RU96122872A - PESTICIDAL ACTIVITY FLUOROFINS - Google Patents

PESTICIDAL ACTIVITY FLUOROFINS

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Publication number
RU96122872A
RU96122872A RU96122872/04A RU96122872A RU96122872A RU 96122872 A RU96122872 A RU 96122872A RU 96122872/04 A RU96122872/04 A RU 96122872/04A RU 96122872 A RU96122872 A RU 96122872A RU 96122872 A RU96122872 A RU 96122872A
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RU
Russia
Prior art keywords
compound
formula
phenyl
paragraphs
soil
Prior art date
Application number
RU96122872/04A
Other languages
Russian (ru)
Other versions
RU2154625C2 (en
Inventor
Полл Синг Камбай Бхупиндер
Лиу Му-Гуанг
Original Assignee
Бритиш Текнолоджи Групп Лтд.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB9408605A external-priority patent/GB9408605D0/en
Application filed by Бритиш Текнолоджи Групп Лтд. filed Critical Бритиш Текнолоджи Групп Лтд.
Publication of RU96122872A publication Critical patent/RU96122872A/en
Application granted granted Critical
Publication of RU2154625C2 publication Critical patent/RU2154625C2/en

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Claims (16)

1. Пестицидное соединение формулы I
Figure 00000001

в которой R1 представляет собой водород и R2 представляет собой циклопропил, или R1 и R2 каждый представляет собой алкильную группу, причем алкильные группы могут быть одинаковыми или разными,
ArA представляет собой необязательно замещенный фенил или нафтил,
ArB представляет собой фенил, замещенный феноксигруппой, фенилом, бензилом или бензоилом, и необязательно содержащий дополнительный заместитель,
конфигурация групп ArA и - CR1 R2 и CH2ArB относительно двойной связи представляет собой транс-конфигурацию.1. The pesticidal compound of formula I
Figure 00000001

in which R 1 represents hydrogen and R 2 represents cyclopropyl, or R 1 and R 2 each represents an alkyl group, and the alkyl groups may be the same or different,
Ar A is optionally substituted phenyl or naphthyl,
Ar B is phenyl substituted with phenoxy, phenyl, benzyl or benzoyl, and optionally containing an additional substituent,
the configuration of the Ar A and - CR 1 R 2 and CH 2 Ar B groups relative to the double bond is a trans configuration. 2. Соединение по п.1, в котором ArA представляет собой замещенный фенил.2. The compound according to claim 1, in which Ar A represents a substituted phenyl. 3. Соединение по п.2, в котором фенил замещен в 4-(пара)положении галогеном, алкокси или галоидалкилом. 3. The compound according to claim 2, in which phenyl is substituted in the 4- (para) position by halogen, alkoxy or haloalkyl. 4. Соединение по любому из пп.1 - 3, в котором ArB представляет собой фенил, замещенный в 3-(мета) положении фенокси, фенилом, бензилом или бензоилом.4. A compound according to any one of claims 1 to 3, wherein Ar B is phenyl substituted at the 3- (meta) position with phenoxy, phenyl, benzyl or benzoyl. 5. Соединение по п. 4, в котором фенил дополнительно замещен фтором в 4-(пара)положении. 5. The compound according to claim 4, in which phenyl is further substituted by fluorine in the 4- (pair) position. 6. Способ получения пестицидного соединения формулы I, по которому соединение, содержащее фрагмент
Figure 00000002

и соединение, содержащее фрагмент
ArB-,
подвергаются взаимодействию с образованием связи -C= C(F)CH2 между
Figure 00000003
и ArB в соединении формулы I.6. A method of obtaining a pesticidal compound of the formula I, in which the compound containing the fragment
Figure 00000002

and a compound containing a fragment
Ar B -,
are reacted to form a —C = C (F) CH 2 bond between
Figure 00000003
and Ar B in the compound of formula I. 7. Способ по п.6, включающий каталитическую реакцию нуклеофильного реагента формулы
ArB -
с соединением формулы
Figure 00000004

