SG11201805512SA - Mixed decyl mercaptans compositions and use thereof as chain transfer agents - Google Patents

Mixed decyl mercaptans compositions and use thereof as chain transfer agents

Info

Publication number
SG11201805512SA
SG11201805512SA SG11201805512SA SG11201805512SA SG11201805512SA SG 11201805512S A SG11201805512S A SG 11201805512SA SG 11201805512S A SG11201805512S A SG 11201805512SA SG 11201805512S A SG11201805512S A SG 11201805512SA SG 11201805512S A SG11201805512S A SG 11201805512SA
Authority
SG
Singapore
Prior art keywords
mercapto
international
chain transfer
nonane
pct
Prior art date
Application number
SG11201805512SA
Inventor
Jason Kreider
Michael Matson
Original Assignee
Chevron Phillips Chemical Co Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillips Chemical Co Lp filed Critical Chevron Phillips Chemical Co Lp
Publication of SG11201805512SA publication Critical patent/SG11201805512SA/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F112/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F112/02Monomers containing only one unsaturated aliphatic radical
    • C08F112/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F112/06Hydrocarbons
    • C08F112/08Styrene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/04Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by addition of hydrogen sulfide or its salts to unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C321/00Thiols, sulfides, hydropolysulfides or polysulfides
    • C07C321/02Thiols having mercapto groups bound to acyclic carbon atoms
    • C07C321/04Thiols having mercapto groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02Monomers containing only one unsaturated aliphatic radical
    • C08F12/04Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06Hydrocarbons
    • C08F12/08Styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2017/116541 Al 6 July 2017 (06.07.2017) WIPO I PCT 11111111111111011101111111111101011111011101110111111111111111111011111111111110111111 (51) International Patent Classification: C08F 2/22 (2006.01) C08F 2/38 (2006.01) C07C 319/00 (2006.01) CO7C 321/04 (2006.01) (21) International Application Number: PCT/US2016/058822 (22) International Filing Date: 26 October 2016 (26.10.2016) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 14/981,428 28 December 2015 (28.12.2015) US 15/284,802 4 October 2016 (04.10.2016) US (71) Applicant: CHEVRON PHILLIPS CHEMICAL COM- PANY LP [US/US]; 10001 Six Pines Drive, The Wood- lands, Texas 77380 (US). (72) Inventors: KREIDER, Jason; 398721 State Hwy 10, Co- pan, Oklahoma 74022 (US). MATSON, Michael; 437 N. Park Hill Loop, Bartlesville, Oklahoma 74006 (US). (74) Agent: JOLLY (32736), Lynda; Chevron Phillips Chem- ical Company LP, 10001 Six Pines Drive, The Woodlands, Texas 77380 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3)) W O 20 17 / 1165 41 Al (54) Title: MIXED DECYL MERCAPTANS COMPOSITIONS AND USE THEREOF AS CHAIN TRANSFER AGENTS (57) : A chain transfer agent composition comprises at least one branched C io mercaptan selected from 5-methyl- 1 -mer- capto-nonane, 3-propy1-1-mercapto-heptane, 4-ethyl-l-mercapto-octane, 2-butyl-1-mercapto-hexane, 5-methyl-2-mercapto-nonane, 3-propyl-2-mercapto-heptane, 4-ethyl-2-mercapto-octane, 5-methyl-5-mercapto-nonane, or combinations thereof. The chain transfer agent composition can be a component of an emulsion polymerization mixture and can be used in a process for emulsion polymeriz - ation for the production of polymers, for example, via free-radical polymerization.
SG11201805512SA 2015-12-28 2016-10-26 Mixed decyl mercaptans compositions and use thereof as chain transfer agents SG11201805512SA (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14/981,428 US9512248B1 (en) 2015-12-28 2015-12-28 Mixed decyl mercaptans compositions and use thereof as chain transfer agents
US15/284,802 US9631039B1 (en) 2015-12-28 2016-10-04 Mixed decyl mercaptans compositions and use thereof as chain transfer agents
PCT/US2016/058822 WO2017116541A1 (en) 2015-12-28 2016-10-26 Mixed decyl mercaptans compositions and use thereof as chain transfer agents

