SE448142B - EXTRA TREATMENT COMPOSITION INCLUDING A TITANAS CHORBIN ACYLATE AND AS STABILIZING ADDITION OR ANY SUBSTANCES SELECTED BY BENZOIC ACID OR SALTS OF IT AND SALICYLIC ACID AND SALTS OF THEREOF - Google Patents
EXTRA TREATMENT COMPOSITION INCLUDING A TITANAS CHORBIN ACYLATE AND AS STABILIZING ADDITION OR ANY SUBSTANCES SELECTED BY BENZOIC ACID OR SALTS OF IT AND SALICYLIC ACID AND SALTS OF THEREOFInfo
- Publication number
- SE448142B SE448142B SE8107796A SE8107796A SE448142B SE 448142 B SE448142 B SE 448142B SE 8107796 A SE8107796 A SE 8107796A SE 8107796 A SE8107796 A SE 8107796A SE 448142 B SE448142 B SE 448142B
- Authority
- SE
- Sweden
- Prior art keywords
- acid
- salts
- titanium
- composition according
- composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 43
- 238000011282 treatment Methods 0.000 title claims description 21
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 title claims description 10
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 title claims description 6
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 title claims description 5
- 229960004889 salicylic acid Drugs 0.000 title claims description 5
- 230000000087 stabilizing effect Effects 0.000 title claims description 4
- 239000005711 Benzoic acid Substances 0.000 title claims description 3
- 235000010233 benzoic acid Nutrition 0.000 title claims description 3
- ODIGIKRIUKFKHP-UHFFFAOYSA-N (n-propan-2-yloxycarbonylanilino) acetate Chemical compound CC(C)OC(=O)N(OC(C)=O)C1=CC=CC=C1 ODIGIKRIUKFKHP-UHFFFAOYSA-N 0.000 title 1
- 239000000126 substance Substances 0.000 title 1
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 claims description 30
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 22
- 239000010936 titanium Substances 0.000 claims description 22
- 229910052719 titanium Inorganic materials 0.000 claims description 22
- 235000010323 ascorbic acid Nutrition 0.000 claims description 15
- 229960005070 ascorbic acid Drugs 0.000 claims description 15
- 239000011668 ascorbic acid Substances 0.000 claims description 15
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 239000000654 additive Substances 0.000 claims description 10
- 150000003839 salts Chemical class 0.000 claims description 10
- 239000000080 wetting agent Substances 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 235000020774 essential nutrients Nutrition 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- 229930195732 phytohormone Natural products 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 239000003337 fertilizer Substances 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 claims description 3
- 230000001070 adhesive effect Effects 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 235000015097 nutrients Nutrition 0.000 claims description 3
- 229930192334 Auxin Natural products 0.000 claims description 2
- WZLMXYBCAZZIRQ-UHFFFAOYSA-N [N].[P].[K] Chemical compound [N].[P].[K] WZLMXYBCAZZIRQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002363 auxin Substances 0.000 claims description 2
- 239000013522 chelant Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 238000005242 forging Methods 0.000 claims 1
- SEOVTRFCIGRIMH-UHFFFAOYSA-N indole-3-acetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CNC2=C1 SEOVTRFCIGRIMH-UHFFFAOYSA-N 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 241000196324 Embryophyta Species 0.000 description 25
- 239000000243 solution Substances 0.000 description 21
- 230000000694 effects Effects 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 241000209140 Triticum Species 0.000 description 6
- 235000021307 Triticum Nutrition 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 150000003608 titanium Chemical class 0.000 description 6
- 235000013339 cereals Nutrition 0.000 description 5
- 230000012010 growth Effects 0.000 description 5
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 5
- 239000004299 sodium benzoate Substances 0.000 description 5
- 235000010234 sodium benzoate Nutrition 0.000 description 5
- 240000004713 Pisum sativum Species 0.000 description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 4
- 244000005700 microbiome Species 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 244000025254 Cannabis sativa Species 0.000 description 3
- 244000141359 Malus pumila Species 0.000 description 3
- 235000010582 Pisum sativum Nutrition 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000035784 germination Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 240000004160 Capsicum annuum Species 0.000 description 2
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 2
- 235000019750 Crude protein Nutrition 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- -1 alpha-naphthyl Chemical group 0.000 description 2
- 235000021016 apples Nutrition 0.000 description 2
- 239000001511 capsicum annuum Substances 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 235000021073 macronutrients Nutrition 0.000 description 2
- 239000011785 micronutrient Substances 0.000 description 2
- 235000013369 micronutrients Nutrition 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 241000167854 Bourreria succulenta Species 0.000 description 1
- 101100352919 Caenorhabditis elegans ppm-2 gene Proteins 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 102000018997 Growth Hormone Human genes 0.000 description 1
- 108010051696 Growth Hormone Proteins 0.000 description 1
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 240000004658 Medicago sativa Species 0.000 description 1
- 241001608711 Melo Species 0.000 description 1
- 108010020943 Nitrogenase Proteins 0.000 description 1
- 241000758706 Piperaceae Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 240000001987 Pyrus communis Species 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000016383 Zea mays subsp huehuetenangensis Nutrition 0.000 description 1
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000005219 brazing Methods 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 230000034303 cell budding Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000019693 cherries Nutrition 0.000 description 1
