IN2014DN02467A - - Google Patents
Info
- Publication number
- IN2014DN02467A IN2014DN02467A IN2467DEN2014A IN2014DN02467A IN 2014DN02467 A IN2014DN02467 A IN 2014DN02467A IN 2467DEN2014 A IN2467DEN2014 A IN 2467DEN2014A IN 2014DN02467 A IN2014DN02467 A IN 2014DN02467A
- Authority
- IN
- India
- Prior art keywords
- catalyst
- solid particles
- catalytic system
- stream
- equivalent
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 abstract 7
- 239000002245 particle Substances 0.000 abstract 4
- 239000007787 solid Substances 0.000 abstract 4
- 230000003197 catalytic effect Effects 0.000 abstract 3
- 239000007788 liquid Substances 0.000 abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 150000004645 aluminates Chemical class 0.000 abstract 2
- 239000000295 fuel oil Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 238000005336 cracking Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 230000008929 regeneration Effects 0.000 abstract 1
- 238000011069 regeneration method Methods 0.000 abstract 1
- 239000002002 slurry Substances 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/04—Sulfides
- B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
- B01J27/051—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/78—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J29/7876—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Abstract
A catalytic system characterized in that it comprises: a first catalyst having a hydrogenating function consisting of solid particles of which at least 95% by volume having an equivalent diameter smaller than 20 µm containing one or more sulfides of metals of group VI and/or VIII B possibly prepared starting from an oil soluble precursor of the same; and a second catalyst having a cracking function consisting of solid particles of which at least 90% by volume having an equivalent diameter larger than 5 µm and smaller than 5 mm containing an amorphous silico aluminate and/or a crystalline silico aluminate and/or an alumina the equivalent average diameter of the solid particles of the second catalyst being greater than the equivalent average diameter of the solid particles of the first catalyst. Said catalytic system can be used in a process for the hydroconversion of heavy oils which comprises sending the heavy oil to a hydroprocessing step carried out in one or more slurry reactors in the presence of hydrogen or a mixture of hydrogen and HS obtaining a stream of products in vapour or liquid vapour phase and extracting at the bottom in continuous or discontinuous a liquid stream containing non converted products together with the two catalysts of said catalytic system said liquid stream extracted then being separated into a clarified primary stream containing the first catalyst which is at least partially recycled to the hydroprocessing step and a stream rich in the second catalyst which is regenerated in a regeneration step and at least partially recycled to the hydroprocessing step.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT001626A ITMI20111626A1 (en) | 2011-09-08 | 2011-09-08 | CATALYTIC SYSTEM AND PROCEDURE FOR THE TOTAL HYDRO-CONVERSION OF HEAVY OILS |
| PCT/EP2012/067412 WO2013034642A1 (en) | 2011-09-08 | 2012-09-06 | Catalytic system and process for the total hydroconversion of heavy oils |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| IN2014DN02467A true IN2014DN02467A (en) | 2015-05-15 |
Family
ID=44872499
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IN2467DEN2014 IN2014DN02467A (en) | 2011-09-08 | 2012-09-06 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US9700880B2 (en) |
| EP (1) | EP2753424B1 (en) |
| CN (1) | CN103842077B (en) |
| AP (1) | AP3713A (en) |
| CA (1) | CA2846759C (en) |
| ES (1) | ES2790975T3 (en) |
| HU (1) | HUE049286T2 (en) |
| IN (1) | IN2014DN02467A (en) |
| IT (1) | ITMI20111626A1 (en) |
| PL (1) | PL2753424T3 (en) |
| PT (1) | PT2753424T (en) |
| RS (1) | RS60372B1 (en) |
| RU (1) | RU2615766C2 (en) |
| WO (1) | WO2013034642A1 (en) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20131137A1 (en) * | 2013-07-05 | 2015-01-06 | Eni Spa | PROCEDURE FOR REFINING THE CRUDE |
| US11414608B2 (en) * | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor used with opportunity feedstocks |
| US11414607B2 (en) | 2015-09-22 | 2022-08-16 | Hydrocarbon Technology & Innovation, Llc | Upgraded ebullated bed reactor with increased production rate of converted products |
| US11421164B2 (en) * | 2016-06-08 | 2022-08-23 | Hydrocarbon Technology & Innovation, Llc | Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product |
| EP3529339A4 (en) * | 2016-10-18 | 2020-07-29 | Mawetal LLC | ENVIRONMENTALLY FRIENDLY SHIP FUEL |
| JP6905056B2 (en) * | 2016-10-18 | 2021-07-21 | マウェタール エルエルシー | Fuel and its manufacturing method |
| US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
