SA06270109B1 - عملية لتكرير مسبق لزيت خام مع تحول مائي متوسط متعدد الخطوة لأسفلت أولي في وجود مادة تخفيف - Google Patents
عملية لتكرير مسبق لزيت خام مع تحول مائي متوسط متعدد الخطوة لأسفلت أولي في وجود مادة تخفيف Download PDFInfo
- Publication number
- SA06270109B1 SA06270109B1 SA06270109A SA06270109A SA06270109B1 SA 06270109 B1 SA06270109 B1 SA 06270109B1 SA 06270109 A SA06270109 A SA 06270109A SA 06270109 A SA06270109 A SA 06270109A SA 06270109 B1 SA06270109 B1 SA 06270109B1
- Authority
- SA
- Saudi Arabia
- Prior art keywords
- oil
- asphalt
- weight
- asphaltenic
- conversion
- Prior art date
Links
- 239000010426 asphalt Substances 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 54
- 238000007670 refining Methods 0.000 title claims abstract description 23
- 239000003085 diluting agent Substances 0.000 title claims abstract description 16
- 239000010779 crude oil Substances 0.000 title abstract description 13
- 239000003921 oil Substances 0.000 claims abstract description 114
- 238000006243 chemical reaction Methods 0.000 claims abstract description 68
- 238000004517 catalytic hydrocracking Methods 0.000 claims abstract description 33
- 238000004821 distillation Methods 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 29
- 239000000047 product Substances 0.000 claims description 29
- 238000011282 treatment Methods 0.000 claims description 23
- 150000001875 compounds Chemical class 0.000 claims description 20
- 229910052717 sulfur Inorganic materials 0.000 claims description 20
- 239000011593 sulfur Substances 0.000 claims description 20
- 238000009835 boiling Methods 0.000 claims description 14
- 239000000463 material Substances 0.000 claims description 14
- 239000005864 Sulphur Substances 0.000 claims description 10
- 238000005194 fractionation Methods 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 238000009903 catalytic hydrogenation reaction Methods 0.000 claims description 4
- 230000005587 bubbling Effects 0.000 claims description 3
- 230000004907 flux Effects 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 239000006227 byproduct Substances 0.000 claims description 2
- 241001136792 Alle Species 0.000 claims 1
- 102100026933 Myelin-associated neurite-outgrowth inhibitor Human genes 0.000 claims 1
- 230000003014 reinforcing effect Effects 0.000 claims 1
- 230000009466 transformation Effects 0.000 abstract description 3
- 239000003054 catalyst Substances 0.000 description 34
- 229910052751 metal Inorganic materials 0.000 description 25
- 239000002184 metal Substances 0.000 description 25
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 17
- 239000007789 gas Substances 0.000 description 17
- 239000000543 intermediate Substances 0.000 description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 13
- 229910052739 hydrogen Inorganic materials 0.000 description 13
- 239000001257 hydrogen Substances 0.000 description 13
- 239000000203 mixture Substances 0.000 description 13
- 239000000446 fuel Substances 0.000 description 11
- 150000002739 metals Chemical class 0.000 description 11
- 230000003197 catalytic effect Effects 0.000 description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- 238000005336 cracking Methods 0.000 description 7
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000003502 gasoline Substances 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 5
- 238000005984 hydrogenation reaction Methods 0.000 description 5
- 239000003350 kerosene Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000011324 bead Substances 0.000 description 4
- 239000001273 butane Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000011733 molybdenum Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000003208 petroleum Substances 0.000 description 4
- 239000011148 porous material Substances 0.000 description 4
- 239000012429 reaction media Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000000295 fuel oil Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 239000001294 propane Substances 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 229910003294 NiMo Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- FSBJPVVVJGASBG-UHFFFAOYSA-N hexane pentane Chemical compound CCCCC.CCCCCC.CCCCCC FSBJPVVVJGASBG-UHFFFAOYSA-N 0.000 description 2
- 239000000852 hydrogen donor Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000010517 secondary reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 241001501536 Alethe Species 0.000 description 1
- 208000019901 Anxiety disease Diseases 0.000 description 1
- 229910020598 Co Fe Inorganic materials 0.000 description 1
- 206010011878 Deafness Diseases 0.000 description 1
- 101150105088 Dele1 gene Proteins 0.000 description 1
- 239000005569 Iron sulphate Substances 0.000 description 1
- 241000234435 Lilium Species 0.000 description 1
- 229910015202 MoCr Inorganic materials 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- PFRUBEOIWWEFOL-UHFFFAOYSA-N [N].[S] Chemical compound [N].[S] PFRUBEOIWWEFOL-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 208000002399 aphthous stomatitis Diseases 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- HOWJQLVNDUGZBI-UHFFFAOYSA-N butane;propane Chemical compound CCC.CCCC HOWJQLVNDUGZBI-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002169 hydrotherapy Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000036512 infertility Effects 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- PTISTKLWEJDJID-UHFFFAOYSA-N sulfanylidenemolybdenum Chemical compound [Mo]=S PTISTKLWEJDJID-UHFFFAOYSA-N 0.000 description 1
