SE538149C2 - Process for Purification and Removal of Pollutants and Phosphorus Compounds from Polluted Water - Google Patents

Process for Purification and Removal of Pollutants and Phosphorus Compounds from Polluted Water Download PDF

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Publication number
SE538149C2
SE538149C2 SE1451133A SE1451133A SE538149C2 SE 538149 C2 SE538149 C2 SE 538149C2 SE 1451133 A SE1451133 A SE 1451133A SE 1451133 A SE1451133 A SE 1451133A SE 538149 C2 SE538149 C2 SE 538149C2
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liquid
cake
ash
water
separation
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SE1451133A
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Swedish (sv)
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SE1451133A1 (en
Inventor
Bengt-Åke Karlsson
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Bengt Åke Karlsson Med Tb Lager F
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Application filed by Bengt Åke Karlsson Med Tb Lager F filed Critical Bengt Åke Karlsson Med Tb Lager F
Priority to SE1451133A priority Critical patent/SE538149C2/en
Priority to PCT/SE2015/050972 priority patent/WO2016048218A1/en
Priority to EP15843543.8A priority patent/EP3197835A4/en
Publication of SE1451133A1 publication Critical patent/SE1451133A1/en
Publication of SE538149C2 publication Critical patent/SE538149C2/en

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/465Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electroflotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/68Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds

Abstract

Sammandrag Uppfinningen avser ett forfarande for rening av fororenat vatten (2) samt avskiljning av forore5 nande amnen och fosforforeningar (1) fran fororenat vatten (2). Enligt forfarandet later man blanda tra- aska eller annan aska (3) i det fOrorenade vattnet (2) samt later igangsatta elektrolys i blandningen far Astad- kommande av separation och avskiljning av fororeningar och fosforforeningar fran den fororenade v&tskan (2). Summary The invention relates to a process for purifying polluted water (2) and separating polluting substances and phosphorus compounds (1) from polluted water (2). According to the process, tracheal ash or other ash (3) is allowed to mix in the contaminated water (2) and electrolysis initiated in the mixture is allowed to effect the separation and separation of contaminants and phosphorus compounds from the contaminated liquid (2).

Description

Forfarande fOr rening av och avskiljning av fororenande amnen och fosforforeningar fran fororenat vatten. Process for the purification and separation of contaminants and phosphorus compounds from contaminated water.

Foreliggande uppf inning avser ett forfa5 rande for rening av och avskiljning av fororenande amnen och fosforforeningar fran fororenat vatten. The present invention relates to a process for purifying and separating contaminants and phosphorus compounds from contaminated water.

Huvudandamalet med den foreliggande uppfinningen är att finna ett enkelt, miljovanligt och effektivt forfarande for att astadkomma rening av och avskilj- fling av fororenande amnen och fosforforeningar frail farorenat vatten sasom t.ex. fran enskilda avloppsreningsverk eller i samband med andra liknande reningsanlaggningar och utan att behava nyttja kemikalier eller andra onodigt och kostnadskravande medel harf8r, med risk fOr miljoforsto- ring. The main object of the present invention is to find a simple, environmentally friendly and efficient process for effecting the purification and separation of polluting substances and phosphorus compounds from hazardous contaminated water such as e.g. from individual sewage treatment plants or in connection with other similar treatment plants and without the use of chemicals or other unnecessary and costly means, with the risk of environmental pollution.

Sagda andamal mojliggares genom ett farfarande av ovan angivet slag, som i huvudsak kannetecknas darav, att man later blanda i traaska eller annan aska i det fororenade vattnet samt igangsatter elektrolys i blandningen varigenom separation och avskiljning sker. Said andamal is made possible by a procedure of the above kind, which is mainly characterized by mixing in ashes or other ash in the polluted water and initiating electrolysis in the mixture whereby separation and separation takes place.

