SE126764C1 - - Google Patents

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Publication number
SE126764C1
SE126764C1 SE126764DA SE126764C1 SE 126764 C1 SE126764 C1 SE 126764C1 SE 126764D A SE126764D A SE 126764DA SE 126764 C1 SE126764 C1 SE 126764C1
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SE
Sweden
Prior art keywords
stub line
line according
safety
compound
safety stub
Prior art date
Application number
Other languages
Swedish (sv)
Publication date
Publication of SE126764C1 publication Critical patent/SE126764C1/sv

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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/20Poisoning, narcotising, or burning insects
    • A01M1/2022Poisoning or narcotising insects by vaporising an insecticide
    • A01M1/2061Poisoning or narcotising insects by vaporising an insecticide using a heat source
    • A01M1/2066Poisoning or narcotising insects by vaporising an insecticide using a heat source burning insecticide, e.g. impregnated candles, burning coils
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/18Vapour or smoke emitting compositions with delayed or sustained release
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/20Combustible or heat-generating compositions
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N29/00Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
    • A01N29/10Halogen attached to an aliphatic side chain of an aromatic ring system
    • A01N29/121,1-Di- or 1,1,1-trihalo-2-aryl-ethane or -ethene or derivatives thereof, e.g. DDT
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/10Pentachlorophenol

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  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Plant Pathology (AREA)
  • Toxicology (AREA)
  • Insects & Arthropods (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Description

Uppfinnare: E. Tones oeh J. S. Flanders. Inventor: E. Tones oeh J. S. Flanders.

Priorilet begard frdn, den 19 april 1945 (Storbritannien). Priorilet begd frdn, 19 April 1945 (Great Britain).

Foreliggande uppfinning hanfor sig till rOkning med pesticida foreningar, varmed avses foreningar for utrotande av skadliga eller icke onskvarda djur, vOxter och svampar, och isynnerhet till astadkommandet av forenklade eller forbattrade medel far den termiska framstallningen av Talc eller angor av pesticida foreningar, som kunna forAngas vid lãmplig uppphettning. Uppfinningen är sdrskin vardefull for andamdlet att roka med brannbara pesticida fOreningar eller pesticida foreningar som latt sdnderdelas vid overhettfling. Uppfinningen underlattar exempelvis den ekonomiska framstdilningen av en riik, som bestar av en aerosol av den kondenserade fingan av en pesticid forening, som kan utfallas pit begransuingsytorna i ett slutet rum, i vilket Token alstras, for att astadkomma ett tunt skikt av den pesticida foreningen, som fOrblir verksamt langt efter att atmosfdren har blivit fri frail den verksamma roken. The present invention relates to smoking with pesticidal compounds, by which is meant compounds for the eradication of harmful or undesirable animals, plants and fungi, and in particular to the provision of simplified or improved agents for the thermal production of talc or pesticide compounds which can be in case of suitable heating. The invention is particularly valuable for the spirit of smoking with flammable pesticidal compounds or pesticidal compounds which are readily decomposed in the event of overheating. The invention facilitates, for example, the economical production of a rich, which consists of an aerosol of the condensed finger of a pesticidal compound, which can be deposited in the confinement surfaces of a closed space in which Token is generated, to provide a thin layer of the pesticidal compound. which remains active long after the atmosphere has become free frail the active smoke.

Ett exempel pa en pesticid, som kan bilda ett sadant skikt, nar en lamplig rokningsmetod anvandes for forangningen, Or den kraftiga insekticiden a,a-di-(para-klorfeny1)-)3,p,,6- trikloretan. Ett annat ex.empel Or den annu kraftigare insekticiden 7,-hexak1orcyklohexan, som kan pd.foras i form av en rok genom forangning fran varma platar eller genom andra upphettningsmetoder. Det har tidigare beskriTits en metod for rokning an ett slutet rum for bekampning ay skadedjur, vilket bestar i behandling av rummet med en aerosol innehallande hexaklorcyklohexan. An example of a pesticide which can form such a layer when a suitable smoking method is used for the evaporation is the strong insecticide a, a-di- (para-chlorophenyl) -) 3, p ,, 6-trichloroethane. Another example is the even more powerful insecticide 7, hexahlorocyclohexane, which can be introduced in the form of a smoke by evaporation from hot plates or by other heating methods. A method of smoking in a closed room for pest control has previously been described, which consists in treating the room with an aerosol containing hexachlorocyclohexane.

