SE417700B - PROCEDURE FOR PRODUCING SULFURIC ACID - Google Patents
PROCEDURE FOR PRODUCING SULFURIC ACIDInfo
- Publication number
- SE417700B SE417700B SE7607631A SE7607631A SE417700B SE 417700 B SE417700 B SE 417700B SE 7607631 A SE7607631 A SE 7607631A SE 7607631 A SE7607631 A SE 7607631A SE 417700 B SE417700 B SE 417700B
- Authority
- SE
- Sweden
- Prior art keywords
- gases
- contacting
- heat
- sulfuric acid
- catalytic reaction
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
- C01B17/7655—Multi-stage SO3-conversion with intermediate absorption
Abstract
The present invention relates to a contact process for producing sulfuric acid from gases containing more than 10% by volume SO2 and which gives a maximum amount of surplus heat in an economical manner and is utilized for an increase in the concentration of dilute sulfuric acids. This improved process comprises the following steps: (a) combining the production of sulfuric acid with an increase of the concentration of dilute sulfuric acid; (b) adding oxygen-containing gases to a partial stream of SO2-containing gases at such a rate that the gas mixture can be reacted at least in a first contacting tray until the reaction has proceeded to an equilibrium below or at the highest temperature which is permissible for the catalyst; (c) heating said resulting gas mixture to the operating temperature of said first contacting tray by subjecting it to heat exchange with hot sulphur trioxidecontaining gases flowing between contacting trays; (d) adding the remaining SO2-containing gas to the sulphur trioxide-containing gas from at least the first contacting tray of the first catalytic reaction stage; (e) controlling the rate at which the partial stream of SO2-containing gases is fed to, the first contacting tray so that SO3 is produced in step (b) at such a rate that the ratio of SO2:SO3 in the mixture produced in step (d) is such that the reaction in the following contacting trays can proceed to an equilibrium below or at the highest temperature which is permissible for the catalyst; (f) removing SO3 from the catalytically reacted gases by interstage and final absorption at operating temperatures of 100-200.degree.C; (g) conducting the catalytic reaction in the second catalytic reaction stage in at least two contacting trays and cooling the gases between the contacting trays; (h) expelling water from the dilute sulfuric acids by directly contacting the acids with hot gases consisting of the contact process exhaust gases which have been subjected to final absorption or of inert gases having a low water content, or a mixture thereof; (i) heating the expelling gases with at least part of the heat which becomes available in the final heat exchanger, which follows the second catalytic reaction stage; (j) heating the expelling gases with at least part of the heat which becomes available during the cooling of the catalytically reacted gases in step (g) or with at least part of the heat which becomes available in the second cooling stage which follows the first catalytic reaction stage and precedes the interstage absorption, or both and (k) using the heat energy derived from the acids which are circulated through at least one of the devices in the group comprising the dryer, the interstage absorber and the final absorber so as to increase the concentration of or to preheat the dilute sulfuric acid, or both.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2529709A DE2529709C3 (en) | 1975-07-03 | 1975-07-03 | Process for the production of sulfuric acid |
Publications (2)
Publication Number | Publication Date |
---|---|
SE7607631L SE7607631L (en) | 1977-01-04 |
SE417700B true SE417700B (en) | 1981-04-06 |
Family
ID=5950590
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SE7607631A SE417700B (en) | 1975-07-03 | 1976-07-02 | PROCEDURE FOR PRODUCING SULFURIC ACID |
Country Status (15)
Country | Link |
---|---|
JP (1) | JPS5235793A (en) |
BE (1) | BE843772A (en) |
BR (1) | BR7604336A (en) |
CA (1) | CA1099484A (en) |
DE (1) | DE2529709C3 (en) |
ES (1) | ES448720A1 (en) |
FI (1) | FI761918A (en) |
FR (1) | FR2316187A1 (en) |
GB (1) | GB1553307A (en) |
IN (1) | IN143873B (en) |
IT (1) | IT1079128B (en) |
NL (1) | NL7604961A (en) |
