SE542463C2 - Depolymerized lignin in hydrocarbon oil - Google Patents

Depolymerized lignin in hydrocarbon oil

Info

Publication number
SE542463C2
SE542463C2 SE1551569A SE1551569A SE542463C2 SE 542463 C2 SE542463 C2 SE 542463C2 SE 1551569 A SE1551569 A SE 1551569A SE 1551569 A SE1551569 A SE 1551569A SE 542463 C2 SE542463 C2 SE 542463C2
Authority
SE
Sweden
Prior art keywords
weight
lignin
composition according
oil
composition
Prior art date
Application number
SE1551569A
Other languages
English (en)
Other versions
SE1551569A1 (sv
Inventor
Alexander Orebom
Original Assignee
Ren Fuel K2B Ab
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ren Fuel K2B Ab filed Critical Ren Fuel K2B Ab
Priority to SE1551569A priority Critical patent/SE542463C2/sv
Priority to PCT/SE2016/051199 priority patent/WO2017095316A1/en
Publication of SE1551569A1 publication Critical patent/SE1551569A1/sv
Publication of SE542463C2 publication Critical patent/SE542463C2/sv

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/06—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation
    • C10G1/065—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by destructive hydrogenation in the presence of a solvent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H6/00—Macromolecular compounds derived from lignin, e.g. tannins, humic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/04—Phenol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G1/00—Lignin; Lignin derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08H—DERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00—Macromolecular compounds derived from lignocellulosic materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/005—Lignin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00—Compositions of lignin-containing materials
    • C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/40—Thermal non-catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Biochemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Claims (21)

1. Ett förfarande för att framställa en komposition innefattande depolymeriseratlignin och ett lösningsmedel där det depolymeriserade ligninet har en viktmedelmolekylvikt av 250-650g/ mol där förfarandet innefattar: -tillsättning av svartlut eller rödlut till en behållare; -försegling av behållaren; -värmning av svart- eller rödluten till 360°C till 420°C för att depolymeriseraligninet till en molekylvikt av 250-650g/ mol för att bilda depolymeriserat lignin; -isolering av det depolymeriserade ligninet; -återföring av kokkemikalier separerade från kompositionen av depolymeriserat lignin till sodapannan vid pappersmassabruket; och -blandning av det depolymeriserade ligninet med ett lösningsmedel; där ingen katalysator av övergångsmetall tillsätts och där lösningsmedlet är enbärarvätska vald från kolväteolja som är i vätskafas under 80°C och har en kokpunkt av 177-371°C.
2. Förfarandet enligt patentkrav 1 där svartluten är svag eller tunn svartlut.
3. Förfarandet enligt något av patentkrav 1 till 2 där halten fast material i svartluten är 15 vikt% eller lägre, så som1O vikt% eller lägre.
4. Förfarandet enligt något av patentkravl till 3 där isoleringen av det depolymeriserade ligninet är utfört genom att använda vätske/vätske-extraktion.
5. Förfarandet enligt patentkrav 4 där etylacetat, diklormetan eller toluen används som extraktionslösningsmedel.
6. Förfarandet enligt något av föregående patentkrav där trycket i den förseglade behållaren är 5 bar eller högre, eller 10bar eller högre, eller 20bar eller högre, eller 30bar eller högre, eller 40bar eller högre, eller 50bar eller högre, eller 60bär ellerhögre, men företrädesvis inte högre än 200bar, eller 180bar eller lägre, eller 150bareller lägre, eller 120bar eller lägre, eller 100bar eller lägre, eller 80 bar eller lägre, eller 65 bär eller lägre.
7. Förfarandet enligt något av föregående patentkrav där temperaturen är 370°C eller högre.
SE1551569A 2015-12-01 2015-12-01 Depolymerized lignin in hydrocarbon oil SE542463C2 (sv)

Priority Applications (2)