Uppfinningen beskrives nedan med hanvisning till de bifogade ritningarna, pa vilka Fig 1-6 schematiskt visar forloppet vid rening av fororenat vatten i olika steg och frekvenser i 25 en behallare, varvid Fig 1 visar ett ihallningsskede av aska i den vatska som onskas renas, Fig 2 visar forloppet under elektrolysbehandling av vatskan, Fig 3 visar bildandet av en kaka av fororeningar pa ytan av vatskan, Fig 4 visar forlopp av fanning av sagda kaka mot behallarens batten, 1 Fig 5 visar renat vatten i behAllaren, och Fig 6 visar uttag av renat vatten respektive pA botten av behAllaren liggande fororening innan kakan med fororeningar sedimenterat, Fig 7-12 visar anlAggning fOr genomforande av f8rfarandet samt i densamma ingAende olika delar och dess anvAndning, varvid Fig 7 visar i perspektiv exempel pA en anlAggning med plastbehAllare, Fig 8 visar ytterligare exempel pA anlAgg- ning i verksamt begynnelselAge, och med behAllaren bildad av glas, Fig 9 visar anlAggningen med ingAende stramkAlla, Fig 10-11 visar anlAggningen i verksamt lAge med visad ytbelagen kaka av fOroreningen, och Fig 12 visar anlAggningen i slutrenande lAge med visade bottenavlagringar och avlAgsnandet av ytkakan. The invention is described below with reference to the accompanying drawings, in which Figs. 1-6 schematically show the process of purifying contaminated water in different steps and frequencies in a container, Fig. 1 showing a retention stage of ash in the liquid to be purified, Figs. Fig. 2 shows the process during electrolysis treatment of the liquid, Fig. 3 shows the formation of a cake of impurities on the surface of the liquid, Fig. 4 shows the process of forming said cake against the bottom of the container, Fig. 5 shows purified water in the container, and Fig. 6 shows removal of purified water and contamination lying on the bottom of the container before the cake with contaminants has settled, Fig. 7-12 shows a plant for carrying out the process and in the same manner different parts and its use, Fig. 7 showing in perspective examples of a plant with a plastic container, Fig. 8 shows further examples of plant in effective initial position, and with the container formed of glass, Fig. 9 shows the plant with incoming stock. 1a, Fig. 10-11 shows the plant in the active position with the surface coated cake of the contaminant shown, and Fig. 12 shows the plant in the final cleaning layer with the bottom deposits shown and the removal of the surface cake.

Genom ett flertal forsok har det visat sig att aska, namligen vanlig vedaska frAn forbrAnning av gran, tall och lovtrAd av olika slag, och som enkelt erhAlles frAn brasor i t.ex. spisar, utgor naturens egen katalysator for omvandling och/eller Andring av olika amnens egenskaper pA biokemisk vAg. Med ytterligare hjalp av elektrolys, liknande effekt som erhAlles frAn Askan i naturen i det fria, kan man nu med hjalp av denna sagda katalysator Astadkomma en separation av oonskade ingredienser i t.ex. fOrorenat vatten. Forsaken visar klart att askan ar en forutsAttning for att kunna genomfOra fOrfarandet med onskat resultat, d.v.s. rening av den aktuella vAtskan. Utan aska sker ingen separation av ingAende delar av vAtskan under en rimlig tidsperiod utan i stAllet sker 2 det pa naturens eget satt over en Fang tidsperiod genom klarning och sedimentering. Through several experiments, it has been shown that ash, namely ordinary wood ash from the combustion of spruce, pine and firewood of various kinds, and which is easily obtained from fires in e.g. stoves, constitute nature's own catalyst for the transformation and / or change of the properties of various substances on a biochemical path. With the further help of electrolysis, a similar effect obtained from Ash in nature in the open air, it is now possible with the aid of this said catalyst to achieve a separation of undesirable ingredients in e.g. Contaminated water. The experiment clearly shows that the ash is a prerequisite for being able to carry out the procedure with the desired result, i.e. purification of the liquid in question. Without ash, no separation of constituent parts of the liquid takes place over a reasonable period of time, but instead it takes place in nature's own way over a period of time through clarification and sedimentation.

Aven annan slags aska an traaska kan nyttjas, exempelvis aska fran brunkol och/eller stenkol. Other types of ash other than ash can be used, for example ash from lignite and / or hard coal.

