SG11201506957XA - High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers - Google Patents

High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers

Info

Publication number
SG11201506957XA
SG11201506957XA SG11201506957XA SG11201506957XA SG11201506957XA SG 11201506957X A SG11201506957X A SG 11201506957XA SG 11201506957X A SG11201506957X A SG 11201506957XA SG 11201506957X A SG11201506957X A SG 11201506957XA SG 11201506957X A SG11201506957X A SG 11201506957XA
Authority
SG
Singapore
Prior art keywords
stabilizers
polymer
high functionality
polyols prepared
functionality isocyanates
Prior art date
Application number
SG11201506957XA
Inventor
Rick L Adkins
Original Assignee
Bayer Materialscience Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer Materialscience Llc filed Critical Bayer Materialscience Llc
Publication of SG11201506957XA publication Critical patent/SG11201506957XA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/83—Chemically modified polymers
    • C08G18/831—Chemically modified polymers by oxygen-containing compounds inclusive of carbonic acid halogenides, carboxylic acid halogenides and epoxy halides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
    • C08F290/14—Polymers provided for in subclass C08G
    • C08F290/147—Polyurethanes; Polyureas
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/16—Catalysts
    • C08G18/22—Catalysts containing metal compounds
    • C08G18/227—Catalysts containing metal compounds of antimony, bismuth or arsenic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/632—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers onto polyethers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/63—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers
    • C08G18/636—Block or graft polymers obtained by polymerising compounds having carbon-to-carbon double bonds on to polymers characterised by the presence of a dispersion-stabiliser
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8108—Unsaturated isocyanates or isothiocyanates having only one isocyanate or isothiocyanate group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/81—Unsaturated isocyanates or isothiocyanates
    • C08G18/8141—Unsaturated isocyanates or isothiocyanates masked
    • C08G18/815—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen
    • C08G18/8158—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen
    • C08G18/8175—Polyisocyanates or polyisothiocyanates masked with unsaturated compounds having active hydrogen with unsaturated compounds having only one group containing active hydrogen with esters of acrylic or alkylacrylic acid having only one group containing active hydrogen

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Graft Or Block Polymers (AREA)
SG11201506957XA 2013-03-04 2014-02-25 High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers SG11201506957XA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US13/783,459 US20140249274A1 (en) 2013-03-04 2013-03-04 High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers
PCT/US2014/018159 WO2014137656A1 (en) 2013-03-04 2014-02-25 High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers

Publications (1)

Publication Number Publication Date
SG11201506957XA true SG11201506957XA (en) 2015-10-29

Family

ID=51421254

Family Applications (2)

Application Number Title Priority Date Filing Date
SG10201707098PA SG10201707098PA (en) 2013-03-04 2014-02-25 High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers
SG11201506957XA SG11201506957XA (en) 2013-03-04 2014-02-25 High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers

Family Applications Before (1)

Application Number Title Priority Date Filing Date
SG10201707098PA SG10201707098PA (en) 2013-03-04 2014-02-25 High functionality isocyanates as polymer polyol stabilizers and the polymer polyols prepared from these stabilizers

Country Status (7)

Country Link
US (1) US20140249274A1 (en)
EP (1) EP2964684A4 (en)
JP (1) JP6258358B2 (en)
KR (1) KR102115636B1 (en)
CN (1) CN105026452A (en)
SG (2) SG10201707098PA (en)
WO (1) WO2014137656A1 (en)