- 210000003763 chloroplast Anatomy 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- JLJLRLWOEMWYQK-GDUNQVSHSA-N giberellic acid Chemical compound C([C@@]1(O)C(=C)C[C@@]2(C1)C1C(O)=O)CC2[C@@]2(OC3=O)C1[C@]3(C)[C@@H](O)CC2 JLJLRLWOEMWYQK-GDUNQVSHSA-N 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 239000000122 growth hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 235000009973 maize Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 238000003359 percent control normalization Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 230000008635 plant growth Effects 0.000 description 1
- 239000003375 plant hormone Substances 0.000 description 1
- 239000004476 plant protection product Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 1
- 150000003112 potassium compounds Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 239000004460 silage Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 229920005552 sodium lignosulfonate Polymers 0.000 description 1
- GROMGGTZECPEKN-UHFFFAOYSA-N sodium metatitanate Chemical compound [Na+].[Na+].[O-][Ti](=O)O[Ti](=O)O[Ti]([O-])=O GROMGGTZECPEKN-UHFFFAOYSA-N 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
- C05D9/00—Other inorganic fertilisers
- C05D9/02—Other inorganic fertilisers containing trace elements
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
- Cultivation Of Plants (AREA)
Description
_15 20 25 30 35 44sg142 ovannämnda nackdelar) dvs nos vilken fyrvärt titan är Z resistent mot oxidation även i mycket utspädd lösning i när- varo av ett stortaöverskott av askorbinsyra efter besprutning på en stor area. Den nva kompositionen är likaså resistent mot mikroorganísmer{' I I Uppfinningen avser sålunda en växtbehandlingskomposition inne- hållande i vattenlösning 0,5-15,0 viktÅ% av ett titanaskorbin- syrakelat uppbyggt av 14~2á mol askornínsyra per mol titan och inställt på ett pH mellan 5 och 7,”O,l-2.0 delar av ett eller flera biokemiskt väsentliga näringsämnen och/eller 0,001-0,01 delar av ett e1ler_fleratfytohormoner per del titan. even- tuellt tillsammans med vätmedel. adhesiver och/eller andra konventionella tillsatser. kännetecknad av att den dessutom innehåller minst ß.0l:vikt-t. räknat på den totala vikten fasta substanser, av en eller flera föreningar valda bland bensoesyra eller salter därav och salicylsyra och salter därav som stabiliserande tillsats, De använda stabiliserande tíllsatserna ingår i lösningen i koncentrationer unp till 25 vikt-% men i en koncentration överstigande 2 vikt-t ökar deras aktivitet i relativt ringa omfattning och därför är det i allmänhet ej ekonomiskt att öka mängden över denna koncentration. 44sg142 above mentioned disadvantages) i.e. nose which tetravalent titanium is Z resistant to oxidation even in very dilute solution in the presence of a large excess of ascorbic acid after spraying over a large area. The present composition thus also relates to microorganisms. The invention thus relates to a plant treatment composition containing in aqueous solution 0.5-15.0% by weight of a titanium ascorbic acid chelate composed of 14 to 2 moles of ascornic acid per mole of titanium and adjusted to a pH. between 5 and 7, “0.1-2.0 parts of one or more biochemically essential nutrients and / or 0.001-0.01 parts of one or several phytate hormones per part of titanium. possibly together with wetting agent. adhesives and / or other conventional additives. characterized in that it also contains at least ß.0l: weight-t. calculated on the total weight solids, of one or more compounds selected from benzoic acid or salts thereof and salicylic acid and salts thereof as stabilizing additive. The stabilizing additives used are included in the solution in concentrations up to 25% by weight but in a concentration exceeding 2% by weight. -t increases their activity to a relatively small extent and therefore it is generally not economical to increase the amount above this concentration.
Det är en stor-fördel med kompositionen enligt uppfinningen ' att på grund av den ökade stabiliteten frekvensen av behand- 'lingar kan minskas eller om frekvensen är oförändrad aktivi- teten dkar med S~8% i jämförelse med de kända kompositionerna. som ej innehåller stabilisatorer; Kompositionerna kan lagras a under lång tid utan någon noterbar förlust í aktiviteten trots den höga askorbínsvrakoncentrationen, även i mycket utspädda vattenlosningar. De biokemiskt väsentliga näringsämnena inklu- derar spårämnena magnesium. järn, mangan, zink. molybden och bor samt växtgödningsmedel i form av konventionella kväve-fos- for-kalíum (NPK)-haltiga gödningsämnen, suspensioner etc. 10 15 20 25 30 35 4-48 el 42 I frånvaro av nämnda tillsatser täcks vätskans yta av kolonier av mikroorganismer redan efter två veckor. Mikroorganismerna minskar koncentrationen av aktiv ingrediens och omöjliggör den ordinarie användningen av lösningarna. Tillsatserna enligt uppfinningen inhiberar tillväxten av mikroorganismkolonier och konserverar följaktligen lösningarna i ett tillstånd lämpat för_appIicering under lång tid och resulterar samtidigt i en »5-8-procentig ökning i utbytet av frukt eller gröda i jäm- förelse med lösningar med samma koncentration aktiv ingrediens men utan tillsatserna enligt uppfinningen. Denna ökning i ut- bvtet_beror av den ökade mikrobiologiska resistansen.It is a great advantage of the composition according to the invention that due to the increased stability the frequency of treatments can be reduced or if the frequency is unchanged the activity increases by S ~ 8% in comparison with the known compositions. which do not contain stabilizers; The compositions can be stored for a long time without any noticeable loss of activity despite the high concentration of ascorbic acid, even in very dilute aqueous solutions. The biochemically essential nutrients include the trace elements magnesium. iron, manganese, zinc. molybdenum and boron as well as plant fertilizers in the form of conventional nitrogen-phosphorus-potassium (NPK) -containing fertilizers, suspensions etc. 4- 15 el 42 In the absence of said additives the surface of the liquid is already covered by colonies of microorganisms after two weeks. The microorganisms reduce the concentration of active ingredient and make the regular use of the solutions impossible. The additives according to the invention inhibit the growth of microorganism colonies and consequently preserve the solutions in a state suitable for long-term application and at the same time result in a »5-8% increase in the yield of fruit or crop compared to solutions with the same concentration of active ingredient but without the additives according to the invention. This increase in yield is due to the increased microbiological resistance.
