SG11201407624XA - Method for producing octadiene - Google Patents

Method for producing octadiene

Info

Publication number
SG11201407624XA
SG11201407624XA SG11201407624XA SG11201407624XA SG11201407624XA SG 11201407624X A SG11201407624X A SG 11201407624XA SG 11201407624X A SG11201407624X A SG 11201407624XA SG 11201407624X A SG11201407624X A SG 11201407624XA SG 11201407624X A SG11201407624X A SG 11201407624XA
Authority
SG
Singapore
Prior art keywords
octadiene
producing
ufa
ibaraki
pct
Prior art date
Application number
SG11201407624XA
Inventor
Osamu Nakayama
Junichi Fuji
Masaki Shimizu
Original Assignee
Kuraray Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Co filed Critical Kuraray Co
Publication of SG11201407624XA publication Critical patent/SG11201407624XA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/2078—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by a transformation in which at least one -C(=O)-O- moiety is eliminated
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/213—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by splitting of esters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

(i2) mwu ft iz s-5 iv x m £ titz s issaj n d9) mm IHMMi _ r4T» allium 2013 if 11 £21 0(21.11.2013) w ,p 0 |PCT (10) WO 2013/172389 A1 (51) C07C1/213 (2006.01) B01J31/24 (2006.01) (21) (22) (25) (26) @(8&M©Wl§: (30) fiBfcfif '— 1 £: 2012-113193 2012 ^5^ 17 0(17.05.2012) JP (71) tti H A : S # # <7 ^ (KURARAY CO., LTD.) [JP/JP]; T 7100801 HUj R5t1ft rfT }g;t 1 6 2 1# ±fe Okayama (JP). (72) ^ BJ # : rp Uj % (NAKAYAMA , Osamu); T 3140197 3 6 #±fe \"7 Ufa Ibaraki (JP). IS $trfT(FUJI, Junichi); T 1008115 E^^-PST —T @ 1 # 3 7UW Tokyo (JP). jf 7K (SHIMIZU Masaki); , T3140197 rfi KfP H 3 6 #±fe \"7 Ufa Ibaraki (JP). (8i) (^ro&i^PBy. IS ft nJ f b): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KM, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) (asrofci^isy > ±T(Dmm(Dfcm% 11^ nlfb): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW), 3. — =j V T (AM, AZ, BY, KG, KZ, RU, TJ, TM), 3 — • V / ^ (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, ML, MR, NE, SN, TD, TG). - (&&£ 21 &(3)) C07C11/12 (2006.01) C07B 61/00 (2006.01) PCT/JP2013/063595 2013 ^ 5 M 15 0(15.05.2013) 0*1S 0*1S (54) Title: METHOD FOR PRODUCING OCTADIENE ^ (54)f§BJ(7):S^ : Vl ON (57) Abstract: The objective of the present invention is to provide method a for producing an octadiene industrially advantageously ^ by maintaining activity of palladium catalytic over an extended period of time when producing an octadiene from 2,7-octadienyl (•— formate. More specifically, provided is a method for producing an octadiene by continuously adding 2,7-octadienyl formate to a re- ^ action in which mixture of system a a palladium compound, tertiary a organic phosphorus compound and solvent a is present and fT) performing reaction while continuously distilling the product including the octadiene out of the reaction system. © (57)^: 2, 7 -if <7 $ yl ~ ~ h ft b * ^ > ZMxkt & lc|$? L> y 2, 7 —^\"<7 £ — h L> -**? 1 yl g tiJ $ ft b £f& £ *T v - t £ 11 % * t $ vx >0)£Iff* t £ „
SG11201407624XA 2012-05-17 2013-05-15 Method for producing octadiene SG11201407624XA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012113193 2012-05-17
PCT/JP2013/063595 WO2013172389A1 (en) 2012-05-17 2013-05-15 Method for producing octadiene

Publications (1)

Publication Number Publication Date
SG11201407624XA true SG11201407624XA (en) 2014-12-30

Family

ID=49583793

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201407624XA SG11201407624XA (en) 2012-05-17 2013-05-15 Method for producing octadiene

Country Status (9)

Country Link
US (1) US9637421B2 (en)
EP (1) EP2851358B1 (en)
JP (1) JP5898766B2 (en)
KR (1) KR102031396B1 (en)
CN (1) CN104302603B (en)
CA (1) CA2873690C (en)
MY (1) MY170219A (en)
SG (1) SG11201407624XA (en)
WO (1) WO2013172389A1 (en)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4717703Y1 (en) 1968-10-15 1972-06-20
JP3120409B2 (en) 1992-02-27 2000-12-25 株式会社クラレ Method for producing optically active 1-alkenes
JP3015200B2 (en) 1992-03-31 2000-03-06 株式会社クラレ Method for producing propene derivative
CA2159135C (en) * 1994-09-28 2002-11-19 Tomoyasu Tsuda Process for producing octadienes
JP4047071B2 (en) * 2002-05-23 2008-02-13 株式会社クラレ Process for producing unsaturated hydrocarbons
WO2010113531A1 (en) 2009-03-31 2010-10-07 株式会社クラレ Method for producing high-purity terminal olefin compound

Also Published As

Publication number Publication date
EP2851358A4 (en) 2016-01-20
JPWO2013172389A1 (en) 2016-01-12
MY170219A (en) 2019-07-10
CN104302603B (en) 2017-03-01
EP2851358B1 (en) 2018-07-04
KR102031396B1 (en) 2019-10-11
US9637421B2 (en) 2017-05-02
CA2873690C (en) 2020-03-31
US20150105598A1 (en) 2015-04-16
EP2851358A1 (en) 2015-03-25
CA2873690A1 (en) 2013-11-21
CN104302603A (en) 2015-01-21
KR20150020173A (en) 2015-02-25
WO2013172389A1 (en) 2013-11-21
JP5898766B2 (en) 2016-04-06

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