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US9522973B2 (en) * 2012-10-02 2016-12-20 Covestro Llc Polyurethane and polyisocyanurate rigid foams for roofing insulation
US10975215B2 (en) * 2016-03-31 2021-04-13 Dow Global Technologies Llc Process making polymer polyol having monodisperse dispersed polymer particles
US11312811B2 (en) * 2016-04-26 2022-04-26 Covestro Llc Flexible foam using polymer polyols produced via DMC catalyzed polyols
CN107090064B (en) * 2017-05-24 2019-04-23 万华化学集团股份有限公司 A method of macromonomer, preparation method with more alkyl structures and polymer polyatomic alcohol is prepared using it
CN109721705B (en) * 2017-10-27 2020-11-20 比亚迪股份有限公司 Fiber sizing agent, preparation method thereof and fiber composite material
EP3904416B1 (en) * 2018-12-26 2023-04-19 Wanhua Chemical Group Co., Ltd. Macromonomeric stabilizer, preparation method thereof, and method for preparing polymeric polyol
CN109810086B (en) * 2018-12-26 2021-02-02 万华化学集团股份有限公司 Isocyanate with unsaturated group and preparation method and application thereof
CN109796575B (en) * 2018-12-27 2022-02-18 万华化学集团股份有限公司 Stabilizer and preparation method thereof, and preparation method and application of polymer polyol
US10781310B2 (en) * 2019-02-08 2020-09-22 Covestro Llc Polymer polyol stabilizers
US11421063B2 (en) 2019-10-10 2022-08-23 Covestro Llc Preformed stabilizers with improved stability
CN112708124B (en) * 2019-10-24 2022-12-09 中国石油化工股份有限公司 Preparation method and application of high-functionality polyether polyol
ES2919658T3 (en) 2020-02-25 2022-07-27 Repsol Sa Process for preparing polymeric polyols
CN114479050B (en) * 2020-10-23 2023-08-04 中国石油化工股份有限公司 Stabilizer precursor and preparation method and application thereof
CN116507652A (en) 2020-11-04 2023-07-28 雷普索尔有限公司 Polyol peroxide based stabilizers and process for preparing polymer polyols
US12006413B2 (en) 2022-01-12 2024-06-11 Covestro Llc Polymer polyols, processes for their preparation, and the use thereof to produce foams exhibiting resistance to combustion
CN114644733A (en) * 2022-02-16 2022-06-21 万华化学集团股份有限公司 Preparation method of polymer polyol

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US4390645A (en) * 1979-11-23 1983-06-28 The Dow Chemical Company Stable dispersions of polymers in polyfunctional compounds having a plurality of active hydrogens and polyurethanes therefrom
US4521546A (en) * 1981-12-21 1985-06-04 Olin Corporation Graft copolymers from vinyl monomers and polyurethane oligomers and polyurethanes prepared therefrom
US5093386A (en) * 1989-05-16 1992-03-03 Stamicarbon B.V. Liquid curable plastic composition
US5169719A (en) * 1989-10-06 1992-12-08 Basf Corporation Nonionically and partially anionically stabilized water-dispersible polyurethane/acrylic graft copolymers
US5196476A (en) * 1990-06-12 1993-03-23 Arco Chemical Technology, L.P. Polymer/polyol and preformed stabilizer systems
JP3503126B2 (en) * 1995-08-28 2004-03-02 日立化成工業株式会社 Air-drying adhesive resin composition
ZA99973B (en) * 1998-02-09 1999-08-10 Shell Int Research Macromer stabiliser precursor for polymer polyols.
US20020052428A1 (en) * 1998-04-03 2002-05-02 Three Bond Co., Ltd. Ultraviolet-curing composition
CA2574143A1 (en) * 2004-07-28 2006-02-02 Novartis Ag Water-based inks for hydrogel lenses
US7160975B2 (en) * 2004-08-02 2007-01-09 Bayer Materialscience Llc Methacrylates as stabilizers for polymer polyols
US7759423B2 (en) * 2004-08-02 2010-07-20 Bayer Materialscience Llc Polymer polyols with ultra-high solids contents
CN101501086B (en) * 2006-07-05 2012-07-04 陶氏环球技术有限责任公司 Copolymer polyols and a process for the production thereof
US7776969B2 (en) * 2006-12-04 2010-08-17 Bayer Materialscience Llc Allophanate-modified stabilizers and the polymer polyols prepared from these stabilizers
US20110306728A1 (en) * 2010-06-11 2011-12-15 Bayer Materialscience Ag Polymer polyols prepared from nitrile-free azo-initiators
WO2012017016A1 (en) * 2010-08-03 2012-02-09 Shell Internationale Research Maatschappij B.V. Process for preparing polymer polyols

Also Published As

Publication number Publication date
JP2016510824A (en) 2016-04-11
EP2964684A4 (en) 2016-10-26
SG10201707098PA (en) 2017-09-28
KR20150124997A (en) 2015-11-06
US20140249274A1 (en) 2014-09-04
CN105026452A (en) 2015-11-04
EP2964684A1 (en) 2016-01-13
JP6258358B2 (en) 2018-01-10
KR102115636B1 (en) 2020-05-26
WO2014137656A1 (en) 2014-09-12

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