SE409291B - PROCEDURE FOR PHOSPHATE-MINERAL FOAM FLOATING - Google Patents
PROCEDURE FOR PHOSPHATE-MINERAL FOAM FLOATINGInfo
- Publication number
- SE409291B SE409291B SE7802427A SE7802427A SE409291B SE 409291 B SE409291 B SE 409291B SE 7802427 A SE7802427 A SE 7802427A SE 7802427 A SE7802427 A SE 7802427A SE 409291 B SE409291 B SE 409291B
- Authority
- SE
- Sweden
- Prior art keywords
- group
- process according
- flotation
- amphoteric
- collector
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 20
- 239000006260 foam Substances 0.000 title claims description 3
- 229910052585 phosphate mineral Inorganic materials 0.000 title 1
- 238000005188 flotation Methods 0.000 claims description 17
- 230000002209 hydrophobic effect Effects 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 8
- 239000011707 mineral Substances 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 239000003153 chemical reaction reagent Substances 0.000 claims description 7
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 239000001506 calcium phosphate Substances 0.000 claims description 2
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 2
- 235000011010 calcium phosphates Nutrition 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 2
- 210000003298 dental enamel Anatomy 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 description 18
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 18
- 229910052586 apatite Inorganic materials 0.000 description 17
- -1 alkylbenzene sulfonate Chemical class 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 13
- 229910021532 Calcite Inorganic materials 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 230000001143 conditioned effect Effects 0.000 description 5
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 150000003141 primary amines Chemical class 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- SZCFXFXQJBVCQI-UHFFFAOYSA-N 3-chloro-3-(1-chloro-2,3-dihydroxypropoxy)propane-1,2-diol Chemical compound OCC(O)C(Cl)OC(Cl)C(O)CO SZCFXFXQJBVCQI-UHFFFAOYSA-N 0.000 description 2
- 229940126062 Compound A Drugs 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- BTFJIXJJCSYFAL-UHFFFAOYSA-N icosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 150000002924 oxiranes Chemical class 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 229910052604 silicate mineral Inorganic materials 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- NQAWQSVOOHTLEY-UHFFFAOYSA-N 1-chlorobutane-1-sulfonic acid Chemical compound CCCC(Cl)S(O)(=O)=O NQAWQSVOOHTLEY-UHFFFAOYSA-N 0.000 description 1
- LHORZPMPPHTXFQ-UHFFFAOYSA-N 1-chloroethanesulfonic acid Chemical compound CC(Cl)S(O)(=O)=O LHORZPMPPHTXFQ-UHFFFAOYSA-N 0.000 description 1
- MCXZBEZHTYZNRE-UHFFFAOYSA-N 1-chloropropane-1-sulfonic acid Chemical compound CCC(Cl)S(O)(=O)=O MCXZBEZHTYZNRE-UHFFFAOYSA-N 0.000 description 1
- NFGXHKASABOEEW-UHFFFAOYSA-N 1-methylethyl 11-methoxy-3,7,11-trimethyl-2,4-dodecadienoate Chemical compound COC(C)(C)CCCC(C)CC=CC(C)=CC(=O)OC(C)C NFGXHKASABOEEW-UHFFFAOYSA-N 0.000 description 1
- PXFBZOLANLWPMH-UHFFFAOYSA-N 16-Epiaffinine Natural products C1C(C2=CC=CC=C2N2)=C2C(=O)CC2C(=CC)CN(C)C1C2CO PXFBZOLANLWPMH-UHFFFAOYSA-N 0.000 description 1
- JKTAIYGNOFSMCE-UHFFFAOYSA-N 2,3-di(nonyl)phenol Chemical compound CCCCCCCCCC1=CC=CC(O)=C1CCCCCCCCC JKTAIYGNOFSMCE-UHFFFAOYSA-N 0.000 description 1
- NSENZNPLAVRFMJ-UHFFFAOYSA-N 2,3-dibutylphenol Chemical class CCCCC1=CC=CC(O)=C1CCCC NSENZNPLAVRFMJ-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical compound CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- RVBUZBPJAGZHSQ-UHFFFAOYSA-N 2-chlorobutanoic acid Chemical compound CCC(Cl)C(O)=O RVBUZBPJAGZHSQ-UHFFFAOYSA-N 0.000 description 1
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical class CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 description 1
- HMWIHOZPGQRZLR-UHFFFAOYSA-N 2-hexadecylphenol Chemical class CCCCCCCCCCCCCCCCC1=CC=CC=C1O HMWIHOZPGQRZLR-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- GDFAOVXKHJXLEI-VKHMYHEASA-N N-methyl-L-alanine Chemical compound C[NH2+][C@@H](C)C([O-])=O GDFAOVXKHJXLEI-VKHMYHEASA-N 0.000 description 1
- AKCRVYNORCOYQT-YFKPBYRVSA-N N-methyl-L-valine Chemical compound CN[C@@H](C(C)C)C(O)=O AKCRVYNORCOYQT-YFKPBYRVSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Chemical class CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 108010077895 Sarcosine Proteins 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 230000036528 appetite Effects 0.000 description 1
- 235000019789 appetite Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- SFVWPXMPRCIVOK-UHFFFAOYSA-N cyclododecanol Chemical compound OC1CCCCCCCCCCC1 SFVWPXMPRCIVOK-UHFFFAOYSA-N 0.000 description 1
- QCRFMSUKWRQZEM-UHFFFAOYSA-N cycloheptanol Chemical compound OC1CCCCCC1 QCRFMSUKWRQZEM-UHFFFAOYSA-N 0.000 description 1
- RCIINNRHOWANBV-UHFFFAOYSA-N cyclohexadecanol Chemical compound OC1CCCCCCCCCCCCCCC1 RCIINNRHOWANBV-UHFFFAOYSA-N 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- FHADSMKORVFYOS-UHFFFAOYSA-N cyclooctanol Chemical compound OC1CCCCCCC1 FHADSMKORVFYOS-UHFFFAOYSA-N 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000006735 epoxidation reaction Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 229910052587 fluorapatite Inorganic materials 0.000 description 1
