SE7503211L - CURABLE BINDING COMPOSITIONS WITH ADDED PHENOLINE CONTENT AND PROCEDURE FOR MAKING THE SAME. - Google Patents
CURABLE BINDING COMPOSITIONS WITH ADDED PHENOLINE CONTENT AND PROCEDURE FOR MAKING THE SAME.Info
- Publication number
- SE7503211L SE7503211L SE7503211A SE7503211A SE7503211L SE 7503211 L SE7503211 L SE 7503211L SE 7503211 A SE7503211 A SE 7503211A SE 7503211 A SE7503211 A SE 7503211A SE 7503211 L SE7503211 L SE 7503211L
- Authority
- SE
- Sweden
- Prior art keywords
- phenol
- formaldehyde
- reaction
- water
- mole ratio
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 15
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 12
- 238000006243 chemical reaction Methods 0.000 abstract 7
- 239000011230 binding agent Substances 0.000 abstract 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 6
- 239000011575 calcium Substances 0.000 abstract 3
- 239000000920 calcium hydroxide Substances 0.000 abstract 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 abstract 3
- 229920003987 resole Polymers 0.000 abstract 3
- 229910052791 calcium Inorganic materials 0.000 abstract 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 abstract 2
- 229940095643 calcium hydroxide Drugs 0.000 abstract 2
- 235000011116 calcium hydroxide Nutrition 0.000 abstract 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 2
- 239000000292 calcium oxide Substances 0.000 abstract 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007859 condensation product Substances 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 2
- 238000002156 mixing Methods 0.000 abstract 2
- 239000000376 reactant Substances 0.000 abstract 2
- 229920005989 resin Polymers 0.000 abstract 2
- 239000011347 resin Substances 0.000 abstract 2
- 235000020354 squash Nutrition 0.000 abstract 2
- LSYXXLMBRSSBGS-UHFFFAOYSA-N 2,4,6-tris(hydroxymethyl)phenol Chemical class OCC1=CC(CO)=C(O)C(CO)=C1 LSYXXLMBRSSBGS-UHFFFAOYSA-N 0.000 abstract 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract 1
- 229920000877 Melamine resin Polymers 0.000 abstract 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 229920001807 Urea-formaldehyde Polymers 0.000 abstract 1
- 229920003180 amino resin Polymers 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 abstract 1
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 239000007822 coupling agent Substances 0.000 abstract 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 abstract 1
- 239000003995 emulsifying agent Substances 0.000 abstract 1
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract 1
- 239000002480 mineral oil Substances 0.000 abstract 1
- 235000010446 mineral oil Nutrition 0.000 abstract 1
- BVJSUAQZOZWCKN-UHFFFAOYSA-N p-hydroxybenzyl alcohol Chemical compound OCC1=CC=C(O)C=C1 BVJSUAQZOZWCKN-UHFFFAOYSA-N 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 229910000077 silane Inorganic materials 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 abstract 1
- 229920001187 thermosetting polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
- C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
- C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
- C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
This specification discloses ecologically desirable, improved binder compositions suitable for bonding fibers. These binders exhibit low pollutant characteristics and improved properties, due to a combination into the binder of aminoplast resins or non phenolic monomeric materials capable of cocondensing with formaldehyde, together with a substantially phenol-free, low mono methylolphenol, high 2,4,6-trimethylol phenols content, water soluble thermosetting phenyl formaldehyde resole solution. Other binder ingredients such as water, mineral oil, emulsifiers, stabilizers, water soluble dye and silane type coupling agents are also included as needed. The non phenolic components may be selected from the group comprising urea, dicyandiamide, urea formaldehyde resins, melamine formaldehyde resin and the like. The phenolic resole resin is made to conform to the desired composition by mixing together a high mole ratio of formaldehyde with phenol and calcium hydroxide with cooling so that very little reaction takes place. The reaction is then allowed to proceed according to a carefully controlled temperature-time cycle without external heat input until substantially all the phenol has reacted to form condensation products and yet the mixture is still infinitely dilutable with water. Such binder compositions may be applied at solids levels of 1% to 80% and contain much