SG11201506098WA - Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers - Google Patents

Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers

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Publication number
SG11201506098WA
SG11201506098WA SG11201506098WA SG11201506098WA SG11201506098WA SG 11201506098W A SG11201506098W A SG 11201506098WA SG 11201506098W A SG11201506098W A SG 11201506098WA SG 11201506098W A SG11201506098W A SG 11201506098WA SG 11201506098W A SG11201506098W A SG 11201506098WA
Authority
SG
Singapore
Prior art keywords
plasticizers
methyl
manufacture
production
substituted biphenyl
Prior art date
Application number
SG11201506098WA
Inventor
Jihad M Dakka
Lorenzo C Decaul
Victor Deflorio
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Publication of SG11201506098WA publication Critical patent/SG11201506098WA/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/367—Formation of an aromatic six-membered ring from an existing six-membered ring, e.g. dehydrogenation of ethylcyclohexane to ethylbenzene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B01J29/0316—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 containing iron group metals, noble metals or copper
    • B01J29/0325—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/085—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/14—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • B01J29/7469—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7615—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76—Iron group metals or copper
    • B01J29/7669—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/74—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition with simultaneous hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/255—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting
    • C07C51/265—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of compounds containing six-membered aromatic rings without ring-splitting having alkyl side chains which are oxidised to carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
    • C07C2529/74—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2601/00—Systems containing only non-condensed rings
    • C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
    • C07C2601/14—The ring being saturated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
SG11201506098WA 2013-03-14 2014-03-07 Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers SG11201506098WA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201361781109P 2013-03-14 2013-03-14
PCT/US2014/021929 WO2014159094A1 (en) 2013-03-14 2014-03-07 Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers

Publications (1)

Publication Number Publication Date
SG11201506098WA true SG11201506098WA (en) 2015-09-29

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SG11201506098WA SG11201506098WA (en) 2013-03-14 2014-03-07 Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers

Country Status (5)

Country Link
US (1) US9556087B2 (en)
EP (1) EP2970045A4 (en)
CN (1) CN105026341A (en)
SG (1) SG11201506098WA (en)
WO (1) WO2014159094A1 (en)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9771466B2 (en) 2010-12-14 2017-09-26 Exxonmobil Chemical Patents Inc. Glycol ether-based cyclohexanoate ester plasticizers and blends therefrom
US9464166B2 (en) 2013-01-28 2016-10-11 Exxonmobil Chemical Patents Inc. Production and use of 3,4' and 4,4'-dimethylbiphenyl isomers
US9085669B2 (en) 2013-01-28 2015-07-21 Exxonmobil Chemical Patents Inc. Alkyl aromatic hydroalkylation for the production of plasticizers
US9534104B2 (en) 2013-01-28 2017-01-03 Exxonmobil Chemical Patents Inc. Plasticizer blends and use thereof
EP2970049B1 (en) 2013-03-14 2019-10-16 ExxonMobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
SG11201506447UA (en) 2013-03-14 2015-09-29 Exxonmobil Chem Patents Inc (methylcyclohexyl)toluene isomer mixtures, their production and their use in the manufacture of plasticizers
CN105050985A (en) 2013-03-14 2015-11-11 埃克森美孚化学专利公司 Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
US9556087B2 (en) 2013-03-14 2017-01-31 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
US9328053B2 (en) 2013-03-14 2016-05-03 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
US9725377B2 (en) 2013-03-14 2017-08-08 Exxonmobil Chemical Patents Inc. Hydroalkylation catalyst and process for use thereof
US9556103B2 (en) 2014-06-13 2017-01-31 Exxonmobil Chemical Patents Inc. Biphenyl esters, their production and their use in the manufacture of plasticizers
US9896393B2 (en) 2014-06-13 2018-02-20 Exxonmobil Chemical Patents Inc. Process for preparing dialkylbiphenyl isomer mixtures
US9758447B2 (en) 2014-10-24 2017-09-12 Exxonmobil Chemical Patents Inc. Activation of dehydrogenation catalysts
EP3233769A4 (en) 2014-12-19 2018-01-24 ExxonMobil Chemical Patents Inc. Production and use of dialkylbiphenyl isomer mixtures
US9856186B2 (en) 2014-12-19 2018-01-02 Exxonmobil Chemical Patents Inc. Production and use of dialkylbiphenyl isomer mixtures
CN107428630A (en) * 2015-03-25 2017-12-01 埃克森美孚化学专利公司 The production of biphenol compound
JP6441501B2 (en) 2015-03-31 2018-12-19 エクソンモービル ケミカル パテンツ インコーポレイテッド Transalkylated cyclohexylbenzyl and biphenyl compounds
JP6533592B2 (en) 2015-04-02 2019-06-19 エクソンモービル・ケミカル・パテンツ・インク Process for producing thermoplastic vulcanizates and thermoplastic vulcanizates produced therefrom
WO2019143495A1 (en) 2018-01-22 2019-07-25 Exxonmobil Chemical Patents Inc. Production and use of 3,4' and 4,4'-dimethylbiphenyl isomers