Ett brannbart rokljus, likadant som det vanliga svavelljuset, skulle vara ett mycket lampligt medel for framstallning av rok an en fOrangad pesticid forening, men yid inanga pesticider skulle det icke vara mojligt att framstalla ett ljts, i vilket en pesticid indrages i en laga for att forfingas, emedan pesticiden darvid skulle sonderdelas eller forbrannas under bildning am oanvandbara sdnder delnings- eller forbranningsprodukter, medan vid anvandning ay svavelljuset det aktiva materialet Or den vid svavlets fdrbranning bildade svaveldioxiden. A flammable smoke candle, like the usual sulfur candle, would be a very suitable means of producing smoke from a preferred pesticide compound, but in the case of pesticides it would not be possible to produce a candle in which a pesticide is incorporated into a law to refined, because the pesticide would thereby be probed or incinerated during the formation of unusable subdivision or combustion products, while when used in the sulfur candle the active material Or the sulfur dioxide formed during the sulfur combustion.

Enligt foreliggande uppfinning bestar medlet for termisk framstallning am rok ay den terrniskt forangningsbara pesticida foreningen av en sAkerhetsstubintrad, marl ett eller flera av overdragen av textilgarn omkring den brannbara kdrnan Or overdraget eller impregnerat med pesticiden, och den pesticida foreningen Or foretrd.desvis skyddad frail direkt kontakt med den pulverformiga karnan med alminstone ett fullstandigt skikt ay textiloverdraget. Den anvanda pesticida foreningen kan exempelvis vara en fast forming ay organisk natur, t. ex. hekaklorcyklohexan eller ett klorerat aromatiskt kolvatederivat. Den pulverformiga karnan i sakerhetsstubintrOden omfattar foretradesvis material, sona lainnar gasformiga forbranningsprodukter vid forbranningen, t. ex. en krutblandning, som lampligen icke innehaller svavel. According to the present invention, the means for thermal production consists in the thermally evaporable pesticidal compound of a safety stub row, but one or more of the coatings of textile yarn around the combustible core is coated or impregnated with the pesticide, and the pesticidal compound is preferably protected frail. contact with the powdered karnan with at least one complete layer ay the textile coating. The pesticidal compound used may, for example, be a solid forming an organic nature, e.g. hecachlorocyclohexane or a chlorinated aromatic hydrocarbon derivative. The powdered core of the safety tubing preferably comprises materials, such as gaseous combustion products during combustion, e.g. a powder mixture, which suitably does not contain sulfur.

Uttrycket »brannbar karnaD omf attar Oven en samrnanhangande, tat, genom utpressning bildad lthrna ay plastiskt material med en brannbar blandning ay pulverformiga oxidations- och reduktionsmedel, t. ex. nitrater sit-soul qempelvis kaliumnitrat, oxider sasom monja, permanganate; klorater och kromater samt oxiderbara metaller, sasom Si, eller metallegeringar, icke-metalliska element, sill-cider, trakol och dylikt. The term "combustible core" also includes a cohesive, dense, extruded film of plastic material with a combustible mixture of powdered oxidizing and reducing agents, e.g. sit-soul nitrates, for example potassium nitrate, oxides such as monja, permanganate; chlorates and chromates as well as oxidizable metals, such as Si, or metal alloys, non-metallic elements, herring-ciders, trachols and the like.

