RU98105687A - APPLICATION AS A COSMETIC PRODUCT OF A crosslinked POLY (2-ACRYLAMIDO-2-METHYLPROPANESULPHIC ACID), 90% NEUTRALIZED, AND COMPOSITIONS CONTAINING IT - Google Patents

APPLICATION AS A COSMETIC PRODUCT OF A crosslinked POLY (2-ACRYLAMIDO-2-METHYLPROPANESULPHIC ACID), 90% NEUTRALIZED, AND COMPOSITIONS CONTAINING IT

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RU98105687A
RU98105687A RU98105687/14A RU98105687A RU98105687A RU 98105687 A RU98105687 A RU 98105687A RU 98105687/14 A RU98105687/14 A RU 98105687/14A RU 98105687 A RU98105687 A RU 98105687A RU 98105687 A RU98105687 A RU 98105687A
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composition according
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acrylamido
cross
methylpropanesulfonic acid
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RU98105687/14A
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Russian (ru)
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RU2152780C2 (en
Inventor
Дюпюи Кристин
Ансенн Изабель
Мобрю Мирей
Себийот-Арно Лоранс
Лоран Ралюка
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Л'Ореаль
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Priority claimed from FR9608107A external-priority patent/FR2750325B1/en
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1. Применение в качестве косметического продукта поперечно-сшитых и по меньшей мере на 90% нейтрализованных полимеров поли(2-акриламидо-2-метилпропансульфоновой кислоты).1. The use as a cosmetic product of cross-linked and at least 90% neutralized polymers of poly (2-acrylamido-2-methylpropanesulfonic acid). 2. Применение в качестве загустителя и/или желирующего компонента в косметических и/или дерматологических композициях поперечно-сшитой и по меньшей мере на 90% нейтрализованной поли(2-акриламидо-2-метилпропансульфоновой кислоты). 2. The use as a thickener and / or gelling component in cosmetic and / or dermatological compositions of cross-linked and at least 90% neutralized poly (2-acrylamido-2-methylpropanesulfonic acid). 3. Применение указанной поперечно-сшитой и по меньшей мере на 90% нейтрализованной поли(2-акриламидо-2-метилпропансульфоновой кислоты) по п.1 или 2, которая включает при случайном распределении а) от 90 до 99,9 вес.% единиц общей формулы (I), приведенной ниже:
Figure 00000001

в которой Х+ обозначает катион или смесь катионов, при этом не более, чем 10 мол.% катионов Х+ может представлять собой протоны Н+; б) от 0,01 до 10 вес. % поперечно-сшитых единиц, полученных по меньшей мере из одного мономера, имеющего по меньшей мере две олефиновых двойных связи; при этом их соотношение определяется относительно общего веса полимера.3. The use of the specified cross-linked and at least 90% neutralized poly (2-acrylamido-2-methylpropanesulfonic acid) according to claim 1 or 2, which includes, with a random distribution of a) from 90 to 99.9 wt.% Units general formula (I) below:
Figure 00000001

in which X + denotes a cation or mixture of cations, while not more than 10 mol.% of cations X + may be H + protons; b) from 0.01 to 10 weight. % cross-linked units derived from at least one monomer having at least two olefinic double bonds; however, their ratio is determined relative to the total weight of the polymer. 4. Применение указанной поперечно-сшитой и по меньшей мере не 90% нейтрализованной поли(2-акриламидо-2-метилпропансульфоновой кислоты) по п.3, содержащей множество единиц формулы (1) в достаточно высоком количестве, так, чтобы можно было получать полимерные частицы, которые в водном растворе имеют гидродинамический объем с радиусом от 10 до 500 нм и распределение которых характеризуется гомогенностью и равномерностью. 4. The use of the specified cross-linked and at least not 90% neutralized poly (2-acrylamido-2-methylpropanesulfonic acid) according to claim 3, containing many units of the formula (1) in a sufficiently high amount, so that it is possible to obtain polymer particles that in an aqueous solution have a hydrodynamic volume with a radius of 10 to 500 nm and whose distribution is characterized by homogeneity and uniformity. 5. Применение указанной поперечно-сшитой и по меньшей мере не 90% нейтрализованной поли(2-акриламидо-2-метилпропансульфоновой кислоты) по п.3 или 4, содержащей от 98 до 99,5 вес.% единиц формулы (I) и от 0,2 до 2 вес.% поперечно-сшитых единиц. 5. The use of said crosslinked and at least not 90% neutralized poly (2-acrylamido-2-methylpropanesulfonic acid) according to claim 3 or 4, containing from 98 to 99.5 wt.% Units of formula (I) and from 0.2 to 2% by weight of crosslinked units. 6. Применение кислоты по одному из пп.3-5, содержащей в формуле (I) катион Х+, который представляет собой NH4 +.6. The use of the acid according to one of claims 3 to 5, containing in the formula (I) a cation X + , which is NH 4 + . 7. Применение по любому из пп.3-6, где поперечно-сшитые мономеры соответствуют общей формуле (2),
Figure 00000002