Mikro- och makronäringsämnen och växthormon påskyndar plant- tillväxten när de tillsättes i en given mängd till komplexet av fyrvärt titan och askorbinsyra. _Kompositioner innehållande makro- och mikronäringsämnen har när de tillföres plantor i låg dos som blad- eller spraygöd- ningsämnen eller användes för frödressing. ett avsevärt in- flytande på utvecklingen av plantor, påskyndar absorptionen av gpmikronäríngsämnen, befrämjar effekten av vâxthormon under det toxiska tröskelvârdet.Micro- and macronutrients and plant hormones accelerate plant growth when added in a given amount to the complex of tetravalent titanium and ascorbic acid. Compositions containing macro- and micronutrients, when applied to low-dose plants as foliar or spray fertilizers or used for seed dressing. a significant influence on the development of plants, accelerates the absorption of micronutrients, promotes the effect of growth hormone below the toxic threshold.
Fytohormonkomponenterna i kompositionen kan vara auxiner, giberlliner. cyklokíniner, heteroauxiner (alfa-naftylättik- syra-beta-indolylättiksyra). etc. Fytohormoner inkluderar p2.4-diklorofenoxiättiksyra och salter därav.The phytohormone components in the composition may be auxins, giberllines. cycloquinines, heteroauxins (alpha-naphthyl acetic acid-beta-indolyl acetic acid). etc. Phytohormones include p2,4-dichlorophenoxyacetic acid and salts thereof.
Kompositionen innehåller 1000-2000 ppm askorbinsyra per liter lösning och mängden askorbinsyra i förhållande till fvrvärt titan utgör mellan 50 000 och 100 000 ppm. Som ytterligare tillsats kan i lösning ingå en eller flera av ovannämnda sta- bilisatorer. Bland mikroelementen kan kompositionen innehålla t ex 1000 ppm bor. 500 ppm mangan, 500 ppm zink. 1000 ppm mag- nesium och 500 ppm järn per 1000 ppm fyrvärt titan. i form av vattenlösliga salter, Kompositionen kan t ex innehålla 25 ppm ' 10 .15 20 25 30 35 44a142 2;4-diklorofenoxiättiksyra eller 10 ppm giberellsyra eller liknande tillsatser pef 1000-2000 ppm titan.The composition contains 1000-2000 ppm ascorbic acid per liter of solution and the amount of ascorbic acid in relation to virgin titanium is between 50,000 and 100,000 ppm. As an additional additive, the solution may include one or more of the above-mentioned stabilizers. Among the microelements, the composition may contain, for example, 1000 ppm boron. 500 ppm manganese, 500 ppm zinc. 1000 ppm magnesium and 500 ppm iron per 1000 ppm tetravalent titanium. in the form of water-soluble salts. The composition may, for example, contain 25 ppm, 10; 4-dichlorophenoxyacetic acid or 10 ppm of gyrelic acid or similar additives of 1000-2000 ppm of titanium.
Växtbehandlingskompositionen enligt uppfinningen kan beredas genom att lösa ett vattenlösligt salt av fyrvärt titan. t ex titantetraklorid ellen natriumtitanat och 14-28 mol askorbin- syna pe; mol titan i vatten; instâlla lösningens pH på 5-7 och sätta vattenlösníngen av mikro- och makronäzingsämnen till den _erhåIlna lösningen. Till denna lösning sättes lämpliga vät- .medel eller adhesíve: beh stabilisatorer. Stabíliseringsmedlen stabiliseraf koneentratíonen av titan och míkroelement på 'växternas yta. som bespçutas med kompositionen. '_ Kompositionen enliot uppfinningen tillföras växterna generelltf genom bespruthing. Experímentella iakttagelser visa: att närínqsämnena tränger_ín i bladens kloroplaster med följd att den fytosyntetiska effekten och enzymaktiviteten ökar.The plant treatment composition according to the invention can be prepared by dissolving a water-soluble salt of tetravalent titanium. eg titanium tetrachloride or sodium titanate and 14-28 moles of ascorbic acid pe; moles of titanium in water; adjust the pH of the solution to 5-7 and add the aqueous solution of micro- and macronutrients to the recovered solution. To this solution are added suitable wetting agents or adhesive stabilizers. The stabilizers stabilize the concentration of titanium and microelements on the surface of the plants. which is sprayed with the composition. The composition according to the invention is generally applied to the plants by spraying. Experimental observations show that the nutrients penetrate into the chloroplasts of the leaves, with the result that the phytosynthetic effect and the enzyme activity increase.
'Vid fältförsök och växthusekperiment under kontrollerade betingelser (t.eiÄ iïluminefing) har man kunnat konstatera att man med användning av kompositionen enligt uppfinningen påskyndar absorptionen av biokemiskt väsentliga näringsäm- nen. Absorbtíonen av magnesium; mangan, järn och zink, vil- ka spelar en viktig noll vid fotosyntesen, har ett direkt inflytande på utbytet hos_fruktträd och spannmål och ökar likaså livsmedelsvärdet. Vid besprutning av ärtväxter och gräs med molybden och vid Behandling av betor i närvaro av bor har utbytet ökat, betingelserna vid kolhydratbildningen förbätttats och en gynnsam effekt på bildningen av cellväg¥ garna iakttagíts. I händelse av näringsfattiga jordar är de: si11räa1igfi'_ att" eförsäcca växsbenandiingsxomposiuionen enligt uppfinningen med även vattenlösliga kväve-fosfor- och kaliumföreningar. I A Små koncentrationen,fytohofmoner och herbícider med hormon- Wílf; ~ d _. 10 15 'm 25 50 55 448i142 aktivitet ökar avsevärt tillväxten av unga plantor och be- främjar tillväxten av skott och knoppar.In field trials and greenhouse experiments under controlled conditions (i.e. luminescence) it has been found that the use of the composition according to the invention accelerates the absorption of biochemically essential nutrients. The absorption of magnesium; manganese, iron and zinc, which play an important role in photosynthesis, have a direct influence on the yield of fruit trees and cereals and also increase the value of food. When spraying pea plants and grass with molybdenum and when treating beets in the presence of boron, the yield has increased, the conditions for carbohydrate formation have been improved and a favorable effect on the formation of the cell pathways has been observed. In the case of nutrient-poor soils, they are suitable for satisfying the plant-bonding composition according to the invention with also water-soluble nitrogen-phosphorus and potassium compounds. 448i142 activity significantly increases the growth of young plants and promotes the growth of shoots and buds.
