SG11201408781YA - Process for acrylate production - Google Patents

Process for acrylate production

Info

Publication number
SG11201408781YA
SG11201408781YA SG11201408781YA SG11201408781YA SG11201408781YA SG 11201408781Y A SG11201408781Y A SG 11201408781YA SG 11201408781Y A SG11201408781Y A SG 11201408781YA SG 11201408781Y A SG11201408781Y A SG 11201408781YA SG 11201408781Y A SG11201408781Y A SG 11201408781YA
Authority
SG
Singapore
Prior art keywords
international
stream containing
novomer
danby
ithaca
Prior art date
Application number
SG11201408781YA
Inventor
Scott D Allen
Geoffrey Coates
Original Assignee
Novomer Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novomer Inc filed Critical Novomer Inc
Publication of SG11201408781YA publication Critical patent/SG11201408781YA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
    • C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
    • C07D305/12—Beta-lactones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
    • C08G63/08—Lactones or lactides

Abstract

(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 9 January 2014 (09.01.2014) WIPOIPCT (10) International Publication Number WO 2014/008232 A2 (51) International Patent Classification: C07C 67/27 (2006.01) (21) International Application Number: (22) International Filing Date: (25) Filing Language: (26) Publication Language: PCT/US2013/049026 2 July 2013 (02.07.2013) English English (30) Priority Data: 61/667,101 2 July 2012 (02.07.2012) (71) Applicant: NOVOMER, INC. [US/US]; 950 Danby Road, Suite 198, Ithaca, New York 14850 (US). (72) Inventors: ALLEN, Scott D.; c/o Novomer, Inc., 950 Danby Road, Suite 198, Ithaca, New York 14850 (US). COATES, Geoffrey; c/o Novomer, Inc., 950 Danby Road, Suite 198, Ithaca, New York 14850 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available)'. AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. Ug (84) Designated States (unless otherwise indicated, for every kind of regional protection available)'. ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). (74) Agents: KLEIN, Daniel A. et al.; CHOATE, HALL & STEWART LLP, Two International Place, Boston, Mas­ sachusetts 02110 (US). Published: — without international search report and to be republished upon receipt of that report (Rule 48.2(g)) CJ CJ m CJ oo o o o CJ O & (54) Title: PROCESS FOR ACRYLATE PRODUCTION (57) Abstract: Disclosed are methods for the continuous flow production of acrylic acid and derivatives thereof from an epoxide feedstock. In one embodiment, the method includes the steps of: contacting process a stream comprising ethylene oxide and an or - ganic solvent with carbonylation a catalyst and carbon monoxide to provide reaction a stream containing beta propiolactone; apply­ ing the reaction stream containing the beta propiolactone to a nanofiltration membrane produce permeate stream containing to a beta lactone and retentate a stream containing carbonylation catalyst; and treating the permeate stream under conditions to convert the beta propiolactone into an acrylate ester. In some embodiments, the retentate stream returned is to the first step of the process where it is recharged with additional epoxide and passed through the sequence again.
SG11201408781YA 2012-07-02 2013-07-02 Process for acrylate production SG11201408781YA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261667101P 2012-07-02 2012-07-02
PCT/US2013/049026 WO2014008232A2 (en) 2012-07-02 2013-07-02 Process for acrylate production

Publications (1)

Publication Number Publication Date
SG11201408781YA true SG11201408781YA (en) 2015-01-29

Family

ID=49882588

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201408781YA SG11201408781YA (en) 2012-07-02 2013-07-02 Process for acrylate production

Country Status (9)

Country Link
US (1) US20150141693A1 (en)
EP (1) EP2867189A4 (en)
JP (1) JP2015523363A (en)
KR (1) KR20150027766A (en)
CN (1) CN104411661A (en)
BR (1) BR112015000002A2 (en)
CA (1) CA2878028A1 (en)
SG (1) SG11201408781YA (en)
WO (1) WO2014008232A2 (en)