в которой R1 обозначает атом водорода или C1-C4алкил.7. The use according to any one of claims 3 to 6, where the cross-linked monomers correspond to the General formula (2),
Figure 00000002

in which R 1 denotes a hydrogen atom or C 1 -C 4 alkyl. 8. Применение по любому одному из пп.3-7, где поли(2-акриламидо-2-метилпропансульфоновая кислота) сшита с помощью поперечных связей с триметилолпропантриакрилатом. 8. The use according to any one of claims 3 to 7, wherein the poly (2-acrylamido-2-methylpropanesulfonic acid) is crosslinked with trimethylolpropane triacrylate. 9. Применение по любому одному из пп.3-8, где полимеры формулы (1) имеют вязкость, определяемую вискозиметром Брукфильда с ротором 4 при скорости вращения 100 оборотов/минуту в 2%-ном водном растворе при температуре 25°С, больше или равную 1000 сантипуаз. 9. The use according to any one of claims 3 to 8, where the polymers of formula (1) have a viscosity determined by a Brookfield viscometer with a rotor 4 at a speed of 100 rpm in a 2% aqueous solution at a temperature of 25 ° C, greater than or equal to 1000 centipoise. 10. Применение по любому одному из пп.3-9, где полимеры формулы (1) имеют вязкость, определяемую вискозиметром Брукфильда с ротором 4 при скорости вращения 100 оборотов/минуту в 2%-ном водном растворе при температуре 25°С, варьирующую от 5000 до 40000 сантипуаз и более предпочтительно, от 6500 до 35000 сантипуаз. 10. The use according to any one of claims 3 to 9, where the polymers of formula (1) have a viscosity determined by a Brookfield viscometer with a rotor 4 at a rotation speed of 100 revolutions / minute in a 2% aqueous solution at a temperature of 25 ° C, varying from 5,000 to 40,000 centipoise, and more preferably, from 6,500 to 35,000 centipoise. 11. Косметическая или дерматологическая композиция, отличающаяся тем, что содержит в косметически приемлемой среде по меньшей мере одну поперечно-сшитую и по меньшей мере на 90% нейтрализованную поли(2-акриламидо-2-метилпропансульфоновую кислоту). 11. Cosmetic or dermatological composition, characterized in that it contains in a cosmetically acceptable medium at least one crosslinked and at least 90% neutralized poly (2-acrylamido-2-methylpropanesulfonic acid). 12. Композиция по п.11, отличающаяся тем, что поперечно-сшитая поли(2-акриламидо-2-метилпропансульфоновая кислота) включает при случайном распределении а) от 90 до 99,9 вес.% единиц общей формулы (1)
Figure 00000003