- 229940077441 fluorapatite Drugs 0.000 description 1
- 238000003682 fluorination reaction Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910001608 iron mineral Inorganic materials 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002367 phosphate rock Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical compound C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000010698 whale oil Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B1/00—Conditioning for facilitating separation by altering physical properties of the matter to be treated
- B03B1/04—Conditioning for facilitating separation by altering physical properties of the matter to be treated by additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/02—Froth-flotation processes
- B03D1/06—Froth-flotation processes differential
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Paper (AREA)
Description
. 1:_-a-=.-.zzz.-._-. aan-_.. .-_--... m..- _... ..,\-\......_.-.-.-..-~.~.-.~.-_ _ .-: - '-.'.-'--=-~=--,.:-_-- M-ädfi-“rrrf- _ ..-v _. -....«_._._-_._ _._..... .. . , _ _ .,. _ - ' '°_.7802ll»27'0 ' _ 2 - har man sökt lösa detta problem genom att först flotera kalcit vid ett lågt pH-värde och sedan öka alkaliteten och flotera apatiten med samma'samlare. Även andra anjoniska samlare som alkylbensensulfonat, alkylfosfat, alkylsulfat och alkylsulfosuccinamat har föreslagits som samlare för apatit men de har icke tillfredsställande löst separa- tionsproblemet. _ Enligt föreliggande uppfinning har det nu visat sig möjligt att med gott resultat skumflotera kalciumfosfathaltiga mineral, så- som apatit och fosforiter under användning av en amfotär ytaktiv fö- rening. Denna amfotära ytaktiva förening kan åskâdliggöras med den allmänna formeln . R1 R - (_ou)n -I (mp - C212 - cmoa) -g C112 - E - cqnzqv 7 'l24. fiïïïïäfießvis l0 - 18 kolatomer, varje A betecknar en oxialkylengrupp med 2 - 4 kolatomer, R]°är en där R är en kolvätegrupp om ïalkylgrupp om l - 4 kolatomer eller väte, Y är gruppen C00 eller gnqr pen S03, n är 0 eller l, p_är ett tal från 0 - 5 och q är l el1er'2,el. salter därav. . 1: _- a - = .-. Zzz.-._-. aan-_ ...-_ - ... m ..- _... .., \ - \ ......_.-.-.-..- ~. ~ .-. ~ .-_ _ .-: - '-.'.-'-- = - ~ = - ,.: -_-- M-äd fi- “rrrf- _ ..- v _. -.... «_._._-_._ _._..... ... , _ _.,. _ - '' ° _.7802ll »27'0 '_ 2 - an attempt has been made to solve this problem by first floating calcite at a low pH value and then increasing the alkalinity and floating the apatite with the same collector. Other anionic collectors such as alkylbenzene sulfonate, alkyl phosphate, alkyl sulfate and alkyl sulfosuccinamate have also been proposed as collectors for apatite but have not satisfactorily solved the separation problem. According to the present invention, it has now been found possible with good results to foam flotate calcium phosphate-containing minerals, such as apatite and phosphorites, using an amphoteric surfactant. This amphoteric surfactant compound can be illustrated by the general formula. R1 R - (_ou) n -I (mp - C212 - cmoa) -g C112 - E - cqnzqv 7 'l24. A ïïïïä fi for example 10 - 18 carbon atoms, each A represents an oxyalkylene group having 2 to 4 carbon atoms, R 10 is one where R is a hydrocarbon group of ïalkyl group of 1 - 4 carbon atoms or hydrogen, Y is the group C00 or g l, p_ is a number from 0 - 5 and q is l el1er'2, el. salts thereof.
Föredragna föreningar enligt uppfinningen är de, där n och q' är 1 och Rl är en metylgrupp. Speciellt föredragna är föreningar, där dessutom R är en alkylfenylgrupp, och Y betecknar gruppen C00. De fö- 'redragna föreningarna kan lätt framställas i höga utbyten under an- vändning av kommersiellt lättillgängliga och billiga utgångsproduk- ter samtidigt som de uppvisar mycket tillfredsställande flotations- egenskaper. _ Samlarreagensets hydrofila och hydrofoba del kan på i och för sig känt sätt varieras för att erhålla en lämplig hydrofil-lipofil- balans som anpassats efter den malm, som skall floteras. Vid lämpliga ' utföringsformer inom uppfinningens ram kan man t ex utan svårighet ur en malm, som endast innehåller 10 % apatit och 35 % kalcit och en lrest av silikatmineral, efter endast tre repeteringar erhålla ett koncentrat med ca 80 % apatit i ett 85-procentigt utbyte.Preferred compounds of the invention are those wherein n and q 'are 1 and R 1 is a methyl group. Particularly preferred are compounds wherein in addition R is an alkylphenyl group, and Y represents the group C00. The preferred compounds can be readily prepared in high yields using commercially available and inexpensive starting materials while exhibiting very satisfactory flotation properties. The hydrophilic and hydrophobic part of the collector reagent can be varied in a manner known per se to obtain a suitable hydrophilic-lipophilic balance adapted to the ore to be floated. In suitable embodiments within the scope of the invention, for example, a concentrate with about 80% apatite can be obtained without difficulty from an ore which contains only 10% apatite and 35% calcite and a residue of silicate mineral. exchange.