NO (1) | NO761603L (en) |
SE (1) | SE417700B (en) |
ZA (1) | ZA762985B (en) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2429748A1 (en) * | 1978-06-28 | 1980-01-25 | B St P Realizac | Catalytic oxidn. of sulphur di:oxide to tri:oxide - in sulphuric acid mfr., by double conversion using wall heat exchange to increase heat exchange intensity |
DE2847602C2 (en) * | 1978-11-02 | 1986-10-23 | Biuro Studiów, Projektów i Realizacji Inwestycji Przemysłu Nieorganicznego Biprokwas, Gleiwitz/Gliwice | Process for the production of sulfuric acid |
DE2945021A1 (en) * | 1979-11-08 | 1981-05-21 | Metallgesellschaft Ag, 6000 Frankfurt | METHOD FOR PRODUCING CONCENTRATED SULFURIC ACID |
CA1146722A (en) * | 1981-04-10 | 1983-05-24 | Gordon M. Cameron | Energy recovery method and system for combined sulphuric and phosphoric acid manufacturing plant |
DE3232446A1 (en) * | 1982-08-12 | 1984-02-16 | Metallgesellschaft Ag, 6000 Frankfurt | METHOD FOR PRODUCING SULFURIC ACID |
DE3303287A1 (en) * | 1983-02-01 | 1984-08-02 | Bayer Ag, 5090 Leverkusen | METHOD FOR PRODUCING SULFURIC ACID |
US4576813A (en) * | 1983-07-05 | 1986-03-18 | Monsanto Company | Heat recovery from concentrated sulfuric acid |
US4670242A (en) * | 1984-11-09 | 1987-06-02 | Monsanto Company | Heat recovery from concentrated sulfuric acid |
JPS60145200A (en) * | 1984-01-06 | 1985-07-31 | 松下電器産業株式会社 | Ironing stand |
JPS62166000U (en) * | 1986-04-10 | 1987-10-21 | ||
DE19800800C2 (en) * | 1998-01-13 | 2001-05-23 | Metallgesellschaft Ag | Process for the production of sulfuric acid |
DE102007058144A1 (en) * | 2007-11-30 | 2009-06-04 | Outotec Oyj | Producing sulfuric acid from a gas containing sulfur dioxide comprises catalytically oxidizing the sulfur dioxide in a converter to obtain sulfur trioxide and absorbing the sulfur trioxide in concentrated sulfuric acid in absorber |
CN110538543B (en) * | 2019-08-30 | 2021-07-13 | 楚雄滇中有色金属有限责任公司 | Method for stably reaching standard of tail gas in initial stage of acid making and coproduction by smelting flue gas |
WO2023225742A1 (en) * | 2022-05-27 | 2023-11-30 | Chemetics Inc. | Tail gas treatment system and method for a sulfuric acid production plant |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL136387C (en) * | 1964-11-06 | |||
DE1567716B2 (en) * | 1966-12-03 | 1977-02-17 | Metallgesellschaft Ag, 6000 Frankfurt | METHOD OF CATALYTIC REALIZATION OF SO LOW 2 AND SO LOW 3 AND SULFUR ACID PRODUCTION |
BE788625A (en) * | 1971-09-11 | 1973-01-02 | Metallgesellschaft Ag | PROCESS FOR THE REMOVAL OF SULFURIC ANHYDRIDE AND SULFURIC ACID MIST CONTAINED IN GASES |
-
1975
- 1975-07-03 DE DE2529709A patent/DE2529709C3/en not_active Expired
-
1976
- 1976-05-10 NL NL7604961A patent/NL7604961A/en not_active Application Discontinuation
- 1976-05-10 NO NO761603A patent/NO761603L/no unknown
- 1976-05-19 ZA ZA762985A patent/ZA762985B/en unknown
- 1976-06-10 ES ES448720A patent/ES448720A1/en not_active Expired
- 1976-06-14 GB GB24600/76A patent/GB1553307A/en not_active Expired
- 1976-06-17 IN IN1063/CAL/76A patent/IN143873B/en unknown
- 1976-06-25 IT IT24701/76A patent/IT1079128B/en active
- 1976-06-25 FR FR7619404A patent/FR2316187A1/en active Granted
- 1976-06-30 CA CA256,082A patent/CA1099484A/en not_active Expired
- 1976-07-01 FI FI761918A patent/FI761918A/fi not_active Application Discontinuation
- 1976-07-02 JP JP51079402A patent/JPS5235793A/en active Pending
- 1976-07-02 BR BR7604336A patent/BR7604336A/en unknown
- 1976-07-02 SE SE7607631A patent/SE417700B/en unknown
- 1976-07-02 BE BE6045582A patent/BE843772A/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
NL7604961A (en) | 1977-01-05 |
DE2529709A1 (en) | 1977-01-20 |
GB1553307A (en) | 1979-09-26 |
NO761603L (en) | 1977-01-04 |
IN143873B (en) | 1978-02-18 |
DE2529709C3 (en) | 1981-02-26 |
BE843772A (en) | 1977-01-03 |
DE2529709B2 (en) | 1980-06-12 |
JPS5235793A (en) | 1977-03-18 |
CA1099484A (en) | 1981-04-21 |
FR2316187A1 (en) | 1977-01-28 |
IT1079128B (en) | 1985-05-08 |
SE7607631L (en) | 1977-01-04 |
FR2316187B1 (en) | 1981-11-06 |
ZA762985B (en) | 1977-04-27 |
FI761918A (en) | 1977-01-04 |
BR7604336A (en) | 1977-07-26 |
ES448720A1 (en) | 1977-07-01 |
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