Den optimala dosen av växtbehandlingskompositionen enligt uppfinningen beror av den väktsort som skall behandlas.The optimal dose of the herbal treatment composition according to the invention depends on the type of plant to be treated.
Vid behandling av grönsaker under deras vegetationsperiod kan man använda 5 - 10 1/ha tre eller fyra gånger. Vid be- handling av spannmål efter bromning räcker det i allmänhet med en enda dos om 1 l/ha. Om unga skott med början från det de uppvisar tre till fyra blad behandlas var tionde dag ökar deras tillväxt avsevärt.When treating vegetables during their growing season, you can use 5 - 10 1 / ha three or four times. When treating grain after brazing, a single dose of 1 l / ha is generally sufficient. If young shoots, starting from the time they have three to four leaves, are treated every ten days, their growth will increase considerably.
Besprutningen kan utföras från flygplan, helikopter eller_ andra besprutningsanordningar. Före användning spädes kom- positionen med vatten till önskad koncentration och använ- des i en mängd av lp- 5 1/ha beroende på appliceringsmeto- den. Av ekonomiska hänsyn är det tillrâdligt att förena be- handlingen med föreliggande komposition med andra växtskydds- V arbeten. Kompositionen enligt uppfinningen är kompatibel med alla neutrala eller svagt sura växtskyddsmedel.The spraying can be performed from airplanes, helicopters or other spraying devices. Before use, dilute the composition with water to the desired concentration and apply in an amount of lp-5 1 / ha depending on the application method. For economic reasons, it is advisable to combine the treatment with the present composition with other plant protection works. The composition according to the invention is compatible with all neutral or slightly acidic plant protection products.
Framställningen och användningen av kompositionerna enligt uppfinningen illustreras i efterföljande exempel._ Exempel l Ett fyrvärt titansalt motsvarande 1 g titan och 100 g askor- binsyra löstes i vatten. Lösningen fylldes upp till l liter, dess pH-värde inställdes på 5 och 1 g salicylsyra tillsat- tes. Lagringsbeständigheten hos den erhållna kompositionen var minst 2 år.The preparation and use of the compositions according to the invention are illustrated in the following examples. Example 1 A tetravalent titanium salt corresponding to 1 g of titanium and 100 g of ascorbic acid was dissolved in water. The solution was made up to 1 liter, its pH was adjusted to 5 and 1 g of salicylic acid was added. The shelf life of the resulting composition was at least 2 years.
Till ovan beredda komposition sattes ett lösligt ammonium- salt motsvarande 3'vikt-% kväve, fosforsyra motsvarande N vikt-% fosforpentoxid och ett kaliumsalt motsvarande 5 vikt-% KQO, där procenttalen hänför sig till den totalas vikten hos lösningen. Lagringsbeständigheten hos den er- 10 15 zoo 25 30 35 obehandlatekontrollprov_ 44ai142 hållna kompositionen överensstämde med lagríngsbeständig- heten hos ovan beredda komposition men den senare innehöll även väsentliga näringsämnen förutom komponenterna användal för behandling av växter.f 41.? Aktiviteten hos ovan beskrivna komposition testades på vete (Rana-l) under vegetationsperioden isen dos av 3 x 1 g titan/ha. Utbytet hos behandlade plantor jämfördes med ut- bytet hos obehandlade kontrollplantor. Följande resultat uppnåddes. utbyte 102 kg/ha p%; vete behandlat med ovan- nämnda komposition I 47,25 121,4 38,93 100,0 7 Exempel 2 Ett fyrvärt titansalt motsvarande leg titan och 95 g askor- binsyra löstes i l liter vatten. Lösningen fylldes upp till l liter, dess pH inställdes på cirka 5 och 0,5 g natrium- bensoat tillsattes. Den erhållna kompositionen kunde lag- ras under mer än 2 år ntan någon aktivitetsförlust.e Kompositionens aktivitet testades vid majsgroningsförsök (TC SBHU/en sort);Följande behandlingar utfördes: obehandlat kontrollprov behandling_utfördes med en komposition med Kontroll I: Kontroll II: V? -ovan angivna ingredienser men utan natrium- ~bensoat.: I Testlösning: kompositionen framställd enligt detta exempel.To the above-prepared composition was added a soluble ammonium salt corresponding to 3% by weight of nitrogen, phosphoric acid corresponding to N% by weight of phosphorus pentoxide and a potassium salt corresponding to 5% by weight of KQO, the percentages relating to the total weight of the solution. The storage stability of the composition obtained in the untreated control sample corresponded to the storage stability of the above-prepared composition, but the latter also contained essential nutrients in addition to the components useful for the treatment of plants.f 41.? The activity of the composition described above was tested on wheat (Rana-1) during the growing season ice dose of 3 x 1 g titanium / ha. The yield of treated plants was compared with the yield of untreated control plants. The following results were obtained. yield 102 kg / ha p%; wheat treated with the above composition I 47.25 121.4 38.93 100.0 7 Example 2 A tetravalent titanium salt corresponding to leg titanium and 95 g of ascorbic acid was dissolved in 1 liter of water. The solution was made up to 1 liter, its pH was adjusted to about 5 and 0.5 g of sodium benzoate was added. The resulting composition could be stored for more than 2 years without any loss of activity. The activity of the composition was tested in maize germination experiments (TC SBHU / one variety); the following treatments were performed: untreated control sample treatment_performed with a composition with Control I: Control II: V? above ingredients but without sodium benzoate: I Test solution: the composition prepared according to this example.