Föreningarna enligt uppfinningen kan framställas under använd- ning av välkända reaktioner. I En metod är att epoxidera en C10-C27-CK-olefin och därefter omsätta den bildade epoxiden med en förening med den allmänna formeln R H ål C H Y _ A q^2q ' .F _¿.__.--... 3 a 78-02427-0 där RI, Y och q har den ovan angivna betydelsen. Epoxideringen kan ütföfas med en organisk peroxid, t ex tertiär butylhydroperoxid eller fiefåttiksyra, vid rumstemperatur eller förhöjd temperatur. Reaktionen mellan epoxiden och föreningen A utföres vid ett neutralt eller lätt bäsiskt pH, företrädesvis mellan 7 och 10, i närvaro av ett polärt lösningsmedel. Reaktionstemperaturen ligger lämpligen inom interval- let 50 - 14006 och reaktionstiden är från ca 15 minuter till ca 3 tinnar . .Én annan metod att framställa föreningarna enligt uppfinning- en år ätt omsätta en eventuellt oxialkylerad hydroxylförening med epiklorhydrin och därefter bringa den bildade klorglyceryletern att reagera med en förening enligt A. Om så önskas kan reaktionen med fö- reningen A utbytas mot ett tvâstegsförfarande, vilket omfattar en första reaktion med ammoniak eller en primär amin med formeln -Ih c H - N - H B där RI har den ovan angivna betydelsen och en andra reaktion med en förening med den allmänna formeln ' ClCqH2qY, C där Y och q har den ovan angivna betydelsen.The compounds of the invention may be prepared using well known reactions. One method is to epoxidize a C10-C27-CK-olefin and then react the formed epoxide with a compound of the general formula RH a1 CHY _ A q ^ 2q '.F _¿ .__. - ... 3 a 78-02427-0 where RI, Y and q have the meaning given above. The epoxidation can be carried out with an organic peroxide, for example tertiary butyl hydroperoxide or acetic acid, at room temperature or elevated temperature. The reaction between the epoxide and the compound A is carried out at a neutral or slightly alkaline pH, preferably between 7 and 10, in the presence of a polar solvent. The reaction temperature is suitably in the range of 50 - 14006 and the reaction time is from about 15 minutes to about 3 hours. Another method of preparing the compounds of the invention is to react an optionally oxyalkylated hydroxyl compound with epichlorohydrin and then react the chloroglyceryl ether formed with a compound of A. If desired, the reaction of compound A can be exchanged for a two step process, which comprises a first reaction with ammonia or a primary amine of the formula -Ih c H - N - HB where R 1 has the meaning given above and a second reaction with a compound of the general formula 'ClCqH2qY, C where Y and q have the above meaning.
Reaktíonen mellan hydroxylföreningen och epiklorhydrin ut- föres vid en temperatur av ca 100 - l50°C i närvaro av en katalysa- tor. Såsom katalysator har speciellt SnCl4, BF3 och HCl04 visat Siä utmärkta ooh de ger en snabb och lätt kontrollerbar reaktion, men även andra sura katalysatorer, såsom toluensulfonsyra och svavelsyra år ânvåndbara. För att erhålla fullständig omsättning av alkoholfö- reningen tillsättes epiklorhydrin vanligtvis i överskott. Amineringen av klorglyéeryletern med den primära aminen eller ammoniak utföres i närvaro av alkali, såsom natriumhydroxid, vid en temperatur av ca 100 ~ lšögê. Vanligtvis utföres reaktionen i närvaro av ett polärt lösningsmedel, t ex vatten eller lågmolekylär alkohol, såsom metanol, etanol, monoetylenglykol, dietylenglykol, etyldietylenglykol och etyletylenglykol. Den primära eller sekundära aminens reaktion med en förening med formeln C utföres i en neutraliserad vattenlösning, Várvid reaktionátemperaturen är 50 - l0O°C och reaktionstiden ca 2 - 6 timmar. innehåller aminen kolvätegrupper och mer än 14 kolatomer »fafe-e-w- w «.- - - -jzaozuzv-o - 4 'har det visat sig.fördelaktigt att även tillsätta en glykolförening, såsom etyldietylenglykol, dels för att öka aminens löslighet dels~ för att sänka reaktionsblandningens viskositet. Hydroxylföreningen enligt uppfinningen kan utgöras av alifatiska alkoholer med 7 - 24 kolatomer och de kan vara såväl syntetiska som härledda ur naturpro- dukter. De "naturligt" härledda, de s k fettalkoholerna, framställes 'vanligtvis genom reduktion av fettsyror eller fettsyreestrar erhåll- na från vegetabiliska oljor, kokosolja, palmolja, sojaolja, linolja, majsolja eller ricinolja, animaliska oljor eller fetter, såsom fisk- olja, valolja, talg eller ister. Som exempel på lämpliga alkoholer bör följande nämnas: decylalkohol, laurylalkohol, myristylalkohol, cetylalkohol, stearylalkohol, eikosylalkohol, oleylalkohol eller ei~ kocenylalkohol. Syntetiska alkoholer framställes företrädesvis en- ligt Zieglerförfarandet eller genom Oxo-processen. De flesta medelst Oxo-processen framställda alkoholerna har en mer eller mindre grenad kolkedja, varför i detta fall ett stort antal isomerer är möjliga.The reaction between the hydroxyl compound and epichlorohydrin is carried out at a temperature of about 100-150 ° C in the presence of a catalyst. As a catalyst, SnCl4, BF3 and HClO4 in particular have shown excellent properties and give a rapid and easily controllable reaction, but other acid catalysts such as toluenesulfonic acid and sulfuric acid are also unusable. To obtain complete conversion of the alcohol compound, epichlorohydrin is usually added in excess. The amination of the chloroglyceryl ether with the primary amine or ammonia is carried out in the presence of alkali, such as sodium hydroxide, at a temperature of about 100 ° C. Usually the reaction is carried out in the presence of a polar solvent, for example water or low molecular weight alcohol, such as methanol, ethanol, monoethylene glycol, diethylene glycol, ethyl diethylene glycol and ethyl ethylene glycol. The reaction of the primary or secondary amine with a compound of formula C is carried out in a neutralized aqueous solution, the reaction temperature being 50 DEG-10 DEG C. and the reaction time about 2 to 6 hours. the amine contains hydrocarbon groups and more than 14 carbon atoms »fafe-ew- w« .- - - -jzaozuzv-o - 4 ', it has been found advantageous to also add a glycol compound, such as ethyldiethylene glycol, partly to increase the solubility of the amine and to lower the viscosity of the reaction mixture. The hydroxyl compound according to the invention may consist of aliphatic alcohols having 7 to 24 carbon atoms and they may be both synthetic and derived from natural products. The "naturally" derived so-called fatty alcohols are usually prepared by reduction of fatty acids or fatty acid esters obtained from vegetable oils, coconut oil, palm oil, soybean oil, linseed oil, corn oil or castor oil, animal oils or fats such as fish oil, whale oil, tallow or lard. Examples of suitable alcohols are the following: decyl alcohol, lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, eicosyl alcohol, oleyl alcohol or eicocenyl alcohol. Synthetic alcohols are preferably prepared according to the Ziegler process or by the Oxo process. Most alcohols produced by the Oxo process have a more or less branched carbon chain, so in this case a large number of isomers are possible.
