SG11201809573SA - Conversion of biomass into a liquid hydrocarbon material - Google Patents

Conversion of biomass into a liquid hydrocarbon material

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Publication number
SG11201809573SA
SG11201809573SA SG11201809573SA SG11201809573SA SG11201809573SA SG 11201809573S A SG11201809573S A SG 11201809573SA SG 11201809573S A SG11201809573S A SG 11201809573SA SG 11201809573S A SG11201809573S A SG 11201809573SA SG 11201809573S A SG11201809573S A SG 11201809573SA
Authority
SG
Singapore
Prior art keywords
international
park
catalyst
biomass
hydropyrolysis
Prior art date
Application number
SG11201809573SA
Inventor
Vikrant Urade
Paggio Alan Del
Soundararajan Laxmi Chilkoor
Madhusudhan Panchagnula
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of SG11201809573SA publication Critical patent/SG11201809573SA/en

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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • B01J31/0209—Esters of carboxylic or carbonic acids
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
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    • B01J37/0201—Impregnation
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    • B01J37/20—Sulfiding
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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
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    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
    • C—CHEMISTRY; METALLURGY
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
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    • C10G3/47—Catalytic treatment characterised by the catalyst used containing platinum group metals or compounds thereof
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
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    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
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    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
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    • C01B2203/0465—Composition of the impurity
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
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    • Y02P30/40—Ethylene production

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 411413111111011114110HOEHEIREMIERMEMIE Organization International Bureau (10) International Publication Number (43) International Publication Date .....0\"\"\" WO 2017/202837 Al 30 November 2017 (30.11.2017) WIPO I PCT (51) International Patent Classification: B.V. [NL/NL]; Carel van Bylandtlaan 30, 2596 HR THE ClOG 3/00 (2006.01) BO1J 31/04 (2006.01) HAGUE (NL). ClOG 1/00 (2006.01) ClOG 1/06 (2006.01) (71) Applicant (for US only): SHELL OIL COMPA- B01J 31/02 G006.01) ClOG 1/10 G006.01) NY [US/US]; SHELL PLAZA 1, HOUSTON, Texas (21) International Application Number: 77252-2463 (US). PCT/EP2017/062395 (72) Inventors: URADE, Vikrant, Nanasaheb; Plot No (22) International Filing Date: 7, Bengaluru Hardware Park, Devanahalli Industrial 23 May 2017 (23.05.2017) Park. Mahadeva Kodigahalli, Bangalore North 562149 (IN). DEL PAGGIO, Alan, Anthony; 18710 Scoresby (25) Filing Language: English Manor Drive, Spring, Texas 77379 (US). CHILKOOR (26) Publication Language: English SOUNDARARAJAN, Laxmi, Narasimhan; Plot No 7, Bengaluru Hardware Park, Devanahalli Industrial Park. Ma- (30) Priority Data: hadeva Kodigahalli, Bangalore North, 562149 Karnataka 201641017931 25 May 2016 (25.05.2016) IN (IN). PANCHAGNULA, Madhusudhan, Rao; Plot No 7, (71) Applicant (for all designated States except US): SHELL Bengaluru Hardware Park, Devanahalli Industrial Park Ma- INTERNATIONALE RESEARCH MAATSCHAPPIJ (54) Title: CONVERSION OF BIOMASS INTO A LIQUID HYDROCARBON MATERIAL = = Figure 1 = 11 _> 12 15 --> 16 _______>. 17 = = 10 13 s l , , 1 4 1.3 = = = = = 21 =24 24 = 22 = 25 = = = _ (57) : The present invention provides a process for producing liquid hydrocarbon products from a biomass, biomass-containing and/or biomass-derived feedstock, said process comprising the steps of: a) contacting the feedstock with one or more hydropyrolysis It catalyst compositions and molecular hydrogen in a hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C and a pressure in the range of from 0.50 to 7.50MPa, to produce a product stream comprising hydropyrolysis product that is at least IN partially deoxygenated, H2O, H2, CO2, CO, C1 - C3 gases, char and catalyst fines; b) removing all or a portion of said char and catalyst f.r1 cc fines from said product stream; c) hydroconverting said hydropyrolysis product in a hydroconversion reactor vessel in the presence of ei one or more hydroconversion catalyst compositions and of at least a portion of the H2O, CO2, CO, H2, and C1 - C3 gases generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1 ei --- - C3 gases, wherein one or both of the hydropyrolysis catalyst composition and the hydroconversion catalyst composition is produced IN ,-1 in a process comprising the © ei O [Continued on next page] WO 2017/202837 Al MIDEDIMOMOIDEIRMEMODIMIlliMEMOVOIMIE hadeva Kodigahalli, Bangalore North, 562149 Karnataka (IN). (74) Agent: MATTHEZING, Robert, Maarten et al.; PO Box 384, 2501 CJ THE HAGUE (NL). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: — as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(0) Published: — with international search report (Art. 21(3)) steps of incorporating one or more metals selected from those of groups 6, 9, and 10 of the periodic table, into a shaped support; and incorporating one or more coordinating organic compounds into said shaped support, thus forming a catalyst precursor; and then either (i) treating the catalyst precursor in the presence of hydrogen and sulfiding it or (ii) calcining the catalyst precursor.
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