Q i: 10 _ Samma test upprepades under fältförsök på sílomajs¿;Fö1eü¿ 15 20 25 30 35 4480142 Kompositionerna användes i samma dos som i exempel l. De uppnådda resultaten framgår àv efterföljande tabell; stjälkmedel- "”0 längd (cm) % kontroll I0 0 0 0 4,09 100,0 kontro11:IIe 0 ~P~ ' h,65 1-'*fï'ï113;7" testlösninÉ0^00 1 l ~ 0 1 ü,7H ïïfï jande resultat uppnåddes. 0 fiubyce el; _ , 102 kg/ha % gg kontroll I l.."0 .ll 0 l-l.~H06,0._ ll_,_¿00,Q _ ~._l kontroll IIV - ffè - ~ï¿ Ä7l,0¿- ¿=f,.l16¿9¿f-~ f testkomposition _, ; . 48ü,O _:-; -119,2 0 0' 0 0 0 0 0 se Exenpel 3 0 Ett fyrvärt titansalt motsvarande 1000 ppm titan, l0O 000 fipm askorbínsyra, 500 pfin mangan, 500 ppm zink och 700-ppm järn i form av vattenlösliga salter löstes i vatten och lös- ningen fylldes upp till l liter. Dess pH inställdes på 5:* óch 0,5 g natriumbensoat och 1000 ppm natriumlignosulfonat (vätmedel) tillsattes.. 0 Den erhållna kómpositíónen användes'efter spädning 200 gånger för behandling àvfpapríka beh efter spädníng'50O «till"l0O0 gångèr'för~behandling av äpplen. Papríka0behand- lades genom0besbrütníng i ett.stadäüm med'4 till 5 blad tre 11 gånger. Äppelträden besprutades när kronbladen föll av och behandlingen upprepades ytterligare två gånger under den tredje och sjätte Veckan därefter. Persika, apríkos, päron ap44sp142 10 15 20 25 30 35 och körsbär kan ookså_med framgång behandlas på samma sätt ;D@ Uppnâdda resultaten på paprika och äpplen framgår av efterföljande tabeller; . 7 ' Paprika-testp 3 p e p ¿p antal/0 p behand' medfiltäï aa" 100 0 askorbínsyrahalt ling _p kg/planta ”vikt-% plantor % mg/loog % - _ / xqntrollp' '7,1»6,-ff'a 100,6 e 280 l1oo,o 72 ioo,o ibehandlat 9,^i9 123,5 3214 115,7 266 369,11 ___! i Äpple-test _ » . putbyte glukoshalt ” sort och behandling e kg/ha %_. % "star-king" kontroll.- 351m 100,0 _ 9,1 ebenanalat 5960 - 168,3 9,8 "Jonathan" kontrcllí 72627 ^lO0,0 7 8,3 ” -behandlat 110660 ~152,3 ' 10,6 Exempel 4 Ett fyrvärt titansalt.motsvarande 1000 ppm titan, ett 28-a pfaldigt molärt överskott av askorbinsyra och 0,5 g salicyl- ~syra löstes i vatten och lösningen fylldes upp till l liter; Dess pH inställdes på S och 10 ppn_giberellsyra och 2000 ppmi ~natriumdodekylbensensulfonat (vätmedel) tillsattes.The same test was repeated during field trials on silage corn. The compositions were used in the same dose as in Example 1. The results obtained are shown in the following table; stem agent "" 0 length (cm)% control I0 0 0 0 4.09 100.0 control11: IIe 0 ~ P ~ 'h, 65 1 -' * fï'ï113; 7 "test solutionÉ0 ^ 00 1 l ~ 0 1 ü, 7H ïïfïjande results were obtained. 0 by ubyce el; _, 102 kg / ha% gg control I l .. "0 .ll 0 ll. ~ H06,0._ ll _, _ ¿00, Q _ ~ ._l control IIV - ffè - ~ ï¿ Ä7l, 0¿- ¿= F, .l16¿9¿f- ~ f test composition _,;. 48ü, O _: -; -119,2 0 0 '0 0 0 0 0 see Example 3 0 A tetravalent titanium salt corresponding to 1000 ppm titanium, l0O 000 fi pm ascorbic acid, 500 p manganese, 500 ppm zinc and 700 ppm iron in the form of water-soluble salts were dissolved in water and the solution was made up to 1 liter, its pH was adjusted to 5: * and 0.5 g sodium benzoate and 1000 ppm Sodium lignosulfonate (wetting agent) was added. The resulting composition was used after dilution 200 times for treatment of papyrus after dilution 50 DEG to 10 times for treatment of apples. Paprika was treated by broaching in one stage with 4 to 5 leaves three 11 times. The apple trees were sprayed when the petals fell off and the treatment was repeated twice more during the third and sixth week thereafter. Peach, apricot, pear ap44sp142 10 15 20 25 30 35 and cherries can also be successfully treated in the same way; D @ The results obtained on peppers and apples are shown in the following tables; . 7 'Paprika testp 3 pep ¿p number / 0 p treat' with fi ltäï aa "100 0 ascorbic acid content lingp _ kg / plant" weight-% plants% mg / loog% - _ / xqntrollp '' 7,1 »6, -ff 'a 100,6 e 280 l1oo, o 72 ioo, o ibehandlat 9, ^ i9 123,5 3214 115,7 266 369,11 ___! i Äpple-test _ ». putbyte glucose content" variety and treatment e kg / ha% _.% "star-king" control.- 351m 100.0 _ 9.1 ebenanalate 5960 - 168.3 9.8 "Jonathan" control 72627 ^ l00.0 7 8.3 "-treated 110660 ~ 152.3 ' 10.6 Example 4 A tetravalent titanium salt corresponding to 1000 ppm titanium, a 28-fold molar excess of ascorbic acid and 0.5 g of salicylic acid was dissolved in water and the solution was made up to 1 liter; its pH was adjusted to S and 10 ppn_giberellic acid and 2000 ppmi ~ sodium dodecylbenzenesulfonate (wetting agent) were added.