в которой Х+ обозначает катион или смесь катионов, при этом не более, чем 10 мол.% катионов Х+ может представлять собой протоны Н+; б) от 0,01 до 10 вес. % поперечно-сшитых единиц, полученных по меньшей мере из одного мономера, имеющего по меньшей мере две олефиновых двойных связи; при этом соотношение их определяется относительно общего веса полимера.12. The composition according to claim 11, characterized in that the cross-linked poly (2-acrylamido-2-methylpropanesulfonic acid) includes, with a random distribution, a) from 90 to 99.9% by weight of units of the general formula (1)
Figure 00000003

in which X + denotes a cation or mixture of cations, while not more than 10 mol.% of cations X + may be H + protons; b) from 0.01 to 10 weight. % cross-linked units derived from at least one monomer having at least two olefinic double bonds; their ratio is determined relative to the total weight of the polymer. 13. Композиция по п.12, отличающаяся тем, что указанная поперечно-сшитая поли(2-акриламидо-2-метилпропансульфоновая кислота) содержит множество единиц формулы (1) в достаточно высоком количестве, так, чтобы можно было получать полимерные частицы, которые в водном растворе имеют гидродинамический объем с радиусом от 10 до 500 нм и распределение которых характеризуется гомогенностью и равномерностью. 13. The composition according to p. 12, characterized in that the cross-linked poly (2-acrylamido-2-methylpropanesulfonic acid) contains many units of the formula (1) in a sufficiently high amount so that it is possible to obtain polymer particles that are aqueous solutions have a hydrodynamic volume with a radius of 10 to 500 nm and the distribution of which is characterized by homogeneity and uniformity. 14. Композиция по п.12 или 13, отличающаяся тем, что указанная поперечно-сшитая поли(2-акриламидо-2-метилпропансульфоновая кислота) содержит от 98 до 99,5 вес.% единиц формулы (1) и от 0,2 до 2 вес.% поперечно-сшитых единиц. 14. The composition according to p. 12 or 13, characterized in that the cross-linked poly (2-acrylamido-2-methylpropanesulfonic acid) contains from 98 to 99.5 wt.% Units of the formula (1) and from 0.2 to 2% by weight of crosslinked units. 15. Композиция по п.11-14, отличающаяся тем, что в формуле (1) катион Х+, который представляет собой NH4 +.15. The composition according to claim 11-14, characterized in that in the formula (1) the cation X + , which is NH 4 + . 16. Композиция по любому одному из пп.11-15, отличающаяся тем, что поперечно-сшитые мономеры соответствуют общей формуле (2),
Figure 00000004

в которой R1 обозначает атом водорода или C1-C4алкил.16. The composition according to any one of paragraphs.11-15, characterized in that the cross-linked monomers correspond to the General formula (2),
Figure 00000004