Genom motstandsmatning har aven konstate- rats att rent vatten (drickbart) har ett betydligt hogre motstand an fororenat vatten pa grund av olika salters och faroreningars inverkan. Det har ¥ visat sig att motstandet andras pa varierande satt genom innehallets paver- kan. Gasbubblor vid katoden och som tyder pa syrgas, har kunnat iakttagas. Vid anoden har kunnat konstateras bildande av vita tradar (skagg) och ett finmaskigt nat vilket kan tyda pa bildandet av aminosyror, proteiner eller liknande. Through resistance feeding, it has also been found that clean water (drinkable) has a significantly higher resistance to polluted water due to the effect of various salts and hazardous pollutants. It has been shown that the resistance of others in various ways through the influence of the content. Gas bubbles at the cathode and indicating oxygen have been observed. At the anode it has been possible to ascertain the formation of white threads (skag) and a fine-meshed net, which may indicate the formation of amino acids, proteins or the like.

Forsok har aven gjorts med elektroder av olika material i viss utstrackning dar elektroder av jamn visat sig vara bast. Vid forsok med elektroder av typen massingslaglod kunde konstateras att gran argliknande del bildades vid anoden som en del i den flytande kakan. vid forsok med avloppsvatten fran en tre- kammarbrunns 2:a kammare med elektroder av jam n i elektrolys kunde direkt konstateras att vatskan svartnade. Troligen bildades jarnoxid i nagon reaktion i samband med elektrolysen. Vatskan klarnade efter viss tid samt att en flytande kaka hade bildats av olika ingredienser i vatskan. Denna flytande kaka sedimenterar sedan under en langre tidsperiod i olika steg. Mellan den flytande kakan samt lite rester pa batten klarnade vatskan ganska snart. Experiments have also been made with electrodes of different materials to a certain extent where electrodes of even have been shown to be solid. In experiments with electrodes of the massing solder type, it could be found that spruce-like part was formed at the anode as a part of the liquid cake. In experiments with wastewater from the 2nd chamber of a three-chamber well with electrodes of iron n in electrolysis, it could be directly established that the liquid turned black. Iron oxide was probably formed in some reaction in connection with the electrolysis. The liquid cleared after a certain time and that a liquid cake had been formed from various ingredients in the liquid. This liquid cake then settles over a long period of time in different steps. Between the liquid cake and some leftovers on the boat, the liquid cleared up pretty quickly.

For forsaken har anvants 12 volt likstram samt vanlig vedaska fran mestadels gran och lavtrad som tillsatts samtidigt med kopplande av stremkallan. Behallare far forsaken har varit sterre glasburkar far att mini- 3 mera ovidkommande amnen samt far att kunna se och iakttaga eventuella forandringar. For the trial, a 12 volt direct current and ordinary wood ash from mostly spruce and lichen have been used, which has been added at the same time as connecting the strip cold. Container father forsaken has been larger glass jars father to minimize 3 irrelevant subjects and father to be able to see and observe any changes.

UtifrAn observation i forsok enligt ovanstaende, med forsok till beskrivning, har senare utveck- lats en biokemisk reaktor grundad pa observationer av repeterbara forsok avsedd f8r undersokning av vatskan mellan den flytande kakan och det sedimenterade materialet pA botten. Based on observations in experiments as above, with experiments for description, a biochemical reactor has later been developed based on observations of repeatable experiments intended for examining the liquid between the liquid cake and the sedimented material at the bottom.

Vid en forsta korning i denna reaktor anvAndes dricksvatten, dels for rengoring, dels far prov. Vatskan svartnade som ovan samt klarnade ganska snart. Den flytande kakan var mycket obetydlig (drickbart vatten). Den avtappade vatskan i behAllaren blev kristallklar samt att ett visst brunt sediment har bildats. Efter senare forsok kanske man kan frAga sig om detta var den i vattnet losta fosforn samt eventuella rester av jam. During a first run in this reactor, drinking water was used, partly for cleaning and partly for testing. The liquid turned black as above and cleared quite soon. The liquid cake was very insignificant (drinkable water). The drained liquid in the container became crystal clear and a certain brown sediment had formed. After later attempts, one may wonder if this was the phosphorus released in the water and any remnants of jam.