| US12559689B2 (en) | 2017-02-12 | 2026-02-24 | Magēmā Technology LLC | Multi-stage process and device for treatment heavy marine fuel and resultant composition and the removal of detrimental solids |
| US12025435B2 (en) | 2017-02-12 | 2024-07-02 | Magēmã Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil |
| US20180230389A1 (en) | 2017-02-12 | 2018-08-16 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
| US12281266B2 (en) | 2017-02-12 | 2025-04-22 | Magẽmã Technology LLC | Heavy marine fuel oil composition |
| US12071592B2 (en) | 2017-02-12 | 2024-08-27 | Magēmā Technology LLC | Multi-stage process and device utilizing structured catalyst beds and reactive distillation for the production of a low sulfur heavy marine fuel oil |
| US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
| US11732203B2 (en) | 2017-03-02 | 2023-08-22 | Hydrocarbon Technology & Innovation, Llc | Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling |
| MX2018002577A (en) | 2017-03-02 | 2018-11-09 | Hydrocarbon Tech & Innovation Llc | Upgraded ebullated bed reactor with less fouling sediment. |
| FR3075220A1 (en) * | 2017-12-19 | 2019-06-21 | IFP Energies Nouvelles | PROCESS FOR HYDROTREATING VACUUM DISTILLATES USING A SPECIFIC COMBINATION OF CATALYSTS |
| CN110791311B (en) * | 2018-08-01 | 2021-10-08 | 中国石油化工股份有限公司 | A kind of heavy oil hydrotreating method |
| CA3057131C (en) | 2018-10-17 | 2024-04-23 | Hydrocarbon Technology And Innovation, Llc | Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms |
| US12497569B2 (en) | 2022-05-26 | 2025-12-16 | Hydrocarbon Technology & Innovation, Llc | Method and system for mixing catalyst precursor into heavy oil using a high boiling hydrocarbon diluent |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4591426A (en) | 1981-10-08 | 1986-05-27 | Intevep, S.A. | Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content |
| AU658937B2 (en) * | 1991-11-19 | 1995-05-04 | Mobil Oil Corporation | Hydrocarbon upgrading process |
| US5871635A (en) * | 1995-05-09 | 1999-02-16 | Exxon Research And Engineering Company | Hydroprocessing of petroleum fractions with a dual catalyst system |
| US6641714B2 (en) * | 2000-07-21 | 2003-11-04 | Exxonmobil Research And Engineering Company | Hydrocarbon upgrading process |
| US20020112987A1 (en) * | 2000-12-15 | 2002-08-22 | Zhiguo Hou | Slurry hydroprocessing for heavy oil upgrading using supported slurry catalysts |
| EP1350831A1 (en) * | 2002-04-05 | 2003-10-08 | Engelhard Corporation | Hydroprocessing of hydrocarbon feedstock |
| ES2585891T3 (en) | 2004-04-28 | 2016-10-10 | Headwaters Heavy Oil, Llc | Boiling bed hydroprocessing methods and systems |
| WO2006009742A1 (en) | 2004-06-17 | 2006-01-26 | Exxonmobil Research And Engineering Company | Catalyst combination and two-step hydroprocessing method for heavy hydrocarbon oil |
| ITMI20071198A1 (en) | 2007-06-14 | 2008-12-15 | Eni Spa | IMPROVED PROCEDURE FOR THE HYDROCONVERSION OF HEAVY OILS WITH BULLETS |
| ITMI20081061A1 (en) * | 2008-06-11 | 2009-12-12 | Eni Spa | CATALYTIC SYSTEM AND PROCEDURE FOR THE HYDRO-CONVERSION OF HEAVY OIL PRODUCTS |
| US8007662B2 (en) | 2009-03-27 | 2011-08-30 | Uop Llc | Direct feed/effluent heat exchange in fluid catalytic cracking |
| CA2772170C (en) * | 2009-10-08 | 2018-03-06 | IFP Energies Nouvelles | Method for hydroconverting heavy carbonaceous loads, including a bubbling bed technology and slurry technology |
-
2011
- 2011-09-08 IT IT001626A patent/ITMI20111626A1/en unknown
-
2012
- 2012-09-06 WO PCT/EP2012/067412 patent/WO2013034642A1/en not_active Ceased
- 2012-09-06 CA CA2846759A patent/CA2846759C/en active Active
- 2012-09-06 RU RU2014112708A patent/RU2615766C2/en active
- 2012-09-06 HU HUE12756708A patent/HUE049286T2/en unknown
- 2012-09-06 EP EP12756708.9A patent/EP2753424B1/en active Active
- 2012-09-06 US US14/343,007 patent/US9700880B2/en active Active
- 2012-09-06 AP AP2014007486A patent/AP3713A/en active
- 2012-09-06 ES ES12756708T patent/ES2790975T3/en active Active
- 2012-09-06 PT PT127567089T patent/PT2753424T/en unknown
- 2012-09-06 CN CN201280043236.2A patent/CN103842077B/en active Active
- 2012-09-06 RS RS20200534A patent/RS60372B1/en unknown
- 2012-09-06 IN IN2467DEN2014 patent/IN2014DN02467A/en unknown
- 2012-09-06 PL PL12756708T patent/PL2753424T3/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2615766C2 (en) | 2017-04-11 |
| ITMI20111626A1 (en) | 2013-03-09 |
| CN103842077A (en) | 2014-06-04 |
| EP2753424A1 (en) | 2014-07-16 |
| CA2846759A1 (en) | 2013-03-14 |
| HUE049286T2 (en) | 2020-09-28 |
| RU2014112708A (en) | 2015-10-20 |
| PL2753424T3 (en) | 2020-10-05 |
| RS60372B1 (en) | 2020-07-31 |
| PT2753424T (en) | 2020-05-04 |
| US9700880B2 (en) | 2017-07-11 |
| CA2846759C (en) | 2019-10-08 |
| AP2014007486A0 (en) | 2014-03-31 |
| CN103842077B (en) | 2016-08-17 |
| EP2753424B1 (en) | 2020-03-11 |
| WO2013034642A1 (en) | 2013-03-14 |
| ES2790975T3 (en) | 2020-10-30 |
| US20140291203A1 (en) | 2014-10-02 |
| AP3713A (en) | 2016-05-31 |
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