Traden, som omfattar den pulverformiga karnan och ett textiloverdrag, antingen det som Or i omedelbar kontakt med karnan eller ett annat, eller mera On ett av textiloverdragen kan overdragas med en pasta, som bestar ay den pulverformiga pesticiden och ett bindemedel, eller ocksa kan den ledas genom den smalta pesticiden eller en losning an pesticiden och dragas genom en matris. The trade, which comprises the powdered karnan and a textile coating, either as Or in immediate contact with the karnan or another, or more On one of the textile coatings may be coated with a paste consisting of the powdered pesticide and a binder, or it may passed through the narrow pesticide or a solution of the pesticide and drawn through a matrix.

NOT sdkerhetsstubintraden brinner, forelig- 2— — ger det en zon, som kryper utefter textiloverdraget i forvag fore den verksamma forbranningsytan hos karnan och som kommer att -Vara vid en temperatur, som är tillracklig for att foranga pesticiden. Salunda aro betingel§erna fordelaktiga for forangningen av pesticiden i atmoslaren utan verksam kontakt mellan denna och den annalkande vitglodande forbranningsytan av den pulverformiga karnan. Expansionen utal av de gasformiga forbranningsprodukterna av den pulverf ormiga karnart och/eller det uppburna textilskiktet i omedelbar kontakt damned genomtranga Vidare det med pesticiden forsedda textiloverdraget och astadkommas stromningar i atmosfaren omedelbart omkring stubinen, varigenom dispergeringen av pesticidangorna beframj as. NOT the safety tube line burns, there is a zone which creeps along the textile cover in front of the active combustion surface of the karnan and which will be at a temperature which is sufficient to evaporate the pesticide. Thus, the conditions are favorable for the evaporation of the pesticide into the atmosphere without effective contact between it and the approaching white-glowing combustion surface of the powdered core. The expansion of the gaseous combustion products of the powdered karnart and / or the supported textile layer in immediate contact dam penetrates. Furthermore, the textile coating provided with the pesticide and flows in the atmosphere are effected immediately around the stub, thereby preventing the dispersion of the pesticide vapors.

Uppfinningen fortydligas av foljande exempel i vilka angivna proeenthalter aro viktsprocent. The invention is illustrated by the following examples in which the stated percentages are by weight.

Exempel 1. Example 1.

En oimpregnerad stubin, som framstallts pa kant satt genom spinning av ett averdrag av jutegarn (2420 m/kg) och ett annat Over-drag ay bomullsgarn ay 3 tradar a 20316 in/ kg omkring en svavelfri krutkarna, overdrogs med en insekticid fernissa av foljande sammansattning. An unimpregnated stub, produced on the edge set by spinning a cover of jute yarn (2420 m / kg) and another coating of cotton yarn of 3 threads of 20316 in / kg around a sulfur-free gunpowder, was coated with an insecticidal varnish of the following composition.

Kaolin 13,7 % .a, a-di- (para-klorf eny1)-p,A18-tri- kloretan 54,% Djurlim 4,3 % Vatten 27,3 % Efter paforing av denna fernissa fordes den halvfardiga stubintraden genom en matris och torkades. Ett Overdrag av bomullsgarn (10 spolar 6 tradar om 50750 m/kg) pafordes darefter, varefter man paforde ett sista over-drag ay en vitfargad fernissa av foljande sammansattning, yarefter stubinen f8rdes genom en matris och torkades: Kaolin 60,6 % Djurlim 12,3 % Vatten 27,3 % Vikten av den pesticida foreningen per lot av den resulterande stubinen var ungefar 0,5 g. Stubinen brinner utan att kasta gnistor at sidorna med en. hastighet av omkring 2 lot per minut och spricler effektivt den insektieida angan. Kaolin 13.7% .a, α-di- (para-chlorophenyl) -p, A18-trichloroethane 54,% Animal glue 4.3% Water 27.3% After coating this varnish, the semi-finished stub line was passed through a matrix and dried. A coating of cotton yarn (10 spools 6 threads of 50750 m / kg) was then applied, after which a final coating was applied to a white varnish of the following composition, after which the tube was passed through a matrix and dried: Kaolin 60.6% Animal glue 12 .3% Water 27.3% The weight of the pesticidal compound per lot of the resulting stub was about 0.5 g. The stub burns without throwing sparks at the sides with a. speed of about 2 lots per minute and effectively sprays the insect-free odor.