NAsta forsok innebar avloppsvatten frAn andra kammaren i en avloppsbrunn. Vatskan svartnade pa samma satt som tidigare forsok med aska. Under detta for- sok anvandes mindre mAngd aska varvid processen forlangdes i tid raknat. PA morgonen hade vatskan klarnat och kunde tappas upp i en starre glasburk for iakttagelser efter processen. Etter nAgra timmar kunde iakttagas en pAgAende process, med flockning i vatskan. FArgen bOrjade Andras till grant. Efter nagra timmar var vatskan morkgron. Tre dagar efter upptappningen i glasburken hade vatskan klarnat helt samt att ett brungult sediment hade bildats. Tiden maste narmare kontrolleras mellan upptappning och fArdig fallning, eftersom overraskningen stallde till det. The next experiment involved wastewater from the second chamber in a sewage well. The liquid turned black in the same way as previous experiments with ash. During this experiment, a smaller amount of ash was used, whereby the process was required in time. By morning, the liquid had cleared and could be poured into a rigid glass jar for observations after the process. After a few hours, an ongoing process could be observed, with flocculation in the liquid. The color began for others. After a few hours, the water was dark green. Three days after bottling in the glass jar, the liquid had completely cleared and a brownish-yellow sediment had formed. The time must be more closely controlled between bottling and finished falling, because the surprise came about.

Vid senare litteraturstudier tyder fenomenet pa en omvandling av fosfor i vatskan, fosforylering i en milj8 med jarnoxid vilket skulle ge den grana fArgen. Med ovanstAende observationer som grund, menar jag att med hjalp 4 av aska som katalysator i elektrolytisk process kunna avlagsna f6rorenande amnen samt fanning av fosfor och fosforforeningar fran min biokemiska reaktor. Forsaken har skapat majligheten att pavisa reningsverkens paverkan i miljon (recipient) genom studier fran utgaende (renat avloppsvatten) samt dess paverkan av det pavaxta materialet vid anoden som visat sig vara mycket kansligt for exempelvis jarnsulfat. Detta resulterade omgaende i ett svartnande och hopskrumpet nat liknande bottendOd som man kan iakttaga i havet utanfOr kommunala reningsverk. In later literature studies, the phenomenon indicates a conversion of phosphorus in the liquid, phosphorylation in an environment 8 with iron oxide, which would give the green color. Based on the above observations, I mean that with the help of ash as a catalyst in the electrolytic process I can remove pollutants and the formation of phosphorus and phosphorus compounds from my biochemical reactor. The research has created the opportunity to demonstrate the impact of the treatment plants in millions (recipient) through studies from outgoing (purified wastewater) and its impact on the grown material at the anode which proved to be very sensitive to, for example, ferrous sulphate. This immediately resulted in a blackening and shrinking night similar to the bottom that can be observed in the sea outside municipal treatment plants.

Majligheter finnes att genom skumning avlagsna den flytande kakan med fOroreningar frail vatska. Ytterligare mOjligheter skapas att kunna ta tram olika fraktioner fran den flytande kakan genom att en biokemisk reaktion pagar med en fanning av olika lager under en langre Lid, med barjan underst pa kakan. Den tredje majligheten är enligt ovan beskrivning att ta vatskan direkt efter klarning fran den svarta fargen samt lata den sjalvgaende processen i denna vatska utfora omvandling samt fanning av fosfor och fosforfOreningar. Det fallda materialet kan sedan avlagsnas fran processen. Bottensediment fran oaktiva delar i askan mm kan mekaniskt avlagsnas frail processen. There are possibilities to remove the liquid cake by foaming with contaminants frail liquid. Additional possibilities are created to be able to take different fractions from the liquid cake by a biochemical reaction with a formation of different layers during a longer Lid, with the bar at the bottom of the cake. The third possibility is, as described above, to take the liquid immediately after clarification from the black color and to let the obvious process in this liquid carry out conversion and formation of phosphorus and phosphorus compounds. The fallen material can then be removed from the process. Bottom sediment from inactive parts of the ash etc. can be mechanically removed from the process.

Den svarta fargen fran bOrjan av processen samt den klarnande delen kan utnyttjas fOr reglering av processens genomforande. Den klara vatskans farg efter reaktorn samt den grOna fargen vid processen, klarnande efter fosforomvandlingen och f&llningen kan utnyttjas vid regleringen av processen. The black color from the beginning of the process and the clarifying part can be used to regulate the execution of the process. The color of the clear liquid after the reactor and the green color of the process, clarifying after the phosphorus conversion and precipitation can be used in the regulation of the process.

