SG11201704004YA - Method for preparing methyl formate - Google Patents

Method for preparing methyl formate

Info

Publication number
SG11201704004YA
SG11201704004YA SG11201704004YA SG11201704004YA SG11201704004YA SG 11201704004Y A SG11201704004Y A SG 11201704004YA SG 11201704004Y A SG11201704004Y A SG 11201704004YA SG 11201704004Y A SG11201704004Y A SG 11201704004YA SG 11201704004Y A SG11201704004Y A SG 11201704004YA
Authority
SG
Singapore
Prior art keywords
methyl formate
preparing methyl
preparing
formate
methyl
Prior art date
Application number
SG11201704004YA
Inventor
Youming Ni
Wenliang Zhu
Yong Liu
Hongchao Liu
Zhongmin Liu
Lina Li
Shiping Liu
Hui Zhou
Original Assignee
Dalian Inst Chemical Physics Cas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dalian Inst Chemical Physics Cas filed Critical Dalian Inst Chemical Physics Cas
Publication of SG11201704004YA publication Critical patent/SG11201704004YA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • B01J31/10—Ion-exchange resins sulfonated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/48—Preparation of compounds having groups
    • C07C41/50—Preparation of compounds having groups by reactions producing groups
    • C07C41/56—Preparation of compounds having groups by reactions producing groups by condensation of aldehydes, paraformaldehyde, or ketones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/04—Formic acid esters
    • C07C69/06—Formic acid esters of monohydroxylic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/043—Dimethyl ether
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/10—Saturated ethers of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02—Formic acid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
    • C08F212/36—Divinylbenzene
SG11201704004YA 2014-11-17 2014-11-17 Method for preparing methyl formate SG11201704004YA (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/CN2014/091289 WO2016077967A1 (en) 2014-11-17 2014-11-17 Method for preparing methyl formate

Publications (1)

Publication Number Publication Date
SG11201704004YA true SG11201704004YA (en) 2017-06-29

Family

ID=56013026

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201704004YA SG11201704004YA (en) 2014-11-17 2014-11-17 Method for preparing methyl formate

Country Status (9)

Country Link
US (1) US9944588B2 (en)
EP (1) EP3222608B1 (en)
JP (1) JP6407428B2 (en)
KR (1) KR101977784B1 (en)
AU (1) AU2014411966B2 (en)
BR (1) BR112017010148A2 (en)
EA (1) EA032799B1 (en)
SG (1) SG11201704004YA (en)
WO (1) WO2016077967A1 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101965523B1 (en) * 2014-11-17 2019-04-03 달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈 Method for Preparing Methyl Formate and Coproducing Dimethyl Ether

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1642689A (en) * 1925-01-22 1927-09-20 Consortium Elektrochem Ind Method of preparation of methyl formate
DE3715035A1 (en) * 1987-05-06 1988-11-17 Basf Ag METHOD FOR THE PRODUCTION OF TRIALKYLAMINES AND METHYL FORMATE IN THE PRODUCTION OF TRIMETHYLOLALKANES
DK173416B1 (en) * 1995-07-21 2000-10-02 Topsoe Haldor As Process for producing hydrogen-rich gas
JP2662649B2 (en) * 1996-04-26 1997-10-15 旭化成工業株式会社 Dehydration reaction method using ZSM-5
JP4281856B2 (en) * 1998-08-03 2009-06-17 旭化成ケミカルズ株式会社 Methylal manufacturing method
US6015875A (en) * 1998-08-11 2000-01-18 Catalytic Distillation Technologies Process for making acetals
US6160186A (en) * 1998-11-12 2000-12-12 Bp Amoco Corporation Preparation of polyoxymethylene dimethyl ethers by catalytic conversion of dimethyl ether with formaldehyde formed by dehydrogenation of dimethyl ether
JP3795272B2 (en) * 1999-09-29 2006-07-12 ダイハツ工業株式会社 Dimethyl ether reforming catalyst and fuel cell device
DE102004059334A1 (en) * 2004-12-09 2006-06-22 Ticona Gmbh Process for the preparation of acetals
EP1871731B1 (en) * 2005-04-15 2012-12-26 University Of Southern California Efficient and selective conversion of carbon dioxide to methanol, dimethyl ether and derived products
JP2008537956A (en) * 2005-04-15 2008-10-02 ユニヴァーシティー オブ サザン カリフォルニア Selective oxidative conversion of methane to methanol, dimethyl ether and derivatives.
CN101327444B (en) * 2008-05-19 2010-09-01 中国科学院山西煤炭化学研究所 Metallic catalyst for synthesizing dimethoxym ethane and methyl formate and production method thereof and use
US7772423B2 (en) * 2008-10-23 2010-08-10 The Regents Of The University Of California Process for the production of alkyl alkoxyacetates
EP2450336A1 (en) * 2010-11-09 2012-05-09 INEOS Paraform GmbH Process for the production of pure methylal
CN103254084A (en) * 2012-02-20 2013-08-21 李坚 Method for preparing DMC, DPC, ortho-carbonate, ortho-formate, dimethyl ether, and the like by using Na2CO3 or sodium formate or CO2 or CO
CN104016857B (en) * 2014-05-26 2016-08-24 北京大学 The method preparing methyl formate
KR101965523B1 (en) * 2014-11-17 2019-04-03 달리안 인스티튜트 오브 케미컬 피직스, 차이니즈 아카데미 오브 사이언시즈 Method for Preparing Methyl Formate and Coproducing Dimethyl Ether

Also Published As

Publication number Publication date
KR20170084175A (en) 2017-07-19
BR112017010148A2 (en) 2018-02-14
EP3222608A4 (en) 2018-05-09
EP3222608B1 (en) 2019-06-12
US20170320808A1 (en) 2017-11-09
KR101977784B1 (en) 2019-05-13
EA032799B1 (en) 2019-07-31
US9944588B2 (en) 2018-04-17
WO2016077967A1 (en) 2016-05-26
JP2017534659A (en) 2017-11-24
JP6407428B2 (en) 2018-10-17
EP3222608A1 (en) 2017-09-27
EA201790993A1 (en) 2017-09-29
AU2014411966A1 (en) 2017-06-15
AU2014411966B2 (en) 2018-05-31

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