где Q представляет собой легко уходящую группу.7. The method according to claim 6, comprising a catalytic reaction of a nucleophilic reagent of the formula
Ar B -
with a compound of the formula
Figure 00000004

where Q is an easily leaving group. 8. Способ по п.7, в котором нуклеофильный реагент присутствует в форме реактива Гриньяра. 8. The method according to claim 7, in which the nucleophilic reagent is present in the form of a Grignard reagent. 9. Пестицидная композиция, включающая пестицидно эффективное количество соединения формулы I, определенного в любом из пп. 1 - 5 вместе с приемлемым носителем или разбавителем. 9. A pesticidal composition comprising a pesticidally effective amount of a compound of formula I, as defined in any one of claims. 1 to 5 together with an acceptable carrier or diluent. 10. Инсектицидная композиция, включающая соединение формулы I, определенное в любом из пп. 1 - 5 вместе с инертным носителем или разбавителем. 10. Insecticidal composition comprising a compound of formula I, as defined in any one of paragraphs. 1 to 5 together with an inert carrier or diluent. 11. Композиция по п.10, подходящая для использования в борьбе с почвенными (зарождающимися в почве) насекомыми вредителями. 11. The composition of claim 10, suitable for use in controlling soil (nascent in the soil) insect pests. 12. Композиция по любому из пп. 9 - 11 в форме гранул, дуста или эмульгируемого концентрата. 12. The composition according to any one of paragraphs. 9 to 11 in the form of granules, dust or emulsifiable concentrate. 13. Композиция по любому из пп. 9 - 12, в которой соединение формулы I присутствует в количестве от 0,5 до 5 вес.%. 13. The composition according to any one of paragraphs. 9 to 12, in which the compound of formula I is present in an amount of from 0.5 to 5 wt.%. 14. Использование для борьбы с почвенными насекомыми-вредителями соединения по любому из пп. 1 - 5 или композиции по любому из пп. 10 - 13. 14. Use for controlling soil insect pests of a compound according to any one of paragraphs. 1 to 5 or composition according to any one of paragraphs. 10 - 13. 15. Способ борьбы с почвенными (зарождающимися в почве) насекомыми-вредителями, включающий применение к почве или для обработки семян композиции по любому из пп. 10-13. 15. A method of controlling soil (nascent in the soil) insect pests, comprising applying to the soil or for treating the seeds of a composition according to any one of claims. 10-13. 16. Способ по п. 15, в котором норма расхода составляет в интервале от 1 до 100 г активного ингредиента на гектар. 16. The method according to p. 15, in which the consumption rate is in the range from 1 to 100 g of active ingredient per hectare.
RU96122872/04A 1994-04-29 1995-04-26 Fluoroolefins having pesticidal activity, method of preparation thereof, insecticidal composition and method of controlling insect pests that originate in soil RU2154625C2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9408605.5 1994-04-29
GB9408605/5 1994-04-29
GB9408605A GB9408605D0 (en) 1994-04-29 1994-04-29 Pesticidal fluoroolefins

Publications (2)

Publication Number Publication Date
RU96122872A true RU96122872A (en) 1999-02-20
RU2154625C2 RU2154625C2 (en) 2000-08-20

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RU96122872/04A RU2154625C2 (en) 1994-04-29 1995-04-26 Fluoroolefins having pesticidal activity, method of preparation thereof, insecticidal composition and method of controlling insect pests that originate in soil

Country Status (21)

Country Link
US (1) US5880162A (en)
EP (1) EP0757668A1 (en)
JP (1) JPH09512543A (en)
KR (1) KR970702836A (en)
CN (1) CN1147242A (en)
AU (1) AU2264995A (en)
BG (1) BG63007B1 (en)
BR (1) BR9507508A (en)
CA (1) CA2187918A1 (en)
CZ (1) CZ310796A3 (en)
FI (1) FI964343A0 (en)
GB (3) GB9408605D0 (en)
HU (1) HU215403B (en)
NO (1) NO307297B1 (en)
PL (1) PL179373B1 (en)
RU (1) RU2154625C2 (en)
SK (1) SK281501B6 (en)
TR (1) TR28774A (en)
TW (1) TW398956B (en)
WO (1) WO1995029887A1 (en)
ZA (1) ZA953119B (en)