Enligt uppfinningen innefattar ett fOrfa- rande fOr rening och avskiljning av fOrorenande amnen 1 fran fOrorenat vatten 2 att man later blanda i traaska eller annan aska 3 i det fororenade vattnet 2 samt later igangsatta elektrolysbehandling av den sagda blandningen 4. Darigenom sker separation och biokemiskt avskiljning av icke Onskvarda fororeningar. Darvid nyttjar man traaska eller annan aska 3 erhallen fran en spis eller nagon annan lamplig eldstad eller fOrbranningskalla. According to the invention, a process for purifying and separating the polluting substances 1 from polluted water 2 comprises mixing in ashes or other ash 3 in the polluted water 2 and initiating electrolysis treatment of the said mixture 4. Thereby separation and biochemical separation takes place. of non-adverse contaminants. In doing so, they use traaska or other ash 3 obtained from a stove or some other suitable fireplace or incinerator.

For elektrolysbehandlingen nyttjar man elektroder 5, 6 av jam, varigenom blandningen 4 forst svartnar i det nyttjade karl 7, for att efter viss tid klarna. Darvid har en flytande kaka 8 bildats ovan vattnet 2 av innehallande fororeningar och fosforforeningar 1 i det fororenade vattnet 2. Efter viss tid later man avtappa renat vatten 9 fran karlet 7 efter det att den sagda kakan 8 med fororeningar 1 dari sedimenterat och att rester 11 darav bildats pa botten 10 av det karl 7 som nyttjas vid det sagda forfarandet. Alternativt kan man genom ej visad men allmant kand skumning lata avlagsna kakan 8 innan sedimentering av densamma sker for senare behandling. Detta kan ske i ett enda skede eller successivt allteftersom kakan 8 hailer pa att bildas alternativt kan filtre- ring utnyttjas nar kakan sedimenterat/sedimenterar fOr erhallande av olika delar i innehallet. For the electrolysis treatment, electrodes 5, 6 of jam are used, whereby the mixture 4 first turns black in the used vessel 7, in order to clear after a certain time. Thereby a liquid cake 8 has been formed above the water 2 of contaminants and phosphorus compounds 1 in the contaminated water 2. After a certain time, purified water 9 is drained from the vessel 7 after the said cake 8 with contaminants 1 has settled therein and residues 11 of which formed on the bottom 10 of the man 7 used in the said process. Alternatively, by not showing but generally known foaming, the cake 8 can be allowed to be deposited before sedimentation of the same takes place for later treatment. This can take place in a single stage or successively as the cake 8 tends to form, alternatively filtration can be used when the cake has settled / sediments to obtain different parts of the content.

Lampligt ar att lata rena avloppsvatten som mottages efter grovavskiljning i sa kallade trekammar- brunnar, i reningsverk eller i andra liknande anlagg- ningar. Darvid tager man avloppsvatten fran en sagda trekammarbrunns tredje kammare fOr rening. Efter viss tid fran iblandning av traaska eller annan aska 3 och elektrolys av blandningen 4 klarnar avloppsvattnet efter bildande av en flytande kaka 8 av fororeningar och fosfor- foreningar 1 och sedimentering av densamma eller Ater-faring till tidigare steg, liknande aktiv slamprocess for senare slamsugning sa att avtappning av renat avloppsvatten 9 sker skilt fran kvarvarande rester 11 av forore- 6 ningar pa botten 10 av brunnen eller annat nyttjat karl i vilket sagda rening Astadkommes. Eftersom vatskan 2 i karlet 7 andrar farg kan man lata styra f6rfarandet efter de farger som bildas under forfarandets gang. It is appropriate to allow clean wastewater that is received after coarse separation in so-called three-chamber wells, in treatment plants or in other similar facilities. In this case, wastewater is taken from the third chamber of a said three-chamber well for treatment. After some time from mixing of ash or other ash 3 and electrolysis of the mixture 4, the wastewater clears after formation of a liquid cake 8 of impurities and phosphorus compounds 1 and sedimentation thereof or re-experience to earlier steps, similar active sludge process for later sludge suction so that the treatment of treated wastewater 9 takes place separately from the remaining residues 11 of contaminants 6 at the bottom 10 of the well or other used man in which said treatment is achieved. Since the liquid 2 in the vessel 7 changes color, the process can be controlled according to the colors formed during the process.

