RU95102936A - Method for production of n-(cyclohexylthio)phthalimide
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Method for production of n-(cyclohexylthio)phthalimide
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RU95102936A
RU95102936ARU95102936/04ARU95102936ARU95102936ARU 95102936 ARU95102936 ARU 95102936ARU 95102936/04 ARU95102936/04 ARU 95102936/04ARU 95102936 ARU95102936 ARU 95102936ARU 95102936 ARU95102936 ARU 95102936A
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FIELD: organic chemistry. SUBSTANCE: cyclohexyl chloride is affected by interaction with homogeneous solution of $$$ and sulfur in aqueous medium. The process takes place by boiling, thus obtained dicyclohexyl disulfide is chlorinated in organic solvent. Thus prepared solution of sulfenyl chloride is added to phthalimide dropwise, the process takes place in the presence of alkali, water or alcohol. Said process is preferable to carry out in the presence of quaternary ammonium salt. EFFECT: improved efficiency.
Claims (1)
Предложен способ получения N-(циклогексилтио)фталимида исходя из циклогексилхлорида, который подвергают взаимодействию с гомогенным раствором Na2S и серы в водной среде при температуре кипения, образующийся при этом дициклогексилдисульфид хлорируют в органическом растворителе и полученный при этом раствор сульфенилхлорида прикапывают к фталимиду в присутствии щелочи, вода или спирта. Предпочтительно вести процесс в присутствии четвертичной аммониевой соли.A method is proposed for producing N- (cyclohexylthio) phthalimide starting from cyclohexyl chloride, which is reacted with a homogeneous solution of Na 2 S and sulfur in an aqueous medium at boiling point, the dicyclohexyl disulfide formed in this case is chlorinated in an organic solvent, and the resulting sulfenyl chloride solution is added dropwise to phthalimide in the presence of alkali, water or alcohol. It is preferable to conduct the process in the presence of a quaternary ammonium salt.
RU95102936A1995-03-021995-03-02Method of preparing n-(cyclohexylthio)phthalimide
RU2091372C1
(en)