RU96115069A - METHOD FOR DETERMINING NITRITE ION IN SOLUTION - Google Patents

METHOD FOR DETERMINING NITRITE ION IN SOLUTION

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Publication number
RU96115069A
RU96115069A RU96115069/25A RU96115069A RU96115069A RU 96115069 A RU96115069 A RU 96115069A RU 96115069/25 A RU96115069/25 A RU 96115069/25A RU 96115069 A RU96115069 A RU 96115069A RU 96115069 A RU96115069 A RU 96115069A
Authority
RU
Russia
Prior art keywords
solution
iodine
ion
nitrite ion
extraction
Prior art date
Application number
RU96115069/25A
Other languages
Russian (ru)
Other versions
RU2105296C1 (en
Inventor
Г.И. Бебешко
Е.М. Нестерина
Original Assignee
Всероссийский научно-исследовательский институт минерального сырья им.Н.М.Федоровского
Filing date
Publication date
Application filed by Всероссийский научно-исследовательский институт минерального сырья им.Н.М.Федоровского filed Critical Всероссийский научно-исследовательский институт минерального сырья им.Н.М.Федоровского
Priority to RU96115069A priority Critical patent/RU2105296C1/en
Priority claimed from RU96115069A external-priority patent/RU2105296C1/en
Application granted granted Critical
Publication of RU2105296C1 publication Critical patent/RU2105296C1/en
Publication of RU96115069A publication Critical patent/RU96115069A/en

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Claims (5)

1. Способ определения нитрит-иона в растворе, основанный на окислении нитрит-ионом иодид-иона до элементного иода, газовой экстракции и поглощении иода, отличающийся тем, что при окислении создают 25 - 2500-кратный избыток иодид-иона к нитрит-иону и проводят газовую экстракцию в токе инертного газа.1. The method of determining the nitrite ion in solution, based on the oxidation of the iodide ion with the nitrite ion to elemental iodine, gas extraction and iodine absorption, characterized in that during oxidation a 25 - 2500-fold excess of iodide ion to the nitrite ion is created and carry out gas extraction in a stream of inert gas. 2. Способ по п.1, отличающийся тем, что в качестве инертного газа используют азот или аргон. 2. The method according to claim 1, characterized in that nitrogen or argon is used as an inert gas. 3. Способ по п.1, отличающийся тем, что образующийся элементный иод поглощают раствором сульфита натрия. 3. The method according to claim 1, characterized in that the resulting elemental iodine is absorbed by a solution of sodium sulfite. 4. Способ по пп.1 и 3, отличающийся тем, что количество поглощенного иода измеряют с помощью иодидселективного электрода. 4. The method according to claims 1 and 3, characterized in that the amount of absorbed iodine is measured using an iodine-selective electrode. 5. Способ по п.1, отличающийся тем, что для устранения мешающего влияния сульфит-иона на мембрану иодидселективного электрода поглотительный раствор после экстракции иода смешивают в соотношении 1 : 1 с перборатным буферным раствором, содержащим на 1 л 62 г H3BO3, 120 мл 10%-ного раствора NaOH и 170 мл 30%-ного раствора H2O2.5. The method according to claim 1, characterized in that in order to eliminate the interfering effect of the sulfite ion on the membrane of the iodine-selective electrode, the absorption solution after iodine extraction is mixed in a 1: 1 ratio with perborate buffer solution containing 62 g of H 3 BO 3 per 1 liter, 120 ml of a 10% solution of NaOH and 170 ml of a 30% solution of H 2 O 2 .
RU96115069A 1996-07-24 1996-07-24 Method of determining nitrite ion in solution RU2105296C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU96115069A RU2105296C1 (en) 1996-07-24 1996-07-24 Method of determining nitrite ion in solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU96115069A RU2105296C1 (en) 1996-07-24 1996-07-24 Method of determining nitrite ion in solution

Publications (2)

Publication Number Publication Date
RU2105296C1 RU2105296C1 (en) 1998-02-20
RU96115069A true RU96115069A (en) 1998-05-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU96115069A RU2105296C1 (en) 1996-07-24 1996-07-24 Method of determining nitrite ion in solution

Country Status (1)

Country Link
RU (1) RU2105296C1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001069217A2 (en) 2000-03-14 2001-09-20 National Research Council Canada Faims apparatus and method with ion diverting device
FR2838518B1 (en) * 2002-04-12 2004-10-01 Chopin METHOD AND APPARATUS FOR AMPEROMETRY MEASUREMENT OF THE IODY ABSORPTION RATE OF A SUBSTANCE
CN114166904B (en) * 2020-10-30 2023-11-28 中国科学院烟台海岸带研究所 Method for detecting nitrate ions

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