Application Number Priority Date Filing Date Title
SE1551569A SE542463C2 (sv) 2015-12-01 2015-12-01 Depolymerized lignin in hydrocarbon oil
PCT/SE2016/051199 WO2017095316A1 (en) 2015-12-01 2016-12-01 Depolymerized lignin in hydrocarbon oil

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SE1551569A SE542463C2 (sv) 2015-12-01 2015-12-01 Depolymerized lignin in hydrocarbon oil

Publications (2)

Publication Number Publication Date
SE1551569A1 SE1551569A1 (sv) 2017-06-02
SE542463C2 true SE542463C2 (sv) 2020-05-12

Family

ID=57544493

Family Applications (1)

Application Number Title Priority Date Filing Date
SE1551569A SE542463C2 (sv) 2015-12-01 2015-12-01 Depolymerized lignin in hydrocarbon oil

Country Status (2)

Country Link
SE (1) SE542463C2 (sv)
WO (1) WO2017095316A1 (sv)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11987759B2 (en) 2021-12-23 2024-05-21 Upm-Kymmene Corporation Solvolysis process

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20200141057A1 (en) * 2017-06-05 2020-05-07 Suncarbon Ab Catalytic conversion of lignin
CA3085199A1 (en) * 2017-12-22 2019-06-27 Green Innovation Gmbh Use of a lignin fraction as a human and animal food supplement ingredient
FI20185919A1 (sv) 2018-10-31 2020-05-01 Upm Kymmene Corp Biodieselkomposition
EP3741828A1 (en) 2019-05-23 2020-11-25 Vertoro B.V. Fluid catalytic cracking process of crude lignin oil (clo)
EP3990523A1 (en) 2019-06-28 2022-05-04 Kat2Biz AB Processes for obtaining substances from bark and a composition containing bark for use in the processes
EP3932929A1 (en) * 2020-06-29 2022-01-05 Sca Forest Products AB Lignin oil from young plants
SE2230429A1 (en) * 2022-12-19 2024-06-20 Votion Biorefineries Ab A method for the production of lignin oil

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4192757A (en) * 1978-04-21 1980-03-11 Exxon Research & Engineering Company Alkyl phenol solutions of organo molybdenum complexes as friction reducing antiwear additives
US6172272B1 (en) * 1998-08-21 2001-01-09 The University Of Utah Process for conversion of lignin to reformulated, partially oxygenated gasoline
US8013195B2 (en) 2007-06-15 2011-09-06 Uop Llc Enhancing conversion of lignocellulosic biomass
WO2011003029A2 (en) 2009-07-01 2011-01-06 The Regents Of The University Of California Catalytic disproportionation and catalytic reduction of carbon-carbon and carbon-oxygen bonds of lignin and other organic substrates
US8772557B2 (en) 2011-07-26 2014-07-08 Uop Llc Aromatic hydrocarbons from depolymerization and deoxygenation of lignin
US20130232852A1 (en) * 2012-03-09 2013-09-12 Thesis Chemistry, Llc Method for tiered production of biobased chemicals and biofuels from lignin
RU2661893C2 (ru) 2013-01-25 2018-07-23 Рен Фьюэл К2Б Аб Композиции материалов биомассы для переработки
CA2913852A1 (en) 2013-05-29 2014-12-04 Kiram Ab A method for the treatment of spent pulping liquor for the removal and production of a lignin containing product
US20160312029A1 (en) 2013-12-16 2016-10-27 Ren Fuel K2B Ab Composition Comprising Esters Of Lignin And Organic Solvent
US9181166B1 (en) * 2014-09-22 2015-11-10 Zuolin Zhu Catalytic method for quantitative hydrolytic depolymerization of lignocelluloses in one-pot

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11987759B2 (en) 2021-12-23 2024-05-21 Upm-Kymmene Corporation Solvolysis process

Also Published As

Publication number Publication date
WO2017095316A1 (en) 2017-06-08
SE1551569A1 (sv) 2017-06-02

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