Den erhållna kompositionen testades vid vetegroningstest och användes för behandling av plantor av Saintpaulis íonantha. Vetekorn dresserades med en lösning innehållande. 0,02 ppm titan. Plantorna av Saintpaulis ionantha bespruta- des med 0,2-procentig lösning av nämnda lösning var tionde 3 -dag,-tillsammans två gånger.The resulting composition was tested in wheat germination test and used to treat plants of Saintpaulis íonantha. Wheat grains were trained with a solution containing. 0.02 ppm titanium. The plants of Saintpaulis ionantha were sprayed with 0.2% solution of said solution every ten 3 days, together twice.
I!! LN 10 15 o20j 25 'so 55 Exempel 5 448 1420 De uppnådda resultaten återges i nedanstående tabeller.IN!! LN 10 15 o20j 25 'so 55 Example 5 448 1420 The results obtained are given in the tables below.
Vetegroningstest medellängd sort och behandling V' ihos planta, cm % "Lublajnaja" kontrolln 5 ' 10,46 100,0 " behandlade, 12,18 ll6,U Saintpaulisdionantha-test plant-diameter (cm) (medeltal för 100 -torrsub-0 bildning av behandling a plantor) _ 5 stans % knoppar % ikontroll 15,75 - 3,96 23 behandlade 21,20 4,58 48 Resultaten visar att vetekorn behandlade med kompositionen enligt uppfinningen grodde på kortare tid och tillväxten av de behandlade plantorna av Saintpaulis ionantha påskyn- dades i jämförelse med respektive kontrollkorn och kon- trollplantor. Samma tillväxtaccelererande effekt kan iakt- tas när prydnadsväxter behandlas. De behandlade växterna -blommade tidigare och kunde till följa därav försäljas cir- ka två veckor tidigare än kontrollplantorna. Ä 5 Ett fyrvärt titansalt motsvarande 2000 ppm titan och 100 000 ppm askorbinsyra löstes i l liter vatten. Man till- satte 0,5 g natriumbensoat och.50O ppm av ett vattenlös- ligt molybdensalt och 1000 ppm polyeten-po1ypropen-seg- mentpolymerisat (vätmedel). Lösningens pH inställdes på 5. 5- till 6-bladiga lucernplantor behandlades med ovan be- 10 15 20 25 .BG 55 5 positionen en gång. Resultaten av behandlingarna framgår ld44sa142 5105 redda konpositíoner före varje slåtter en gång i en dos av 2 l/ha. Grönärter behandlades med ovan beredda konposition eunder-knoppningsperioden och först med en dos av 2 l/ha, tillsammans två gånger; Gräs besprutades med 1 l/ha av kom- (54 e av efterföljande tabeller. 'k tBehandling av gröna ärter medelvärde 5 - 5 utbyte 5 läckerhet sackaros sort øcn,behand1ings akg/har 5 %oa (T) % npugebu Kontroll' ¿ Hu5o '1oo,od 1ho,5_ 5,35 behandlade 5250 118,0 127,55 75,88 eflerüne" kontroll _ .Melo 100,05 136;2. 5,55 behandlade 5 5260 _12u;9 5d123,8e 5,75 Lucern-test torr 5 upp- 5 5 grön* substans- rå- tagbart astärkelse- 5 5 massa halt 5 protein protein värde dÅbehandling kg/m3 g/hg' ' g/kg g/kg g/kg kontroll dd1,25 Ät 905 128 55 93 5 301 behandlade 1,87 5915' 5 171 l2fl 316 Å Gräs-:est _ f 5 e'd'utbvte rå-protein stärkelsevärde behandling _- kg/ha ' _ % E/kg 5%/RE kontroll 4300 ~lÛQ,0 - us 110 behandlat 151,2 H75 106 6500 *AW fr. . 10 .p 15 720 25 30, 0055 0449 142 101 - Ovan erhållna resultat visar att utbytet av och läckerhe- ten hos erhållna grönärter starkt.förbättrades genom be- handlingen enligt uppfinningen.Wheat germination test medium length variety and treatment V 'ihos plant, cm% "Lublajnaja" control 5' 10.46 100.0 "treated, 12.18 ll6, U Saintpaulisdionantha test plant diameter (cm) (average for 100 -dry sub-0 formation of treatment of plants) _ 5 punch% buds% icon control 15.75 - 3.96 23 treated 21.20 4.58 48 The results show that wheat grains treated with the composition according to the invention germinated in a shorter time and the growth of the treated plants of Saintpaulis ionantha was accelerated in comparison with the respective control grains and control plants.The same growth-accelerating effect can be observed when ornamental plants are treated.The treated plants -flowered earlier and could consequently be sold about two weeks earlier than the control plants.Ä 5 A four-valued titanium salt corresponding to 2000 ppm titanium and 100,000 ppm ascorbic acid was dissolved in 1 liter of water, 0.5 g of sodium benzoate and 5050 ppm of a water-soluble molybdenum salt and 1000 ppm polyethylene-polypropylene segments were added. graft polymer (wetting agent). The pH of the solution was adjusted to 5. 5- to 6-leaf alfalfa plants were treated with the above position once again. The results of the treatments appear ld44sa142 5105 saved compositions before each mowing once in a dose of 2 l / ha. Green peas were treated with the above-prepared composition during the budding period and first with a dose of 2 l / ha, together twice; Grass was sprayed with 1 l / ha of com- (54 e of the following tables. 