Family Cites Families (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US28341A (en) 1860-05-22 Improvement in apparatus for condensing coal-oil
US2520084A (en) 1948-05-27 1950-08-22 Monsanto Chemicals Plasticized vinyl chloride polymers
US2634248A (en) * 1949-09-14 1953-04-07 Monsanto Chemicals Vinyl chloride polymers plasticized with dialkyl esters of biphenyldicarboxylic acid
US2976266A (en) 1957-10-17 1961-03-21 American Viscose Corp Film-forming polyesters of bibenzoic acid
NL6503410A (en) 1963-02-21 1965-09-20
US3442795A (en) 1963-02-27 1969-05-06 Mobil Oil Corp Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom
US3296065A (en) 1963-10-07 1967-01-03 Monsanto Co Paper products containing carboxylic acid esters and process for preparing such products
US3308069A (en) 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite
US3293192A (en) 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
SU412182A1 (en) 1971-08-02 1974-01-25
US3766093A (en) 1972-01-07 1973-10-16 Mobil Oil Corp Treatment of organic cationcontaining zeolites
GB1387335A (en) 1972-07-21 1975-03-12 Ici Ltd Manufacture of polyesters
US3842041A (en) 1972-07-21 1974-10-15 Ici Ltd Solid state manufacture of polyesters
US3894104A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3923636A (en) 1974-06-03 1975-12-02 Texaco Inc Production of lubricating oils
US3928484A (en) 1974-07-05 1975-12-23 Texaco Inc Production of aromatic compounds by oxidative dehydrogenation
US3928481A (en) * 1974-07-05 1975-12-23 Texaco Inc Preparation of polyphenyls
US3972983A (en) 1974-11-25 1976-08-03 Mobil Oil Corporation Crystalline zeolite ZSM-20 and method of preparing same
US3962362A (en) 1975-03-31 1976-06-08 Texaco Development Corporation Method for preparing polyphenyls
US4123470A (en) 1977-06-06 1978-10-31 Phillips Petroleum Company Biaryl production
JPS5528904A (en) 1978-08-18 1980-02-29 Mitsubishi Petrochem Co Ltd Preparation of biphenyl derivative
JPS5535026A (en) 1978-09-05 1980-03-11 Ube Ind Ltd Production of biphenyl compound
US4218572A (en) 1978-09-28 1980-08-19 Standard Oil Company Process for the production of polyphenyls
US4401556A (en) 1979-11-13 1983-08-30 Union Carbide Corporation Midbarrel hydrocracking
US4463207A (en) 1983-09-23 1984-07-31 Shell Oil Company Arene alkylation with metal oxide-tantalum halide/oxide catalysts
US4959450A (en) 1988-12-23 1990-09-25 Eastman Kodak Company Copolyesters from 4,4'biphenyldicarboxylic acid, 1,4-cyclohexanedimethanol and 1,6-hexanediol
JP2614329B2 (en) 1989-09-19 1997-05-28 新日鐵化学株式会社 Method for producing 4,4'-dialkylbiphenyl
US5001296A (en) 1990-03-07 1991-03-19 Mobil Oil Corp. Catalytic hydrodealkylation of aromatics
US5138022A (en) 1991-08-01 1992-08-11 The Dow Chemical Company Thermoplastic polyesters containing biphenylene linkages
DE4243524A1 (en) 1992-12-22 1994-06-23 Hoechst Ag Mixtures of isomeric nonanols and decanols, their preparation, phthalic acid esters obtainable from them and their use as plasticizers
