SG11201408665XA - Two stage gasification with dual quench - Google Patents
Two stage gasification with dual quenchInfo
- Publication number
- SG11201408665XA SG11201408665XA SG11201408665XA SG11201408665XA SG11201408665XA SG 11201408665X A SG11201408665X A SG 11201408665XA SG 11201408665X A SG11201408665X A SG 11201408665XA SG 11201408665X A SG11201408665X A SG 11201408665XA SG 11201408665X A SG11201408665X A SG 11201408665XA
- Authority
- SG
- Singapore
- Prior art keywords
- international
- quench
- syngas
- june
- pct
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/02—Dust removal
- C10K1/024—Dust removal by filtration
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/466—Entrained flow processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/485—Entrained flow gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/005—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
- C10K3/003—Reducing the tar content
- C10K3/008—Reducing the tar content by cracking
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/09—Mechanical details of gasifiers not otherwise provided for, e.g. sealing means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
- C10K3/003—Reducing the tar content
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
Abstract
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 3 January 2014 (03.01.2014) WIPOIPCT (10) International Publication Number WO 2014/004646 A1 (51) International Patent Classification: C10J3/46 (2006.01) C10K1/28 (2006.01) (21) International Application Number: (22) International Filing Date: (25) Filing Language: (26) Publication Language: PCT/US2013/047851 26 June 2013 (26.06.2013) English English (30) Priority Data: 61/664,415 26 June 2012 (26.06.2012) US (71) Applicant: LUMMUS TECHNOLOGY INC. [US/US]; 1515 Broad Street, Bloomfield, NJ 07003-3096 (US). (72) Inventors: KEELER, Clifton, G.; 17131 Post Oak Hol low, Spring, TX 77379 (US). WILLIAMS, Chancelor, L.; 26607 Sandy Arbor Lane, Katy, TX 77494 (US). BUSTAMANTE, Ivan, O.; 7011 Chatham Lake Lane, Richmond, TX 77407 (US). (74) Agents: GRIFFITH, Aron, T. et al.; Osha- Liang LLP, 909 Fannin Street, Suite 3500, Houston, TX 77010 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available)'. AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available)'. ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Published: — with international search report (Art. 21(3)) — before the expiration of the time limit for amending the claims and to be republished in the event of receipt of amendments (Rule 48.2(h)) (54) Title: TWO STAGE GASIFICATION WITH DUAL QUENCH rsoa ,:r ft 1—| 60a Tf o o FIG. 2 o CJ O (57) Abstract: Improved two-stage entrained-flow gasification systems and processes that reduce the cost and complexity of the design and increase the reliability, while maintaining the efficiency by implementing a first chemical quench followed by a second water quench of the produced syngas. The quenched syngas is maintained above the condensation temperature of at least one con - densable component of the syngas, allowing residual particulates to be removed by dry particulate filtration.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261664415P | 2012-06-26 | 2012-06-26 | |
PCT/US2013/047851 WO2014004646A1 (en) | 2012-06-26 | 2013-06-26 | Two stage gasification with dual quench |
Publications (1)
Publication Number | Publication Date |
---|---|
SG11201408665XA true SG11201408665XA (en) | 2015-01-29 |
Family
ID=49783826
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SG11201408665XA SG11201408665XA (en) | 2012-06-26 | 2013-06-26 | Two stage gasification with dual quench |