Exempel 2. Example 2.

Forfaringssattet var detsamma som i exempel 1 med undantag av att man i den insektieida fernissan i stallet f Or a,a-di-(para-klorfeny1)-p,p,fi-trikloretanen an-vande samman mangd av y-hexakloreyklohexan. Den resulterande sakerhetsstubintraden brann pa likhalide satt som den enligt exempel 1 fram stallda stubinen och utstrodde effekti4 de in.sekticida angorna. The procedure was the same as in Example 1 except that in the insecticidal varnish in the stable of Or a, α-di- (para-chlorophenyl) -p, p, f-trichloroethane the amount of γ-hexachloroyclohexane was used together. The resulting safety stub row burned on the likhalide set as the stub prepared according to Example 1 and spread the effect of the insecticidal fumes.

Exempel 3. Example 3.

En homogen blandning av 80 delar pulverformiga bestandsdelar, bestaende av 70 delar monja, 30 delar kaliumnitrat och 20 delar kisel med 20 delar av ett termopla§tiskt bindemedel, bestaende av 50 delar nitrobomull, 48 delar dibutylftalat och 2 delar difenylamin, framstalles pa foljande att. Kiseln inarbetas i det termoplastiska bindemedlet i en angmantlad Werner-Pfleiderer blandningsmaskin yid en temperatur av omkring 100° C, tills den Sr val fordelad i det plastiska materialet. Monj an och.kaliumnitratet inarbetas i det plastiska materialet i tva steg. Bearbetningen I maskinen fortsattes, tills monjeblandningen Sr val fordelad och blandningen har en sammanhangande plastisk konsistens. Den resulterande blandningen utpressas omkring en koppartrad av 0,193 mm diameter, sâ att diametern hos den utpressade kiirnan ar 1,22 mm. A homogeneous mixture of 80 parts of powdered constituents, consisting of 70 parts of monja, 30 parts of potassium nitrate and 20 parts of silicon with 20 parts of a thermoplastic binder, consisting of 50 parts of nitro cotton, 48 parts of dibutyl phthalate and 2 parts of diphenylamine, is prepared as follows: . The silicon is incorporated into the thermoplastic binder in a steam-coated Werner-Pfleiderer mixing machine at a temperature of about 100 ° C, until the Sr choice is distributed in the plastic material. The monj an and the potassium nitrate are incorporated into the plastic material in two steps. The processing in the machine was continued, until the monje mixture Sr selection is distributed and the mixture has a coherent plastic consistency. The resulting mixture is extruded about a copper row of 0.193 mm diameter, so that the diameter of the extruded core is 1.22 mm.

Den salunda utpressade karnan omges med ett overdrag av jutegarn, atfoljt av ett bornullsoverdrag. The thus extruded karnan is surrounded by a coating of jute yarn, followed by a borne wool coating.

Denna oimpregnerade stubin overdrages med en insektieid fernissa med foljande sammansattning: Kaolin a, a-di- (para-klorf enyl) -18,13,fi-tri- kloretan 13,7 54,4 % % Djurlim 4,% Vatten 27,3 % Efter paforingen av denna fernissa behandlas den halvfardiga stubintraden sasom i exempel 1. This impregnated stub is coated with an insect varnish with the following composition: Kaolin α, α-di- (para-chlorophenyl) -18.13, fi-trichloroethane 13.7 54.4%% Animal glue 4,% Water 27, 3% After the paving of this varnish, the semi-finished stubble row is treated as in Example 1.

Den resulterande sakerhetsstubintraden brinner pa samma satt som den enligt exempel 1 framstallda stubinen och sprider effektiyt den insekticida foreningen. The resulting safety stubble row burns in the same manner as the stub prepared according to Example 1 and effectively spreads the insecticidal compound.

Exempel 4. Example 4.