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US5849958A (en) * 1997-03-17 1998-12-15 American Cyanamid Company 1,4,diaryl-2-fluoro-2-butene insecticidal and acaricidal agents
ZA974582B (en) * 1996-06-03 1998-11-26 American Cyanamid Co Process and intermediate compounds for the preparation of pesticidal fluoroolefin compounds
US5998673A (en) * 1996-06-03 1999-12-07 American Cyanamid Company 1, 4-diaryl-2-fluoro-2-butene insecticidal and acaricidal agents
DE69714145T2 (en) * 1996-06-03 2002-12-12 Basf Ag 1,4-Diaryl-2-fluoro-2-butenes as insecticidal and acaricidal agents
US5892131A (en) * 1997-05-29 1999-04-06 American Cyanamid Company Process for the preparation of pesticidal fluoroolefin compounds
US5962742A (en) * 1996-06-14 1999-10-05 American Cyanamid Company Process for the preparation of 5-bromo-2 fluorobenzeneboronic acid
US6198008B1 (en) * 1997-06-06 2001-03-06 American Cyanamid Company Process for the preparation of 5-bromo-2-fluorobenzeneboronic acid
GEP20022795B (en) * 1997-06-19 2002-09-25 American Cyanamid Co Process and Intermediate Compounds for Preparation of Pesticidal Fluoroolefin Compounds
TW467889B (en) * 1997-11-12 2001-12-11 American Cyanamid Co 1,4-diaryl-2,3-difluoro-2-butene insecticidal and acaricidal agents
IL127856A0 (en) * 1998-01-30 1999-10-28 American Cyanamid Co 1,4-Diaryl-3-fluoro-2-butene compounds for protecting animals and humans against attack and infestation by anthropod parasites
US6235754B1 (en) 1998-01-30 2001-05-22 American Cyanamid Company Methods and compositions for protecting animals and humans against attack and infestation by arthropod and helminth parasites
IL127852A0 (en) * 1998-01-30 1999-10-28 American Cyanamid Co Methods and compositions for protecting animals and humans against attack and infestation by arthropod and helminth parasites
US6646166B1 (en) * 1998-11-16 2003-11-11 Basf Aktiengesellschaft Processes for the preparation of 1,4-diaryl-2-fluoro-1,3-butadiene and 1,4-diaryl-2-fluoro 2 butene compounds
AU6225101A (en) 2000-05-04 2001-11-12 Basf Aktiengesellschaft 1,4-diaryl-2-fluoro-4-cyano-2-butenes, process for their preparation and intermediates useful therefor
AU2002223534A1 (en) 2000-09-12 2002-03-26 Basf Aktiengesellschaft 1,4-diaryl-2,3-difluoro-2-butene insecticidal and acaricidal agents
IL154438A0 (en) * 2000-09-12 2003-09-17 Basf Ag Process and intermediate compounds for the preparation of pesticidal fluoroolefin compounds
TWI780112B (en) * 2017-03-31 2022-10-11 美商科迪華農業科技有限責任公司 Molecules having pesticidal utility, and intermediates, compositions, and processes, related thereto

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60115545A (en) * 1983-11-25 1985-06-22 Sumitomo Chem Co Ltd Hydrocarbon compound, its production and insecticide containing said compound as active component
GB8409195D0 (en) * 1984-04-09 1984-05-16 Elliott M Pesticides
US4975451A (en) * 1989-03-02 1990-12-04 Fmc Corporation Insecticidal cyclopropyl di(aryl) 2-butenes
GB9219612D0 (en) * 1992-09-16 1992-10-28 Khambay Bhupinder P S Pesticidal fluoroolefins

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