'K tTreatment of green peas average 5 - 5 yield 5 delicacy sucrose variety øcn, treatment akg / has 5% oa (T)% npugebu Control' ¿Hu5o '1oo, od 1ho, 5_ 5,35 treated 5250 118,0 127,55 75,88 e fl erüne "control _ .Melo 100,05 136; 2. 5,55 treated 5 5260 _12u; 9 5d123,8e 5,75 Lucern -test dry 5 up- 5 5 green * substance- removable starch- 5 5 mass content 5 protein protein value dÅ treatment kg / m3 g / hg '' g / kg g / kg g / kg control dd1.25 Eat 905 128 55 93 5 301 treated 1.87 5915 '5 171 l2 fl 316 Å Grass: est _ f 5 e'd'utbvte crude protein starch value treatment _- kg / ha' _% E / kg 5% / RE control 4300 ~ lÛQ, 0 - us 110 treated 151.2 H75 106 6500 * AW fr. 10 .p 15 720 25 30, 0055 0449 142 101 - The results obtained above show that the yield and deliciousness of obtained green peas was greatly improved by the document according to the invention.
I fallet med lu1:rn uppnåddes förutom kvantitativa och kva- litativa förbättringar en avsevärd ökning av antalet röt- -.ter och nitrogenasenzymaktiviteten påskyndades. Vid be- sprutning av gräs kunde man iaktta en kraftig ökning av grönmassan medan råprotein- och stärkelsevärdena förblev i huvudsak oförändrade.In the case of lu1, in addition to quantitative and qualitative improvements, a considerable increase in the number of rots was achieved and nitrogenase enzyme activity was accelerated. When spraying grass, a sharp increase in the green mass could be observed, while the crude protein and starch values remained largely unchanged.
Exempel 6' Ett vattenlösligt, fyrvärt titansalt motsvarande 1000 ppm titan och 900 000 ppm askorbinsyra löstes i vatten och lös-0 ningen fylldes upp till 1 liter. Lösningens pH inställdes pâi5 och 25 ppm 2,U-diklorofenoxiättiksyranatriumsalt, O,É g natriumbensoat och petroleumsulfonatnatriumsalt (vät- medel) tlllsatçes;l ' Med ovan beredda komposition besprutades efter spädning vin- druvsplantor tre gånger under deras vegetatíonperiod. Resul- taten framgår av efterföljande tabell.Example 6 A water-soluble, tetravalent titanium salt corresponding to 1000 ppm titanium and 900,000 ppm ascorbic acid was dissolved in water and the solution was made up to 1 liter. The pH of the solution was adjusted to 5 and 25 ppm 2, U-dichlorophenoxyacetic acid sodium salt, 0.30 g of sodium benzoate and petroleum sulphonate sodium salt (wetting agent) were added; The results are shown in the following table.
Vindruvs-test_ glukos _ socker/syra- sort och behandling g/100 ml 0% förhållande "Treasure of Pannonia" _ kontfoll * 8,0 100,0 13,2 behandlad 0 0 9,4 117,5 19,2 "Italian ríesling" I kontroll _l2,6 loo,o 0 15,1 behandlad _ 0 f 17,6 0 139,6 0 28=3 44sÉ142lll 1í2l i Ovan erhållna. resultat visar att behandlingen ökar kol- ~hydrathalteñ hos vindrušor och därmed ökar också socker!- syra-förhållandet. _ I .ff/la (ät d]Grape test_ glucose _ sugar / acid variety and treatment g / 100 ml 0% ratio "Treasure of Pannonia" _ contfoll * 8.0 100.0 13.2 treated 0 0 9.4 117.5 19.2 "Italian ríesling "I control _l2,6 loo, o 0 15,1 treated _ 0 f 17,6 0 139,6 0 28 = 3 44sÉ142lll 1í2l i Above obtained. results show that the treatment increases the carbohydrate content of grapes and thus also increases the sugar-acid ratio. _ I .ff / la (ät d]
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| HU803133A HU186758B (en) | 1980-12-29 | 1980-12-29 | Compositions for conditioning plants containing titane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| SE8107796L SE8107796L (en) | 1982-06-30 |
| SE448142B true SE448142B (en) | 1987-01-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| SE8107796A SE448142B (en) | 1980-12-29 | 1981-12-28 | EXTRA TREATMENT COMPOSITION INCLUDING A TITANAS CHORBIN ACYLATE AND AS STABILIZING ADDITION OR ANY SUBSTANCES SELECTED BY BENZOIC ACID OR SALTS OF IT AND SALICYLIC ACID AND SALTS OF THEREOF |
Country Status (24)
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| JP (1) | JPS6011881B2 (en) |
| AR (1) | AR227570A1 (en) |
| AT (1) | AT377972B (en) |
| AU (1) | AU558131B2 (en) |
| BE (1) | BE891618A (en) |
| BG (1) | BG41123A3 (en) |
| BR (1) | BR8108410A (en) |
| CA (1) | CA1159273A (en) |
| CH (1) | CH654981A5 (en) |
| DD (1) | DD201844A5 (en) |
| DE (1) | DE3151612A1 (en) |
| DK (1) | DK158036C (en) |
| ES (1) | ES508202A0 (en) |
| FI (1) | FI67533C (en) |
| FR (1) | FR2497065B1 (en) |
| GB (1) | GB2090585B (en) |