Publications (1)

Publication Number Publication Date
SG11201805512SA true SG11201805512SA (en) 2018-07-30

Family

ID=57399897

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201805512SA SG11201805512SA (en) 2015-12-28 2016-10-26 Mixed decyl mercaptans compositions and use thereof as chain transfer agents

Country Status (7)

Country Link
US (4) US9512248B1 (en)
EP (2) EP3397655B1 (en)
KR (3) KR102433068B1 (en)
MY (1) MY182326A (en)
SG (1) SG11201805512SA (en)
TW (1) TWI707877B (en)
WO (1) WO2017116541A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10011564B2 (en) 2015-12-28 2018-07-03 Chevron Phillips Chemical Company Lp Mixed decyl mercaptans compositions and methods of making same
US9512071B1 (en) 2015-12-28 2016-12-06 Chevron Phillips Chemical Company Lp Mixed decyl mercaptans compositions and methods of making same
US10294200B2 (en) 2015-12-28 2019-05-21 Chevron Phillips Chemical Company, Lp Mixed branched eicosyl polysulfide compositions and methods of making same
US10040758B2 (en) 2015-12-28 2018-08-07 Chevron Phillips Chemical Company Lp Mixed decyl mercaptans compositions and methods of making same
US9512248B1 (en) 2015-12-28 2016-12-06 Chevron Phillips Chemical Company Lp Mixed decyl mercaptans compositions and use thereof as chain transfer agents
CN107417833B (en) * 2017-03-06 2020-04-17 山东大学 Amino modified nano polystyrene and preparation method thereof
EP3814322A1 (en) 2018-06-28 2021-05-05 Chevron Phillips Chemical Company LP Process of producing polysulfides crude product composition

