RU98114867A - CHARGED ION EXCHANGE RESINS, METHODS FOR PRODUCING AND THEIR APPLICATION - Google Patents

CHARGED ION EXCHANGE RESINS, METHODS FOR PRODUCING AND THEIR APPLICATION

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Publication number
RU98114867A
RU98114867A RU98114867/12A RU98114867A RU98114867A RU 98114867 A RU98114867 A RU 98114867A RU 98114867/12 A RU98114867/12 A RU 98114867/12A RU 98114867 A RU98114867 A RU 98114867A RU 98114867 A RU98114867 A RU 98114867A
Authority
RU
Russia
Prior art keywords
ion exchange
exchange resin
charged ion
metal
iodide
Prior art date
Application number
RU98114867/12A
Other languages
Russian (ru)
Other versions
RU2214994C2 (en
Inventor
Лоренс Кэри Джон
Дейвид Джонс Майкл
Дейвид Пул Эндрю
Original Assignee
Бп Кемикэлз Лимитед
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GBGB9715489.2A external-priority patent/GB9715489D0/en
Application filed by Бп Кемикэлз Лимитед filed Critical Бп Кемикэлз Лимитед
Publication of RU98114867A publication Critical patent/RU98114867A/en
Application granted granted Critical
Publication of RU2214994C2 publication Critical patent/RU2214994C2/en

Links

Claims (14)

1. Заряженная ионообменная смола, которая заряжена в сжатом состоянии.1. A charged ion exchange resin that is charged in a compressed state. 2. Заряженная ионообменная смола по п. 1, которая представляет собой гелеобразную смолу. 2. The charged ion exchange resin according to claim 1, which is a gel-like resin. 3. Заряженная ионообменная смола по любому из пп. 1 или 2, которая заряжена ионами Н+, по меньшей мере одним металлом и/или группой атомов, которые совместно образуют заряженный остаток.3. The charged ion exchange resin according to any one of paragraphs. 1 or 2, which is charged with H + ions, at least one metal and / or a group of atoms that together form a charged residue. 4. Заряженная ионообменная смола по п. 3, в которую металл введен в форме катиона металла. 4. The charged ion exchange resin according to claim 3, in which the metal is introduced in the form of a metal cation. 5. Заряженная ионообменная смола по любому из пп. 1-4, в которую введен металл группы Ib, IIb, III, Va, VIa, VIIa или VIII Периодической таблицы элементов. 5. The charged ion exchange resin according to any one of paragraphs. 1-4, which introduced the metal of groups Ib, IIb, III, Va, VIa, VIIa or VIII of the Periodic table of elements. 6. Заряженная ионообменная смола по любому из пп. 1-5, в которую введено серебро, палладий или ртуть. 6. The charged ion exchange resin according to any one of paragraphs. 1-5, in which silver, palladium or mercury is introduced. 7. Способ получения заряженной ионообменной смолы по п. 1, который включает зарядку ионообменной смолы в ее сжатом состоянии. 7. A method of producing a charged ion exchange resin according to claim 1, which includes charging the ion exchange resin in its compressed state. 8. Способ по п. 7, в котором перевод смолы в ее сжатое состояние достигают путем изменения окружающей смолу жидкой среды с заменой среды, вызывающей набухание, средой, вызывающей сжатие. 8. The method according to p. 7, in which the transfer of the resin into its compressed state is achieved by changing the surrounding liquid environment of the resin with the replacement of the medium that causes swelling, the medium that causes compression. 9. Способ удаления иодидных соединений из жидкой карбоновой кислоты и/или ангидрида карбоновой кислоты, полученных путем карбонилирования спиртов и/или их реакционноспособных производных, катализированного благородным металлом группы VIII и сокатализированного алкилиодидом, который включает контактирование жидкой карбоновой кислоты и/или ангидрида карбоновой кислоты с заряженной металлом ионнобменной смолой по п.1, в которой металлом служит один или несколько таких металлов, как серебро, палладий и ртуть. 9. A method for removing iodide compounds from liquid carboxylic acid and / or carboxylic anhydride obtained by carbonylation of alcohols and / or their reactive derivatives, catalyzed by a Group VIII noble metal and cocatalized with an alkyl iodide, which comprises contacting the liquid carboxylic acid and / or carboxylic anhydride with The metal-charged ion exchange resin according to claim 1, wherein the metal is one or more metals such as silver, palladium and mercury. 10. Способ по п.9, в котором эта ионообменная смола представляет гелеобразную смолу. 10. The method according to claim 9, in which this ion exchange resin is a gel-like resin. 11. Способ либо по п.9 или 10, в котором в смолу вводят серебро. 11. The method according to claim 9 or 10, in which silver is introduced into the resin. 12. Способ по любому из пп.9-11, в котором иодидные соединения включают C1-C10алкилиодиды, иодиды водорода и/или иодидные соли.12. The method according to any one of claims 9 to 11, in which the iodide compounds include C 1 -C 10 alkyl iodides, hydrogen iodides and / or iodide salts. 13. Способ по п.12, в котором иодидные соединения включают метилиодид и/или C5-C7иодиды.13. The method according to item 12, in which the iodide compounds include methyl iodide and / or C 5 -C 7 iodides. 14. Способ по любому из пп.9-13, в котором иодидные соединения удаляют из уксусной кислоты и/или уксусного ангидрида, полученных катализируемым родием и сокатализируемым метилиодидом карбонилированием метанола и/или метилацетата. 14. The method according to any one of claims 9 to 13, in which the iodide compounds are removed from acetic acid and / or acetic anhydride obtained by catalyzed rhodium and cocatalized methyl iodide by carbonylation of methanol and / or methyl acetate.
RU98114867/12A 1997-07-23 1998-07-22 Charged ion-exchange resins, methods for preparation thereof, and their application RU2214994C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9715489.2 1997-07-23
GBGB9715489.2A GB9715489D0 (en) 1997-07-23 1997-07-23 Composition