Country Status (20)
Country | Link |
---|---|
US (1) | US9567538B2 (en) |
EP (1) | EP2875103B1 (en) |
JP (2) | JP2015525810A (en) |
KR (1) | KR101644760B1 (en) |
CN (1) | CN104428401B (en) |
BR (1) | BR112014032652B1 (en) |
CA (1) | CA2877691C (en) |
CL (1) | CL2014003528A1 (en) |
CO (1) | CO7240436A2 (en) |
EA (1) | EA029814B1 (en) |
ES (1) | ES2804520T3 (en) |
IN (1) | IN2014MN02547A (en) |
MX (1) | MX2014015735A (en) |
MY (1) | MY167593A (en) |
PH (1) | PH12015500011A1 (en) |
PT (1) | PT2875103T (en) |
SG (1) | SG11201408665XA (en) |
UA (1) | UA112362C2 (en) |
WO (1) | WO2014004646A1 (en) |
ZA (1) | ZA201409449B (en) |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6025603B2 (en) * | 2013-02-21 | 2016-11-16 | 三菱重工業株式会社 | CO shift reaction apparatus and CO shift conversion method |
US20160122669A1 (en) * | 2014-11-05 | 2016-05-05 | General Electric Company | System and method for gasification |
NL2014786B1 (en) * | 2015-05-11 | 2017-01-26 | Dahlman Renewable Tech B V | Method and systems for treating synthesis gas. |
CN108601646B (en) | 2015-11-12 | 2021-10-12 | 博奥司时代有限责任公司 | Systems and methods for producing gastrointestinal tract tissue |
CN109072103B (en) * | 2016-03-04 | 2021-08-03 | 鲁姆斯科技有限责任公司 | Two-stage gasifier with feedstock flexibility and gasification process |
AU2017307385A1 (en) * | 2016-08-04 | 2019-01-31 | Reliance Industries Limited | A process and a system for producing synthesis gas |
NL2019552B1 (en) * | 2017-09-14 | 2019-03-27 | Torrgas Tech B V | Process to prepare a char product and a syngas mixture |
JP2022521284A (en) * | 2019-02-21 | 2022-04-06 | テクノロギアン トゥトキムスケスクス ヴェーテーテー オイ | Methods and process sequences for producing hydrocarbons, and uses |
CN114479942A (en) * | 2020-10-26 | 2022-05-13 | 中国石化工程建设有限公司 | Method and system for preparing coal gasification synthesis gas |
ES2965008T3 (en) * | 2021-01-06 | 2024-04-10 | Gidara Energy B V | Process to produce synthesis gas through thermochemical conversion of biomass and waste materials |
CN113234493A (en) * | 2021-06-10 | 2021-08-10 | 哈尔滨理工大学 | Improve gaseous solid-liquid-gas separation system who constitutes of WGSR behind coal gasification |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
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US4069024A (en) | 1977-05-09 | 1978-01-17 | Combustion Engineering, Inc. | Two-stage gasification system |
US4872886A (en) * | 1985-11-29 | 1989-10-10 | The Dow Chemical Company | Two-stage coal gasification process |
US5415673A (en) | 1993-10-15 | 1995-05-16 | Texaco Inc. | Energy efficient filtration of syngas cooling and scrubbing water |
US6141796A (en) | 1996-08-01 | 2000-11-07 | Isentropic Systems Ltd. | Use of carbonaceous fuels |
RU2402596C2 (en) | 2005-05-02 | 2010-10-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Procedure for production of synthetic gas and system for implementation of this procedure |
US20070225382A1 (en) * | 2005-10-14 | 2007-09-27 | Van Den Berg Robert E | Method for producing synthesis gas or a hydrocarbon product |
JP2009535471A (en) * | 2006-05-01 | 2009-10-01 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ | Gasification reactor and its use |
US8211191B2 (en) | 2007-08-07 | 2012-07-03 | Phillips 66 Company | Upright gasifier |
US8460410B2 (en) * | 2008-08-15 | 2013-06-11 | Phillips 66 Company | Two stage entrained gasification system and process |
US20100132257A1 (en) * | 2008-12-01 | 2010-06-03 | Kellogg Brown & Root Llc | Systems and Methods for Increasing Carbon Dioxide in Gasification |
TWI449781B (en) * | 2008-12-17 | 2014-08-21 | Lummus Technology Inc | Gasification system and process with staged slurry addition |