Family Cites Families (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1774183A (en) 1927-05-13 1930-08-26 Barrett Co Concentration of minerals
US2125337A (en) 1929-12-24 1938-08-02 Antoine M Gaudin Flotation reagents and method of use
US2374983A (en) 1941-04-29 1945-05-01 Shell Dev Sulphur compounds
US2411961A (en) 1944-06-26 1946-12-03 Shell Dev Process for catalyzed abnormal addition reactions
US2551813A (en) 1949-02-25 1951-05-08 Du Pont Free radical addition of h2s to olefins
US2820831A (en) 1953-04-06 1958-01-21 Union Oil Co Preparation of mercaptans
US3059774A (en) 1961-07-31 1962-10-23 United States Borax Chem Method and means for beneficiating ores
US3219709A (en) 1962-12-26 1965-11-23 Phillips Petroleum Co Preparation of mercaptan and thio ether compounds
US3221056A (en) 1962-12-26 1965-11-30 Phillips Petroleum Co Preparation of mercaptans and thio-ether compounds
US3419614A (en) 1965-09-30 1968-12-31 Phillips Petroleum Co Preparation of thiols and thioether compounds
US3567608A (en) 1968-04-29 1971-03-02 Phillips Petroleum Co Mercaptan synthesis using ultraviolet radiation and a promoter containing a phosphite and azobisisobutyronitrile
US4119549A (en) 1975-03-21 1978-10-10 The Lubrizol Corporation Sulfurized compositions
ZA767089B (en) 1976-11-26 1978-05-30 Tekplex Ltd Froth flotation process and collector composition
FR2424907A1 (en) 1978-05-05 1979-11-30 Elf Aquitaine PERFECTION IN THE SYNTHESIS OF MERCAPTANS
SE436000B (en) 1978-06-27 1984-11-05 Elf Aquitaine PROCEDURE FOR FLOTATION OF MINERALS
US4439314A (en) 1982-08-09 1984-03-27 Phillips Petroleum Company Flotation reagents
FR2534492A1 (en) 1982-10-13 1984-04-20 Elf Aquitaine IMPROVEMENT IN MINERAL FLOTATION
US4822483A (en) 1984-09-13 1989-04-18 The Dow Chemical Company Collector compositions for the froth flotation of mineral values
CA1270076A (en) 1985-05-31 1990-06-05 The Dow Chemical Company Collectors for the selective froth flotation of mineral sulfides
US5310683A (en) * 1988-11-25 1994-05-10 Sievers Research, Inc. Process for simultaneous measurement of sulfur and non-sulfur containing compounds
EP0443864A1 (en) 1990-02-23 1991-08-28 Mitsubishi Petrochemical Company Limited Thermoplastic elastomer and a process for its production
US5304683A (en) 1992-07-02 1994-04-19 Phillips Petroleum Company Conversion of alkyl mercaptan to dialkyl sulfide and catalyst therefor
FR2758478B1 (en) * 1997-01-21 1999-02-26 Elf Aquitaine PROCESS FOR THE PRESULFURIZATION OF CATALYSTS
US6242489B1 (en) 1997-09-25 2001-06-05 Ecological Technologies Corporation Malodorant compositions
US6827220B1 (en) 1998-08-11 2004-12-07 Versitech, Inc. Flotation of sulfide mineral species with oils
US6844290B1 (en) * 1999-03-29 2005-01-18 Basf Aktiengesellschaft Oligomerization catalyst
EP1209203B1 (en) 1999-04-23 2006-08-16 Kaneka Corporation Processing aid for thermoplastic resin and thermoplastic resin composition containing the same
US6417306B1 (en) 1999-12-13 2002-07-09 Nippon Shokubai Co., Ltd, Transparent heat-resistant resin and production process therefor
CN1399620A (en) 1999-12-29 2003-02-26 菲利浦石油公司 Processes for preventing generation of hydrogen halides in oligomerization product recovery system
CN1260254C (en) * 2001-11-30 2006-06-21 上海市合成树脂研究所 Controllable free radical polymerization process with thioether compound as chain transferring agent
FR2857278B1 (en) 2003-06-16 2005-08-26 Atofina MERCAPTAN COMPOSITIONS FOR USE IN A METHOD FOR FLOATING ORES
DE10340252A1 (en) * 2003-08-29 2005-03-24 Basf Ag Tert.-dodecylmercaptan for use as mol. wt. regulator, especially in production of polymer dispersions for films and coatings, obtained by acid-catalysed addition of hydrogen sulfide to a special 12C olefin mixture
NZ549073A (en) 2004-02-17 2010-10-29 Agrium Inc Thiol ester compositions and processes for making and using same
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
DE102004060320A1 (en) * 2004-12-15 2006-06-22 Basf Ag Preparation of alkyl thiol, useful as odoriferous substances, components in lubricants and intermediate in radical polymerization, comprises adding hydrogen sulfide at the double bonds of olefin in presence of organic liquid acid
US7217843B2 (en) 2005-04-27 2007-05-15 Chevron Phillips Chemical Company Lp Method of making 2-thiols
US7470744B2 (en) 2006-04-12 2008-12-30 Baker Hughes Incorporated Copolymers useful as demulsifiers and clarifiers
US20090264669A1 (en) 2008-04-21 2009-10-22 Chevron Phillips Chemical Company Lp Methods and Systems for Making Thiol Compounds from Terminal Olefinic Compounds
EP2112187A1 (en) 2008-04-21 2009-10-28 Stichting Dutch Polymer Institute Process for the preparation of polycarbonates
US8471085B2 (en) 2008-10-31 2013-06-25 Chevron Phillips Chemical Company Lp Oligomerization catalyst system and process for oligomerizing olefins
CN102282184B (en) 2009-01-14 2014-06-18 斯泰隆欧洲有限责任公司 Increased monomer conversion in emulsion polymerization
CN102286127B (en) 2010-06-18 2014-12-10 罗门哈斯公司 Emulsion polymer containing microdomains
US8883907B2 (en) 2012-02-08 2014-11-11 Basf Se Aqueous dispersion
CA2800268C (en) 2012-12-21 2020-02-25 Nova Chemicals Corporation Continuous ethylene tetramerization process
US20140221692A1 (en) 2013-02-04 2014-08-07 Chevron Phillips Chemical Company Lp Flow Reactor Vessels and Reactor Systems
CN105985774B (en) 2015-02-09 2019-05-28 纳晶科技股份有限公司 The application of nanocrystalline-ligand complex, preparation method, printing material and printing material
WO2017010998A1 (en) 2015-07-14 2017-01-19 Chevron Phillips Chemical Company Lp Olefin compositions
US9512071B1 (en) 2015-12-28 2016-12-06 Chevron Phillips Chemical Company Lp Mixed decyl mercaptans compositions and methods of making same
US9505011B1 (en) 2015-12-28 2016-11-29 Chevron Phillips Chemical Company Lp Mixed decyl mercaptans compositions and use thereof as mining chemical collectors
US10011564B2 (en) 2015-12-28 2018-07-03 Chevron Phillips Chemical Company Lp Mixed decyl mercaptans compositions and methods of making same
US9512248B1 (en) 2015-12-28 2016-12-06 Chevron Phillips Chemical Company Lp Mixed decyl mercaptans compositions and use thereof as chain transfer agents