JPH07173086A (en) 1993-12-16 1995-07-11 Cosmo Sogo Kenkyusho:Kk Method for producing dialkylbiphenyl compounds
JPH0820548A (en) 1994-07-07 1996-01-23 Mitsubishi Gas Chem Co Inc Production of biphenyls
JP3603908B2 (en) 1994-09-29 2004-12-22 三菱瓦斯化学株式会社 Process for producing 4-methylbiphenyl and 4,4'-dimethylbiphenyl
GB9615089D0 (en) 1996-07-18 1996-09-04 Exxon Chemical Patents Inc Esters and compositions comprising them
BR9813786B1 (en) 1997-12-19 2013-11-12 PROCESS FOR HYDROGENATING DI (ISONONIL) FTALATO OR DI (ISODECIL) FTALATO OR A MIX OF TWO OR MORE OF THESE
US6355711B1 (en) 1998-04-23 2002-03-12 Exxonmobil Chemical Patents Inc. High performance plasticizers from branched oxo alcohols
US6103919A (en) 1998-07-07 2000-08-15 Arteva North America S.A.R.L. Catalytic system and method for coupling of aromatic compounds
US6037513A (en) 1998-07-09 2000-03-14 Mobil Oil Corporation Hydroalkylation of aromatic hydrocarbons
US6433236B1 (en) * 2000-03-21 2002-08-13 Arteva North America S.A.R.L. Acid catalyzed isomerization of substituted diaryls
EP2258760B1 (en) 2001-09-25 2014-06-25 ExxonMobil Chemical Patents Inc. Plasticised polyvinyl chloride
US6652774B2 (en) 2001-12-20 2003-11-25 Ferro Corporation Glycerin triester plasticizer
US6777514B2 (en) 2002-08-27 2004-08-17 Exxonmobil Research And Engineering Company Geminally disubstituted olefin-carbon monoxide-ethylene polymer useful as a polyvinyl chloride plasticizer and a method of making same
GB0227087D0 (en) 2002-11-20 2002-12-24 Exxonmobil Chem Patents Inc Hydrogenation of benzene polycarboxylic acids or derivatives thereof
RU2003133192A (en) 2003-11-12 2005-05-10 Дженерал Электрик Компани (US) CONTINUOUS PRODUCTION OF 4, 4-DIISOPROPYLBIPHENIL
US20050215433A1 (en) * 2004-03-26 2005-09-29 Benitez Francisco M Aromatic fluid as agricultural solvent
US20090299111A1 (en) 2005-07-26 2009-12-03 Yutaka Kanbara (alkylphenyl) alkylcyclohexane and method for producing (alkylphenyl) alkylcyclohexane or alkylbiphenyl
WO2008121847A1 (en) 2007-03-30 2008-10-09 Exxonmobil Chemical Patents Inc. Polyketone plasticizers
US7847128B2 (en) 2007-09-21 2010-12-07 Exxonmobil Chemical Patents Inc. Process for producing cyclohexylbenzene
US8178728B2 (en) * 2008-04-14 2012-05-15 Exxonmobil Chemical Patents Inc. Process for producing cyclohexylbenzene
US8476350B2 (en) 2008-12-24 2013-07-02 Exxonmobil Research And Engineering Company Triglyceride plasticizer and process of making
WO2010138248A2 (en) 2009-05-26 2010-12-02 Exxonmobil Chemical Patents Inc. Transalkylation of polycyclohexylbenzenes
US20110184105A1 (en) 2009-09-29 2011-07-28 Exxonmobil Research And Engineering Company Phenylene Oxo-Diester Plasticizers and Methods of Making
US8771815B2 (en) 2009-12-17 2014-07-08 Exxonmobil Research And Engineering Company Process for making triglyceride plasticizer
WO2011096993A2 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation process