Förutom alifatiska alkoholer kan även cykloalifatiska och framförallt aromatiska hydroxylföreningar utnyttjas som utgângspro- dukt. Lämpliga cykloalifatiska alkoholer är cyklohexanol, cyklohepta- nol, cyklooktanol, cyklododekanol och cyklohexadekanol. Av lämpliga aromatiska hydroxylföreningar bör framförallt framhållas syntetiskt framställda mono- och dialkylsubstituerade fenoler, sâsom-oktylfe- nol, nonylfenol, dodecylfenol, hexadecylfenol, dibutylfenol, dick- tylfenol och dinonylfenol. " Lämpliga monoaminer är metylamin och etylamin, vilka båda är kommersiellt tillgängliga. Föreningen med formeln C bör för erhål- lande av en snabb reaktion med den primära eller sekundära_aminerade hydroxylföreningen vara alfamonohalogenerad. Exempel på sådana före- dragna alfa-monohalogenerade föreningar är monoklorättiksyra, alfa- monoklorpopionsyra och alfa-monoklorsmörsyra samt monokloretansul- fonsyra, alfa-mcnoklorpropansulfonsyra och alfa-klorbutansulfonsyra.In addition to aliphatic alcohols, cycloaliphatic and, above all, aromatic hydroxyl compounds can also be used as starting material. Suitable cycloaliphatic alcohols are cyclohexanol, cycloheptanol, cyclooctanol, cyclododecanol and cyclohexadecanol. Of the suitable aromatic hydroxyl compounds, particular mention should be made of synthetically produced mono- and dialkyl-substituted phenols, such as octylphenol, nonylphenol, dodecylphenol, hexadecylphenol, dibutylphenol, dictylphenol and dinonylphenol. Suitable monoamines are methylamine and ethylamine, both of which are commercially available. The compound of formula C should be alpha monohalogenated to obtain a rapid reaction with the primary or secondary aminated hydroxyl compound. Examples of such preferred alpha-monohalogenated compounds are monochloroacetic acid, alpha monochloropopionic acid and alpha-monochlorobutyric acid as well as monochloroethanesulfonic acid, alpha-monochloropropanesulfonic acid and alpha-chlorobutanesulfonic acid.
AN föreningar med formeln A bör framförallt framhållas alfa-amino- föreningar, även om t ex betaaminoföreningar i princip kan användas.AN compounds of the formula A should above all be emphasized alpha-amino compounds, although, for example, beta-amino compounds can in principle be used.
Speciellt kan nämnas metylglycin, metylalanin och metylvalin samt metyltaurin; ' Den amfiotära föreningens floteranäe förmåga kan ytterligare förstärkas genom närvaro av en hydrofob-sekundärsamlare, företrädes- vis i form av en polär, vattenolöslig, hydrofob substans med affini- ...,.-... ....._. ........... .....-,--.....__..',. ..-. ..-__ _... - _. --.~.-__.«.~__...... ....-....__.._,.... .. ...__ .H .. -.._ ..- . ...__ . .-.___ ..._ --._.,.._... \ -- ------Ir..? _.. ...L S: :::-__.--.-.;.~.~.:.,....\_- < ., s 7802427-0 tet till de mineralpartiklar, som överdragits av den amfotära före- ningen. Den amfotära föreningen tillsättes vanligtvis i en halt av 50 --1000, företrädesvis 100 - 750 g per ton mineral och den po- lära, vattenolösliga, hydrofoba substansen i en mängd från 0 - 1000 g, företrädesvis 5 - 750 g per ton mineral. I det fall både den amfotära föreningen och den hydrofoba substansen användes kan förhål- 'landet dem emellan varieras inom vida gränser men det ligger vanligt-_ vis inom intervallet 1:20 - 20:l, företrädesvis 1:5 - 5:1. Den vatten- olösliga hydrofoba substansen, som enligt uppfinningen kan betecknas som en sekundärsamlare utgöres företrädesvis av en polär substans, som eventuellt lösts i ett kolväte. För att erhålla en stabil emul- sidn i vatten och en god fördelning kan man även tillsätta en konven- tionell emulgator t ex en nonjonisk ytaktiv förening, vilken i det fall den är vattenolöslig skall inräknas i den polära substansen.Mention may be made in particular of methylglycine, methylalanine and methylvaline and methyltaurine; The flotation capacity of the amine compound can be further enhanced by the presence of a hydrophobic secondary collector, preferably in the form of a polar, water-insoluble, hydrophobic substance with affine ...,.-... ....._. ........... .....-, --.....__ .. ',. ..-. ..-__ _... - _. -. ~.-__. «. ~ __...... ....-....__.._, .... .. ...__ .H .. -.._ ..-. ...__. .-.___ ..._ --._., .._... \ - ------ Ir ..? _ .. ... LS: ::: -__. - .-.;. ~. ~.:., .... \ _- <., S 7802427-0 tet to the mineral particles, which have been coated by the amphoteric association. The amphoteric compound is usually added at a level of 50-1000, preferably 100-750 g per tonne of mineral and the polar, water-insoluble, hydrophobic substance in an amount of from 0 to 1000 g, preferably 5 to 750 g per tonne of mineral. In case both the amphoteric compound and the hydrophobic substance are used, the ratio between them can be varied within wide limits, but it is usually in the range 1:20 - 20: 1, preferably 1: 5 - 5: 1. The water-insoluble hydrophobic substance, which according to the invention can be described as a secondary collector, is preferably a polar substance, which is optionally dissolved in a hydrocarbon. In order to obtain a stable emulsion in water and a good distribution, it is also possible to add a conventional emulsifier, for example a nonionic surfactant, which, in the event that it is water-insoluble, is to be included in the polar substance.