Avlagsning av den flytande kakan 8 pa vatskan 2 i karlet 7 sker genom foljande atgarder: att man later skumma av den flytande kakan 8, eller att man later ta fram olika fraktioner fran den flytande kakan 8 genom att en biokemisk reaktion pagar med en fallning av olika lager av fororeningar och fosforfareningar under viss tid med borjan underst pa den flytande kakan, eller att man later ta ut vatskan 2 direkt efter klar- ning fran markfargad vatska och sedan later en sjalvgaende process i sagda vatska 2 utfora omvandling samt utfallning av fosfor och fosforforeningar varefter det utfallda materialet avlagsnas och bottensediment 11 fran den joke aktiva delen av askan 3 och ovrigt innehAll mekaniskt avlagsnas fran karlet 7. Deposition of the liquid cake 8 on the liquid 2 in the vessel 7 takes place by the following procedures: that the liquid cake 8 is allowed to foam, or that different fractions are produced from the liquid cake 8 by a biochemical reaction with a precipitation of different layers of impurities and phosphorus compounds for a certain time with the beginning at the bottom of the liquid cake, or that the liquid 2 is allowed to be taken out immediately after clarification from soil-colored liquid and then an independent process in said liquid 2 is carried out to convert and precipitate phosphorus and phosphorus compounds after which the precipitated material is deposited and bottom sediment 11 from the joke active part of the ash 3 and other contents are mechanically deposited from the vessel 7.

En anlaggning 20 som lampar sig speciellt fOr genomforande av ett forfarande enligt uppfinningen far att astadkomma rening av vatska 2 och avskiljning av fororenande amnen 1 fran ferorenat vatten 2 innefattar foljande: Ett }car]. 7 bildat av foretradesvis glas eller annat kemiskt neutralt material. Elektroder 5, 6 for elektrolysbehandling av det foreorenade vattnet 2 som ar mottagbart i sagda karl 7 samt traaska eller annan aska 3, foretradesvis i pulverform bildar separationsmedel for fororeningar 1 i fororenat vatten 2 under begransad Lids-period. 7 Sagda elektroder 5, 6 till elektrolysbehandlingen bestar av jam. Vedaskan 3 am frail barr- eller lovtr&d. Nyttjas annan aska 3 kan denna vara t.ex. frAn brunkol och/eller stenkol. Elen till elektrolysbehand- lingen am foretradesvis likstrom. Vid forsok erhallen fran foretradesvis 12 volt, exempelvis ett bilbatteri 21. Karlet 7 till anlaggningen 20 uppvisar foretradesvis Atminstone en del som ãr genomsynlig utifran. Anlaggningen 20 kan innefatta medel 22 for avtappning av renad vatska 9 frail sagda karl 7, innan kakan 8 barjat sedimentera biokemiskt, exempelvis am en kran anordnad vid karlets nedre parti men pa en niva 23 ovanfor ett omrade 24 pa botten 10 i karlet 7 dar avlagringar av fororeningar 1 bildas. A plant 20 which is particularly suitable for carrying out a process according to the invention is allowed to effect purification of liquid 2 and separation of polluting substances 1 from polluted water 2 comprises the following: A} car]. 7 formed of preferably glass or other chemically neutral material. Electrodes 5, 6 for electrolysis treatment of the contaminated water 2 which are receptive in said vessel 7 as well as traaska or other ash 3, preferably in powder form form separation means for contaminants 1 in contaminated water 2 during a limited Lids period. Said electrodes 5, 6 for the electrolysis treatment consist of jam. Vedaskan 3 am frail coniferous or lovtr & d. If other ash 3 is used, this can be e.g. from lignite and / or hard coal. The electricity for the electrolysis treatment is preferably direct current. In experiments, the container is preferably from 12 volts, for example a car battery 21. The vessel 7 to the plant 20 preferably has at least a part which is transparent from the outside. The plant 20 may comprise means 22 for draining purified liquid 9 from said man 7, before the cake 8 has begun to settle biochemically, for example in a tap arranged at the lower part of the man but at a level 23 above an area 24 on the bottom 10 of the man 7 where deposits of pollutants 1 is formed.