WO2011096989A1 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation of cyclohexanone to produce phenol
WO2011096991A1 (en) 2010-02-05 2011-08-11 Exxonmobil Chemical Patents Inc. Dehydrogenation process
JP2011187565A (en) 2010-03-05 2011-09-22 Toshiba Corp Method of manufacturing solid state imaging device, and the solid state imaging device
US8653313B2 (en) 2010-11-02 2014-02-18 Basf Se Process for preparing a phenylcyclohexane
JP6014943B2 (en) 2010-12-17 2016-10-26 エクソンモービル ケミカル パテンツ インコーポレイテッド Dehydrogenation catalyst and method
KR20160043130A (en) 2011-03-28 2016-04-20 엑손모빌 케미칼 패턴츠 인코포레이티드 Dehydrogenation process
US8684260B2 (en) 2011-04-01 2014-04-01 Reynolds Consumer Products Inc. Paperboard plate with corner walls
CN103619788B (en) 2011-05-18 2015-11-25 宇部兴产株式会社 3,3',4,4'-tetraalkylcyclohexylbenzene and its preparation method
US8829093B2 (en) 2013-01-28 2014-09-09 Exxonmobil Chemical Patents Inc. Alkyl aromatic hydroalkylation for the production of plastisizers
US9464166B2 (en) 2013-01-28 2016-10-11 Exxonmobil Chemical Patents Inc. Production and use of 3,4' and 4,4'-dimethylbiphenyl isomers
US9534104B2 (en) 2013-01-28 2017-01-03 Exxonmobil Chemical Patents Inc. Plasticizer blends and use thereof
US20150080546A1 (en) 2013-01-28 2015-03-19 Exxonmobil Chemical Patents Inc. Production and Use of 3,4' and 4,4'-Dimethylbiphenyl Isomers
US9085669B2 (en) 2013-01-28 2015-07-21 Exxonmobil Chemical Patents Inc. Alkyl aromatic hydroalkylation for the production of plasticizers
US9556087B2 (en) 2013-03-14 2017-01-31 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
CN105050985A (en) 2013-03-14 2015-11-11 埃克森美孚化学专利公司 Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
SG11201506447UA (en) 2013-03-14 2015-09-29 Exxonmobil Chem Patents Inc (methylcyclohexyl)toluene isomer mixtures, their production and their use in the manufacture of plasticizers
EP2970049B1 (en) 2013-03-14 2019-10-16 ExxonMobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
US9725377B2 (en) * 2013-03-14 2017-08-08 Exxonmobil Chemical Patents Inc. Hydroalkylation catalyst and process for use thereof
US9328053B2 (en) 2013-03-14 2016-05-03 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
EP2973816B1 (en) 2013-03-15 2018-07-25 ExxonMobil Research and Engineering Company Integrated electrical power and chemical production using fuel cells
US9896393B2 (en) 2014-06-13 2018-02-20 Exxonmobil Chemical Patents Inc. Process for preparing dialkylbiphenyl isomer mixtures
US9758447B2 (en) 2014-10-24 2017-09-12 Exxonmobil Chemical Patents Inc. Activation of dehydrogenation catalysts
US9856186B2 (en) 2014-12-19 2018-01-02 Exxonmobil Chemical Patents Inc. Production and use of dialkylbiphenyl isomer mixtures

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US20140316155A1 (en) 2014-10-23
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US9556087B2 (en) 2017-01-31
WO2014159094A1 (en) 2014-10-02

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