- XCUPBHGRVHYPQC-UHFFFAOYSA-N sulfanylidenetungsten Chemical compound [W]=S XCUPBHGRVHYPQC-UHFFFAOYSA-N 0.000 description 1
- -1 sulfur metals Chemical class 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
- 238000000844 transformation Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/14—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only
- C10G65/18—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural parallel stages only including only cracking steps
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
- C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
- C10G67/04—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including solvent extraction as the refining step in the absence of hydrogen
- C10G67/0454—Solvent desasphalting
- C10G67/049—The hydrotreatment being a hydrocracking
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0504300A FR2885134B1 (fr) | 2005-04-28 | 2005-04-28 | Procede de prerafinage de petrole brut avec hydroconversion moderee en plusieurs etapes de l'asphalte vierge en presence de diluant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SA06270109B1 true SA06270109B1 (ar) | 2010-02-02 |
Family
ID=35677627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SA06270109A SA06270109B1 (ar) | 2005-04-28 | 2006-04-24 | عملية لتكرير مسبق لزيت خام مع تحول مائي متوسط متعدد الخطوة لأسفلت أولي في وجود مادة تخفيف |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20080289999A1 (ru) |
| CA (1) | CA2607443A1 (ru) |
| FR (1) | FR2885134B1 (ru) |
| RU (1) | RU2412978C2 (ru) |
| SA (1) | SA06270109B1 (ru) |
| WO (1) | WO2006114489A1 (ru) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2854163B1 (fr) * | 2003-04-25 | 2005-06-17 | Inst Francais Du Petrole | Procede de valorisation de charges lourdes par desasphaltage et hydrocraquage en lit bouillonnant |
| EP2234710A2 (en) | 2007-11-28 | 2010-10-06 | Saudi Arabian Oil Company | Process for catalytic hydrotreating of sour crude oils |
| US8372267B2 (en) | 2008-07-14 | 2013-02-12 | Saudi Arabian Oil Company | Process for the sequential hydroconversion and hydrodesulfurization of whole crude oil |
| EP2300566B1 (en) * | 2008-07-14 | 2016-09-07 | Saudi Arabian Oil Company | Process for the treatment of heavy oils using light hydrocarbon components as a diluent |
| WO2011005476A2 (en) * | 2009-06-22 | 2011-01-13 | Saudi Arabian Oil Company | Alternative process for the treatment of heavy crudes in a coking refinery |
| US8540870B2 (en) * | 2009-06-25 | 2013-09-24 | Uop Llc | Process for separating pitch from slurry hydrocracked vacuum gas oil |
| US8202480B2 (en) * | 2009-06-25 | 2012-06-19 | Uop Llc | Apparatus for separating pitch from slurry hydrocracked vacuum gas oil |
| US8231775B2 (en) | 2009-06-25 | 2012-07-31 | Uop Llc | Pitch composition |
| US8568583B2 (en) * | 2009-12-28 | 2013-10-29 | James J. Colyar | High conversion partial upgrading process |
| US8597495B2 (en) * | 2010-02-12 | 2013-12-03 | IFP Energies Nouvelles | Partial uprading utilizing solvent deasphalting and DAO hydrocracking |
| KR101779605B1 (ko) * | 2010-06-04 | 2017-09-19 | 에스케이이노베이션 주식회사 | 감압증류된 탈아스팔트유를 이용한 윤활기유 제조방법 |
| RU2510643C2 (ru) * | 2011-10-07 | 2014-04-10 | Общество с ограниченной ответственностью "ЛУКОЙЛ-Нижегородский научно-исследовательский и проектный институт по переработке нефти ООО "ЛУКОЙЛ-Нижегородниинефтепроект" | Способ переработки битуминозных нефтей |
| US9150470B2 (en) | 2012-02-02 | 2015-10-06 | Uop Llc | Process for contacting one or more contaminated hydrocarbons |
| GB2505864B (en) * | 2012-07-06 | 2019-04-24 | Statoil Canada Ltd | A method and system of recovering and processing a hydrocarbon mixture from a subterranean formation |
| RU2698807C2 (ru) * | 2014-12-17 | 2019-08-30 | Хальдор Топсеэ А/С | Способ конверсии углеводородного потока |
| CA2993442A1 (en) * | 2015-07-24 | 2017-02-02 | Exxonmobil Research And Engineering Company | Fixed bed hydroprocessing of deasphalter rock |
| WO2019104243A1 (en) * | 2017-11-21 | 2019-05-31 | Chevron U.S.A. Inc. | Process and system for upgrading hydrocracker unconverted heavy oil |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL7610511A (nl) * | 1976-09-22 | 1978-03-28 | Shell Int Research | Werkwijze voor het omzetten van koolwater- stoffen. |
| US4698146A (en) * | 1986-01-23 | 1987-10-06 | Uop Inc. | Hydrocracking and recovering polynuclear aromatic compounds in slop wax stream |
| US7214308B2 (en) * | 2003-02-21 | 2007-05-08 | Institut Francais Du Petrole | Effective integration of solvent deasphalting and ebullated-bed processing |
-
2005
- 2005-04-28 FR FR0504300A patent/FR2885134B1/fr active Active
-
2006
- 2006-03-24 RU RU2007144060/04A patent/RU2412978C2/ru active
- 2006-03-24 WO PCT/FR2006/000672 patent/WO2006114489A1/fr active Application Filing
- 2006-03-24 CA CA002607443A patent/CA2607443A1/fr not_active Abandoned
- 2006-03-24 US US11/912,774 patent/US20080289999A1/en not_active Abandoned
- 2006-04-24 SA SA06270109A patent/SA06270109B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR2885134A1 (fr) | 2006-11-03 |
| RU2412978C2 (ru) | 2011-02-27 |
| CA2607443A1 (fr) | 2006-11-02 |
| RU2007144060A (ru) | 2009-06-10 |
| US20080289999A1 (en) | 2008-11-27 |
| FR2885134B1 (fr) | 2008-10-31 |
| WO2006114489A1 (fr) | 2006-11-02 |
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