RU94004970A - COATING APPLICATION METHOD, COATING APPLICATION DEVICE, PAIR APPLICATION DEVICE, SUBSTRATE, COATING COMPOSITION, PAIR-FORMING COATING COMPOSITION - Google Patents

COATING APPLICATION METHOD, COATING APPLICATION DEVICE, PAIR APPLICATION DEVICE, SUBSTRATE, COATING COMPOSITION, PAIR-FORMING COATING COMPOSITION

Info

Publication number
RU94004970A
RU94004970A RU94004970/33A RU94004970A RU94004970A RU 94004970 A RU94004970 A RU 94004970A RU 94004970/33 A RU94004970/33 A RU 94004970/33A RU 94004970 A RU94004970 A RU 94004970A RU 94004970 A RU94004970 A RU 94004970A
Authority
RU
Russia
Prior art keywords
coating
silicon
pair
glass
application device
Prior art date
Application number
RU94004970/33A
Other languages
Russian (ru)
Other versions
RU2138453C1 (en
Inventor
Рузаковски Этей Патриция
Самюэль Досон Дуглас
Эмиль Лекок Дэвид
Эндрю Нойман Джорж
Фрэнк Сопко Джон
Линн Стюарт-Дэвис Ройэнн
Original Assignee
ППГ Индастриз, Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/017,930 external-priority patent/US5356718A/en
Application filed by ППГ Индастриз, Инк. filed Critical ППГ Индастриз, Инк.
Publication of RU94004970A publication Critical patent/RU94004970A/en
Application granted granted Critical
Publication of RU2138453C1 publication Critical patent/RU2138453C1/en

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Claims (1)

Устройство для нанесения покрытия на стеклянную ленту содержит отводящий элемент с каждой стороны элемента нанесения покрытия, удаленный от него на разное расстояние. При таком расположении части ленты, находящиеся вверху и внизу относительно элемента нанесения покрытия, подвергаются воздействию паров покрытия из элемента нанесения покрытия в течение разного времени. Смесь состава покрытия включает оловосодержащий и кремнийсодержащий прекурсоры. Кремнийсодержащий прекурсор имеет структурную общую формулу
Figure 00000001

где R1 - группа, которая не содержит кислород, способный образовать перекись; R2 - функциональная группа, придающая кремний-содержащему прекурсору способность легко проникать в покрытие из окиси кремния; R3 - мостиковая группа для образования множества атомов кремния; R4 - завершает связь на основном атоме кремния. Ускоритель, например фосфорсодержащий прекурсор, может использоваться наряду с металлсодержащими прекурсорами для повышения скорости осаждения покрытия. Покрытие, осажденное на стекло, состоит из районов постоянно изменяющегося содержания окиси кремния и окиси олова по мере удаления от поверхности раздела стекла и покрытия, причем поверхность покрытия, максимально удаленная от этой поверхности раздела, содержит преимущественно окись олова. Составляющие покрытие районы имеют разные показатели преломления, что исключает переливчатость за счет увеличения толщины окиси олова на внешней поверхности покрытия и придает стеклянному изделию с таким покрытием нейтральный цвет. При использовании фосфора в качестве ускорителя процент кристалличности уменьшается, приближаясь к О и снижая таким образом или полностью исключая впечатление дымчатости.A device for applying a coating to a glass ribbon contains a diverting element on each side of the coating element that is spaced at a different distance from it. With this arrangement, the parts of the tape that are at the top and bottom of the coating element are exposed to the vapor of the coating from the coating element for different times. The mixture of the coating composition includes tin-containing and silicon-containing precursors. Silicon precursor has a structural general formula
Figure 00000001

where R 1 is a group that does not contain oxygen, capable of forming a peroxide; R 2 - a functional group that gives the silicon-containing precursor the ability to easily penetrate into the coating of silicon oxide; R 3 is a bridging group for the formation of many silicon atoms; R 4 - completes the bond on the main silicon atom. An accelerator, for example a phosphorus-containing precursor, can be used along with metal-containing precursors to increase the deposition rate of the coating. The coating deposited on the glass consists of areas of constantly changing content of silicon oxide and tin oxide as they move away from the interface of the glass and coating, and the surface of the coating that is as far as possible from this interface contains mostly tin oxide. Covering areas have different refractive indices, which excludes iridescence by increasing the thickness of tin oxide on the outer surface of the coating and gives the glass product with such a coating a neutral color. When using phosphorus as an accelerator, the percentage of crystallinity decreases, approaching O and thus reducing or completely eliminating the appearance of haze.
RU94004970A 1993-02-16 1994-02-14 Method of applying coatings, substrate (versions), and vaporous coating composition RU2138453C1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/017,930 US5356718A (en) 1993-02-16 1993-02-16 Coating apparatus, method of coating glass, compounds and compositions for coating glasss and coated glass substrates
US08/017930 1993-02-16
US08/017,930 1993-02-16

Publications (2)

Publication Number Publication Date
RU94004970A true RU94004970A (en) 1995-12-10
RU2138453C1 RU2138453C1 (en) 1999-09-27

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU94004970A RU2138453C1 (en) 1993-02-16 1994-02-14 Method of applying coatings, substrate (versions), and vaporous coating composition

Country Status (18)

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US (2) US5356718A (en)
EP (2) EP1092688A1 (en)
JP (2) JP3058792B2 (en)
KR (1) KR970001212B1 (en)
CN (2) CN1089320C (en)
AT (1) ATE243173T1 (en)
AU (1) AU672853B2 (en)
CA (1) CA2114971C (en)
DE (1) DE69432827T2 (en)
DK (1) DK0611733T3 (en)
ES (1) ES2201065T3 (en)
FI (2) FI113759B (en)
MX (1) MX9401182A (en)
NZ (4) NZ328148A (en)
PT (1) PT101462B (en)
RU (1) RU2138453C1 (en)
TW (1) TW325457B (en)
ZA (1) ZA94790B (en)

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