Lämpliga polära kmnponenter är vattenolösliga tvàlar såsom kalcium- tvâlar; vattenolösliga ytaktiva alkylenoxidaddukter; organiska fos- fatföreningar, såsom tributylfosfat och tri(2-etylhexyl)fosfat; och estrar av karbonsyror,sàsom tributylester och tri(2-etylhexyl)ester av Nfc-A, samt dioktylftalat. ' Vid tillämpning av förfarandet enligt uppfinningen kan man även på i och för sig känt sätt tillsätta pH-reglerande substanser samt tryckande och aktiverande substanser. I de flesta flotations- ~-° fikfarandenär pH-värdet av betydelse för erhållande av en god sepa- ' ration. Flotationsförfarandet enligt uppfinningen är också beroende av pH-värdet, vilket ger ökade möjligheter att optimera separationen av olika mineraler genom lämpligt pH. Således varierar den amfotära ytaktiva föreningens karaktär avsevärt med pH-värdet. I stark sur miljö är den övervägande katjonisk medan den i alkalisk miljö, exem- pelvis vid ett pH-värde av 10 är övervägande anjonisk. Vid separation av malm innehållande apatit och silikat eller apatit och kalcit er- hålles en god selektiv anriktning om flotationen utföres vid pH-vär- den omkring 8 - ll. Om man så anser lämpligt kan man även tillsätta 'i och för sig kända skumbildare och tryckande och aktiverande reagens.Suitable polar components are water-insoluble soaps such as calcium soaps; water-insoluble alkylene oxide adduct additives; organic phosphate compounds such as tributyl phosphate and tri (2-ethylhexyl) phosphate; and esters of carboxylic acids, such as tributyl ester and tri (2-ethylhexyl) ester of Nfc-A, and dioctyl phthalate. When applying the process according to the invention, it is also possible to add pH-regulating substances as well as pressing and activating substances in a manner known per se. In most flotation procedures, the pH value is important for obtaining a good separation. The flotation process according to the invention is also dependent on the pH value, which provides increased possibilities to optimize the separation of different minerals by suitable pH. Thus, the nature of the amphoteric surfactant compound varies considerably with the pH value. In a strongly acidic environment it is predominantly cationic while in an alkaline environment, for example at a pH value of 10 it is predominantly anionic. When separating ore containing apatite and silicate or apatite and calcite, a good selective enrichment is obtained if the flotation is carried out at pH values around 8 - 11. If deemed appropriate, it is also possible to add per se known foaming agents and pressing and activating reagents.
Några generella regler kan icke uppsättas, eftersom varje malm slut- giltigt måste behandlas med hänsyn till sin egen kemiska och fysi- kaliska sammansättning.No general rules can be set, as each ore must be finally treated with regard to its own chemical and physical composition.
Förfarandet enligt uppfinningen äskâdliggöres ytterligare av följande försök. ,. ...nwxv _' .. .....-.~........,.....--._--.. ........... .,,...... . _.. _... 7- ..-..._..,. _.._..........._............-.. . ',?so2427-o 6 -malda materialet: passerade 80 % en_sikt med maskvidden 280;nn.The process of the invention is further illustrated by the following experiments. ,. ... nwxv _ '.. .....-. ~ ........, ..... - ._-- .. ............ ,, ....... _ .. _... 7- ..-..._ ..,. _.._..........._............- ... ',? so2427-o 6 -molded material: passed 80% a sieve with a mesh size of 280; nn.
Rep: 4; -_ Exempel l _ - _ ._ En malm, innehållande 9,9 % fluorapatit, 37 % kalcit och i öv- rigt silikatmineral, krossades till ca l cm stora bitar och homoge- niserades. Av det homogeniserade materialet togs 1,00 kg ut och mal- des i_5 minuter tillsammans med 0,8 1 vatten. Vid provsiktning av det - Efter malningen slammàdes malmen upp i totalt 2,2 l vatten och hälldes upp i en mätcylinder. Efter ca 5 minuters sedimentation sögs det vatten och slam, som befann sig ovanför delstrecket i 1000 ml, av.Rep: 4; Example 1 An ore, containing 9.9% of fluorapatite, 37% of calcite and other silicate mineral, was crushed into about 1 cm large pieces and homogenized. 1.00 kg of the homogenized material was taken out and ground for 5 minutes together with 0.8 l of water. When testing it - After grinding, the ore was slurried in a total of 2.2 l of water and poured into a measuring cylinder. After about 5 minutes of sedimentation, the water and sludge, which was above the dash in 1000 ml, were sucked off.
Torrhalten i detta slam utgjorde 64 g, d v s 6,4 % av malmmängden.The dry matter content of this sludge was 64 g, i.e. 6.4% of the amount of ore.
