/044Activating, forming or electrochemical attack of the supporting material
    • H01M4/0445Forming after manufacture of the electrode, e.g. first charge, cycling
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/38Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/386Silicon or alloys based on silicon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/483Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027Negative electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1391Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1395Processes of manufacture of electrodes based on metals, Si or alloys
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property :::` , Organization 3 MD HIM 01E101011M 3E1 0 1011101fl 0111 00I1011 NH ill OEN International Bureau (10) International Publication Number (43) International Publication Date .....•\"\"- WO 2018/042361 Al 08 March 2018 (08.03.2018) WIP0 I PCT (51) International Patent Classification: CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, HO1M 4/36 (2006.01) C01B 33/02 (2006.01) DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, (21) International Application Number: HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, PCT/IB2017/055236 KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, (22) International Filing Date: OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, 31 August 2017 (31.08.2017) SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (25) Filing Language: English (26) Publication Language: English (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, (30) Priority Data: GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, 62/383,372 02 September 2016 (02.09.2016) US UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, 62/478,535 29 March 2017 (29.03.2017) US TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, (71) Applicant: EOCELL LIMITED [CN/CN]; Room 804, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, Lap Fai Building, 6-8 Pottinger Street, Central, Hong Kong, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, Hong Kong (CN). KM, ML, MR, NE, SN, TD, TG). (72) Inventors: MATUS, Yuriy; 4025 Rennellwood Way, Pleasanton, California 94566 (US). HAN, Yongbong; 226 Published: Laidley Street, San Francisco, California 94131 (US). PAK, — with international search report (Art. 21(3)) — Michael; 2200 Lake Road, Belmont, California 94002 = (US). = (81) Designated States (unless otherwise indicated, for every _ kind of national protection available): AE, AG, AL, AM, — AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, = = = = (54) Title: VOLUME CHANGE COMPENSATED SILICON-SILICON OXIDE-LITHIUM COMPOSITE MATERIAL HAVING _ NANO SILICON PARTICLES EMBEDDED IN A SILICON: SILICON LITHIUM SILICATE COMPOSITE MATRIX, AND CY- _ CLICAL EX-SITU MANUFACTURING PROCESSES = (57) : A method for producing a volume change compensated silicon: silicon ox- 110 = = Produce Prelithiated SSLC Material Exhibiting Enhanced, Substantially Complete or Complete Lithiation ide: lithium composite (SSLC) material is disclosed. The method includes producing an initially prelithiated SSLC material; delithiating the initially prelithiated material to pro- duce delithiated least iteration Produce Partially Lithiated SSLC Material a SSLC material; and performing at one of a volume change compensation process involving: (a) re-prelithiating the delithiated SSLC material to pro- = 2 114 --) duce are-prelithiated SSLC material; and (b) delithiating the re-prelithiated SSLC material = = = Complete Reaction of Unreacted Lithium and SiO in the Partially x Lithiated SSLC Material to Produce Further Lithiated SSLC Material produced in (a), wherein at least one of the following is satisfied: (i) prior to performing the at least one iteration of the volume change compensation process the initially prelithi- ated SSLC material is essentially completely lithiated; and (ii) at least one iteration of the = - 120 -, 1 volume change compensation process produces a re-prelithiated SSLC material that is es- — L = Delithiate the Produced Prelithiated SSLC Material to Produce Completely DelithiatedSSLC Material Having Si Nano Particles Embedded in a Porous Plastically Deformable Li. SLC Matrix sentially completely prelithiated. In a fmal iteration of the volume change compensation process, delithiating the re-prelithiated SSLC material produced in (a) completely delithi- ates the re-prelithiated SSLC material to produce the volume change compensated SSLC material. The aforesaid is to, or ex situ with respect to, the fabri- process performed prior _ 130 i cation of an anode that contains the produced volume change compensated SSLC material. Filter / Wash / Dry the Delithiated SSLC Material Il 140 V; Mechanically Stabilize the Delithiated SSLC Material en el 150 i 71 . © GC Enhance the Electrical Conductivity of the Delithiated SSLC Material with Carbon / Carbon Based Matenal(s) (e g , Graphite) 11 © el FIG. 1 loo
SG11201901880SA 2016-09-02 2017-08-31 Volume change compensated silicon-silicon oxide-lithium composite material having nano silicon particles embedded in a silicon: silicon lithium silicate composite matrix, and cyclical ex-situ manufacturing processes SG11201901880SA (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662383372P 2016-09-02 2016-09-02
US201762478535P 2017-03-29 2017-03-29
PCT/IB2017/055236 WO2018042361A1 (en) 2016-09-02 2017-08-31 Volume change compensated silicon-silicon oxide-lithium composite material having nano silicon particles embedded in a silicon: silicon lithium silicate composite matrix, and cyclical ex-situ manufacturing processes

Publications (1)

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SG11201901880SA true SG11201901880SA (en) 2019-03-28

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US (1) US10347907B2 (en)
EP (1) EP3507845B1 (en)
JP (1) JP6940595B2 (en)
KR (1) KR102355992B1 (en)
CN (1) CN109923706B (en)
HU (1) HUE055597T2 (en)
MY (1) MY190556A (en)
PL (1) PL3507845T3 (en)
SG (1) SG11201901880SA (en)
TW (1) TWI778974B (en)
WO (1) WO2018042361A1 (en)

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EP3507845B1 (en) 2021-03-31
KR102355992B1 (en) 2022-01-26
EP3507845A4 (en) 2020-04-01
CN109923706B (en) 2022-01-04
TW201817063A (en) 2018-05-01
PL3507845T3 (en) 2021-07-19
KR20190042655A (en) 2019-04-24
HUE055597T2 (en) 2022-05-28
JP2019533878A (en) 2019-11-21
US20180069233A1 (en) 2018-03-08
CN109923706A (en) 2019-06-21
EP3507845A1 (en) 2019-07-10
TWI778974B (en) 2022-10-01
MY190556A (en) 2022-04-27
US10347907B2 (en) 2019-07-09
WO2018042361A1 (en) 2018-03-08
JP6940595B2 (en) 2021-09-29

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