lower phenolic resin component than binders of prior art with similar bonding characteristics. A very satisfactory resole which conforms to this composition is produced by reacting U.S.P. phenol and formaldehyde in a high mole ratio of 2.8 to 4.5 or preferably 3.2 to 4.4 moles formaldehyde per mole of phenol in the presence of from 6 to 10 moles of water per mole of reactants using calcium oxide or calciumhydroxide as an alkaline catalyst, said catalyst being employed at a level of 0.08 to 0.16 moles calcium (Ca) per mole of phenol (3.5% to 7.0% Ca metal on wt. of phenol) and carrying out the condensation under closely programmed conditions. Suitable conditions are for example: 1. Blending phenol and formaldehyde at a temperature of about 85.degree.F. 2. Introducing calcium oxide or hydroxide at such a rate and with cooling of the mixture so that the reactants so not heat above 125.degree.F during the first hour of the reaction. 3. Continuing the reaction without heat input at a temperature which does not exceed 155.degree.F until analyses indicates that all the phenol has reacted to form condensation products, yet the resinous mass has not advanced to a stage at which it is no longer infinitely dilutable with water. This "end point" for the reaction depends on the mole ration of formaldehyde to phenol and is in the range 4.5 wt.% for mole ratio 2.8:1 to 14% for mole ratio 4.5:1, the precise value depending on the reaction temperatures and the operating characteristics of the reaction equipment.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/453,646 US3932334A (en) | 1973-09-24 | 1974-03-21 | Calcia catalyzed resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SE7503211L true SE7503211L (en) | 1975-09-22 |
Family
ID=23801462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7503211A SE7503211L (en) | 1974-03-21 | 1975-03-20 | CURABLE BINDING COMPOSITIONS WITH ADDED PHENOLINE CONTENT AND PROCEDURE FOR MAKING THE SAME. |
Country Status (2)
| Country | Link |
|---|---|
| CA (1) | CA1092741A (en) |
| SE (1) | SE7503211L (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796879A (en) * | 2019-02-19 | 2019-05-24 | 江苏卓尔新建材科技有限公司 | A kind of building materials glue |
| CN113897156A (en) * | 2021-10-13 | 2022-01-07 | 广西至善新材料科技有限公司 | Calcium phenolic resin modified carboxylic styrene butadiene rubber adhesive and preparation method thereof |
-
1975
- 1975-03-20 SE SE7503211A patent/SE7503211L/en unknown
- 1975-03-20 CA CA222,679A patent/CA1092741A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CA1092741A (en) | 1980-12-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4014726A (en) | Production of glass fiber products | |
| SU507250A3 (en) | Press position | |
| US5032431A (en) | Glass fiber insulation binder | |
| US2990307A (en) | Bonded glass fiber structures and compositions employed in same | |
| JPH05178952A (en) | Manufacture of phenolic resin binder | |
| US6028133A (en) | Phenolic resins compatible with wax emulsions | |
| US2748101A (en) | Water-soluble phenol-formaldehyde condensation products | |
| US5296520A (en) | Latent acid curable compositions | |
| SE7503211L (en) | CURABLE BINDING COMPOSITIONS WITH ADDED PHENOLINE CONTENT AND PROCEDURE FOR MAKING THE SAME. | |
| GB1293744A (en) | Fibreglass resin lignin coating | |
| US3072595A (en) | Punk resistant, water-dilutable binder compositions comprising a phenolic resole anda polymeric condensation product of an alkyl ether of dimethylol urea, and mineral fibers bonded therewith | |
| US4647631A (en) | Modified liquid resole phenolic resinous composition for friction materials | |
| US3326843A (en) | Phenol formaldehyde resins and cured friction elements therefrom | |
| US2392686A (en) | Resinous compositions | |
| GB2218995A (en) | Phenolic moulding compositions | |
| US3792020A (en) | High-temperature stable modified aromatic amine-aldehyde molding powders modified with aromatic polycarboxylic compounds | |
| US2683133A (en) | Acetone formaldehyde resin | |
| US3218279A (en) | High temperature resistant borated alkyd resins and their preparation | |
| US2357091A (en) | Dispersion of pine-wood pitch-phenol-formaldehyde resinous reaction products | |
| JPS56152832A (en) | Flexible epoxy resin composition | |
| US2399735A (en) | Phenol-aldehyde resins and methods of making and using the same | |
| US3463747A (en) | Dicyandiamide modified resin binders | |
| US2853460A (en) | Binding agent for extrudable brake lining material | |
| JPS5599981A (en) | Adhesive composition | |
| JPS56112961A (en) | Thermosetting resin composition |