' Av resterande 936 g-malm och vatten bereddes en pulp med to- talvolym 2 l, som konditionerades under 10 minuter i närvaro av 250 4 mg av föreningen 1 - . " + __-~ -R - öH2 - CH(0H) e CH2NHçCn3) - CHZCOC _ 1 där R är en blandning av raka och ogrenade alkylkedjor med 10 till 13 kolatomer. .Û ' . _ I Därefter genomfördes en råflotation i en 2 liters cell och _fyra repeteringar i en l liters cell med följande resultat.Of the remaining 936 g of ore and water, a pulp with a total volume of 2 l was prepared, which was conditioned for 10 minutes in the presence of 250 mg of the compound 1 -. "+ __- ~ -R - öH2 - CH (OH) e CH2NHçCn3) - CHZCOC _ 1 where R is a mixture of straight and unbranched alkyl chains with 10 to 13 carbon atoms. .Û '. _ I liter cell and _4 repetitions in a 1 liter cell with the following results.
Apatit Kalcit - övrigt_ ; x) ' 2) ^ Renhet Utbyte Renhet Utbyte 3 _ t ._ % g i Råfiøtatiøn 46,2 96,6 44,1 26,1 9,7 å Rep. 1 57,6 "94,0 38,0 17,3 4,4 5 Rep. 2 67,9 90,7 28,9 10,8 3,2 É Rep. 3 79,4 85,9 18,2 5,6 2,4 88,6 71,1 8,0 1,8 3,4 x)Utbytet är beräknat på avslammad malma _ Av resultaten framgår att samlarreagenset enligt uppfinningen har mycket god förmåga att separera apatit från kalcit vid flora- tionspulpens naturliga pH-värde, som ligger inom området 9,9 ~ 9,2.Apatite Calcite - other_; x) '2) ^ Purity Yield Purity Yield 3 _ t ._% g in Råfiøtatiøn 46.2 96.6 44.1 26.1 9.7 å Rep. 1 57.6 "94.0 38.0 17.3 4.4 5 Rep. 2 67.9 90.7 28.9 10.8 3.2 É Rep. 3 79.4 85.9 18.2 5 .6 2.4 88.6 71.1 8.0 1.8 3.4 x) The yield is calculated on slurried ore. The results show that the collector reagent according to the invention has a very good ability to separate apatite from calcite in the natural pulp of the fluorination pulp. pH value, which is in the range 9.9 ~ 9.2.
Medan förhållandet apatit/kalcit är 0,27 i den ingående malmen, är det ll efter den fjärde repeteringen.While the apatite / calcite ratio is 0.27 in the constituent ore, it is ll after the fourth repetition.
Exempel 2- .__.._@.:_._ Samma malm som i Exempel 1 krossades, homogehiserades och mal- des som i Exempel 1. _; -_ _..- :_=~_-. san-e. ..-. ...__ --... , i 7802427-0 Efter malningen bereddes en pulp av malmen och vatten med to- talvolym med 2 1 som konditionerades 5 minuter i flotationscell i när-. varo av 100 mg av föreningen _ §+ _ _ Cl6H33 - 0 - CHZCFCHZ ~ ? ~ CHZCOO ' ' OH CH3 - Därefter genomfördes en råflotation i en 2 1 cell och fyra re- peteringar i en l 1 cell. Vid behov tillsattes en skumbildare av ty- pen polypropylenglykoleter. Den sammanlagda mängden polypropylengly- koleter uppgick till 85 mg. Pulpens naturliga pH-värde var under för- söket 9,7 - 9,2. Följande resultat erhölls Apatit Kalcit övrigt Renhet Utbyte Renhet Utbyte f' % % % % % I Råflotation 35,7 88,6 42,3 27,3 22,0 - Rep. 1 46,5 87,5 43,2 21,2 10,3 Rep. 2 54,1 85,4 40,0 16,7 5,9 Rep. 3 63,8 82,7 31,1 10,5 5,1 Rep. 4 75,1 78,7 19,5 5,4 5,4 Av resultaten framgår, att efter fyra repeteringar var flota- tets apatithalt 75,1 % jämfört med 9,9 % i utgångsmalmen. Kalcithal- ten hade samtidigt sjunkit från 37 % till 5,4 % _: Qgempel 3 Samma malm som i Exempel 1 krossades, homogeniserades och mal- des som i Exempel 1.Example 2- .__.._ @.: _._ The same ore as in Example 1 was crushed, homogenized and ground as in Example 1. _; -_ _..-: _ = ~ _-. san-e. ..-. ...__ --..., in 7802427-0 After grinding, a pulp was prepared from the ore and water with a total volume of 2 l which was conditioned for 5 minutes in a flotation cell near be of 100 mg of the compound _ § + _ _ Cl6H33 - 0 - CHZCFCHZ ~? ~ CHZCOO '' OH CH3 - Then a crude flotation was performed in a 2 l cell and four repetitions in a 1 l cell. If necessary, a polypropylene glycol ether type foamer was added. The total amount of polypropylene glycols was 85 mg. The natural pH value of the pulp during the experiment was 9.7 - 9.2. The following results were obtained Apatite Calcite other Purity Yield Purity Yield f '%%%%% I Crude flotation 35.7 88.6 42.3 27.3 22.0 - Rep. 1 46.5 87.5 43.2 21.2 10.3 Rep. 2 54.1 85.4 40.0 16.7 5.9 Rep. 3 63.8 82.7 31.1 10.5 5.1 Rep. 4 75.1 78.7 19.5 5.4 5.4 The results show that after four repetitions, the fleet's appetite content was 75.1% compared with 9.9% in the starting ore. At the same time, the calcite content had dropped from 37% to 5.4%: Example 3 The same ore as in Example 1 was crushed, homogenized and ground as in Example 1.