Also Published As

Publication number Publication date
US20170190811A1 (en) 2017-07-06
TWI707877B (en) 2020-10-21
US9631039B1 (en) 2017-04-25
WO2017116541A1 (en) 2017-07-06
TW201736403A (en) 2017-10-16
KR20180099694A (en) 2018-09-05
KR102433068B1 (en) 2022-08-16
US20180105623A1 (en) 2018-04-19
EP3397655A1 (en) 2018-11-07
MY182326A (en) 2021-01-19
US9512248B1 (en) 2016-12-06
KR20220119506A (en) 2022-08-29
EP3397655B1 (en) 2020-03-18
US9879102B2 (en) 2018-01-30
EP3686221B1 (en) 2023-08-02
WO2017116541A9 (en) 2017-11-02
KR20220119505A (en) 2022-08-29
US10000590B2 (en) 2018-06-19
EP3686221A1 (en) 2020-07-29

Similar Documents

Publication Publication Date Title
SG11201805512SA (en) Mixed decyl mercaptans compositions and use thereof as chain transfer agents
SG11201805508XA (en) Mixed decyl mercaptans compositions and methods of making same
SG11201407923TA (en) Liquid optical adhesive compositions
SG11201804528YA (en) Multi-passenger ride vehicle
SG11201811324VA (en) Flowcell cartridge with floating seal bracket
SG11201900746RA (en) Engineered antibodies and other fc-domain containing molecules with enhanced agonism and effector functions
SG11201807252QA (en) Anti-lag-3 antibodies
SG11201809857TA (en) Anti-CTLA-4 Antibodies
SG11201803907QA (en) A process for recovering hydrocarbons in a solution polymerisation process
SG11201805927YA (en) Spiroheptane salicylamides and related compounds as inhibitors of rock
SG11201808775PA (en) Noninvasive diagnostics by sequencing 5-hydroxymethylated cell-free dna
SG11201909274WA (en) Annular motion simulation amusement park attraction
SG11201901909QA (en) Acid aromatization catalyst with improved activity and stability
SG11201804674UA (en) Heteroarylhydroxypyrimidinones as agonists of the apj receptor
SG11201807382RA (en) A single- or multiple component composition for producing a hydrogel
SG11201907421QA (en) Chemical composition
SG11201807596YA (en) Gitr antibodies, methods, and uses
SG11201810857PA (en) Pai-based coating compositions
SG11201805898RA (en) Liquid composition comprising a multistage polymer, its method of preparation and its use
SG11201807775SA (en) Aqueous polymer dispersions, a method for their preparation and the use thereof as pour-point depressants for crude oil, petroleum, and petroleum products
SG11201805387RA (en) Meta-azacyclic amino benzoic acid derivatives as pan integrin antagonists
SG11201901414RA (en) Process for conversion of dimethyl sulfide to methyl mercaptan
SG11201810202UA (en) Polysulfonamide redistribution compositions and methods of their use
SG11201803979PA (en) Sulfur-containing compounds as solvents
SG11201906807VA (en) Compositions and methods for promoting hair growth with mpc1 inhibitors