Forfaringssattet var detsanima som i exempel 1 med undantag av att fernissan innehod fungiciden pentaklorfenol i stallet for ins ekticiden a,a-di (para-klorf enyl ) -A/3,134Hkloretan. Den resulterande sakerhetsstubintraden brann pa samma satt som den enligt exempel 1 framstallda stubintraden och ut- spred effektivt den fungicida f8reningen. The procedure was the same as in Example 1 except that the varnish contained the fungicide pentachlorophenol instead of the insecticide α, α-di (para-chlorophenyl) -A / 3,134H-chloroethane. The resulting safety stub row burned in the same manner as the stub row prepared according to Example 1 and effectively dispersed the fungicidal compound.

Claims (9)

Patentansprak:Patent claim: 1. Sakerhetsstubintrad, i vilken ett eller flera av textilgarnsoverdragen onikring den brannbara karnan Oro 8verdragna eller impregnerade med en termiskt forangningsbar pesticid forening.Safety stub line, in which one or more of the textile yarn coatings onyx the combustible core Oro 8 are coated or impregnated with a thermally evaporable pesticide compound. 2. Sakerhetsstubintrad enligt patentanspraket 1, kanneteeknad daray, att foreningen Or — —3 skyddad Iran direkt kontakt med den brdnnbara karnan genom atminstone ett fullstandigt skikt av textiloverdraget.2. A security stub line according to patent claim 1, characterized in that the association Or - —3 protected Iran in direct contact with the combustible core through at least one complete layer of the textile cover. 3. Sakerhetsstubintrad enligt patentan.spraket 2, kannetecknad &ray, att den pesticida foreningen är en fast forening av organisk natur.3. The safety stub line according to patent claim 2, can be stated & ray, that the pesticidal compound is a solid compound of organic nature. 4. Sakerhetsstubintrad enligt patentansprdket 3, kanneteeknad darav, att den fasta foreningen av organisk natur ãr y-hexaklorcyklohexan.4. A safety stub line according to claim 3, characterized in that the solid compound of organic nature is γ-hexachlorocyclohexane. 5. Sdkerhetsstubintrad enligt patentanspraket 3, kannetecknad darav, att den fasta foreningen av organisk natur är ett klorerat aromatiskt klorvdtederivat.The safety stub line according to patent claim 3, characterized in that the solid compound of organic nature is a chlorinated aromatic chlorine derivative. 6. Sakerhetsstubintrad enligt nagot av de foregaende patentanspraken, kannetecknad ddrav, att den brannbara karnan till sakerhetsstubintraden innehdller material, som lamina gasformiga forbranningsprodukter vid forbrdnningen.Safety stub line according to one of the preceding patent claims, characterized in that the combustible core of the safety stub line contains materials which laminate gaseous combustion products during combustion. 7. Sakerhetsstubintrad enligt patentansprdlet 6, kdnnetecknad ddrav, aft den brannbara karnan är en krutblandning.7. A safety stub line according to claim 6, characterized in that the combustible core is a powder mixture. 8. Sakerhetsstubintrad enligt patentanspraket 7, kannetecknad ddrav, att krutblandningen ãr fri fran svavel.A safety stub line according to claim 7, characterized in that the powder mixture is free of sulfur. 9. Sdkerhetsstubintrad enligt nagot av de foreghende patentanspraken, kannetecknad ddrav, att ett eller flera .av textiloverdragen besta av garn, som forsetts med ett overdrag, t. ex. i form av en pasta, smdlta eller losning, av den pesticida foreningen och ett bindemedel, och dragits genom en matris. Stockholm 1919. Kung,I. Poktr. P. A. Norstedt & &bier 4900899. A safety stub line according to any one of the preceding patent claims, characterized in that one or more of the textile covers consist of yarn, which is continued with a cover, e.g. in the form of a paste, smelt or solution, of the pesticidal compound and a binder, and drawn through a matrix. Stockholm 1919. Kung, I. Poktr. P. A. Norstedt & & beer 490089
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