Efter malningen bereddes en pulp och konditionerades som i Exempel 2 men med 188,5 mg av nedanstående blandning V - H _ I g _ 40 % C9Hl9 f-[:;]'-' O(C2H4O)2 “ C32 - ?H - CH2 - å - CH2COO OH C 1/ .60 i C9H19 *Û-w- 0(C2H40)2;1 Därefter genomfördes en råflotation 1 en 2 l cell och två re- peteringar i en l l cell. pä-värdet var vid försöket pulpens natur- liga, d v s 9,6 - 3,8. Efter andra repeteringen erhölls ett flotat med en apatitkcncentration av 54,9 % vid ett utbyte av 91,1 %. l.. _ l“N_W“r l-J fïsnzuzv-o se Exemgel 4 l kg av ett avfall efter magnetiskt anrikad järnmalm med ca ,8 % apatit (resterande järnmineral och silikater) maldes under 5 minuter i närvaro av 0,8 l vatten. Vid provsiktning av det malda ma- terialet passerade 80 % en sikt med maskvidden l78}mn. _ Efter malningen bereddes en pulp av malmen och vatten med to- talvolym 2 l, som konditionerades 5 minuter tillsammans med 400 mg av följande förening.After grinding, a pulp was prepared and conditioned as in Example 2 but with 188.5 mg of the following mixture V - H - I g - 40% C9H19 f - [:;] '-' O (C2H4O) 2 “C32 -? H - CH2 - å - CH2COO OH C 1 / .60 in C9H19 * Û-w- 0 (C2H40) 2; 1 Then a crude flotation 1 was performed in a 2 l cell and two repetitions in a ll cell. The pä value at the experiment was the pulp's natural, i.e. 9.6 - 3.8. After the second repetition, a fleet with an apatite concentration of 54.9% was obtained in a yield of 91.1%. l .. _ l “N_W“ r l-J fïsnzuzv-o se Exemgel 4 l kg of a waste after magnetically enriched iron ore with approx. 8% apatite (residual iron mineral and silicates) was ground for 5 minutes in the presence of 0.8 l of water. When screening the ground material for test screening, 80% passed a screen with a mesh size of 178 m. After grinding, a pulp was prepared from the ore and water with a total volume of 2 l, which was conditioned for 5 minutes together with 400 mg of the following compound.
H l _ 4- - g Cl4H29 - 9 ~ CH2?HCH2 ~ ? - CHZCHZSO3 ' ~ ' OH H Därefter genomfördes en râflotation i en 2 l cell. Följande resultat erhölls.H l _ 4- - g Cl4H29 - 9 ~ CH2? HCH2 ~? CHZCH2SO3 '~' OH H Subsequently, a crude flotation was performed in a 2 l cell. The following results were obtained.
Apatit Renhet Utbyte % % Râflotation ' 83,2 98,4 Resultaten visar att efter endast en råflotation har apatitens renhet ökat till 53,2 % vid ett utbyte av 98,4 %.Apatite Purity Yield%% Crude flotation 83.2 98.4 The results show that after only one crude flotation, the purity of the apatite has increased to 53.2% at a yield of 98.4%.
Exemgel 5 7 l kg av ett avfall efter niagnetiskt anrikad järrmñm med saznrnansät-.t- ' ning enligt tabell 1 maldes 5 minuter i närvaro av 0,8 l vatten. Av- sikten med malningen var i första hand att renskrubba minexalytorna.Sample gel 5 7 kg of a waste after magnetically enriched iron ore with a composition according to Table 1 were ground for 5 minutes in the presence of 0.8 l of water. The purpose of the grinding was primarily to scrub the minex surfaces clean.
Vid provsiktning av materialet före malning passerade.80 % en sikt med maskvidden l00¿um.During sample screening of the material before grinding, 80% passed a screen with a mesh size of l00¿um.
Tabell 1 Apafit 40 % Fe 7,4 % rez* 1,7 % s u,13 s, Kalcit 7,0 % Efter malningen bereddes en pulp av malmen och 2 l vatten.Table 1 Apafit 40% Fe 7.4% rez * 1.7% s u, 13 s, Calcite 7.0% After grinding, a pulp of the ore and 2 l of water were prepared.