Families Citing this family (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104529950A (en) 2009-04-08 2015-04-22 诺沃梅尔公司 Process for beta-lactone production
JP2014527456A (en) 2011-05-13 2014-10-16 ノボマー， インコーポレイテッド Catalysts and methods for catalytic carbonylation
EP3375769B1 (en) 2011-10-26 2022-03-09 Novomer, Inc. Process for the preparation of acrylates from epoxides
CN104245659B (en) 2012-02-13 2016-08-24 诺沃梅尔公司 The method being produced acid anhydrides by epoxides
CN106170334B (en) 2013-12-07 2019-07-09 诺沃梅尔公司 Nano-filtration membrane and application method
CN106232607A (en) 2014-03-14 2016-12-14 诺沃梅尔公司 Carbonylation of epoxides catalyst
WO2015171372A1 (en) 2014-05-05 2015-11-12 Novomer, Inc. Catalyst recycle methods
KR20170012479A (en) 2014-05-30 2017-02-02 노보머, 인코포레이티드 Integrated methods for chemical synthesis
KR20170047248A (en) 2014-07-25 2017-05-04 노보머, 인코포레이티드 Synthesis of metal complexes and uses thereof
MA41508A (en) 2015-02-13 2017-12-19 Novomer Inc POLYACRYLIC ACID PRODUCTION SYSTEMS AND PROCESSES
MA41513A (en) 2015-02-13 2017-12-19 Novomer Inc DISTILLATION PROCESS FOR ACRYLIC ACID PRODUCTION
CN107406362B (en) 2015-02-13 2020-12-22 诺沃梅尔公司 Flexible chemical production platform
US10662283B2 (en) * 2015-02-13 2020-05-26 Novomer, Inc. Process and system for production of polypropiolactone
MA41514A (en) 2015-02-13 2017-12-19 Novomer Inc INTEGRATED CHEMICAL SYNTHESIS PROCESSES
US10221150B2 (en) * 2015-02-13 2019-03-05 Novomer, Inc. Continuous carbonylation processes
MA41510A (en) 2015-02-13 2017-12-19 Novomer Inc ACRYLIC ACID PRODUCTION PROCESS
MA41507A (en) * 2015-02-13 2017-12-19 Novomer Inc POLYMER PRODUCTION SYSTEMS AND PROCESSES
US9718755B2 (en) 2015-07-01 2017-08-01 Novomer, Inc. Methods for coproduction of terephthalic acid and styrene from ethylene oxide
WO2017004349A2 (en) 2015-07-01 2017-01-05 Novomer, Inc. Methods for production of terephthalic acid from ethylene oxide
CA2994403A1 (en) * 2015-07-31 2017-02-09 Novomer, Inc. Production system/production process for acrylic acid and precursors thereof
AU2017236914A1 (en) 2016-03-21 2018-11-08 Novomer, Inc. Improved acrylic acid production process
MX2018011140A (en) 2016-03-21 2018-11-21 Novomer Inc Systems and methods for producing superabsorbent polymers.
MX2019005098A (en) 2016-11-02 2019-08-12 Novomer Inc Absorbent polymers, and methods and systems of producing thereof and uses thereof.
US10144802B2 (en) 2016-12-05 2018-12-04 Novomer, Inc. Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof
US10500104B2 (en) 2016-12-06 2019-12-10 Novomer, Inc. Biodegradable sanitary articles with higher biobased content
WO2018107450A1 (en) * 2016-12-16 2018-06-21 Rhodia Operations Electrochemical process for producing a propiolactone compound
US10065914B1 (en) * 2017-04-24 2018-09-04 Novomer, Inc. Thermolysis of polypropiolactone to produce acrylic acid
CN107473957A (en) * 2017-06-08 2017-12-15 赢创特种化学（上海）有限公司 The method of chromium compound is enriched with from homogeneous organic liquid composition
US10781156B2 (en) 2017-06-30 2020-09-22 Novomer, Inc. Compositions for improved production of acrylic acid
US10676426B2 (en) 2017-06-30 2020-06-09 Novomer, Inc. Acrylonitrile derivatives from epoxide and carbon monoxide reagents
US10590099B1 (en) 2017-08-10 2020-03-17 Novomer, Inc. Processes for producing beta-lactone with heterogenous catalysts
US11814498B2 (en) 2018-07-13 2023-11-14 Novomer, Inc. Polylactone foams and methods of making the same
WO2020185420A1 (en) 2019-03-08 2020-09-17 Novomer, Inc. Integrated methods and systems for producing amide and nitrile compounds
KR20230150283A (en) 2021-02-26 2023-10-30 노보머, 인코포레이티드 Method for producing biodegradable polyester
WO2022187010A1 (en) 2021-03-02 2022-09-09 Novomer, Inc. Process for the recovery and/or regeneration of catalyst components
WO2022221266A1 (en) 2021-04-16 2022-10-20 Novomer, Inc. Polypropiolactones and methods of preparation
WO2023003890A1 (en) 2021-07-21 2023-01-26 Novomer, Inc. Methods for beta-lactone copolymerization

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0577206B1 (en) * 1992-06-29 1998-08-26 Shell Internationale Researchmaatschappij B.V. Carbonylation of epoxides
KR100447932B1 (en) * 2001-10-19 2004-09-08 한국화학연구원 Silicone-added polyamide composite nanofiltration membrane organic separation, and method for preparing them
EP1817097A2 (en) * 2004-10-21 2007-08-15 Dow Gloval Technologies Inc. Membrane separation of a metathesis reaction mixture
WO2008033687A2 (en) * 2006-09-15 2008-03-20 Dow Global Technologies Inc. Process for producing acrylic acid
CN104529950A (en) * 2009-04-08 2015-04-22 诺沃梅尔公司 Process for beta-lactone production

Also Published As

Publication number Publication date
EP2867189A4 (en) 2016-03-16
WO2014008232A3 (en) 2014-02-27
CN104411661A (en) 2015-03-11
US20150141693A1 (en) 2015-05-21
BR112015000002A2 (en) 2017-06-27
KR20150027766A (en) 2015-03-12
JP2015523363A (en) 2015-08-13
EP2867189A2 (en) 2015-05-06
WO2014008232A2 (en) 2014-01-09
CA2878028A1 (en) 2014-01-09

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