Funktion och beskaffenhet av uppfin- ningen torde ha forstAtts klart av det ovan angivna och med kannedom aven am det pa ritningarna visade men uppfinningen am naturligtvis inte begransad till de ovan beskrivna och pa de bifogade ritningarna visade utforandena. Modifieringar am mojliga, sarskilt nar det galler de olika delarnas beskaffenhet, eller genom anvandande av likvardig teknik, utan att man frangar skyddsomradet for uppfinningen, sasom den definieras i patentkraven. 8 The function and nature of the invention should have been clearly understood from the above and with knowledge also from what is shown in the drawings, but the invention is of course not limited to the embodiments described above and shown in the accompanying drawings. Modifications are possible, especially when it comes to the nature of the various parts, or by the use of equivalent techniques, without departing from the scope of the invention as defined in the claims. 8

Claims (1)

Patentkrav 1. Farfarande far rening av och avskiljning av fororenande amnen och fosforforeningar (1) frail farore- nat vatten (2), kannetecknat darav, att man later blanda i traaska eller annan aska (3) i det farorenade vattnet (2) samt igangsatter elektrolys i blandningen (4) varigenom separation och avskiljning sker. 10 2.Parfarande enligt patentkrav 1, kanneteck- nat darav, att man nyttjar traaska eller annan aska (3) frail spis eller annan farbranningskalla. 3. Forfarande enligt nagot av patentkraven 1-2, kannetecknat darav, att man nyttjar elektroder (5, 6) av jam n vid elektrolysbehandlingen varigenom blandningen (4) forst svartnar i det 'car' (7) man nyttjar vid genomfarandet av farfarandet for att efter viss tid klarna och att en flytande kaka (8) bildas av innehallande forore- ningar och fosforforeningar (1) i det fororenade vattnet (2). 4. Farfarande enligt patentkrav 3, kanneteck- nat darav, att man efter viss tid later avtappa renat vatten (9) efter det att den sagda kakan (8) med faroreningar och fosforfareningar (1) sedimenterat och rester (11) bildats pa botten (10) av det karl (7) som nyttjas vid sagda forfarande eller att man genom skumning innan sedimentering sker later avlagsna kakan (8) med forore- ningar i ett skede eller successivt allteftersom den bildas eller genom filtrering nar kakan (8) sedimenterat/sedimenterar f6r erhallande av olika delar i innehallet. 9 5. Forfarande enligt nagot av ovan angivna patentkrav, kannetecknat darav, att man later taga avloppsvatten fran en trekammarbrunns tredje kammare fOr reningsverk efter 5 grovavskiljning och sandfangrening, och att efter viss tid fran iblandning av traaska eller annan aska (3) och elektrolys av blandningen (4) klarnar avloppsvattnet efter bildande av en flytande kaka (8) av fororeningar (1) och sedimentering av densamma, sa att avtappning av renat 10 avloppsvatten (9) sker skilt fran kvarvarande rester av fororeningar pa botten (10) av nyttjat karl (7) i vilket sagda rening Astadkommes. 6. Forfarande enligt patentkrav 5, kanneteck- nat darav, att man later styra forfarandet efter de farger som bildas under forfarandets gang pa vatskan (2) i karlet (7). 7. Forfarande enligt nagot av patentkraven 5-6, kannetecknat darav, att man avlagsnar den flytande kakan (8) med fororeningar fran vatskan (2) genom: 1. skumning av den flytande kakan (8), 2. att lata La fram olika fraktioner fran den flytande kakan (8) genom att en biokemisk reaktion pagar med en fanning av olika lager av fororeningar under viss tid med borjan underst pa den flytande kakan (8), eller 3. att lata ta ut vatskan (2) direkt efter klarning frail morkfargad vatska och lata en sjalvgaende process i sagda vatska (2) utfora omvandling samt utfallning av fosfor och fosforforeningar varefter det utfallda materialet avlagsnas, och att sedan bottensediment (11) fran den icke aktiva delen av askan (3) och ovrigt innehall mekaniskt avlagsnas fran karlet (7). 10 1/ --\ \ \ \ 1 \ \ ■--- \ \i -------------/:( 0, (0!,‘ (\‘\; '/--)\ .---- )) () ._ ) C\I «11, /// ( - ( (7; ri/ , / ., 0 LLClaim 1. Process for the purification and separation of polluting substances and phosphorus compounds (1) from hazardous water (2), characterized in that mixing is carried out in traaska or other ash (3) in the hazardous water (2) and initiated electrolysis in the mixture (4) whereby separation and separation take place. 2. A method according to claim 1, characterized in that using traaska or other ash (3) frail stove or other incinerator. 