| HU (1) | HU186758B (en) |
| IE (1) | IE52344B1 (en) |
| LU (1) | LU83853A1 (en) |
| NL (1) | NL8105864A (en) |
| PL (1) | PL134889B1 (en) |
| PT (1) | PT74194B (en) |
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| SE (1) | SE448142B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60202805A (en) * | 1984-03-27 | 1985-10-14 | Agency Of Ind Science & Technol | Plant growth promoter and method of plant treatment using it |
| AT383688B (en) * | 1984-11-30 | 1987-08-10 | Stolitzka Gerhard Dipl Ing Dr | METHOD FOR DETECTING CURVED AND STRAIGHT INTERFACES WITH CAVITY AREAS |
| AT396785B (en) * | 1991-03-25 | 1993-11-25 | Agrolinz Agrarchemikalien | Foliar fertilizer and spray mixture for foliar feeding comprising plant nutrients and an acid |
| ES2049127B1 (en) * | 1991-06-13 | 1994-10-01 | Tioxide Espa A S A | CORRECTOR OF MICROELEMENTS LAWS FOR AGRICULTURAL SOILS AND PROCEDURE FOR ITS PREPARATION. |
| HU9302976D0 (en) * | 1993-10-21 | 1994-01-28 | Koeroesi | Plains foodelementsource and heavy-metal and isotope-intake using produces and process for producing it |
| JPH11501608A (en) * | 1995-03-06 | 1999-02-09 | ノノムラ，アーサー，エム | Methods and compositions for enhancing formyltetrahydropteroyl polyglutamate in plants |
| AT1189U1 (en) * | 1995-06-29 | 1996-12-27 | Karner Robert | FERTILIZERS, PLANT CARE PRODUCTS AND PLANT PROTECTION SOLUTION |
| RU2114805C1 (en) * | 1997-06-19 | 1998-07-10 | Тульский государственный университет | Agent for stimulation of agriculture crop growth |
| CZ296300B6 (en) * | 2004-06-04 | 2006-02-15 | Jihoceská univerzita v Ceských Budejovicích | Composition for inducing increase of formation of biologically active compounds in plants and use thereof |
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| CN104892065A (en) * | 2015-05-25 | 2015-09-09 | 王绪征 | Solid-titanium-containing minor element water-soluble fertilizer multielement preparation and preparation method thereof |
| RU2643726C1 (en) * | 2017-05-11 | 2018-02-05 | Акционерное общество "Щелково Агрохим" | Crops growth stimulation method |
| PL239086B1 (en) * | 2017-05-15 | 2021-11-02 | Intermag Spolka Z Ograniczona Odpowiedzialnoscia | The method of obtaining metal-ascorbic acid complexes and the use of complexes obtained in this way |
| CN109369278A (en) * | 2018-12-14 | 2019-02-22 | 青岛苏贝尔作物营养有限公司 | A kind of humic acid Modified Titanium fertilizer and preparation method thereof |
| ES2926970B2 (en) | 2021-04-27 | 2023-07-17 | Gestion Ecosistemas Agricolas S L | COMPOSITION TO REDUCE THE ABIOTIC STRESS OF PLANTS AND/OR IMPROVE THE EFFICIENCY OF THEIR METABOLISM |
| EP4574861A1 (en) * | 2023-12-21 | 2025-06-25 | Ems-Chemie Ag | Aqueous dipping bath compositions for treating reinforcement inserts, and use and method for producing an adhesive reinforcement insert |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR480509A (en) * | 1914-12-23 | 1916-08-17 | Jan Willem Hendrik Van Der Toorn Jacobus | Process to increase the productive power of the soil |
| DE542357C (en) * | 1928-04-23 | 1932-01-23 | Daniel Gardner | Fertilizer |
| FR688255A (en) * | 1929-04-03 | 1930-08-21 | Soil fertilization improvements | |
| US3130038A (en) * | 1961-03-13 | 1964-04-21 | Int Minerals & Chem Corp | Granular fertilizers |
| BE786946A (en) * | 1971-07-29 | 1973-01-29 | Ciba Geigy | CHELATES TO COMBAT SYMPTOMS OF METAL DEFICIENCY IN BIOLOGICAL SYSTEMS |
| FR2244402B1 (en) * | 1973-09-25 | 1976-10-01 | Philagro Sa |
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1980
- 1980-12-29 HU HU803133A patent/HU186758B/en not_active IP Right Cessation
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1981
- 1981-11-27 AT AT0511581A patent/AT377972B/en not_active IP Right Cessation
- 1981-12-07 CA CA000391622A patent/CA1159273A/en not_active Expired
- 1981-12-07 FI FI813916A patent/FI67533C/en not_active IP Right Cessation
- 1981-12-10 CH CH7899/81A patent/CH654981A5/en not_active IP Right Cessation
- 1981-12-18 DD DD81235955A patent/DD201844A5/en not_active IP Right Cessation
- 1981-12-18 GB GB8138190A patent/GB2090585B/en not_active Expired
- 1981-12-21 ES ES508202A patent/ES508202A0/en active Granted
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- 1981-12-28 JP JP56210120A patent/JPS6011881B2/en not_active Expired
- 1981-12-28 SE SE8107796A patent/SE448142B/en not_active IP Right Cessation
- 1981-12-28 NL NL8105864A patent/NL8105864A/en not_active Application Discontinuation
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1982
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