TW201026395A (en) * | 2008-12-24 | 2010-07-16 | Conocophillips Co | Tar-free gasification system and process |
US9074149B2 (en) | 2009-01-21 | 2015-07-07 | Lummus Technology Inc. | Methods and systems for treating a gasification slag product |
US8357216B2 (en) * | 2009-04-01 | 2013-01-22 | Phillips 66 Company | Two stage dry feed gasification system and process |
US9611437B2 (en) | 2010-01-12 | 2017-04-04 | Lummus Technology Inc. | Producing low methane syngas from a two-stage gasifier |
US8268023B2 (en) * | 2010-04-26 | 2012-09-18 | General Electric Company | Water gas shift reactor system for integrated gasification combined cycle power generation systems |
CN101906324B (en) * | 2010-07-20 | 2013-04-03 | 武汉凯迪控股投资有限公司 | Indirect gasification process of biomass water vapor and equipment thereof |
CN102226107A (en) * | 2011-05-26 | 2011-10-26 | 中国林业科学研究院林产化学工业研究所 | Technology and equipment for preparation of synthetic gas by two-stage high temperature biomass gasification |
US8951313B2 (en) * | 2012-03-28 | 2015-02-10 | General Electric Company | Gasifier cooling system with convective syngas cooler and quench chamber |
-
2013
- 2013-06-26 ES ES13810468T patent/ES2804520T3/en active Active
- 2013-06-26 JP JP2015520430A patent/JP2015525810A/en active Pending
- 2013-06-26 EA EA201590090A patent/EA029814B1/en unknown
- 2013-06-26 WO PCT/US2013/047851 patent/WO2014004646A1/en active Application Filing
- 2013-06-26 BR BR112014032652-5A patent/BR112014032652B1/en active IP Right Grant
- 2013-06-26 UA UAA201500407A patent/UA112362C2/en unknown
- 2013-06-26 KR KR1020157001909A patent/KR101644760B1/en active IP Right Grant
- 2013-06-26 MY MYPI2014003580A patent/MY167593A/en unknown
- 2013-06-26 IN IN2547MUN2014 patent/IN2014MN02547A/en unknown
- 2013-06-26 PT PT138104682T patent/PT2875103T/en unknown
- 2013-06-26 CA CA2877691A patent/CA2877691C/en active Active
- 2013-06-26 MX MX2014015735A patent/MX2014015735A/en active IP Right Grant
- 2013-06-26 CN CN201380033902.9A patent/CN104428401B/en active Active
- 2013-06-26 EP EP13810468.2A patent/EP2875103B1/en active Active
- 2013-06-26 US US14/411,015 patent/US9567538B2/en active Active
- 2013-06-26 SG SG11201408665XA patent/SG11201408665XA/en unknown
-
2014
- 2014-12-19 ZA ZA2014/09449A patent/ZA201409449B/en unknown
- 2014-12-24 CL CL2014003528A patent/CL2014003528A1/en unknown
- 2014-12-26 CO CO14284179A patent/CO7240436A2/en unknown
-
2015
- 2015-01-05 PH PH12015500011A patent/PH12015500011A1/en unknown
-
2016
- 2016-08-12 JP JP2016158467A patent/JP6371809B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
JP2017020038A (en) | 2017-01-26 |
CA2877691A1 (en) | 2014-01-03 |
CL2014003528A1 (en) | 2015-07-03 |
CO7240436A2 (en) | 2015-04-17 |
MY167593A (en) | 2018-09-20 |
US9567538B2 (en) | 2017-02-14 |
ZA201409449B (en) | 2015-12-23 |
JP2015525810A (en) | 2015-09-07 |
PT2875103T (en) | 2020-06-23 |
CA2877691C (en) | 2018-06-12 |
CN104428401A (en) | 2015-03-18 |
EP2875103A1 (en) | 2015-05-27 |
US20150299590A1 (en) | 2015-10-22 |
UA112362C2 (en) | 2016-08-25 |
JP6371809B2 (en) | 2018-08-08 |
BR112014032652B1 (en) | 2021-07-20 |
EA029814B1 (en) | 2018-05-31 |
EP2875103A4 (en) | 2016-05-11 |
MX2014015735A (en) | 2015-06-05 |
EA201590090A1 (en) | 2015-04-30 |
BR112014032652A2 (en) | 2021-04-20 |
KR101644760B1 (en) | 2016-08-01 |
ES2804520T3 (en) | 2021-02-08 |
EP2875103B1 (en) | 2020-04-29 |
CN104428401B (en) | 2017-03-08 |
PH12015500011B1 (en) | 2015-04-06 |
PH12015500011A1 (en) | 2015-04-06 |
WO2014004646A1 (en) | 2014-01-03 |
KR20150023873A (en) | 2015-03-05 |
IN2014MN02547A (en) | 2015-07-24 |
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