3. A method according to any one of claims 1-2, characterized in that electrodes (5, 6) of iron are used in the electrolysis treatment whereby the mixture (4) first turns black in the 'car' (7) used in carrying out the process for that after a certain time clear and that a liquid cake (8) is formed by containing contaminants and phosphorus compounds (1) in the contaminated water (2). A method according to claim 3, characterized in that after a certain time purified water (9) is allowed to be drained after the said cake (8) with hazardous impurities and phosphorus impurities (1) has settled and residues (11) have formed on the bottom ( 10) of the vessel (7) used in said process or that by foaming before sedimentation the deposited cake (8) is left with contaminants in a stage or successively as it is formed or by filtration when the cake (8) has sedimented / sedimented for obtaining different parts of the content. A method according to any one of the preceding claims, characterized in that wastewater is allowed to be taken from a third chamber of a three-chamber well for treatment plants after coarse separation and sand trap treatment, and that after a certain time from mixing of ash or other ash (3) and electrolysis of the mixture (4) clarifies the waste water after formation of a liquid cake (8) of impurities (1) and sedimentation thereof, so that drainage of purified waste water (9) takes place separately from remaining residues of impurities on the bottom (10) of utilized vessel (7) in which said purification is accomplished. A method according to claim 5, characterized in that the process is controlled according to the colors formed during the process on the liquid (2) in the vessel (7). A method according to any one of claims 5-6, characterized in that the liquid cake (8) is removed with contaminants from the liquid (2) by: 1. foaming the liquid cake (8), 2. letting different fractions from the liquid cake (8) by a biochemical reaction paging with a formation of different layers of impurities for a certain time with the beginning at the bottom of the liquid cake (8), or 3. having the liquid (2) removed immediately after clarification frail dark-colored liquid and allow an independent process in said liquid (2) to carry out conversion and precipitation of phosphorus and phosphorus compounds after which the precipitated material is removed, and then bottom sediment (11) from the inactive part of the ash (3) and other contents is mechanically removed fran karlet (7). 10 1 / - \ \ \ \ 1 \ \ ■ --- \ \ i ------------- / :( 0, (0 !, '(\' \; '/ - -) \ .----)) () ._) C \ I «11, /// (- ((7; ri /, /., 0 LL 1. 13 9 .0Id 1R \ \ 6/ ZZ 9W 0 Z6 9 'Old N I. Z 3/ N. CO ......... . 7.. . ............ • ............. ............ ............ ............ • ........... . ............. .......... ......... " .1. 13 9 .0Id 1R \ \ 6 / ZZ 9W 0 Z6 9 'Old N I. Z 3 / N. CO .......... 7 ... ............ • ............. ............ ............ ............ • ............ ............. .......... ......... ".
SE1451133A 2014-09-25 2014-09-25 Process for Purification and Removal of Pollutants and Phosphorus Compounds from Polluted Water SE538149C2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
SE1451133A SE538149C2 (en) 2014-09-25 2014-09-25 Process for Purification and Removal of Pollutants and Phosphorus Compounds from Polluted Water
PCT/SE2015/050972 WO2016048218A1 (en) 2014-09-25 2015-09-17 Process for waste water clarification and separation of contaminants and phosphorous compounds from the waste water
EP15843543.8A EP3197835A4 (en) 2014-09-25 2015-09-17 Process for waste water clarification and separation of contaminants and phosphorous compounds from the waste water

Applications Claiming Priority (1)

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SE1451133A SE538149C2 (en) 2014-09-25 2014-09-25 Process for Purification and Removal of Pollutants and Phosphorus Compounds from Polluted Water

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4928119B1 (en) * 1967-08-28 1974-07-23
WO2005096713A2 (en) * 2004-04-07 2005-10-20 Moi University An electro-coagulation method of color removal in wastewater or water with low power consumption
JP4907950B2 (en) * 2005-10-31 2012-04-04 住友大阪セメント株式会社 Method and apparatus for removing metal from waste water
JP2010005491A (en) * 2008-06-24 2010-01-14 Tokyo Metropolis Electrolytic phosphorus recovery device and sewage treatment system using it
CA2758872A1 (en) * 2011-04-07 2012-10-07 Dpra Canada Incorporated Electrokinetic process and apparatus for consolidation of oil sands tailings

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SE1451133A1 (en) 2016-03-22
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EP3197835A4 (en) 2018-03-28

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