Det hela konditicnerades i 30 minuter tillsammans med 800 mg av föl- jande blandning. CH I s _ N +_ _ _ o s cH2oH-n2 u- _cH¿cn2so3 on . H 3 50 % Cl4H29 - _ e' .ru u. ___.. ..«.. ... ...,..=.~....«..._..=.~ --..-.-_=.-=-=-..f~:-.=.~ ._...._.. __ 9 7802427-0 so % ' cgfllg -@-- o (cnzcuz -_o)2H _ Därefter genomfördes en râflotation och tre repeteringar i en 2 1 oell. Följande resultat erhöllsÄ Apatít Kalcit övrigt henhet Utbyte Renhet Utbyte % % % % ' % Râflotation 69,2 96,6 8,0 75,0 22,8 Rep. 1 80,5 91,7 7,5 57,9 12,0 Rep. 2 83,2 88,5 7,3 52,8 9,5 Rep. 3 _ 84,3 85,1 7,0 48,0 8,7 -' Av försöken framgår att apatiten anrikats i flotatet till en koncentration av 84,3 % vid ett utbyte av 85,1 %. Flotatets kalcit~ koncentration var däremot endast 7 %, vilket svarar mot ett utbyte av-48 %. övriga beståndsdelar har reducerats från 53 % till 8,7 %. _ ...www .wThe whole was conditioned for 30 minutes together with 800 mg of the following mixture. CH I s _ N + _ _ _ o s cH2oH-n2 u- _cH¿cn2so3 on. H 3 50% Cl4H29 - _ e '.ru u. ___ .. .. «.. ... ..., .. =. ~ ....« ..._ .. =. ~ -. .-.-_ = .- = - = - .. f ~: -. =. ~ ._...._ .. __ 9 7802427-0 so% 'cg fl lg - @ - o (cnzcuz -_o) 2H _ Then a raw flotation and three repetitions were performed in a 2 1 oell. The following results were obtained Apatite Calcite other henhet Yield Purity Yield%%%% '% Raw flotation 69.2 96.6 8.0 75.0 22.8 Rep. 1 80.5 91.7 7.5 57.9 12.0 Rep. 2,83.2 88.5 7.3 52.8 9.5 Rep. 84.3 85.1 7.0 48.0 8.7 - The experiments show that the apatite is enriched in the fleet to a concentration of 84.3% at a yield of 85.1%. The calcite concentration of the fleet, on the other hand, was only 7%, which corresponds to a yield of -48%. other components have been reduced from 53% to 8.7%. _ ... www .w
Claims (8)
Priority Applications (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE7802427A SE409291B (en) | 1978-03-03 | 1978-03-03 | PROCEDURE FOR PHOSPHATE-MINERAL FOAM FLOATING |
| IL56668A IL56668A (en) | 1978-03-03 | 1979-02-14 | Process for froth flotation of phosphate containing minerals and collector compounds therefor |
| YU409/79A YU39861B (en) | 1978-03-03 | 1979-02-20 | Process for foam-flotation of calcium phosphate containing minerals |
| MX176721A MX150982A (en) | 1978-03-03 | 1979-02-26 | IMPROVEMENTS IN THE FLOATING METHOD OF MINERALS CONTAINING CALCIUM PHOSPHATE |
| ZA79902A ZA79902B (en) | 1978-03-03 | 1979-02-26 | "froth flotation process of phosphate containing minerals and compounds" |
| IN186/CAL/79A IN150769B (en) | 1978-03-03 | 1979-03-01 | |
| FI790725A FI63527C (en) | 1978-03-03 | 1979-03-02 | FOERFARANDE FOER SKUMFLOTATION AV FOSFATHALTIGT MINERAL SAMT MEDEL DAERFOER |
| BR7901288A BR7901288A (en) | 1978-03-03 | 1979-03-02 | FLOATING PROCESS WITH MINING FOAM CONTAINING PHOSPHATE |
| AU44764/79A AU524935B2 (en) | 1978-03-03 | 1979-03-02 | Froth flotation process |
| CA322,738A CA1129437A (en) | 1978-03-03 | 1979-03-05 | Process for the froth flotation of calcium phosphate-containing minerals and flotation agents therefor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SE7802427A SE409291B (en) | 1978-03-03 | 1978-03-03 | PROCEDURE FOR PHOSPHATE-MINERAL FOAM FLOATING |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SE409291B true SE409291B (en) | 1979-08-13 |
Family
ID=20334173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SE7802427A SE409291B (en) | 1978-03-03 | 1978-03-03 | PROCEDURE FOR PHOSPHATE-MINERAL FOAM FLOATING |
Country Status (10)
| Country | Link |
|---|---|
| AU (1) | AU524935B2 (en) |
| BR (1) | BR7901288A (en) |
| CA (1) | CA1129437A (en) |
| FI (1) | FI63527C (en) |
| IL (1) | IL56668A (en) |
| IN (1) | IN150769B (en) |
| MX (1) | MX150982A (en) |
| SE (1) | SE409291B (en) |
| YU (1) | YU39861B (en) |
| ZA (1) | ZA79902B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017162563A2 (en) | 2016-03-22 | 2017-09-28 | Akzo Nobel Chemicals International B.V. | Use of emulsifier in collector composition |
| US10376901B2 (en) | 2014-09-18 | 2019-08-13 | Akzo Nobel Chemicals International B.V. | Use of branched alcohols and alkoxylates thereof as secondary collectors |
-
1978
- 1978-03-03 SE SE7802427A patent/SE409291B/en not_active IP Right Cessation
-
1979
- 1979-02-14 IL IL56668A patent/IL56668A/en unknown
- 1979-02-20 YU YU409/79A patent/YU39861B/en unknown
- 1979-02-26 ZA ZA79902A patent/ZA79902B/en unknown
- 1979-02-26 MX MX176721A patent/MX150982A/en unknown
- 1979-03-01 IN IN186/CAL/79A patent/IN150769B/en unknown
- 1979-03-02 BR BR7901288A patent/BR7901288A/en unknown
- 1979-03-02 FI FI790725A patent/FI63527C/en not_active IP Right Cessation
- 1979-03-02 AU AU44764/79A patent/AU524935B2/en not_active Expired
- 1979-03-05 CA CA322,738A patent/CA1129437A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10376901B2 (en) | 2014-09-18 | 2019-08-13 | Akzo Nobel Chemicals International B.V. | Use of branched alcohols and alkoxylates thereof as secondary collectors |
| WO2017162563A2 (en) | 2016-03-22 | 2017-09-28 | Akzo Nobel Chemicals International B.V. | Use of emulsifier in collector composition |
Also Published As
| Publication number | Publication date |
|---|---|
| FI63527C (en) | 1983-07-11 |
| YU40979A (en) | 1983-01-21 |
| YU39861B (en) | 1985-04-30 |
| FI63527B (en) | 1983-03-31 |
| BR7901288A (en) | 1979-11-20 |
| AU524935B2 (en) | 1982-10-14 |
| IN150769B (en) | 1982-12-11 |
| IL56668A (en) | 1983-02-23 |
| ZA79902B (en) | 1980-02-27 |
| FI790725A (en) | 1979-09-04 |
| MX150982A (en) | 1984-09-04 |
| CA1129437A (en) | 1982-08-10 |
| IL56668A0 (en) | 1979-05-31 |
| AU4476479A (en) | 1979-09-06 |
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