EP3233769A4 - Production and use of dialkylbiphenyl isomer mixtures - Google Patents

Production and use of dialkylbiphenyl isomer mixtures Download PDF

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Publication number
EP3233769A4
EP3233769A4 EP15870658.0A EP15870658A EP3233769A4 EP 3233769 A4 EP3233769 A4 EP 3233769A4 EP 15870658 A EP15870658 A EP 15870658A EP 3233769 A4 EP3233769 A4 EP 3233769A4
Authority
EP
European Patent Office
Prior art keywords
production
isomer mixtures
dialkylbiphenyl
dialkylbiphenyl isomer
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP15870658.0A
Other languages
German (de)
French (fr)
Other versions
EP3233769A1 (en
Inventor
Michael Salciccioli
Jihad M. Dakka
Emiel De Smit
Neeraj Sangar
Scott J. WEIGEL
Sumathy RAMAN
Terry E. Helton
Lorenzo C. Decaul
Christine N. Elia
Chuansheng Bai
Ranjita Ghose
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP3233769A1 publication Critical patent/EP3233769A1/en
Publication of EP3233769A4 publication Critical patent/EP3233769A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/74—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition with simultaneous hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27—Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2729—Changing the branching point of an open chain or the point of substitution on a ring
    • C07C5/2732—Catalytic processes
    • C07C5/2737—Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/367—Formation of an aromatic six-membered ring from an existing six-membered ring, e.g. dehydrogenation of ethylcyclohexane to ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
EP15870658.0A 2014-12-19 2015-12-02 Production and use of dialkylbiphenyl isomer mixtures Withdrawn EP3233769A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201462094218P 2014-12-19 2014-12-19
EP15157265 2015-03-03
PCT/US2015/063491 WO2016099893A1 (en) 2014-12-19 2015-12-02 Production and use of dialkylbiphenyl isomer mixtures

Publications (2)

Publication Number Publication Date
EP3233769A1 EP3233769A1 (en) 2017-10-25
EP3233769A4 true EP3233769A4 (en) 2018-01-24

Family

ID=52595199

Family Applications (1)

Application Number Title Priority Date Filing Date
EP15870658.0A Withdrawn EP3233769A4 (en) 2014-12-19 2015-12-02 Production and use of dialkylbiphenyl isomer mixtures

Country Status (3)

Country Link
EP (1) EP3233769A4 (en)
CN (1) CN107001184A (en)
WO (1) WO2016099893A1 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0899914A (en) * 1994-09-29 1996-04-16 Mitsubishi Gas Chem Co Inc Production of 4-methylbiphenyl and 4,4'=dimethylbiphenyl
WO2014159104A1 (en) * 2013-03-14 2014-10-02 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2976266A (en) 1957-10-17 1961-03-21 American Viscose Corp Film-forming polyesters of bibenzoic acid
NL6503410A (en) 1963-02-21 1965-09-20
US3442795A (en) 1963-02-27 1969-05-06 Mobil Oil Corp Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom
US3308069A (en) 1964-05-01 1967-03-07 Mobil Oil Corp Catalytic composition of a crystalline zeolite
US3293192A (en) 1965-08-23 1966-12-20 Grace W R & Co Zeolite z-14us and method of preparation thereof
US3766093A (en) 1972-01-07 1973-10-16 Mobil Oil Corp Treatment of organic cationcontaining zeolites
US3842041A (en) 1972-07-21 1974-10-15 Ici Ltd Solid state manufacture of polyesters
GB1387335A (en) 1972-07-21 1975-03-12 Ici Ltd Manufacture of polyesters
US3894104A (en) 1973-08-09 1975-07-08 Mobil Oil Corp Aromatization of hetero-atom substituted hydrocarbons
US3972983A (en) 1974-11-25 1976-08-03 Mobil Oil Corporation Crystalline zeolite ZSM-20 and method of preparing same
US4021447A (en) 1975-04-30 1977-05-03 Mobil Oil Corporation Synthesis of zeolite ZSM-4
US4016218A (en) 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4401556A (en) 1979-11-13 1983-08-30 Union Carbide Corporation Midbarrel hydrocracking
US4959450A (en) 1988-12-23 1990-09-25 Eastman Kodak Company Copolyesters from 4,4'biphenyldicarboxylic acid, 1,4-cyclohexanedimethanol and 1,6-hexanediol
JP2614329B2 (en) * 1989-09-19 1997-05-28 新日鐵化学株式会社 Method for producing 4,4'-dialkylbiphenyl
US5138022A (en) 1991-08-01 1992-08-11 The Dow Chemical Company Thermoplastic polyesters containing biphenylene linkages
JPH07173086A (en) * 1993-12-16 1995-07-11 Cosmo Sogo Kenkyusho:Kk Method for producing dialkylbiphenyl compounds
US6103919A (en) * 1998-07-07 2000-08-15 Arteva North America S.A.R.L. Catalytic system and method for coupling of aromatic compounds
US6433236B1 (en) * 2000-03-21 2002-08-13 Arteva North America S.A.R.L. Acid catalyzed isomerization of substituted diaryls
US8829093B2 (en) 2013-01-28 2014-09-09 Exxonmobil Chemical Patents Inc. Alkyl aromatic hydroalkylation for the production of plastisizers
US9085669B2 (en) 2013-01-28 2015-07-21 Exxonmobil Chemical Patents Inc. Alkyl aromatic hydroalkylation for the production of plasticizers
BR112015021665A2 (en) 2013-03-14 2017-07-18 Exxonmobil Chemical Patents Inc mixtures of (methylcyclohexyl) toluene isomers, their production and use in the manufacture of plasticizers
WO2014159101A1 (en) 2013-03-14 2014-10-02 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers
WO2014159094A1 (en) 2013-03-14 2014-10-02 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0899914A (en) * 1994-09-29 1996-04-16 Mitsubishi Gas Chem Co Inc Production of 4-methylbiphenyl and 4,4'=dimethylbiphenyl
WO2014159104A1 (en) * 2013-03-14 2014-10-02 Exxonmobil Chemical Patents Inc. Methyl-substituted biphenyl compounds, their production and their use in the manufacture of plasticizers

Also Published As

Publication number Publication date
EP3233769A1 (en) 2017-10-25
CN107001184A (en) 2017-08-01
WO2016099893A1 (en) 2016-06-23

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