in which R 1 denotes a hydrogen atom or C 1 -C 4 alkyl. 17. Композиция по любому одному из пп.11-16, отличающаяся тем, что поли(2-акриламидо-2-метилпропансульфоновая кислота) сшита с помощью поперечных связей с триметилолпропантриакрилатом. 17. The composition according to any one of paragraphs.11-16, characterized in that the poly (2-acrylamido-2-methylpropanesulfonic acid) is crosslinked with trimethylolpropane triacrylate. 18. Композиция по любому одному из пп.11-17, отличающаяся тем, что поперечно-сшитая поли(2-акриламидо-2-метилпропансульфоновая кислота) имеет вязкость, определяемую вискозиметром Брукфильда в 2%-ном водном растворе при температуре 25°С, больше или равную 1000 сантипуаз. 18. The composition according to any one of paragraphs.11-17, characterized in that the cross-linked poly (2-acrylamido-2-methylpropanesulfonic acid) has a viscosity determined by a Brookfield viscometer in a 2% aqueous solution at a temperature of 25 ° C, greater than or equal to 1000 centipoise. 19. Композиция по любому одному из пп.11-18, отличающаяся тем, что поперечно-сшитая поли(2-акриламидо-2-метилпропансульфоновая кислота) имеет вязкость, определяемую вискозиметром Брукфильда в 2%-ном водном растворе при температуре 25°С, варьирующую от 5000 до 40000 сантипуаз и более предпочтительно, от 6500 до 35000 сантипуаз. 19. The composition according to any one of paragraphs.11-18, characterized in that the cross-linked poly (2-acrylamido-2-methylpropanesulfonic acid) has a viscosity determined by a Brookfield viscometer in a 2% aqueous solution at a temperature of 25 ° C, ranging from 5,000 to 40,000 centipoise, and more preferably from 6,500 to 35,000 centipoise. 20. Композиция по любому одному из пп.11-19, отличающаяся тем, что поперечно-сшитая поли(2-акриламидо-2-метилпропансульфоновая кислота) присутствует в концентрациях предпочтительно от 0,01 до 20 вес.% относительно веса всей композиции и более предпочтительно от 0,1 до 10 вес.%. 20. The composition according to any one of paragraphs.11-19, characterized in that the cross-linked poly (2-acrylamido-2-methylpropanesulfonic acid) is present in concentrations preferably from 0.01 to 20 wt.% Relative to the weight of the whole composition and more preferably from 0.1 to 10 wt.%. 21. Композиция по любому одному из пп.11-20, отличающаяся тем, что она имеет вид дисперсии типа лосьона или сыворотки; водного или масляного геля; эмульсии жидкой или полужидкой консистенции типа молочка, полученной при диспергировании жирной фазы в водной фазе (масло/вода) или, наоборот, (вода/масло); суспензий или эмульсий мягкой, полутвердой или твердой консистенции кремообразного или гелеобразного типа; твердого мыла. 21. The composition according to any one of paragraphs.11-20, characterized in that it has the form of a dispersion such as lotion or serum; water or oil gel; emulsions of a liquid or semi-liquid consistency of the type of milk obtained by dispersing the fatty phase in the aqueous phase (oil / water) or, conversely, (water / oil); suspensions or emulsions of a soft, semi-solid or solid consistency of a creamy or gel type; solid soap. 22. Композиция по любому одному из пп.11-21, отличающаяся тем, что содержит косметически и/или дерматологически приемлемую водную среду. 22. The composition according to any one of paragraphs.11-21, characterized in that it contains a cosmetically and / or dermatologically acceptable aqueous medium. 23. Композиция по п.22, отличающаяся тем, что значение рН в ней варьирует от 1 до 13. 23. The composition according to p. 22, characterized in that the pH value in it varies from 1 to 13. 24. Композиция по любому одному из пп.11-23, отличающаяся тем, что указанная косметически и/или дерматологически приемлемая среда состоит из воды или воды и по меньшей мере одного органического растворителя, выбранного из группы, включающей гидрофильные органические растворители, липофильные органические растворители, амфифильные органические растворители и их смеси. 24. A composition according to any one of claims 11-23, wherein said cosmetically and / or dermatologically acceptable medium consists of water or water and at least one organic solvent selected from the group comprising hydrophilic organic solvents, lipophilic organic solvents , amphiphilic organic solvents and mixtures thereof. 25. Композиция по п.24, отличающаяся тем, что органические растворители выбирают из группы, включающей моно- или полифункциональные спирты, не обязательно оксиэтиленированные полиэтиленгликоли, сложные эфиры пропиленгликоля, сорбит и его производные, ди- и алкилизосорбиды, эфиры гликоля и пропиленгликоля, а также сложные эфиры жирных кислот. 25. The composition according to paragraph 24, wherein the organic solvents are selected from the group consisting of mono- or polyfunctional alcohols, optionally hydroxyethylenated polyethylene glycols, propylene glycol esters, sorbitol and its derivatives, di- and alkyl isosorbides, glycol and propylene glycol ethers, and also fatty acid esters. 26. Композиция по п.24 или 25, отличающаяся тем, что органический растворитель или растворители составляют от 5 вес.