RU96123204A - METHOD FOR REMOVING NICKEL FROM WASTE SOLUTIONS OF ELECTRICAL PRODUCTION - Google Patents

METHOD FOR REMOVING NICKEL FROM WASTE SOLUTIONS OF ELECTRICAL PRODUCTION

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Publication number
RU96123204A
RU96123204A RU96123204/02A RU96123204A RU96123204A RU 96123204 A RU96123204 A RU 96123204A RU 96123204/02 A RU96123204/02 A RU 96123204/02A RU 96123204 A RU96123204 A RU 96123204A RU 96123204 A RU96123204 A RU 96123204A
Authority
RU
Russia
Prior art keywords
nickel
regeneration
ion exchanger
acid
filter
Prior art date
Application number
RU96123204/02A
Other languages
Russian (ru)
Other versions
RU2125105C1 (en
Inventor
М.Ю. Хазель
П. Лют
Г.С. Зародин
Original Assignee
Внедренческий научно-экспериментальный центр "Экотур"
Filing date
Publication date
Application filed by Внедренческий научно-экспериментальный центр "Экотур" filed Critical Внедренческий научно-экспериментальный центр "Экотур"
Priority to RU96123204A priority Critical patent/RU2125105C1/en
Priority claimed from RU96123204A external-priority patent/RU2125105C1/en
Application granted granted Critical
Publication of RU2125105C1 publication Critical patent/RU2125105C1/en
Publication of RU96123204A publication Critical patent/RU96123204A/en

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Claims (2)

1. Способ извлечения никеля из отработанных растворов гальванических производств, включающий сорбцию никеля на ионообменной смоле, ее регенерацию кислотой и промывку водой, отличающийся тем, что сорбцию никеля осуществляют по меньшей мере на двух ионитовых фильтрах - сначала на первом до проскока ионов никеля в фильтрат, затем на обоих фильтрах до полного насыщения обменной емкости первого фильтра, после чего его выводят на регенерацию, а сорбцию продолжают на втором фильтре с одновременной регенерацией первого отработанного фильтра, по окончании которой сорбцию никеля осуществляют снова на обоих фильтрах до вывода на регенерацию второго фильтра, и т.д., а регенерацию проводят в четыре этапа: сначала осуществляют прокачивание ионита сверху сжатым воздухом в течение 5 - 10 мин, затем ионитовый фильтр заполняют регенерационным раствором - кислотой до уровня, не превышающего верхний уровень ионита более чем на 5 - 10 см, причем подачу кислоты осуществляют снизу, выдерживают ионит в контакте с кислотой в течение 20 - 35 мин, после чего кислоту подают сверху, регенерат с содержанием никеля Ni > 40,0 г/л и рН > 4,0 возвращают в производство для приготовления электролита, остальной регенерат используют для приготовления регенерационного раствора, а послерегенерационную отмывку ионита осуществляют деионизованной водой, причем подачу воды осуществляют прямотоком.1. A method for extracting nickel from spent solutions of galvanic production, including sorption of nickel on an ion exchange resin, its regeneration with acid and washing with water, characterized in that the sorption of nickel is carried out on at least two ionite filters - first, on the first one, before nickel ions slip into the filtrate, then on both filters until the exchange capacity of the first filter is completely saturated, after which it is taken out for regeneration, and sorption is continued on the second filter with simultaneous regeneration of the first spent filter, according to at the end of which sorption of nickel is carried out again on both filters until the second filter is withdrawn for regeneration, etc., and the regeneration is carried out in four stages: first, the ion exchanger is pumped from above with compressed air for 5-10 minutes, then the ion exchanger filter is filled with a regeneration solution - acid to a level that does not exceed the upper level of the ion exchanger by more than 5 - 10 cm, and the acid is supplied from below, the ion exchanger is kept in contact with the acid for 20 - 35 minutes, after which the acid is fed from above, the regenerate contains n Of nickel Ni> 40.0 g / l and a pH of> 4.0 in the manufacture of recycled for the preparation of electrolyte reclaimed remainder used to prepare the regenerating solution, and washing of the ion exchanger is carried posleregeneratsionnuyu deionized water, wherein the water supply is carried out co-currently. 2. Способ по п. 1, отличающийся тем, что в качестве ионита используют гранулированный иминодиацетатный ионит, размеры гранул которого составляют 0,5 - 1,0 мм. 2. The method according to p. 1, characterized in that the granite iminodiacetate ion exchanger is used as the ion exchange resin, the granule sizes of which are 0.5-1.0 mm.
RU96123204A 1996-12-06 1996-12-06 Method of nickel recovery from sheet solutions of electroplating RU2125105C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU96123204A RU2125105C1 (en) 1996-12-06 1996-12-06 Method of nickel recovery from sheet solutions of electroplating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU96123204A RU2125105C1 (en) 1996-12-06 1996-12-06 Method of nickel recovery from sheet solutions of electroplating

Publications (2)

Publication Number Publication Date
RU2125105C1 RU2125105C1 (en) 1999-01-20
RU96123204A true RU96123204A (en) 1999-01-20

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU96123204A RU2125105C1 (en) 1996-12-06 1996-12-06 Method of nickel recovery from sheet solutions of electroplating

Country Status (1)

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RU (1) RU2125105C1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101805831B (en) * 2010-03-24 2011-07-20 埃梯星(厦门)电子科技有限公司 Method for directly extracting nickel in alkaline chemical nickel-plating waste liquid
CN101817607B (en) * 2010-03-24 2011-08-10 埃梯星(厦门)电子科技有限公司 Method for directly extracting nickel in acidic chemical nickel plating waste solution
CA2740249C (en) * 2010-05-25 2015-08-04 Dow Global Technologies Llc A process for separating copper and nickel from cobalt containing solutions
CN101892389A (en) * 2010-07-14 2010-11-24 王昊杨 Method for preparing nano metallic nickel in spent electroless nickel plating solution
CN104692581B (en) * 2015-03-26 2017-07-14 埃梯星(厦门)电子科技有限公司 It is a kind of to be used for nickeliferous or phosphorus waste liquid processing equipment
RU2666859C2 (en) * 2016-12-01 2018-09-12 Акционерное общество "Уралэлектромедь" Method for complex purification of mine waters

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