Publications (2)

Publication Number Publication Date
RU98114867A true RU98114867A (en) 2000-05-20
RU2214994C2 RU2214994C2 (en) 2003-10-27

Family

ID=10816298

Family Applications (1)

Application Number Title Priority Date Filing Date
RU98114867/12A RU2214994C2 (en) 1997-07-23 1998-07-22 Charged ion-exchange resins, methods for preparation thereof, and their application

Country Status (14)

Country Link
US (1) US6197997B1 (en)
EP (1) EP0893160B1 (en)
JP (1) JP4173222B2 (en)
KR (1) KR100562737B1 (en)
CN (1) CN1112971C (en)
DE (1) DE69817937T2 (en)
GB (1) GB9715489D0 (en)
ID (1) ID20612A (en)
MY (1) MY122500A (en)
RU (1) RU2214994C2 (en)
SA (1) SA98190405B1 (en)
SG (1) SG67523A1 (en)
TW (1) TW581712B (en)
UA (1) UA53639C2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6783662B2 (en) 1999-03-18 2004-08-31 Exxonmobil Research And Engineering Company Cavitation enhanced liquid atomization
US6211408B1 (en) * 1999-03-24 2001-04-03 Celanese International Corporation Method of removing iodides from non-aqueous organic media utilizing silver or mercury exchanged macroporous organofunctional polysiloxane resins
WO2001014500A1 (en) 1999-08-26 2001-03-01 Exxonmobil Research And Engineering Company Superheating atomizing steam with hot fcc feed oil
US6225498B1 (en) * 2000-03-24 2001-05-01 Celanese International Corporation Method of removing organic iodides from organic media
US6770250B2 (en) * 2001-09-24 2004-08-03 Cooper Environmental Services Apparatus and methods for removing mercury from fluid streams
KR100434725B1 (en) * 2001-10-25 2004-06-07 니카코리아 (주) Recovery of Iodine by Ion Exchange Resin
KR101140087B1 (en) * 2002-06-13 2012-04-30 쓰리엠 이노베이티브 프로퍼티즈 캄파니 System of controlled certificate production and management
US20100113827A1 (en) * 2008-11-03 2010-05-06 Wei Wang Removing iodobenzene compounds from acetic acid
US7588690B1 (en) 2009-02-10 2009-09-15 The Purolite Company Method of iodide removal
US20110086929A1 (en) * 2009-10-13 2011-04-14 Brotech Corporation, doing business as The Purolite Company Method of iodide removal
EP3445475B1 (en) * 2016-04-18 2022-09-07 MECS, Inc. Removal of sulfate from solvent solutions using an anion exchange resin

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4615806B1 (en) 1985-03-07 1994-05-03 Hoechst Co American Removal of iodide compounds from non-aqueous organic media
EP0296584B1 (en) 1987-06-24 1992-03-25 Union Carbide Corporation Removal of halides from carboxylic acids
US5139981A (en) * 1987-06-24 1992-08-18 Union Carbide Chemicals & Plastics Technology Corporation Process for preparing silver(I)-exchanged resins
GB9211671D0 (en) * 1992-06-02 1992-07-15 Bp Chem Int Ltd Process

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