% до 98 вес.% от веса всей композиции. 26. The composition according to paragraph 24 or 25, characterized in that the organic solvent or solvents comprise from 5 wt.% To 98 wt.% Of the weight of the entire composition. 27. Композиция по любому одному из пп.11-26, отличающаяся тем, что включает также по меньшей мере одну жирную фазу. 27. The composition according to any one of paragraphs.11-26, characterized in that it also includes at least one fatty phase. 28. Композиция по любому одному из пп.11-27, отличающаяся тем, что указанная жирная фаза составляет от 0 до 50 вес.% от веса всей композиции. 28. The composition according to any one of paragraphs.11-27, characterized in that the said fatty phase is from 0 to 50 wt.% By weight of the entire composition. 29. Композиция по любому одному из пп.11-28, отличающаяся тем, что включает также по меньшей мере одну добавку, выбранную из группы, состоящей из стандартных водных или липофильных желирующих компонентов и/или загустителей; гидрофильных или липофильных активных агентов; консервантов; антиоксидантов; парфюмерных отдушек; эмульгаторов; увлажнителей; умягчающих веществ; компонентов, способствующих шелушению; поверхностно-активных веществ; полимеров; подщелачивающих или подкисляющих агентов; наполнителей; средств, связывающих свободные радикалы; церамидов; солнцезащитных фильтров; репеллентов против насекомых; средств, способствующих скольжению; красителей; бактерицидных средств; противоперхотных средств. 29. The composition according to any one of paragraphs.11-28, characterized in that it also includes at least one additive selected from the group consisting of standard aqueous or lipophilic gelling components and / or thickeners; hydrophilic or lipophilic active agents; preservatives; antioxidants; perfume fragrances; emulsifiers; humidifiers; emollients; components that promote peeling; surfactants; polymers; alkalizing or acidifying agents; fillers; free radical binding agents; ceramides; sunscreens; insect repellents; slip aids; dyes; bactericidal agents; anti-dandruff agents. 30. Композиция по любому одному из пп.11-29, отличающаяся тем, что используется как смываемое средство или как оставляемый на волосах продукт для мытья, ухода, кондиционирования, поддержания укладки или формы волос. 30. The composition according to any one of paragraphs.11-29, characterized in that it is used as a rinse off agent or as a product left on the hair to wash, care, condition, maintain styling or shape of the hair. 31. Композиция по любому одному из пп.11-29, отличающаяся тем, что используется как средство для ухода и/или как гигиеническое средство. 31. The composition according to any one of paragraphs.11-29, characterized in that it is used as a care product and / or as a hygiene product. 32. Композиция по любому одному из пп.11-29, отличающаяся тем, что используется как средство макияжа. 32. The composition according to any one of paragraphs.11-29, characterized in that it is used as a means of makeup. 33. Композиция по любому одному из пп.11-29, отличающаяся тем, что используется как солнцезащитное средство. 33. The composition according to any one of paragraphs.11-29, characterized in that it is used as a sunscreen. 34. Композиция по любому одному из пп.11-29, отличающаяся тем, что используется как средство ухода за полостью рта. 34. The composition according to any one of paragraphs.11-29, characterized in that it is used as a means of caring for the oral cavity. 35. Способ нетерапевтического косметического воздействия на кожу, волосистую часть головы, волосы, ресницы, брови, ногти или слизистые оболочки, отличающийся тем, что включает применение композиций, определенных в пп. 11-29. 35. The method of non-therapeutic cosmetic effects on the skin, scalp, hair, eyelashes, eyebrows, nails or mucous membranes, characterized in that it involves the use of the compositions defined in paragraphs. 11-29.
RU98105687/14A 1996-06-28 1997-06-18 Thickening and/or jelling agent of cosmetic and/or dermatological compositions, cosmetic or dermatologic composition, method of nontherapeutic cosmetic action to skin, hair, eyelashes, eyebrows, nails or mucous membranes RU2152780C2 (en)

Applications Claiming Priority (2)

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FR96/08107 1996-06-28
FR9608107A FR2750325B1 (en) 1996-06-28 1996-06-28 COSMETIC USE OF A POLY (2-ACRYLAMIDO 2- METHYLPROPANE SULFONIC) CROSSLINKED AND NEUTRALIZED AT LEAST 90% AND TOPICAL COMPOSITIONS CONTAINING THEM

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US (1) US6120780A (en)
EP (1) EP0815828B1 (en)
JP (1) JP3115001B2 (en)
KR (1) KR100272886B1 (en)
AT (1) ATE176863T1 (en)
BR (1) BR9706550B1 (en)
CA (1) CA2227975A1 (en)
DE (1) DE69700119T2 (en)
ES (1) ES2131428T3 (en)
FR (1) FR2750325B1 (en)
PL (1) PL325374A1 (en)
RU (1) RU2152780C2 (en)
WO (1) WO1998000094A1 (en)

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FR2780883B1 (en) * 1998-07-09 2001-04-06 Oreal DYE COMPOSITION FOR KERATINIC FIBERS WITH CATIONIC DIRECT DYE AND THICKENER POLYMER
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